共查询到20条相似文献,搜索用时 15 毫秒
1.
?brahim Uslu Tuncay Tun? 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(1):183-189
In this study, polyvinyl alcohol (PVA) and boric acid (BA) were mixed in an aqueous medium by heating in order to prepare
a PVA/BA hybrid material. The viscosity and pH values of the PVA/BA hybrid material mixed in various proportions were determined.
Then the hybrid polymer was electrospun to give dimensions to fibers. The FT-IR spectra of these fibers revealed that BA chemically
reacted with PVA and formed B–O–C bonds. The fibers were first calcified at 500 °C and then the calcified products were pelleted
and exposed to the sintering process at 1300 °C. The XRD peaks of the sintered product were seen at 2θ = 34.7 and 37.7° verified
the formation of boron carbide. The study proved that it was possible to use sub-micron fibers for the production of sub-micron
boron carbide material. 相似文献
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Jinho Kim Toshio Kimura Takashi Yamaguchi 《Journal of the American Ceramic Society》1989,72(8):1390-1395
The phase change, densification, and microstructure development of ZnO doped with both Bi2 O3 and Sb2 O3 are studied to better understand the sintering behavior of ZnO varistors. The densification behavior is related to the formation of pyrochlore and liquid phases; the densification is retarded by the former and promoted by the latter. The pyrochlore phase, whose composition is Bi3/2 ZnSb3/2 O7 , appears below 700°C. The formation temperature of the liquid phase depends on the Sb/Bi ratio: about 750°C for Sb/Bi < 1 by the eutectic melting in the system ZnO—Bi2 O3 , and about 1000°C for Sb/Bi > 1 by the reaction of the pyrochlore phase with ZnO. Hence, the densification rate is determined virtually by the Sb/Bi ratio and not by the total amount of additives. The microstructure depends on the sintering temperature. Sintering at 1000°C forms intragrain pyrochlore particles in ZnO grains as well as intergranular layers, but the intragrain particles disappear at 1200°C by the increased amount of liquid phase, which enhances the mobility of the solid second phase. 相似文献
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An Yang Xiaoming Tao Geoffrey Kin Hung Pang Kenneth Guei Gu Siu 《Journal of the American Ceramic Society》2008,91(1):257-262
The electrospinning method is adopted to prepare utralong PEO/stannic hydroxide composite nanofibers. Tin-oxide nanobelts can be obtained by calcination of the composite nanofibers in an open atmosphere. The nanobelts were characterized by a field emission scanning electron microscope, X-ray diffraction, a transmission electron microscope, a Raman spectromicroscope, and Fourier transform infrared spectroscopy. Microstructural analysis has shown that the nanobelts prepared consist of a continuous network of interconnected SnO2 grains. As a result, the SnO2 nanobelts possess a high surface area and continuous porosity, which may be applied for the fabrication of sensitive gas sensors. 相似文献
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Maria Teresa Malachevsky Jorge Eduardo Fiscina Daniel Antonio Esparza 《Journal of the American Ceramic Society》2001,84(7):1575-1577
A comparative study of the solid-state reaction synthesis of cordierite with and without the use of a flux was performed, varying the sintering temperatures between 900° and 1400°C. Bi2 O3 proved to be a useful additive for lowering the temperature needed for the reaction to take place. The deviation from the ordered β-cordierite phase was analyzed using the distortion index Δ as a factor of merit. The values obtained for Δ in all compositions showed that cordierite tended to a much-ordered structure with increased sintering temperatures. 相似文献
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Ryan W. Dupon Richard L. McConville Douglas J. Musolf Adam C. Tanous Mark S. Thompson 《Journal of the American Ceramic Society》1990,73(2):335-339
Bismuth oxide has been found to be a useful flux for the preparation of dense body cordierite (Mg2 Al4 Si5 O18 ). The addition of as little as 2 at.% of bismuth ion to the appropriate stoichiometric mix of commercially available oxide starting materials gives fully dense cordierite after firing for 12 h at 1000°C. The lower-temperature limit for this reaction is 960°C, with essentially no reaction occurring below this temperature. There is also a temperature-dependent induction period prior to cordierite formation. The microstructure of the sintered body has the residual bismuth oxide flux distributed in discontinuous domains at the grain boundaries and at the triple points. The cordierite body has a dielectric constant of 5.0, unperturbed by the presence of the bismuth oxide. 相似文献
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Ultra-thin fibers of zinc oxide (ZnO) were prepared by sol–gel processing and the electrospinning technique using poly(vinyl acetate) and zinc acetate as precursors. The fibers were characterized by thermogravimetric analysis, scanning electron microscopy, Fourier-transfer infrared, and X-ray diffraction, respectively. The results showed that the diameter of the precursor fibers increased with increasing zinc acetate content, and the size of the inorganic ZnO nanofibers decreased obviously as the calcining time increased. 相似文献
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Yiquan Wu Larry L. Hench Jing Du Kwang-Leong Choy Jingkun Guo 《Journal of the American Ceramic Society》2004,87(10):1988-1991
Hydroxyapatite (Ca10 (PO4 )6 (OH)2 , HA) fibers were prepared by electrospinning a precursor mixture of Ca(NO3 )2 ·4H2 O and (C2 H5 O)3 PO with a polymer additive, followed by a thermal treatment. The X-ray diffraction (XRD) analysis of the annealed composite fibers revealed that pure HA phase could be obtained by annealing at 600°C for 1 h. The scanning electron microscopy (SEM) analysis showed the surface of as-electrospun composite fibers with an average diameter of 50 μm was smooth due to the amorphous nature of the polymer. However, the surface of the calcined HA fibers was rough because of the complete removal of the polymer. The pure HA fibers obtained by electrospinning in this work were up to 10 mm in length and 10–30 μm in diameter and the hydroxyapatite grain size was ∼1 μm in the HA fibers. 相似文献
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固体氧化物燃料电池(SOFC)是一种可以将燃料中的化学能直接转化为电能的发电装置,具有燃料选择灵活、效率高、环境友好等优点。基于SOFC运行成本和长期稳定性的要求,降低工作温度已成为当前研究的热点。传统阴极较低的催化活性制约了SOFC的技术发展,因此开发具有良好催化性能的阴极材料至关重要。大量的研究表明,铋离子的掺杂能够有效提高材料的电导率和氧催化活性。从铋离子掺杂的角度出发,综述了铋离子掺杂对阴极材料的制备、结构、电导率和电化学性能的影响,并对掺铋SOFC阴极材料未来的发展趋势进行了展望。 相似文献
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采用静电纺丝技术制备了PVP/[La(NO3)3+Al(NO3)3]复合纳米纤维,经过800 ℃焙烧8 h热处理后成功制备出大量的LaAlO3 纳米纤维.采用XRD、SEM、EDS、TEM、SAED、FTIR等测试技术对样品进行了系统地表征.结果表明,PVP/[La(NO3)3+Al(NO3)3]复合纳米纤维为非晶态,所制备的LaAlO3 纳米纤维为菱形晶系,空间群为R3m.PVP/[La(NO3)3+Al(NO3)3]复合纳米纤维表面光滑,平均直径约为180 nm;LaAlO3 纳米纤维的平均直径为80 nm,长度大于300 μm.LaAlO3 纳米纤维由纳米粒子构成,纳米粒子平均直径为15 nm,为多晶结构.对LaAlO3 纳米纤维的形成机理进行了讨论. 相似文献
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SUMIO SAKKA 《Journal of the American Ceramic Society》1969,52(2):69-73
Calcium, strontium, and barium tungstates and their solid solutions, doped with a small amount of bismuth, color remarkably on exposure to ultraviolet light and return to the original white by thermal fading or optical bleaching. The factors affecting the darkening and fading processes were studied experimentally. Under the same irradiation conditions the intensity of uv-induced coloration depended on the Bi content and preparation temperature of the tungstates. Bi contents higher than 0.1 molyo and preparation temperatures higher than 1250°C gave strong coloration. The rate of fading of uv-induced color increased with increasing Bi content. The fading was accelerated by heating; almost all the uv-induced color disappeared at 230°C in 30 min. The fading rate was also increased by visible light exposure. The uv-induced absorption spectra varied systematically with the composition of the tungstates. 相似文献
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综述了掺铝氧化锌薄膜的各种制备方法,包括磁控溅射法、脉冲激光法和溶胶凝胶法等;重点分析了掺铝氧化锌(ZAO)薄膜的结构、导电机理及光电性能;最后对薄膜的存在问题和应用情况进行了分析。 相似文献
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通过水热法合成纯WO3,并采用原位水热合成的方法制备不同碳纳米管掺杂量(0.2%,0.4%,0.6%,0.8%,1.0%)WO3/CNTS复合材料。复合之前,从四种纯WO3(K2SO4为添加的矿化剂且含量依次为15 g、30 g、40 g、0 g)中选取一种气敏性能最好的合成工艺。结果表明无K2SO4的合成工艺较好,同时对四种纯WO3进行了XRD表征,结果显示无K2SO4的氧化钨为两相晶体,且粒径较小。纯WO3与S-WCNTS掺杂制备复合材料,然后由复合材料制备气敏元件,对H2S进行气敏测试,结果表明S-WCNTS含量为0.6%的复合材料效果最佳,恢复性好且工作电压较低,可达2.68 V,且检出限可达到3 mg/kg,连续曲线的测定也较好。 相似文献
17.
Nam seok. Baik Go Sakai Norio Miura Noboru Yamazoe 《Journal of the American Ceramic Society》2000,83(12):2983-2987
Stable colloidal suspensions of tin oxide (content 0.9–6.1 wt%) were synthesized by subjecting conventionally prepared tin oxide gels to hydrothermal treatment with an ammonia solution (pH 10.5) at 200°C for 3 h in an autoclave. Based on X-ray diffractometry analyses, the tin oxide crystallites after hydrothermal treatment were resistant to thermal growth at elevated temperatures, and this feature became more conspicuous as the tin oxide content of the colloidal suspension decreased. For the powder derived from a 1.8 wt% colloidal suspension, for example, the mean sizes of the tin oxide crystallites were 7.5 and 13 nm after calcination at 600° and 900°C, respectively, in comparison with corresponding values of 13.5 and 29 nm for the untreated gel-derived powder. Thin film spin-coated from the same suspension had good uniformity, packed with tin oxide grains (crystallites) of a mean size of 6 nm after calcination at 600°C. Optical determination of the tin oxide sol particle size, as well as gravimetric analysis of the dehydration from the powder samples, were conducted to determine effects of hydrothermal treatment. 相似文献
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