共查询到19条相似文献,搜索用时 78 毫秒
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聚苯胺是一种非常有前途的导电聚合物。掺杂能提高聚苯胺的导电性、稳定性及其他性能,聚苯胺的掺杂受到了人们的广泛关注,尤其是有机酸的掺杂。有机酸种类众多且性能各异,能够使聚苯胺很多性质发生变化。本文重点综述了分别以单一有机酸、有机酸和金属氧化物、有机酸和无机酸、有机酸和其他无机物为掺杂剂合成聚苯胺的研究现状,详细介绍了各种掺杂态聚苯胺的性能及应用,简要介绍了影响聚苯胺性能的因素,并比较了不同掺杂态聚苯胺的优缺点。分析结果表明:与单一有机酸掺杂的聚苯胺相比,采用两种类型的掺杂剂共掺杂合成的聚苯胺具有更突出的性能及更大的应用前景。提出了采用两种或两种以上不同类型的掺杂剂共掺杂将是聚苯胺今后的主要研究方向。 相似文献
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导电高分子聚苯胺的合成及应用 总被引:10,自引:0,他引:10
聚苯胺(PANI)是研究最为广泛的导电高分子材料之一。综述了聚苯胺的结构、特性及几种合成聚苯胺的方法,介绍了聚苯胺的掺杂方法及聚苯胺的应用前景。 相似文献
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导电聚合物聚苯胺的化学合成 总被引:3,自引:0,他引:3
研究了导电聚苯胺化学合成的工艺条件及碳粉添加剂对聚笨胺产率及电导率的影响。用红外光谱及XPS分析确定了化学合成聚笨胺的组成及结构为1/2氧化态的聚苯胺盐,它具有与电化学合成聚苯胺相同的结构和良好的电导率。 相似文献
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为了促进聚苯胺在工业领域中的进一步应用,必须要解决聚苯胺难以溶于水的这一基本性质。文章通过合成一种聚苯胺的衍生物有效的解决了这一问题,该衍生物不仅具备聚苯胺的基本性能,同时还能有效溶于水,可以进一步促进聚苯胺的应用。 相似文献
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Removal of phenols from the aqueous solutions based on their electrochemical polymerization on the polyaniline electrode 总被引:1,自引:0,他引:1
Ya Zhang 《Electrochimica acta》2010,55(24):7219-7224
Phenol and 3-nitrophenol in a aqueous solution of NaCl with pH 4.0 can be polymerized on the polyaniline electrode to form polyaniline/polyphenol and polyaniline/poly(3-nitrophenol) composites, respectively, using potential cycling between −0.20 and 1.00 V (vs. SCE). Polyaniline played an important role in lowering passivation of the electrode, which made the consecutive electrochemical polymerization of phenol and 3-nitrophenol become possible. The growth of the polyaniline/polyphenol and polyaniline/poly(3-nitrophenol) films in the electrolytic process was proved by the increasing area of the cyclic voltammograms as the electrolysis proceeded. The SEM images and IR spectra of polyaniline and phenolic polymers demonstrated the formation of the phenolic polymers on the polyaniline electrode. Therefore, the removal of both phenolic compounds is based on the formation of their polymers on the polyaniline film. 相似文献
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ZnO–polyaniline nanocomposite with core–shell nanostructure was prepared by in situ polymerization of aniline monomer in the presence of ZnO nanoparticles. Fourier transform infrared spectroscopy, X-ray diffraction patterns, field emission scanning electron microscopy and transmission electron microscopy techniques were used to characterize the composition and structure of ZnO–polyaniline nanocomposite. d.c. electrical conductivity measurement showed that the electrical conductivity of ZnO–polyaniline nanocomposite pellets is higher than that of pristine polyaniline and ZnO nanoparticles pellets. The addition of ZnO nanoparticles causes to the increasing of polyaniline electrical conductivity. ZnO–polyaniline nanocomposite was mixed with polyvinyl chloride (PVC) through a solution mixing method and the three components PVC/ZnO–polyaniline hybrid material was applied as coating on iron coupon by the solution casting method. Corrosion protection efficiency of PVC/ZnO–polyaniline hybrid coating on iron coupons was studied by open circuit potential and Tafel techniques in 3.5% NaCl solution as corrosive environment. According to the results, PVC/ZnO–polyaniline hybrid nanocomposite coating showed dramatically increased corrosion protection effect on iron samples compared to that of uncoated iron coupon and pure polyaniline anticorrosive coating. It was found that ZnO nanoparticles improve the barrier and electrochemical anticorrosive properties of polyaniline and the addition of polyvinyl chloride increases the barrier effect of polyaniline coating. 相似文献
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Anil Kumar 《Polymer-Plastics Technology and Engineering》2018,57(2):70-97
Synthesis of polyaniline and hybrid carbon nanotube reinforced polyaniline nanocomposites by various methods has discussed in this review. Different routes used for functionalization of carbon nanotube have been reported. The electrical, mechanical, and thermal properties of polyaniline/carbon nanotube nanocomposites are also discussed. The dispersion of functionalized carbon nanotube, filler concentration, and their alignment in the interior of polyaniline matrix affect their morphology. Furthermore, article focussed upon the various morphologies of polyaniline and polyaniline/carbon nanotube nanocomposites obtained with different methods along with electrical conductivity. Possible applications of polyaniline/carbon nanotube nanocomposites in the areas of actuators, sensors, electromagnetic interference shielding have also discussed. 相似文献
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以十二烷基苯磺酸(DBSA)作为掺杂酸合成掺杂态聚苯胺,并以掺杂态聚苯胺和特导炭黑做为导电填料,线性低密度聚乙烯(LLDPE)为基体,乙烯-乙酸乙烯酯(EVA)作为增塑剂,掺杂态聚苯胺和特导炭黑作为导电填料,制备导电塑料。使用四探针法测定了掺杂态聚苯胺和导电塑料的电导率,使用扫描电子显微镜、X射线衍射、红外光谱法、热重法对掺杂态聚苯胺进行分析和表征,并且测试了导电塑料的力学性能和流动性能。研究表明:掺杂态聚苯胺具有良好的导电性能,可以作为导电塑料的导电填料使用;并且使用掺杂态聚苯胺和特导炭黑作为导电填料制备的导电塑料比单独使用掺杂态聚苯胺具有更好的导电性能,力学性能。 相似文献
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十二烷基苯磺酸掺杂聚苯胺的性能研究 总被引:7,自引:1,他引:7
用十二烷基苯磺酸 (DBSA)对本征态聚苯胺 (PAn)进行掺杂 ,得到溶解性、成膜性和光电性能俱佳的掺杂态聚苯胺。红外光谱研究表明 :DBSA掺杂PAn的吸收峰都向低频方向移动。探讨DBSA浓度、掺杂温度和时间以及洗涤滤液pH值对聚苯胺电导率的影响。结果表明 :当c(DBSA) =1 0mol/L ,T =32 3K ,t=8h ,洗涤滤液 pH =3时 ,聚苯胺的电导率为 0 90 9S/cm。紫外 -可见吸收光谱表明 ,掺杂态聚苯胺的吸收峰变宽而且发生红移。X射线衍射在 2θ =8 86°,1 7 7° ,2 1 4°和 2 6 7°处出现 4个较强的低角度衍射峰 ,表明DBSA掺杂的聚苯胺具有较强的结晶性能。 相似文献