压缩天然气在乘用车上的应用

压缩天然气(CNG)是一种可替代汽油、柴油、丙烷或液化石油气的化石燃料。虽然它的燃烧会产生温室气体,但比其它燃料对环境的污染小得多,而且比其他燃料更安全,天然气比空气轻,泄露后很快发散在空气中。CNG通过压缩天然气(主要成分是甲烷[CH4])获得,常压下其体积仅占不足空气的1%,因此需要加压储存在20～25 MPa圆筒形或球形的压力容器中。CNG可以在传统的汽油机车辆的基础上改装,成为汽油、CNG双燃料车。由于汽油价格上涨,天然气车辆已经逐渐在亚太区域、拉丁美洲、欧洲和美国应用。受高燃料价格和环境要求的影响,CNG正在出租车和公交车上逐渐推广应用。     

A review of hydrogen usage in internal combustion engines (gasoline-Lpg-diesel) from combustion performance aspect

Demand for fossil fuels is increasing day by day with the increase in industrialization and energy demand in the world. For this reason, many countries are looking for alternative energy sources against this increasing energy demand. Hydrogen is an alternative fuel with high efficiency and superior properties. The development of hydrogen-powered vehicles in the transport sector is expected to reduce fuel consumption and air pollution from exhaust emissions. In this study, the use of hydrogen as a fuel in vehicles and the current experimental studies in the literature are examined and the results of using hydrogen as an additional fuel are investigated. The effects of hydrogen usage on engine performance and exhaust emissions as an additional fuel to internal combustion gasoline, diesel and LPG engines are explained. Depending on the amount of hydrogen added to the fuel system, the engine power and torque are increased at most on petrol engines, while they are decreased on LPG and diesel engines. In terms of chemical products, the emissions of harmful exhaust gases in gasoline and LPG engines are reduced, while some diesel engines increase nitrogen oxide levels. In addition, it is understood that there will be a positive effect on the environment, due to hydrogen usage in all engine types.     

Effects of consumer subsidy on household fuel switching from coal to cleaner fuels: A case study for anthracites in Korea

The Korean coal industry is in a transition under low carbon policy through the steady reduction of coal production. Since consumer subsidy for the consumption of anthracites briquette in low-income households caused a distortion in domestic coal market, the so-called coupon program will be the first target in energy reform policy in order to induce fuel switching from anthracites to alternative clean energy. This paper tries to identify various factors that influence households' fuel switching decision. Disutility from briquette consumption is also considered as an important factor. Using the 2007 census data on briquette-consuming households, it is found that the coupon program provides an adverse effect to switching fuels to clean energy while the disutility of briquettes is positively associated with the probability of fuel switching. However, the empirical finding suggests that the policy alone attempting to remove coupon program may fail to switch fuels unless the cost of boiler changes is substantially reduced through the provision of accessible networks to alternative energy sources. It indicates that reform policy for consumer subsidy must be understood in line with more comprehensive regional energy plans to resolve energy poverty issue.     

Review of NOx reduction technologies in CI engines fuelled with oxygenated biomass fuels

Oxygenated fuels like biodiesel and alcohols have the potential to provide a reliable and a cost effective alternative to India's increasing future energy demands. They have a prospective future since they are renewable and can be produced easily in India's rural areas. Due to rapid industrialization and the increased number of vehicles on the road, the energy needs of the country are increasing rapidly. Oxygenated fuels can substantially replace the large demand for diesel to generate power for the industries and to fuel diesel engines of the vehicles. In spite of the many advantages of using them, most of the researchers have reported higher NO_x emissions, which is a deterrent to the market expansion of these fuels. The present program aims to review the NO_x emissions from the CI engines fuelled with oxygenated fuels. To meet the stringent emission norms, the various NO_x reduction technologies like use of additives, retarded fuel injection timing, biodiesel emulsion with water, and exhaust gas recirculation are reviewed. The results of the most effective and low cost technique of EGR in DI diesel engine fuelled with biodiesel–diesel blends and tri-compound oxygenated diesel fuel blends (ethanol–biodiesel–diesel fuel blends and methanol–biodiesel–diesel fuel blends) are presented.     

Sulfur content of gasoline and diesel fuels in northern China

In order to investigate vehicle fuel quality in northern China, the sulfur content of fuels purchased from the market has been studied. 235 samples from urban areas and highway service stations were collected and tested with energy dispersive X-ray fluorescence spectrometry. 88% of the gasoline samples contained sulfur below 500 ppm, the limit then in effect, and 92.5% of the diesel fuel samples were below 2000 ppm, the required limit. China's Ministry of Environmental Protection recommend lower sulfur to assure that the vehicles using the fuels comply with the China III emission standards—those limits are 150 ppm sulfur for gasoline and 350 ppm for diesel fuel. The recommended limits were not often met: in Jinan, Shanghai, Changchun and Xi'an, 0%, 11%, 46% and 60% of the gasoline sampled were below 150 ppm sulfur. For samples from highway stations, only 14–58% of gasoline was under the 150 ppm sulfur and only 0–67% of diesel samples below 350 ppm in different regions. This mismatch, between fuel sulfur levels that would enable vehicle emission controls to operate effectively, and the actual fuel sulfur levels at service stations, results in unnecessarily high pollution from potentially cleaner vehicles.     

Performance, emission and economic assessment of clove stem oil–diesel blended fuels as alternative fuels for diesel engines

In this study the performance, emission and economic evaluation of using the clove stem oil (CSO)–diesel blended fuels as alternative fuels for diesel engine have been carried out. Experiments were performed to evaluate the impact of the CSO–diesel blended fuels on the engine performance and emissions. The societal life cycle cost (LCC) was chosen as an important indicator for comparing alternative fuel operating modes. The LCC using the pure diesel fuel, 25% CSO and 50% CSO–diesel blended fuels in diesel engine are analysed. These costs include the vehicle first cost, fuel cost and exhaust emissions cost. A complete macroeconomic assessment of the effect of introducing the CSO–diesel blended fuels to the diesel engine is not included in the study. Engine tests show that performance parameters of the CSO–diesel blended fuels do not differ greatly from those of the pure diesel fuel. Slight power losses, combined with an increase in fuel consumption, were experienced with the CSO–diesel blended fuels. This is due to the low heating value of the CSO–diesel blended fuels. Emissions of CO and HC are low for the CSO–diesel blended fuels. NO_x emissions were increased remarkably when the engine was fuelled with the 50% CSO–diesel blended fuel operation mode. A remarkable reduction in the exhaust smoke emissions can be achieved when operating on the CSO–diesel blended fuels. Based on the LCC analysis, the CSO–diesel blended fuels would not be competitive with the pure diesel fuel, even though the environmental impact of emission is valued monetarily. This is due to the high price of the CSO.     

浅谈汽车发动机燃料(二)

较为详细地介绍了汽车发动机常规燃料——汽油、柴油，代用燃料——液化石油气和压缩天然气，醇类燃料和氢气等的理化性质、排放特点、优缺点和使用时应解决的问题。     

浅谈汽车发动机燃料(一)

较为详细地介绍了汽车发动机常规燃料——汽油、柴油，代用燃料——液化石油气和压缩天然气；醇类燃料和氢气等的理化性质、排放特点、优缺点和使用时应解决的问题。     

Thermodynamic analysis of fossil fuels reforming for fuel cell application

At present, the infrastructure of hydrogen production, storage and transportation is poor. Fuel reforming for hydrogen production from liquid fossil fuels such as kerosene, petrol and diesel is of great significance for wide application of on-board fuel cell and distributed energy resources. In this work, the produced and heat released of kerosene, petrol and diesel reformed by different reforming methods (autothermal reforming, partial oxidation, steam reforming) were studied by means of thermodynamic analysis. Based on the thermodynamic analysis, the effect of reforming methods on the system's ideal thermal efficiency are analysed. The results show that the hydrogen concentration of syngas obtained from steam reforming is highest regardless of the fuel types. The hydrogen yielded by per unit volume of diesel is largest under same reforming method. Autothermal reforming has the largest ideal thermal efficiency among three reforming methods.     

Energy for sustainable road transportation in China: Challenges,initiatives and policy implications

This paper presents an overview of the initiatives launched in energy supply and consumption and the challenges encountered in sustainable road transportation development in China. It analyzes the main energy challenges related to road transportation development arising in the context of economic development, rapid urbanization, and improvement in living standards. It also discusses technological- and policy initiatives needed to deal with these challenges, drawing comparisons with foreign experience: promoting the development and dissemination of alternative fuels and clean vehicles such as: LPG, CNG, EV, HEV, FCV, ethanol, methanol, DME, bio-diesel, and CTL, strengthening regulations relating to vehicle fuel economy and emission, improving traffic efficiency and facilitating public transport development, and strengthening management of the soaring motor vehicle population. If the current pattern continues, by the year 2030, the vehicle population in China will be 400 million and fuel demand will be 350 million tons. The potential energy saving capacity being 60%, the actual oil demand by 2030 from on-road vehicles might technically be kept at the current level by improving fuel economy, propagating use of HEV and diesel vehicles, improving supply of alternative fuels, and developing public transport. Several uncertainties are identified that could greatly influence the effect of the technical proposals: traffic efficiency, central government's resolve, and consumers' choice.     

Analysis of ignition delay period of a dual fuel diesel engine with hydrogen and LPG as secondary fuels

In this study, experiments were performed on 4 cylinder turbocharged, intercooled with 62.5 kW gen-set diesel engine by using hydrogen, liquefied petroleum gas (LPG) and mixture of LPG and hydrogen as secondary fuels. The experiments were performed to measure ignition delay period at different load conditions and various diesel substitutions. The experimental results have been compared with ignition delay correlation laid down by other researchers for diesel and dual fuel diesel engine. It is found that ignition delay equation based on pressure, temperature and oxygen concentration for a dual fuel diesel engine run on diesel-biogas gives variation up to 6.56% and 14.6% from the present experimental results, while ignition delay equation for a pure diesel engine gives 7.55% and 33.3% variation at lower and higher gaseous fuel concentrations, respectively. It is observed that the ignition delay of dual fuel engine depends not only on the type of gaseous fuels and their concentrations but also on charge temperature, pressure and oxygen concentration.     

Transient simulation and techno-economic assessment of a near-zero energy building using a hydrogen storage system and different backup fuels

Proposing a cost-effective off-grid Hybrid Renewable Energy System (HRES) with hydrogen energy storage with a minimum CO2 emission is the main objective of the current study. The electricity demand of an office building is considered to be supplied by Photovoltaic Panels and wind turbines. The office building, modeled in Energy Plus and Open studio, has annual electricity consumption of 500 MWh electricity. 48.9% of the required electricity can be generated via renewable resources. Considering a system without energy storage, the remaining amount of electricity is generated from diesel generators. Hence, for reducing CO2 emission and fuel costs, a hydrogen energy storage system (ESS) is integrated into the system. Hydrogen ESS is responsible for supplying 38.6% of the demand electricity, which means that it can increase the energy supplying ability of the system from 48.9% to 87.5%. In addition to analyzing the application of the hydrogen storage system, the effect of four different kinds of fuel is considered as well. effects of Natural gas, Diesel, Propane, and LPG on the system's application are investigated in this study. Results indicate that natural gas emits less amount of CO2 compared to other fuels and also has a fuel cost of 3054 $/year, while hydrogen ESS is available. For the renewable system without ESS, the fuel cost rises to 10,266 $/year. However, liquid gas, Propane, and LPG have better performance in terms of CO2 emission and fuel cost, respectively.     

Comparative study of regulated and unregulated gaseous emissions during NEDC in a light-duty diesel engine fuelled with Fischer Tropsch and biodiesel fuels

In this study, regulated and unregulated gaseous emissions and fuel consumption with five different fuels were tested in a 4-cylinder, light-duty diesel EURO IV typically used for the automotive vehicles in Europe. Three different biodiesel fuels obtained from soybean oil, rapeseed oil and palm oil, a Fischer Tropsch fuel and an ultra low sulphur diesel were studied. The test used was the New European Driving Cycle (NEDC), this allowed tests to be carried out on an engine warmed up beforehand to avoid the effect of cold starts and several tests a day. Regulated emissions of NO_X, CO, HC and CO₂ were measured for each fuel. Unburned Hydrocarbon Speciation and formaldehyde were also measured in order to determine the maximum incremental reactivity (MIR) of the gaseous emissions. Pollutants were measured without the diesel oxidation catalyst (DOC) to gather data about raw emissions. When biodiesel was used, increases in regulated and unregulated emissions were observed and also significant increases in engine fuel consumption. The use of Fischer Tropsch fuel, however, caused lower regulated and unregulated emissions and fuel consumption than diesel.     

Synthetic fuels and combustion

As the supply of hydrocarbons for transportation fuels includes an increasing proportion of low hydrogen-to-carbon ratio sources, such as coal, the cost and waste of energy of converting these materials to the high hydrogen-to-carbon ratio fuels now required by land and air propulsion systems will increase. In the extreme, where coal is the major source of liquid fuel, elimination of restrictions on aromatics content (H/C ratio) could reduce refining energy cost by as much as 20% of the heat of combustion of the syncrude being processed. Refining costs are approximately proportional to refining energy consumption, and an energy saving of this magnitude would reduce the total cost of refined products by one-third. For a syncrude product cost of 30 $/bbl, this would be a cost saving of 25 ¢/gal. of product.Such a large conservation and economic driving force provides a powerful incentive for choice of power plants capable of burning fuels of low hydrogen-to-carbon ratio in a clean and environmentally acceptable manner.The main combustion problem is the increasing difficulty of avoiding the emission of soot, and the relative ability of power plants to completely burn out the soot formed in the early stages of combustion will be an important selection criterion.In automotive systems, the combustion problems appear much more easily solved for the Stirling cycle and the gas turbine because of the steady flow conditions and the potentially longer time that can be provided for soot burnout. The liquid injection Diesel and stratified charge engines are at a disadvantage in this regard and may not be able to compete successfully with the Otto cycle engine, for which aromatics offer an improvement in efficiency because of their high octane number. Improvement in the ability of aircraft engines to burn highly aromatic, wide boiling range fuels offers the possibility of advances in economics and fuel conservation in air transportation.Fortunately, there is every indication that combustion research and development can be expected to eliminate the need for high levels of hydrogenation and boiling range conversion in fuels manufacture. Much more research is needed in the chemistry of soot formation and burnout, and the mechanics of reactive flows involving high molecular weight liquids and vapors and soot, for the complex systems of practical interest. In development programs, highly aromatic fuels should be used even though the economic and conservation driving force for fuel specification changes might appear well into the future. While the examples and numbers used in this discussion are based on an extreme that is indeed well into the next century, the trend toward lower hydrogen-to-carbon ratio feed stocks is already underway, and it is timely to begin moving toward less energy intensive fuels manufacture in addition to working on more thermodynamically efficient propulsion machinery.     

Preparation,characterization, engine combustion and emission characteristics of rapeseed oil based hybrid fuels

In this study, hybrid fuels consisting of rapeseed oil/diesel blend, 1% aqueous ethanol and a surfactant (oleic acid/1-butanol mixture) were prepared and tested as a fuel in a direct injection (DI) diesel engine. The main fuel properties such as the density, viscosity and lower heating value (LHV) of these fuels were measured, and the engine performance, combustion and exhaust emissions were investigated and compared with that of diesel fuel. The experimental results showed that the viscosity and density of the hybrid fuels were decreased and close to that of diesel fuel with the increase of ethanol volume fraction up to 30%. The start of combustion was later than that of diesel fuel and the peak cylinder pressure, peak pressure rise rate and peak heat release rate were higher than those of diesel fuel. The brake specific fuel consumption (BSFC) of hybrid fuels was increased with the volume fraction of ethanol and higher than that of diesel. The brake specific energy consumption (BSEC) was almost identical for all test fuels. The smoke emissions were lower than those for diesel fuel at high engine loads, the NO_x emissions were almost similar to those of diesel fuel, but CO and HC emissions were higher, especially at low engine loads.     

适合柴油—甲醇—水复合乳化的新型乳化剂研究

介绍了一种适合于柴油-甲醇-水复合乳化的高分子乳化剂的制取方法,对该种乳化剂的乳化过程进行了机理和试验研究,试验结果表明,用该种乳化剂配制的乳液稳定时间长,而乳化剂的用量比较低。探讨了用CR-2型乳化装置配制柴油-甲醇-水复合乳液的工艺,并在柴油机试验台架上考察了用该种乳化剂配制的乳液的适应性。     

Status,challenges and opportunities of dual fuel hybrid approaches-a review

Consumers conventionally adopt diesel generation to meet the energy needs where the grid connection is unreliable or unavailable. While electrification has provided these communities a variety of economic and social opportunities, diesel consumption has resulted in adverse costs and environmental pollution. Two technologies available to reduce the expense and emissions of diesel fuel reliance include dual fuel or hybrid diesel applications. The dual-fuel approach involves a supplementary gas fuel charge in support of reduced diesel fuel consumption. Hybrid applications involve the integration of renewable generation to displace diesel fuel consumption. This paper reviews the potential for hybrid dual-fuel applications, identifying engine flexibility as a major integration barrier. In comparing the flexibility of various dual-fuel technologies to operate dynamically, this paper presents a critical review across hydrogen, liquified petroleum gas (LPG), natural gas (NG) and blended hydrogen and NG derivatives. The results identify a range of approaches able to improve engine flexibility and thus reduce the cost and carbon intensity of diesel-fired internal combustion engines. At low load conditions, while NG and LPG exhibit similar performance, the use of hydrogen and hydrogen blends provide improved engine performance and response. Unfortunately, given the current cost of hydrogen fuel, significant commercial barriers exist to the adoption of hydrogen or hydrogen blended fuels. Despite this, this review indicates the potential of hydrogen-NG blends to offer additional flexibility in comparison to alternative dual-fuel technologies. This position is furthered considering near term cost targets associated with the development of a global green hydrogen industry, coupled with its ability to serve as a demand-side management approach within isolated power systems, one of the multiple future research themes.     

Effects of hydrogenation of fossil fuels with hydrogen and hydroxy gas on performance and emissions of internal combustion engines

Energy security is an important consideration for development of future transport fuels. Among the all gaseous fuels hydrogen or hydroxy (HHO) gas is considered to be one of the clean alternative fuels. Hydrogen is very flammable gas and storing and transporting of hydrogen gas safely is very difficult. Today, vehicles using pure hydrogen as fuel require stations with compressed or liquefied hydrogen stocks at high pressures from hydrogen production centres established with large investments.Different electrode design and different electrolytes have been tested to find the best electrode design and electrolyte for higher amount of HHO production using same electric energy. HHO is used as an additional fuel without storage tanks in the four strokes, 4-cylinder compression ignition engine and two-stroke, one-cylinder spark ignition engine without any structural changes. Later, previously developed commercially available dry cell HHO reactor used as a fuel additive to neat diesel fuel and biodiesel fuel mixtures. HHO gas is used to hydrogenate the compressed natural gas (CNG) and different amounts of HHO-CNG fuel mixtures are used in a pilot injection CI engine. Pure diesel fuel and diesel fuel + biodiesel mixtures with different volumetric flow rates are also used as pilot injection fuel in the test engine. The effects of HHO enrichment on engine performance and emissions in compression-ignition and spark-ignition engines have been examined in detail. It is found from the experiments that plate type reactor with NaOH produced more HHO gas with the same amount of catalyst and electric energy. All experimental results from Gasoline and Diesel Engines show that performance and exhaust emission values have improved with hydroxy gas addition to the fossil fuels except NO_x exhaust emissions. The maximum average improvements in terms of performance and emissions of the gasoline and the diesel engine are both graphically and numerically expressed in results and discussions. The maximum average improvements obtained for brake power, brake torque and BSFC values of the gasoline engine were 27%, 32.4% and 16.3%, respectively. Furthermore, maximum improvements in performance data obtained with the use of HHO enriched biodiesel fuel mixture in diesel engine were 8.31% for brake power, 7.1% for brake torque and 10% for BSFC.     

Household energy consumption pattern and socio-cultural dimensions associated with it: A case study of rural Haryana, India

A survey of household energy consumption pattern was carried out in a village of Jhajjhar district of Haryana, India in the year 2007. The households surveyed covered heterogeneous population belonging to different income, educational and social groups. There was more availability and utilization of solid biomass fuels as energy resources in domestic sector as compared to the commercial fuels. Dung cakes, crop residues and firewood were found to be the three main fuels used for cooking, though LPG was also used along with biomass fuels. But complete conversion to cleaner fuels has not taken place yet even in households that has been using LPG for many years. Income was an important factor determining the choice of fuel for cooking, but there were some socio-cultural factors which were equally important in making fuel preferences at household level.     

Natural gas and other alternative fuels for transportation purposes

Natural gas has been used as fuel for transportation for decades and, currently, about half a million vehicles of different types are running either on compressed natural gas (CNG) or on liquefied natural gas (LNG) in a number of countries, including Italy, New Zealand, the U.S.A., Australia, Iran and France. The country with the most developed program on utilization of natural gas as a transportation fuel is Italy, where almost 300,000 vehicles are running on CNG. Several other countries such as Brazil, Egypt, Canada, Bangladesh and the Soviet Union are implementing programs to use natural gas for domestic transportation needs. Natural gas is composed essentially of methane, which can be obtained also through anaerobic fermentation of different organic products yielding biogas (60% methane). The role of methane as a fuel has shown increasing importance due to the growth in digester construction all over the world, and especially in developing countries. Natural gas can also be used as raw material for the production of liquid fuels suitable for transportation purpose such as methanol, ammonia, gasoline, diesel oils, methyl esters of vegetable oils, and MTBE, a high-octane component of gasoline. In addition, natural gas liquids (propane/butane) can also be used as automotive fuels. This paper covers the technical-economic aspects of natural gas and methanol as fuels for transportation and presents a summary of worldwide experience with emphasis on the existing experience in a developing country such as Brazil, including its commercial large-scale experience with ethanol fuels.