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以Al(NO3)3·9H2O、Y2O3、Nd2O3、尿素和NH4HCO3为主要原料,分别采用均相法和共沉淀法制备了Nd:YAG纳米粉体和透明陶瓷。对比研究了两种方法的粉体的制备工艺,物相,形貌和陶瓷的透过率、形貌。结果发现,均相法制备的前驱体疏松,1200℃煅烧时先形成YAP相,后形成纯相粉体。共沉淀法制备的前驱体较硬,1000℃锻烧直接形成纯相粉体。最后,两种方法制备的陶瓷素坯经真空烧结、处理后,在1064 nm的透过率达80%。共沉淀法条件温和,易于得到纯相YAG,更适合于工业化开发。 相似文献
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以Al(NO3)3.9H2O、Y(NO3)3.6H2O、Nd(NO3)3.6H2O为主要原料,C6H8O7.H2O为燃烧剂,采用溶胶-凝胶法制备了Nd:YAG纳米粉体,系统的研究了Nd:YAG纳米粉体的最佳制备条件。用X射线衍射和红外吸收光谱对其进行物相鉴定,表明在800℃煅烧2h就可以合成YAG粉末。用荧光光谱分析可知800℃制得的粉体在243nm处有一显著的激发谱带,在728nm处有一显著的发射谱带,粉体具有良好的荧光性能。用激光粒度仪分析可知所得粉体分散性良,平均粒度在147.7nm左右。 相似文献
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本文以异丙醇铝,醋酸钇和醋酸钕为原料,用溶胶-凝胶和冷冻干燥法制备了Nd3+原子掺杂浓度为1.0%的Nd:YAG粉体.利用X-射线衍射仪和透射电镜对粉体的物相组成和粒度进行了分析测试,结果表明,前驱体经900℃高温煅烧2h后已完全转变为纯YAG相,平均粒径为40nm左右.随着煅烧温度的升高,粒径逐渐增大.采用热压和热等静压相结合工艺烧结出尺寸为φ50 mm ×2.5 mm的Nd∶YAG透明陶瓷,样品1064 nm的透过率为82.5%. 相似文献
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为了获得制备纯相YAG纳米粉体且重现性好的工艺,本实验以Al(NO3)3·9H2O、Nd2O3、Y2O3和NH4HCO3为原料,(NH4)2SO4为静电稳定剂,采用L9(34)正交试验方案研究了金属离子溶液浓度、NH4HCO3浓度、滴速和pH值4个重要因素对YAG粉体制备的影响,结果表明pH值是影响YAG纯相的主要因素。获得最佳工艺条件并进行了重复性试验研究,均得到了纯相YAG粉体。采用TG/DTA、XRD、FT-IR、TEM等测试手段对YAG粉体及前体进行表征,结果发现在1000℃煅烧温度下前体已完全转变成YAG相,得到了类球形、分散性较好、尺寸为23nm的YAG粉体。 相似文献
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以Y_2O_3 和Nd_2O_3为原料,采用溶胶-凝胶燃烧法制备出Nd:Y_2O_3激光陶瓷纳米粉体.XRD测试结果表明粉体的最佳煅烧温度为1000 ℃,并且晶化完全.原子力显微镜观察结果表明粉体的粒度约为200 nm,分布均匀.差热-热重分析表明,柠檬酸在447 ℃分解放热, 而晶型转变温度为590 ℃,荧光光谱测试表明粉体最强的荧光发射峰位于9421.646 cm~(-1)(即波长1061.4 nm处) ,是 Nd~(3+4)F_(3/2)-~4I_(11/2)谱相导致的荧光发射. 相似文献
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以Mg(NO3)2、K8Nb6O19·10H2O为前驱体,以H3BO3做助剂,采用共沉淀法在650℃制备单相的MgNb2O6陶瓷粉末。该方法将MgNb2O6陶瓷的合成温度降低约500℃。通过XRD结合ICP-MS定量分析其物相组成。加入硼酸有利于推动合成MgNb2O6单相晶体的热力学过程。加入硼酸的量不同,合成的陶瓷粉末形貌不同。硼酸与前驱体粉末中的金属离子形成低共熔化合物,易于在较低温度下使前驱物粉体形成液相从而促进反应进行。 相似文献
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《Ceramics International》2007,33(6):1047-1052
Nanosized Nd:YAG powders with different doping concentrations were synthesized at a significantly low temperature by a gel combustion method with citric acid as fuel and nitrate as oxidizer. It is found that the precursor is composed of hydroxycarbonate and dehydrates at below 500 °C to form carbonate. Mono-phase Nd:YAG crystallites can be formed without any intermediate phase at 850 °C. The value of crystallite size of the 850 °C calcined 1.0 at% Nd:YAG powder is 59 nm and the average particle size is 86 nm. The doping of neodymium into YAG garnets increases the lattice constant and the fluorescent intensity decreases drastically when the neodymium concentration is higher than 3 at% because of the fluorescent quenching effect. 相似文献
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一步共沉淀法合成钇铝石榴石纳米粉体 总被引:1,自引:0,他引:1
以Ai(NO3)y9H20和Y(NO3)3-6H20为原料,NH4HCO3为沉淀剂,十二烷基苯磺酸(C18H30SO3)为分散剂,采用一步共沉淀法合成钇铝石榴石(Y3A15O12,YAG)纳米粉体。利用X射线衍射仪、Fourier红外光谱仪、同步热分析仪和场发射扫描电子显微镜对YAG前驱体及不同温度煅烧后的粉体进行表征。结果表明:YAG前驱体化学组成为10[Al(Oh)3]·3[Y2(CO3)3+3H2O],900℃煅烧2h后转变为纯YAG相,1000℃煅烧2h后得到的粉体晶型完整、分散性好、颗粒尺寸分布均匀,形状近似球形,平均粒径约为65nm。该方法较传统共沉淀法操作步骤简化、参量减少、可重复性提高,因此,更有利于实现工业化批量生产。 相似文献
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Nanostructured neodymium doped yttrium aluminum garnet (Nd:YAG) powders were synthesized at low temperature by a gel combustion method with citric acid as fuel and nitrate as oxidizer. The method involves exothermic decomposition of an aqueous citrate–nitrate gel. The decomposition is based on a thermally induced anionic redox reaction. A variety of 1.0 at% Nd:YAG powders with different agglomerate structures were obtained by altering the citrate-to-nitrate ratio γ. The gel with γ = 0.277 yielded nanocrystalline Nd:YAG at 800 °C without the formation of any intermediate phase. For other gels nanostructured Nd:YAG powders were obtained at 850 °C. The gel with γ = 0.1 yielded nanostructured Nd:YAG powder with an average particle size of ∼40 nm. The stoichiometric citrate-to-nitrate ratio (γ = 0.277) gave the lowest amount of agglomeration. The decomposition of the gel was investigated by TG–DSC and FTIR. The produced ashes and calcined powders were characterized by XRD, BET and FETEM analysis. 相似文献