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研究耐高温植物源抗菌抗病毒助剂与三聚氰胺甲醛浸渍树脂适配性能,使用抑菌圈法确认助剂添加比例,并进行耐高温性能评估,探讨植物源抗菌抗病毒助剂在浸渍胶膜纸饰面细木工板应用的可行性。结果表明,植物源抗菌抗病毒助剂能与浸渍树脂互溶,热压后抗菌抗病毒颗粒能够均匀分布在胶膜纸表面,130~200℃高温热压后仍具有良好的抗菌性能。抗菌抗病毒助剂添加量为1%时,制得的浸渍胶膜纸具良好的抗菌抗病毒效果。该浸渍胶膜纸压贴制备的抗菌抗病毒饰面细木工板表面对甲流病毒(H3N2)抑制率达80.83%,对大肠杆菌抑制率达99.99%。 相似文献
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介绍了一种新型的HN-300型银离子无机抗菌剂的抗菌原理和特性,阐述了开发生产抗菌干法腈纶的方法和技术.经过一系列实验,确定了银离子无机抗菌剂添加到纤维中的比例.通过原液制备、纺丝、丝束水洗、卷曲和烘干等工艺,制得了含有1%抗菌剂的干法腈纶纤维产品,纤维具有良好的可纺性能,能满足消费者对保健纺织品日益增长的需求,抗菌干法腈纶纤维及其后加工纺织品都有很好的永久性抗菌性能.结果表明,HN-300型银离子无机抗菌剂在纤维中分散均匀,纤维对金黄色葡萄球菌、大肠杆菌的抗菌率均达99%以上.同时,纤维的抗菌性能耐水洗、耐热,具有持久性. 相似文献
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将尼龙/棉混纺织物进行数位印花颜料喷印后,添加不同浓度抗菌剂及红外线吸收剂加工后处理,探讨添加抗菌剂及红外线吸收剂对尼龙/棉混纺织物的印花色彩性、耐水洗牢度、耐摩擦牢度、抗近红外线性能、抗菌性能的影响。结果表明,红外线吸收剂及抗菌剂添加后,对布面的外观力度及色相的影响不显著。数印织物经PU树脂后处理,能够提升水洗牢度及耐摩擦牢度2~3级。以红外线吸收剂1%处理数印织物后,经红外线热像仪测试可以达到良好的红外线遮蔽效果。除此之外,数印织物经抗菌加工可发现,随着抗菌剂浓度增高其抗菌效果愈好,且抗菌剂对金黄色葡萄球菌之效果较大肠杆菌佳,尤其抗菌剂质量分数达1%时灭菌率可达98%以上。数位印花的多机能性加工经过适当工艺程序可达到实用效果。 相似文献
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为了研究添加抗菌剂后,聚乳酸复合膜的抗菌性能,选取了壳聚糖、茶多酚、MgO和银四种抗菌剂,与聚乳酸形成四种复合膜,对比了不同抗菌剂的效果,并利用红外光谱仪对复合膜的结构进行了表征。实验发现,无论哪种抗菌剂,均表现了良好的抗菌效果。当壳聚糖/聚乳酸、茶多酚/聚乳酸均按质量比5:5组成复合膜时,抗菌率分别为68.54%和70.26%,当MgO的添加量为2%时,抗菌率为71.01%,而银表现出了极强的抗菌效果,添加量为1%时,抗菌率达到了98.53%。透光率随着抗菌剂的加入都有不同程度的减小,其中茶多酚的影响最大,从88.67%下降到33.75%。薄膜DSC曲线显示,未添加抗菌剂时,薄膜T_m为80.3℃,添加Ag和MgO后,薄膜T_m分别下降了1.7℃和1.4℃,说明抗菌剂的添加对薄膜T_m几乎无影响。由此可以看出,天然抗菌剂的抗菌效果要略差于无机抗菌剂。 相似文献
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Dynamic mechanical properties of decorative papers impregnated with melamine formaldehyde resin 总被引:1,自引:1,他引:0
Papers impregnated with melamine formaldehyde based resins are widely used in decorative surface finishing of engineered wood based panels for indoor and outdoor applications. For cost-effective production of high-quality impregnated papers it is of great importance to understand the complex interplay between manufacturing conditions and technological property profile. In the present study, three raw papers from different suppliers were impregnated with melamine formaldehyde resin in an industrial scale experiment to study the influence of some important manufacturing variables on the processability of impregnated papers. As numerical factors the resin loading, the final moisture content and the amount of curing catalyst were systematically varied according to a statistical central composite design. The model papers were analyzed for their rheological and thermal properties using the dynamic mechanical method developed by Golombek. As target values flow time, cure time, curing rate and flexibility were used to calculate quantitative models for the processability of the impregnated papers using response surface methodology. It is shown that the relevant rheological and thermal paper parameters are significantly influenced by the supplier of the raw paper as well as the manufacturing variables. 相似文献
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A. Grigoriou 《Holz als Roh- und Werkstoff》1987,45(8):335-338
The bending deflection of six different wood based materials used as shelves in the manufacture of furniture (unlaminated particleboard, melamine laminated particleboard, veneered particleboard, block-board, plywood and solid wood panel) of approximately equal thickness was investigated. Deflection data were obtained by applying loads to the board surfaces for a period of 28 days followed by a period of unloading of equal length. For all types of particleboards the deflections appeared to be greater than for the other wood based panels. The lowest bending deflection was found for the solid wood panel while plywood performed better than blockboard. Surface treatments improved the performance of particleboards but veneering appeared to be more advantagous than laminating with melamine. The bending deflection of the tested panels is strongly related to their bending strength and modulus of elasticity. 相似文献
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Melamine impregnated paper offcuts and waste has been shown to be usable both directly, in finely powdered form, as a binder for particle board and as a melamine substitute during the formulation and preparation of liquid MUF resins. Both approaches were based on the residual activity of the MF resin present in the resin. Amounts of waste melamine paper of 22% on dry wood, equivalent to 10% melamine resin solids on total dry panel weight, were shown necessary for water resistant particleboard, and 18.5% for interior particleboard. Due to problems connected to excessive viscosity increase only a maximum of 25% of the total melamine in the formulated melamine resin could be substituted to good effect in the formulation of liquid MUF resin adhesives. 相似文献
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Siham Amirou Abdelatif Zerizer Antonio Pizzi Imane Haddadou Xiaojian Zhou 《Holz als Roh- und Werkstoff》2013,71(6):717-723
Date palm biomass is a renewable natural resource that has not widely been utilized in industry. The objective of this study was to examine some chemical properties of date palm trunk and rachis (holocellulose, cellulose, lignin and extractives) and to evaluate their suitability to produce composite panels. Particleboards were produced using trunk and rachis as an alternative raw material for forest products industry in the presence of two types of polycondensation resins (phenol–formaldehyde and melamine urea–formaldehyde) which were selected as binding agents. The panels were tested for their physical (water absorption and thickness swelling) and mechanical (modulus of rupture, modulus of elasticity and internal bond strength) properties. The internal bond strength of date palm trunk and date palm rachis based boards met the requirements of the general purpose product standards (EN 312) at 0.70 g/cm3 density. The panels made with phenol–formaldehyde resin showed better performance with respect to the panels made with melamine urea–formaldehyde. In addition, the particleboard made with date palm trunk particles had better quality compared to the particleboard made from date palm rachis particles. Based on preliminary results of this work, raw materials from date palm trunks and rachis can have a promising potential in the manufacture of particleboards and as a substitute for wood in board production. 相似文献
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Andreas Kandelbauer Primoz Petek Sergej Medved Antonio Pizzi Alfred Teischinger 《Holz als Roh- und Werkstoff》2010,68(1):63-75
The decorative laminates industry is a highly competitive industrial sector. To be profitable, manufacturers of impregnated papers for surface laminated MDF and particleboards need to significantly reduce their production costs. Melamine formaldehyde resin (MF) formulations are commonly used for impregnation and coating of such papers, melamine being an important, but costly raw material used in high quantities. While MF is substituted by cheaper urea formaldehyde resins (UF) in the core impregnation, for paper surface films pure MF is used. Therefore, a further reduction in cost could be achieved if a portion of the melamine in the surface film was replaced by urea. In the present contribution, recent results of technological tests on paper laminates using a novel melamine–urea–formaldehyde resin (MUF) formulation are reported and their performance is compared to traditional surfaces made from MF. 相似文献
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Effects of formaldehyde/urea mole ratio and melamine content on the hydrolytic stability of cured urea-melamine-formaldehyde resin 总被引:1,自引:0,他引:1
The influence of formaldehyde/urea (F/U) mole ratio and melamine content on the hydrolytic stability
of urea-melamine-formaldehyde (UMF) resin was investigated. The hydrolytic stability of cured UMF resin
was determined by measuring the mass loss and the liberated formaldehyde concentration after acid hydrolysis.
A higher F/U mole ratio and greater melamine content of UMF resins resulted in lower hydrolytic stability.
These results indicated that higher F/U mole ratio and greater melamine content resulted in more branched
network structure, which subsequently increases the susceptibility of cured UMF resin toward acid hydrolysis. 相似文献
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The influence of formaldehyde/urea (F/U) mole ratio and melamine content on the hydrolytic stability
of urea-melamine-formaldehyde (UMF) resin was investigated. The hydrolytic stability of cured UMF resin
was determined by measuring the mass loss and the liberated formaldehyde concentration after acid hydrolysis.
A higher F/U mole ratio and greater melamine content of UMF resins resulted in lower hydrolytic stability.
These results indicated that higher F/U mole ratio and greater melamine content resulted in more branched
network structure, which subsequently increases the susceptibility of cured UMF resin toward acid hydrolysis. 相似文献
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Qiang Gao Chang Liu Jianlin Luo Xiaona Li Liou Chen Wen Wang Jianzhang Li 《Holz als Roh- und Werkstoff》2018,76(4):1253-1261
The pre-pressing performance of urea formaldehyde resins has a significant impact on plywood production efficiency. This paper reports on the effects of the time elapsed after the addition of the hardener (“resin open time”) and of a melamine addition on the cold pre-pressing performance of UF resins. The changes in pH and viscosity, the thermal behaviour, and the structural composition as well as the performance during cold pre-pressing of veneers were investigated. Cold pre-pressing performance was measured by testing pre-pressed three-ply plywood stacks. The results showed that the cold pre-pressing performance is enhanced with longer time after preparation of the resin mix before application onto the veneers and also by longer pre-pressing times. All plywood stacks with at least 2 h pre-pressing time reached the so-called G1 grade (where the re-opened area of the cold pre-pressed plywood stack was 0), which meets the industrially accepted requirements for plywood fabrication. Further, the addition of melamine improved the cold pre-pressing behaviour compared to the investigated UF resin without melamine, showing an earlier start of the development of the pre-pressing shear strength and higher G grades at the various cold pressing times. There are two main reasons for the enhanced cold pre-pressing performance of the resin under the investigated conditions: (1) influence of the “resin open time”: a certain further condensation of the resin after preparing the glue mix (addition of hardener) leading to increased molar mass and viscosity ultimately transforming the resin from liquid-state to gel-state; (2) a higher methylol content in the resin after incorporation of melamine into the resin, which enhanced the formation of hydrogen bonds between the resin and the wood surface. These conclusions represent a feasible approach for the improvement of the cold pre-pressing properties and thus the practical applicability of UF resins with low molar ratios. 相似文献