多元陶瓷增强铜基复合材料的摩擦磨损性能

以6-6-3青铜粉为基体,加入Si C、Si3N4、B4C多元陶瓷作为颗粒增强相,利用粉末冶金法通过真空烧结工艺制备了Si C、Si3N4、B4C多元陶瓷/铜基复合材料,在MRH-3型高速环块磨损试验机上研究了复合材料在不同温度下的摩擦磨损性能。分析了Si C、Si3N4、B4C多元陶瓷增强相含量对复合材料耐磨性能、摩擦系数以及热导率的影响。结果表明:Si C、Si3N4、B4C多元陶瓷/铜复合材料在耐热性能、耐磨性能、抗弯强度等方面性能优异;多元陶瓷质量分数分别为15%、25%、35%的多元陶瓷/铜基复合材料中,硬度、抗弯强度以及耐磨性能均随着陶瓷颗粒质量分数的增加先提高后降低;摩擦系数先减小后增大,基本稳定在0.49左右,受温度影响波动不大;陶瓷颗粒的加入对材料的导热性能有一定影响,从而影响耐磨性能。     

纤维类型和涂层对纤维增强MoSi2复合材料弯曲性能的影响

以短切碳纤维(Cf)和碳化硅纤维(SiCf)为增强相,并用化学气相渗透法对部分纤维进行炭涂层处理,采用热压法制备了4种纤维增强MoSi2基复合材料(SiCf-MoSi2、SiCf/C-MoSi2、Cf-MoSi2和Cf/C-MoSi2),研究了纤维类型及表面炭涂层对MoSi2基复合材料弯曲性能的影响.结果表明纤维的加入明显提高了MoSi2的抗弯强度,加入5%SiCf和5%Cf的复合材料的强度比纯MoSi2分别提高了9.0%和22.8%,Cf增强作用明显优于SiCf;纤维类型相同时,具有炭涂层的纤维增强效果更显著,5%Cf/C-MoSi2复合材料的强度最高,达到了364.7MPa,比纯MoSi2的强度提高了30%;扫描电镜分析表明,无炭涂层的SiCf与MoSi2基体间存在着明显的裂缝,炭涂层改变了纤维与基体的界面结合;有涂层纤维的断裂机制为首先脱粘然后拔出.     

短碳纤维含量对温压-熔渗工艺制备C/C-SiC复合材料力学性能的影响

以短切碳纤维为增强体,采用温压–熔渗工艺(WP-LSI)制备纤维体积分数分别为20%、25%和30%的C/CSiC复合材料,研究纤维含量对C/C-SiC复合材料力学性能的影响,并与国外同类产品进行对比。结果表明:随碳纤维含量增加,复合材料的开孔率降低,抗弯强度和抗压强度均提高,纤维体积分数为30%的复合材料密度达2.00 g/cm3,开孔率仅2.88%,其抗弯和垂直抗压强度分别为104.63 MPa和167.99 MPa,比纤维体积分数为20%的材料分别提高86.04%和44.76%,比国外同类产品分别提高2.03%和11.99%;随碳纤维含量增加,复合材料的破坏形式由假塑性破坏向脆性破坏转变。     

不同烧结气氛下SiAlON/cBN陶瓷复合材料的性能研究

以Si3N4、Al N、Al2O3和c BN为原材料,采用放电等离子烧结,在氮气、氩气和真空三种不同烧结气氛下制备Si Al ON/c BN陶瓷复合材料.通过XRD、SEM及力学性能评估等手段研究了材料的物相组成、显微组织、体积密度、硬度以及断裂韧性等性能.结果表明:真空气氛下制备的Si Al ON/c BN陶瓷复合材料显微组织相对致密,具有较高的体积密度、硬度和断裂韧性.     

SPS工艺制备SiCp/Si3N4复相陶瓷及其力学性能的研究

使用Si3N4、SiC陶瓷微粉为原料,氧化铝(Al2O3)和氧化钇(Y2O3)为烧结助剂,通过放电等离子烧结(SPS)技术快速制备了SiC/Si3N4复相陶瓷,并研究了SiC的添加量、SPS的 烧结温度、压力和保温时间等参数对烧结试样相对密度、力学性能及显微结构的影响.结果表明,SiC颗粒补强增韧Si3N4陶瓷的最佳添加量为15%,相对与单相Si3N4陶瓷,维氏硬度提高了6.6%,断裂韧性提高了5%,抗弯强度提高了24%,样品晶粒比较均匀,SiC颗粒诱发穿晶断裂和钉扎效应提高了基体的断裂韧性.     

碳纤维增强建筑用ZL109合金的组织及拉伸性能分析北大核心

以M40J碳纤维作为增强材料,在铝镁系ZL109合金表面通过真空压力浸渗工艺处理得到体积比为50%的纤维增强Cf/Al基复合材料。通过实验测试手段研究其组织及力学性能,研究结果表明:Cf/Al基材料密度与基体合金相比发生了一定程度的减小,实现减重的效果。编织预制体经过浸渗处理后并未发生畸变,纤维束间隙受到基体金属的紧密填充,各纤维束保持整齐排列状态。纤维偏聚部位形成了一些微孔并产生微裂纹,纤维浸渗后引起了较大的畸变。C纤维与Al基体之间出现了界面反应。复合材料室温拉伸发生脆性断裂,在断裂区域纤维和基体达到了紧密结合状态。提高拉伸温度形成了更加不平整的断口组织和大量拔出纤维,形成了剪切破坏类型的断口。     

ZrO2/Si3N4颗粒增强MoSi2基复合材料的显微组织和力学性能

采用放电等离子烧结法(SPS)制备了不同体积分数的MoSi2及其复合材料,研究了复合材料的显微组织和力学性能.结果表明:10%ZrO2/20%Si3N4/MoSi2复合材料的致密度、显微硬度、抗压强度、断裂韧性分别为92.3%、15.17 GPa、2105 MPa、6.61 MPa·m1/2.与20%ZrO2/MoSi2复合材料相比,断裂韧性下降2.9%,显微硬度和抗压强度分别提高了22.8%,13.4%;与20%Si3N4/MoSi2复合材料相比,断裂韧性提高了5.3%,显微硬度和抗压强度相近;经500℃氧化300 h,氧化增重与ZrO2和Si3N4单独增强的相近,均是纯MoSi2的1/10左右,抗氧化效果显著.     

短Cf增强SiC基复合材料及制备压力和Cf含量对其性能的影响

采用先驱体浸渍裂解(PIP)法、联合液相硅漫渍(LSI)工艺和纤维干磨分散技术制备了纤维随机分布的、其体积分数ψ(Cf)分别为5%、10%和15%的短纤维增强SiC基复合材料,并研究了模压压力及纤维体积分数对该复合材料力学性能的影响.结果表明纤维增强SiC基复合材料的力学性能随其模压压力变化有所改变,最佳模压压力为20 MPa;随短纤维体积分数ψ(Cf)在一定范围内增加,复合材料的性能有所上升,当ψ(Cf)为15%时,该复合材料的断裂韧性、弯曲强度、弹性模量和显微硬度(HV25)分别为4.42 MPa·m1/2、170.1 MPa、149.6GPa和5191.     

B_4C颗粒对C/C-SiC复合材料微观结构与力学性能的影响

采用浆料浸渗结合先驱体浸渍-裂解法制备B_4C颗粒改性C/C-SiC复合材料,研究B_4C颗粒对C/C-SiC复合材料力学行为的影响。结果表明,B_4C颗粒改性的C/C-SiC复合材料的抗弯强度和断裂韧性分别为250.41 MPa和13.56 MPa·m~(1/2),与C/C-SiC复合材料相比,其抗弯强度下降45.5%,而断裂韧性提高46.0%。B_4C颗粒可促进SiC基体的烧结,但由于大量闭孔和基体弱界面的形成,导致材料抗弯强度降低。B_4C颗粒改性的C/C-SiC复合材料断裂韧性提高的主要原因在于,B_4C颗粒与SiC基体中的弱界面使裂纹在SiC基体中得到有效偏转,增加了裂纹在基体中的扩展路径,使得材料的断裂韧性提高。     

包埋法制备SiC涂层C/C复合材料及真空热处理对涂层的影响

采用Si、C及Al2O3粉末为原料,利用包埋法结合真空热处理在C/C复合材料表面制备SiC涂层.并利用XRD、SEM等测试手段分析真空热处理对涂层C/C复合材料的组织结构和力学性能的影响.研究结果表明:包埋粉料中Si含量为84.5%和87.0%(质量分数)时,所制备的SiC过渡层由β-SiC、α-SiC和Si三相组成....     

China's Major Non-ferrous Metals Imports & Exports

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Zinc Production by Province in 2014

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80% of Chinese Firms Purchasing Overseas Mines Ended up in the Red

<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic     

Copper Processing Profit Dropped Sharply,Copper Consumption Will Face Impact in the Second Half of the Year

正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,     

Central Geological Prospecting Fund Newly Added 16.47 Million Tonnes of Bauxite in 2013

正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF     

Manufacturers of Copper Tube for Central Air Conditioner Use Face Mounting Pressure in the Final Quarter of the Year

正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure     

Xinjiang Ranks No.1 in Production of Primary Aluminum in China

正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,     

Shenhuo Coal Industry and Electricity Power Completed800,000 t/a Aluminum Project in Xinjiang

正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.     

Guangdong Metal Transaction Center has Become the Second Largest Precious Metal Transaction Platform Nationwide

正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.     

Seven Rare Earth Projects Involving Close to 3 Billion Yuan Investment Landed In the HighTech Zone

正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.