共查询到17条相似文献,搜索用时 46 毫秒
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应用热力学方法探讨了298K时钾长石、钠长石、霞石在碱性环境下的碱析出能力,并对这些含碱矿物分解析出的碱对碱-硅酸反应(ASR)的影响进行了讨论.结果表明,由于矿物类型不同,碱性环境下的分解难易程度不同,其中霞石较易分解,钠长石次之,钾长石较难分解;随着溶液pH值增大,除霞石分解能力略有降低外,钠长石、钾长石的分解能力均显著提高.此外,通过加速实验方法证实含有霞石、钠长石、钾长石矿物的集料在使用低碱水泥条件下能显著促进ASR膨胀. 相似文献
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本文研究了38℃下LiNO_3对石英玻璃在NaOH溶液中碱硅酸反应(ASR)的影响,采用等离子发射光谱仪(ICP)、酸化处理、X射线衍射仪(XRD)和扫描电镜(SEM)对溶液中的离子浓度、SiO_2分布、固相产物的组成和微观形貌进行分析和表征。测定了长龄期在38℃湿气养护下LiNO_3对沸石化珍珠岩和防城港砂岩混凝土微柱中ASR膨胀的作用效果。结果表明:掺LiNO_3的碱溶液中,Li~+先于Na~+与溶出的SiO_4~(4-)反应,生成低溶解性的含锂产物,并附着在石英玻璃表面,降低了溶液中OH~-对石英玻璃的溶蚀,进而减缓了ASR的反应速率。混凝土试件中[Li]/[Na+K]摩尔比越高,LiNO_3抑制ASR膨胀效果越好;随着龄期的延长,后期掺锂试件仍存在ASR膨胀。短龄期下LiNO_3抑制活性集料的ASR膨胀效果良好,长龄期作用效果减弱。 相似文献
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碱-集料反应使混凝土体积膨胀,严重时会导致混凝土的破坏,影响碱-集料反应的因素很多,混凝土的蒸压又加速了一反应。本文应用人工神经元网络这样一种以样本集体系为基础的因果关系手段,预测诸因素的影响和膨胀率之间的关系,其结果和实测值比较具有较高的精度。 相似文献
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以锂辉石为原材料,在简化石灰石法的基础上,对抑制碱-集料反应用LiNO3的制备工艺和工艺参数进行了研究,并对抑制效果进行了评价.合成试验表明:在锂辉石∶碳酸钙=1∶2.7、焙烧温度为1100℃、焙烧时间为60 min和浸出时间为120 min的工艺参数情况下,Li的溶出率可高达88.45%;抑制试验表明:在80℃养护条件下,碱含量为2.5%和Li/Na摩尔比为0.74时,掺加试验室合成的硝酸锂可取得与硝酸锂分析纯较为接近的抑制效果,均可使3种集料成型砂浆试件90d时的膨胀率小于0.1%. 相似文献
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本文就混凝土中碱的来源、碱存在的形式及性质、碱-集料反应的机理和危害性、不同碱活性检测方法比较等方面作了概述,提出利用适宜的实验方法检测集料的活性,为混凝土施工前合理选材提供依据,使碱含量超标的混凝土用材得到有效控制,是预防碱-集料反应发生,保证混凝土工程强度、耐久性等质量指标达到设计要求的最安全最可靠途径。 相似文献
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本文介绍了混凝土碱骨料反应的有关概念,结合空军某机场水泥混凝土道面的腐蚀情况,分析了其碱骨料反应,并提出预防机场水混凝土道面碱骨料反应的几点措施。 相似文献
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采用硅灰、氯化钙和碳酸锂等外加剂分别对物理发泡水泥混凝土的凝结硬化性能进行单一和复合改进试验。结果表明,氯化钙能够有效促进水泥泡沫混凝土的凝结与硬化,当氯化钙掺量为2%(36 g)时,混凝土的初凝和终凝时间均缩短了11 h,7 d抗压强度增加了0.8 MPa;硅灰对水泥泡沫混凝土凝结硬化有一定的促进作用;碳酸锂促凝效果不明显;硅灰和氯化钙复掺没有表现出较大的复合效应。 相似文献
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Assessing relationships among properties of demolished concrete, recycled aggregate and recycled aggregate concrete using regression analysis 总被引:2,自引:0,他引:2
Recycled demolished concrete (DC) as recycled aggregate (RA) and recycled aggregate concrete (RAC) is generally suitable for most construction applications. Low-grade applications, including sub-base and roadwork, have been implemented in many countries; however, higher-grade activities are rarely considered. This paper examines relationships among DC characteristics, properties of their RA and strength of their RAC using regression analysis. Ten samples collected from demolition sites are examined. The results show strong correlation among the DC samples, properties of RA and RAC. It should be highlighted that inferior quality of DC will lower the quality of RA and thus their RAC. Prediction of RAC strength is also formulated from the DC characteristics and the RA properties. From that, the RAC performance from DC and RA can be estimated. In addition, RAC design requirements can also be developed at the initial stage of concrete demolition. Recommendations are also given to improve the future concreting practice. 相似文献
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废弃混凝土再生利用技术的研究进展 总被引:4,自引:1,他引:4
废弃混凝土再生利用对于保护环境、减少资源与能源浪费以及实现可持续发展具有重要意义。从混凝土再生骨料对混凝土性能的影响、混凝土再生骨料的应用、提高再生混凝土性能的方法3个方面介绍了目前国内外废弃混凝土再生利用技术的研究现状。指出除了进一步加大相关试验及基础理论研究外,国家以及相关机构还应在政策、资金等方面进行支持,并建立废弃混凝土再利用的具体实施标准、规范等,最终实现废弃混凝土"零排放"。 相似文献
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Micronized biomass silica (MBS) is an agricultural waste obtained from controlled burning of rice husk and grind in jar mill. This paper investigates the optimum percentage of MBS for the replacement of cement by conducting several experiments with the blended cement paste and mortar with MBS percentages varying from 0, 4, 8 and 12. In addition, hydration products were also investigated in the blended cement paste through X-ray diffraction. Due to the pozzolanic reaction of MBS with cement hydrates, secondary calcium silicate hydrates (CSH) were formed and also MBS which has a potential to reduce the intensity of Ca(OH)2 exhibited improved properties. The experimental results showed that the optimum percentage of MBS for the replacement of cement was 8% for the materials used in this study. The mechanical and durability properties of recycled aggregate concrete by replacing cement with 8% MBS were also carried out and it was found that the concrete exhibited improved properties. There by, using MBS one can overcome the drawbacks of recycled aggregate concrete as it acts as a supplementary cementitious material. Thus, by combining recycled concrete aggregate with MBS will achieve sustainable development. 相似文献
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