耐热铝合金FVS0812板材冲压成形性能研究

通过在293K～723K的温度范围内对耐热铝合金FVS0812板材进行拉伸实验,研究了FVS0812板材主要冲压成形性能指标。研究结果表明,FVS0812板材具有较小的延伸率和塑性应变比,较大的屈强比,FVS0812板材的冲压成形性能不佳。     

喷射沉积FVS0812耐热铝合金板高温拉伸变形与断裂行为的研究

通过对FVS0812铝合金薄板在250℃-450℃的温度范围内和在0．001s^-1-0．1s^-1的应变速率下的拉伸试验，以及断口的SEM分析，研究了喷射沉积FVS0812铝合金板的高温拉伸变形与断裂行为。结果表明：加工硬化率随着温度的降低而加大，随着应变速率的增加而略有降低；应变速率敏感性指数随着温度的升高而上升；流变应力随着应变速率的增加而增大，随着变形温度的增加而降低；伸长率不仅随着温度的升高而增加．同时也随着应变速率的提高而加大，与常规铝合金薄板的变化规律恰好相反。     

两种粉末冶金铝合金

1 FVS0812(快速凝固的Al-Fe-V-Si合金) FVS0812是一种快速凝固的Al-Fe-V-Si合金,它兼有传统航空铝合金的强度、延展性和断裂韧性特性,以及FVS铝合金的高温强度和稳定性。 1.1 化学成分铁,8.5％;钒,1.3％;硅,1.7％;     

耐热铝合金(FVS0812)板材温拉伸本构方程

通过在523K~723K的温度范围内和应变速率为0.001s-1~0.1s-1下对耐热铝合金(FVS0812)板进行温拉伸实验,研究耐热铝合金板温拉伸性能,以及该合金在升温条件下流变应力与变形温度、应变速率之间的关系,并使用改进了的Fields and Backofen方程建立FVS0812合金在温拉伸时应力-应变本构模型。     

航空用6061铝合金恒载荷应力腐蚀行为

采用恒载荷全浸腐蚀拉伸、断口扫描和室温拉伸等方法研究了拉应力对两种热处理状态6061铝合金(6061-T4和6061-T6)应力腐蚀行为的影响。结果表明，在O₂和Cl^-共存环境中，6061-T4铝合金的应力腐蚀敏感性很低，力学性能降低主要受腐蚀介质的电化学腐蚀影响；6061-T6铝合金的应力腐蚀开裂敏感性高于6061-T4铝合金，其应力腐蚀开裂倾向受腐蚀影响为主，力学因素影响为辅；应力腐蚀后，6061-T4和6061-T6铝合金表层腐蚀区域为沿晶脆断，次表层为准解离断裂，中心为穿晶断裂；在腐蚀介质与应力同时作用下，6061-T4铝合金由点蚀发展为晶间腐蚀，并随应力增大变为剥落腐蚀；6061-T6铝合金点蚀不明显，但晶间腐蚀深度随应力增大而加深。     

FVS0812铝合金的制备与性能

介绍了FVS0812铝合金的制备方法－平流铸造、喷射沉积，以及用不同方法制备的该合金的各种性能。     

Sc对6061合金组织与性能的影响

通过添加Sc对6061铝合金组织及性能进行改性。通过真空感应熔炼制备了6061和6061-0.2Sc铸锭并经550℃×12 h均匀化退火,随后进行了热挤压变形和570℃×1 h水淬+175℃×5 h空冷的固溶时效热处理,研究挤压变形前后Sc微合金化铝合金挤压型材的组织与性能演变。结果表明,Sc具有晶粒细化效应,均匀化后6061-0.2Sc晶粒尺寸为20～50μm。挤压并经固溶时效热处理后6061-0.2Sc晶粒相比于6061更细小均匀。添加Sc后,合金的抗拉强度和伸长率均得到提升,宏观断口平整,拉伸断裂模式由韧脆性混合断裂转为韧性断裂,腐蚀电流密度由946.62μA/cm²下降为568.05μA/cm²,耐腐蚀性能显著提高。     

喷射沉积-轧制工艺制备的FVS0812薄板的高温组织和力学性能

用喷射沉积-轧制工艺制备了FVS0812耐热铝合金薄板,研究了该板材在高温下的组织与性能.实验表明,板材具有优异的高温力学性能和热稳定性,可归因于基体上弥散分布的纳米尺寸的Al12(Fe,V)3Si相.FVS0812合金在200～300℃温区内延性降低,是铁原子扩散而造成的动态应变时效(DSA)的结果.较高温度下板材的拉伸断口呈晶间断裂,可能是由于DSA效应中铁原子和Al12(Fe,V)3Si扩散到晶界而造成的晶界弱化的结果.     

Ni-W-P-SiC脉冲复合镀层的耐蚀性研究

采用腐蚀溶液浸泡、阳极极化曲线和中性盐雾试验3种方法较系统地研究了Ni-W-P-SiC脉冲复合镀层的耐蚀性.其结果表明：镀层在HCl、H2SO4、H3PO4溶液中的腐蚀速率都比较低，而镀层在FeCl3溶液中的腐蚀速率远大于前三者；镀层在H2SO4和H3PO4中的钝化区较宽，有过钝化区、二次钝化区和二次过钝化区出现，而在HCl和FeCl3中的钝化区较窄，且只有过钝化区；3种腐蚀试验方法均表明脉冲频率和占空比对试样的腐蚀速率都有不同程度的影响；不同脉冲参数条件下的400℃热处理镀层的腐蚀速率都比镀态镀层的腐蚀速率小得多.      

面积比对Al 6061-SS 304电偶腐蚀行为的影响

对30%硝酸环境中的Al 6061-SS 304电偶对开展浸泡实验和电化学实验,研究了Al 6061材料在30%硝酸环境中的电偶腐蚀现象和不同阴阳面积比对腐蚀行为的影响,借助SEM、EDS、电化学测量等方法对腐蚀前后Al 6061的表面形貌、腐蚀坑数量、电化学参数进行了测量与分析。结果表明:Al 6061耦合SS 304后,两者间的腐蚀驱动电位差达到583 mV,Al 6061作为反应阳极发生溶解腐蚀;在SEM照片中可以明显看出耦合后出现了三类电偶腐蚀现象,其中第二相粒子与铝基体耦合引起的微电偶腐蚀是腐蚀坑的主要类型。同时,阴阳面积比增加导致电偶电位减小和腐蚀电流增大,电偶电流与阴阳面积比满足定量关系式,且经K-S检验理论与实际吻合度高。     

Effect of Al2O3 reinforcement and precipitates on corrosion behaviour of 2618 and 6061 aluminium MMCs

ABSTRACT

The corrosion resistance features of two different Metal Matrix Composites based on 6061 and 2618 aluminium alloys reinforced by 20% Al₂O₃ particles by stir casting process, were studied in 3.5% NaCl and compared. The composites and their respective base alloys were characterised in terms of microstructure by optical and scanning electron microscopy and in terms of corrosion resistance by polarisation curves and electrochemical impedance. Results show how the presence of Al₂O₃ has different effects depending on matrix composition. In 6061 MMC, Al₂O₃ promotes the formation of Mg₂Si which has a cathodic behaviour altering the pitting susceptibility of the composite. In 2618 MMC, the high content of Cu induces a strong uniform attack. The subsequent increase in the Open Circuit Potential caused a pitting attack.     

Tribological Properties of Nanostructured Al/Al_(12)(Fe,V)_3Si Alloys

Tribological behavior of nanostructured pure Al and Al–Al12(Fe,V)3Si alloys containing 27(FVS0812) and 37(FVS1212) vol% of Al12(Fe,V)3Si precipitates was investigated. All samples were prepared using mechanical alloying followed by hot pressing. Wear tests were performed at room temperature using a pin-on-disk machine. Results showed that the presence of Al12(Fe,V)3Si precipitates increases the wear resistance of nanostructured Al, and the wear resistance increases with increasing the Al12(Fe,V)3Si content. Scanning electron microscopy images of worn surfaces and wear debris demonstrated that abrasion and adhesion are the governing wear mechanisms for the nanostructured FVS0812 alloy at 2 and 5 N normal loads, whereas for the nanostructured FVS1212 alloy, the dominant wear mechanism is abrasion at these loads. A mechanically mixed layer(MML) containing Fe and O was formed on the worn surfaces of FVS0812 and FVS1212 samples at 10 N normal load. Formation and delamination of MML controls the wear behavior of these samples at the normal load of 10 N. It is also found that the presence of Al12(Fe,V)3Si precipitates decreases the friction coefficient of nanostructured Al.     

球面形耐热铝合金零件拉深成形工艺研究

耐热铝合金FVS0812板的成形性能差,拉深成形球面形零件更是困难.本文在实验研究的基础上提出了一种新型的拉深成形工艺,即包覆拉深,采用该工艺成功拉深出相对厚度小的球面形耐热铝合金零件.该工艺可以有效地防止皱曲和破裂的产生,可以使板料的变形均匀分散,从而提高板料的冲压成形性能.包覆拉深工艺是一种适合于低塑性材料拉深成形的工艺方法.     

Effect of nano Al (Scx−1Zrx) precipitates on the mechanical and corrosion behavior of Al‐2.5 Mg alloys

Microanalytical, mechanical, and corrosion studies were undertaken to investigate the effect of nano‐precipitates of Al(Sc_x−1Zr_x) on the mechanical and corrosion characteristics of Al 2.5 alloy containing 0, 0.15, 0.3, 0.6, and 0.9 wt% of Sc with 0.15 wt% Zr. Addition of 0.3% Sc significantly increased the yield strength due to small precipitates sizes (5–19 nm) and the high coherency of the nano‐particles. Largest contributor to the strength was grain boundary strengthening caused by pinning of grain boundary precipitates. The alloys showed a good resistance to corrosion in 3.5 wt% neutral chloride solution. The alloy offered a high passivation tendency because of homogeneous coherent nano Al(Sc_x−1Zr_x) precipitates. The nano precipitates interfaces and homogeneously distributed Al₃Sc precipitates offer a high degree of corrosion resistance to Al 2.5 Mg Sc alloys compared to conventional aluminum alloys, such as Al 6061 and Al6013.     

Effect of trace Sc and Zr on aging behavior and tensile properties of 2618 alloy

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Optimization of In-Situ Shot-Peening-Assisted Cold Spraying Parameters for Full Corrosion Protection of Mg Alloy by Fully Dense Al-Based Alloy Coating

Magnesium-based alloys have excellent physical and mechanical properties for a lot of applications. However, due to high chemical reactivity, magnesium and its alloys are highly susceptible to corrosion. In this study, Al6061 coating was deposited on AZ31B magnesium by cold spray with a commercial Al6061 powder blended with large-sized stainless steel particles (in-situ shot-peening particles) using nitrogen gas. Microstructure and corrosion behavior of the sprayed coating was investigated as a function of shot-peening particle content in the feedstock. It is found that by introducing the in-situ tamping effect using shot-peening (SP) particles, the plastic deformation of deposited particles is significantly enhanced, thereby resulting in a fully dense Al6061 coating. SEM observations reveal that no SP particle is deposited into Al6061 coating at the optimization spraying parameters. Porosity of the coating significantly decreases from 10.7 to 0.4% as the SP particle content increases from 20 to 60 vol.%. The electrochemical corrosion experiments reveal that this novel in-situ SP-assisted cold spraying is effective to deposit fully dense Al6061 coating through which aqueous solution is not permeable and thus can provide exceptional protection of the magnesium-based materials from corrosion.     

On the Stress corrosion cracking behaviour of aluminium alloy sheet in an aqueous solution of 3% NaCl + 0.3% H2O2

The stress corrosion cracking (SCC) behaviour of aluminium alloy sheet was investigated in the long transverse direction using the slow strain rate testing technique. The synthetic environment used was an aqueous solution of 3% NaCl + 0.3% H₂O₂. No indications of SCC sensitivity are observed for the alloys 2024-T351, 8090-T81, and 2091 CPHK-T8X. The alloys 2091 T8X and 6061-T4 are found to be susceptible to intergranular stress corrosion cracking. At strain rates below 4 · 10^?7 s^?1, the slow strain rate testing technique indicates a slight SCC sensitivity with alloy 6013-T6. Fractography reveals transgranular stress corrosion cracking. Transgranular stress corrosion cracking is also observed with 6061-T4 specimens which are dynamically strained at strain rates below 5 · 10^?7 s^?1. Aqueous 3% NaCl solution with hydrogen peroxide addition promotes pitting and intergranular corrosion. The loss of ductility caused by these corrosion processes interferes with the evaluation of the results of the slow strain rate testing technique.     

T6I6时效对6061铝合金拉伸及晶间腐蚀性能的影响

对T6I6时效处理的6061铝合金的拉伸性能、晶间腐蚀性能和电导率进行了测试,并采用OM和TEM对其组织进行了观察.结果表明,6061铝合金经180℃×8 h T6峰值时效后,虽然强度较高,但有严重晶间腐蚀倾向;T6I6预时效时间对拉伸性能影响不大,但中断时效温度和时间对其影响显著.由于较高的中断时效温度和较长的中断时间能获得高密度的晶内析出相和呈球状不连续分布的晶界析出相,因此,T6I6时效处理后的6061铝合金不仅能保持较高强度,同时还能显著提高晶间腐蚀抗力.经180℃×2 h+150℃×2160 h+180℃×8 h T6I6时效,合金抗拉强度和屈服强度分别为348.5和326.9 MPa,相对于T6状态,仅分别下降了2.1%和1.4%,腐蚀类型由T6状态的晶间腐蚀转变为均匀腐蚀,腐蚀深度约为30μm.     

Evaluation of corrosion behavior of Al-Mg-Li alloys in seawater

Weldalite 050, a high-strength Al-Mg-Li alloy, was evaluated for its corrosion resistance in deaerated and air saturated Arabian Gulf water to determine its suitability for marine applications. Weight loss and electrochemical studies showed that the alloy had minimum corrosion rates of 1.82 and 4.82 mpy (mils per year), respectively, in deaerated and air saturated Arabian Gulf water with very high total dissolved solids (TDS) content. Weldalite 050 exhibited good resistance to corrosion at velocities up to 3.9 m/s. The formation of Al₂MgLi, Al-Li, Al₁₂Mg₁₇, and Al-Li precipitates has a pronounced effect on its corrosion resistance. The corrosion resistance of Weldalite 050 compares favorably with that of alloys 5052 and 5054, wrought alloys 6061 and 6013, and silicon carbide (SiC) reinforced alloys 6061 and 6013.