共查询到19条相似文献,搜索用时 109 毫秒
1.
悬浮法PVC专用树脂技术进展 总被引:2,自引:2,他引:2
PVC树脂的改性有物理方法和化学方法两种途径,文中从产品性能、生产工艺、牌号及用途几方面介绍了几种改性悬浮法PVC专用树脂,如低聚合PVC、高聚合度PVC、交联PVC、氯化聚氯乙烯、粉末涂层用PVC专用树脂、球形树脂、直接挤出成型加工硬质PVC专用树脂、耐热PVC树脂、氯乙烯-醋酸乙烯系一旬共聚树脂、内增塑PVC树脂、氯乙烯-乙烯/醋酸乙烯接枝共聚物、氯乙烯-丙烯酸酯共聚树脂、PVC合金专用料等。指出了我国发展PVC专和树脂的重要性。 相似文献
2.
综述了聚氯乙烯(PVC)树脂耐热改性和增韧改性的研究进展。PVC耐热改性方法主要有添加热稳定剂、交联、共混、共聚、氯化及无机纳米粒子改性;增韧改性的主要方法包括弹性体、纳米粒子、聚合物/无机纳米复合材料、纳米级微纤增韧以及原位聚合的方法。最后,提出了PVC耐热和增韧改性的发展方向。 相似文献
3.
4.
5.
以具有核壳结构的纳米级交联粒子为耐热改性剂,系统研究了聚氯乙烯(PVC)树脂/粒子耐热改性剂/甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物(MBS)树脂三元共混体系的力学性能、维卡耐热性能及流变行为,探讨了刚性粒子和橡胶粒子在PVC树脂增韧和耐热改性过程中的相互作用及关键影响因素。结果表明:具有核壳结构的纳米离子型耐热改性剂可以显著提高PVC树脂的维卡软化温度,加入MBS树脂可提高共混物冲击强度。研究发现,PVC中加入8份MBS和15份耐热改性剂,可制得耐热、抗冲兼备的PVC共混新材料。 相似文献
6.
7.
8.
9.
10.
11.
综述了聚氯乙烯(PVC)树脂的主要耐热改性方法,主要包括添加热稳定剂、交联改性、共混改性、共聚合改性以及氯化改性等,指出了其今后研究开发的方向。 相似文献
12.
Novel surface‐modified kaolin with liquid‐like behavior was prepared. The characteristics of the solvent‐free kaolin fluid were evaluated by using Fourier transform infrared spectroscopy, WAXD, thermogravimetric analysis, and transmission electron microscopy. The polyvinyl chloride (PVC)/solvent‐free kaolin fluid composites were also fabricated via melt mixing. Owing to the novel surface modification, the hydrophilic kaolin surface grafted long organic chains, which made that the solvent‐free kaolin fluid could be well dispersed in PVC matrix and firmly integrated with the PVC matrix. The resulted composites exhibited better heat resistance and mechanical properties than neat PVC resins. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers 相似文献
13.
以氯乙烯-丙烯酸丁酯-甲基丙烯酸甲酯共聚弹性体(VCE)增韧改性PVC树脂提高聚氯乙烯(PVC)的抗冲击性能,并与传统抗冲击改性剂甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物(MBS)、ACR及氯化聚乙烯(CPE)改性的PVC材料比较。对改性PVC的流变性能、力学性能、热变形性能及断面结构进行表征和微观观察。结果表明,随着VCE含量的增加,PVC的拉伸强度与弯曲强度逐渐减小,抗冲击强度与断裂伸长率逐渐增加,热变形温度逐渐降低;在相同用量的条件下,VCE对 PVC的改性效果优于ACR及CPE,达到MBS改性PVC的水平,VCE能够增韧PVC,提高PVC的抗冲击性能,是一种性能优异的新型PVC抗冲击改性剂。 相似文献
14.
综述了近3年采酚醛树脂耐热和增韧改性的研究进展简要介绍了各种方法的改性机理及研究现状最后对酚醛树脂改性方法的发展前景作出了展望. 相似文献
15.
16.
17.
James G. Bryner 《乙烯基与添加剂工艺杂志》1990,12(2):105-110
SMA polymer modifiers for PVC, of the ELIX 300 type, increase the practical heat resistance of rigid PVC blends to > 100 C, allowing cost effective competition with high heat fire retardant engineering resins. The PVC/SMA blend technology, physical property characteristics, and fire retardant properties are presented. A definition of practical heat resistance and the correlation of practical heat resistance to Vicat heat resistance measurements are given with comparisons to competitive high heat fire retardant plastics. Current commercial application experience in rigid injection molding and profile extrusion is described which has confirmed the cost/performance advantage of PVC/SMA blends. Potential market opportunities for PVC/SMA blends will be presented for discussion. 相似文献
18.
19.
To improve the processability and prevent the thermal degradation of poly(vinyl chloride) (PVC), various plasticizers and heat stabilizers have to be compounded. Phthalic plasticizers and metal soap stabilizers are usually used with epoxides as costabilizers. Epoxidized soybean oil (ESO), is one of the most commonly used epoxides because of its typical combined roles as a plasticizer and heat stabilizer in PVC compounds. ESO, however, sometimes causes surface contamination of PVC compounds because saturated fatty acids such as stearic and palmitic acids in soybean oil easily bleed onto the surface. In addition, some ingredients in ESO with hydroxide groups and unreacted double bonds during epoxidization also tend to increase the bleeding of ESO. This is due to their low compatibility with PVC resins. In this study, a novel plasticizer of PVC resins, glycidylethylhexylphthalate (GEHP), was synthesized, and its performance was evaluated. GEHP was designed to act as a plasticizer like normal phthalic plasticizers and to act as a heat stabilizer like ESO. Through the addition of epoxy groups in phthalic compounds, the resistance to bleeding was improved, and the plasticizing and heat‐stabilizing effects on the PVC compounds were preserved. Soft PVC films were prepared with GEHP. The mechanical properties, thermal stability, and bleeding properties of the films were investigated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1347–1356, 2005 相似文献