Effect of hydrogen in aluminium and aluminium alloys: A review

Susceptibility of aluminium and its alloys towards hydrogen embrittlement has been well established. Still a lot of confusion exists on the question of transport of hydrogen and its possible role in stress corrosion cracking. This paper reviews some of the fundamental properties of hydrogen in aluminium and its alloys and its effect on mechanical properties. The importance of hydrogen embrittlement over anodic dissolution to explain the stress corrosion cracking mechanism of these alloys is also examined in considerable detail. The various experimental findings concerning the link between hydrogen embrittlement and stress corrosion cracking are also discussed.     

Improving the properties of aluminium alloys by retrogression and reageing

Retrogression and reageing heat treatments offer the potential of improved tensile properties in combination with greatly increased resistance to stress corrosion cracking. The potential of this technique is reviewed with respect to the current application in the European and North American Aerospace Industry. To illustrate the performance increase associated with RRA treatments, the stress corrosion cracking performance of the established aerospace plate and forging alloy 7010 has been evaluated using an alternate immersion constant load tensile type test (ECSS‐Q‐70‐37A) Specimens were cut from a large aerospace rectilinear forging and tested in three different tempers, T652, T7452 and a retrogressed and reaged condition (RRA). In the T652 condition the material has been shown to be highly susceptible to intergranular corrosion and stress corrosion cracking. In the T7452 and RRA conditions 7010 showed much improved resistance to SCC but pitting corrosion resulted in failure of some specimens within the 30day requirement of the test standard.     

Micromechanisms of fatigue crack growth in aluminium alloys

The fatigue crack growth characteristics of high-strength aluminium alloys are discussed in terms of behaviour during mechanical testing and fracture surface appearance. For a wide range of crack growth rates, the crack extends both by the formation of ductile striations and by the coalescence of micro-voids. Dimples are observed at stress intensities very much less than the plane strain fracture toughness, and this is explained in terms of the probability of inclusions lying close to the crack tip. The striation formation process is described as a combination of environmentally-enhanced cleavage processes and plastic blunting of the crack tip.     

Distribution of lead in lead-containing aluminium alloys obtained by liquid phase co-spray forming technique

Liquid phase co-spray forming (LPCSF) technique was employed to produce Al-Pb and Al-Si-Pb alloys to show that it is possible, using this technique, to distribute lead into very fine-sized particles in Al/Al alloy matrix at low melt temperatures. Microstructural studies were carried out to explore the mechanisms governing lead distribution in the matrix of the alloys during processing. Results showed that, regardless of the alloy compositions and experimental conditions, the microstructures of the preforms exhibited great similarity, i.e. less uniform distribution of Pb particles in the base region, and uniform distribution of fine Pb particles in the equiaxed region. During LPCSF process, the behaviour of Pb droplets was similar to that of ceramic particles, except that the shape and size of liquid Pb phase varied corresponding to local solidification condition.     

Effect of alloying with zinc on SFE of aluminium by study of lattice imperfections in cold worked Al-Zn alloys

A detailed X-ray Fourier line shape analysis has been performed on three compositions of Al-Zn alloys viz. Al-3.55 wt% Zn, Al-14.7 wt% Zn and Al-19.3 wt% Zn infcc phase. It has been found that deformation stacking faults, both intrinsic ά and extrinsic α are absent in the cold worked state and twin fault β is found to be slightly present in the deformed lattice of the two initial compositions of the alloys. Similar to the effect of solute germanium and copper, respectively in Al-Ge and Al-Cu systems, hexagonal zinc also fails to impart faulting infcc Al-Zn system. This corroborates the fact that aluminium has high stacking fault energy.     

Gel electrode imaging of fatigue cracks in aluminium alloys

Previous papers have described a gel electrode technique recently devised for detecting and imaging fatigue cracks in aluminium tested in simple bending. In this study, the technique is shown to be applicable to testing in both bending and torsion and to high strength aluminium alloys 7075-T6, 2024-T3 and 2024-T4. Fatigue cracks as short as 10 μm in length are consistently detected and located. The flow of charge during image formation under standard conditions provides a quantitative measure of crack length, which is independent of alloy composition. A crack 100 μm long can be reliably detected by charge flow measurement; thus, this approach is not as sensitive as the information contained in the actual images.     

Variation of the cyclic strain-hardening exponent in advanced aluminium alloys

The cyclic strain-hardening exponents for five fatigue-resistant aluminium alloys were determined throughout the fatigue life to study the degree of cyclic stability of these alloys. Data were compared with results for 2024-T4 aluminum and for two high-pressure steels. The strain-hardening exponent increased logarithmically in all cases except 2024-T4, although the increase was small and did not exceed 33% over the fatigue life. 7475-T351 aluminium alloy was found to be entirely stable, and 7075-T7351 almost so. These were followed in order of rising sensitivity by 2014-T6, 7050-T73651, and 2124-T851 aluminium alloys, and 28NiCrMo7.4 and 30CrNiMo8 steels. 2024-T4 aluminum alloy demonstrated a strong decrease in strain-hardening exponent with fatigue life.     

A unified approach to complex crystalline and so-called quasicrystalline phases in aluminium alloys

Recent developments in the complex and controversial, but fertile and fascinating field of aluminium-transition metal alloys are reviewed with particular reference to the so-called quasicrystalline phases and their rational approximants. Pauling’s several approaches to icosahedral phases on the basis of twinning in cubic crystals with large unit cells are described and examined along with the difficulties in checking the structures proposed by him. A new unified crystallographic approach is presented by the author, starting with icosahedral atomic clusters in concerned alloy melts, and it is shown that this integral approach leads to a reasonably good understanding of the interrelationship between the numerous known solid phases in aluminium alloys, including icosahedral phases, decagonal phases and their rational approximants. DEDICATED TO THE MEMORY OF PROFESSOR LINUS PAULING (1901–1994).     

Effect of hydrogen charging on the mechanical properties of medium strength aluminium alloys 2091 and 2014

Cathodic hydrogen charging in 3·5% NaCl solution altered the mechanical properties of 2091-T351 (Al-Cu-Li-Mg-Zr) determined by a slow (10⁻³/s) strain rate tensile testing technique. UTS and YS decreased in the case of 2091-T351 and 2014-T6(Al-Cu-Mn-Si-Mg) with increase in charging current density. Elongation showed a decrease with increase in charging current density for both the alloys. However, elongation occurring throughout the gauge length in uncharged specimens changed over to localized deformation, thus increasing the reduction in area in charged specimens. A transition in fracture mode from surface (brittle) to the core (ductile) was observed. The presence of hydrogen increased the hardness, mostly indicative of solution strengthening and it decreased with depth confirming the existence of hydrogen concentration gradient. The effects were similar in 2014-T6, but to a slightly smaller extent.     

Comparison of hardenability and over-aging precipitation behaviour of three 7xxx aluminium alloys

The purpose of the paper is to compare hardenability and aging precipitation behaviour of three 7xxx aluminium alloys (7150, 7055 and 7056). The hardenability has been studied by Jominy test. The aging precipitation behaviour has been investigated according to their hardness and electrical conductivity after over-aging treatment. The micro-structural characterisation has been observed by scanning electron microscope and transmission electron microscope. These results show that AA7056 has the highest hardenability and sensitivity to over-aging treatment compared with AA7150 and AA7055. The highest w(Zn)/w(Mg) ratio and the lowest Cu content of AA7056 are beneficial for inhibiting quench precipitates and decreasing the stability of meta-stable η′ phase.     

S-N-P curves in 7075 T7351 and 2024 T3 aluminium alloys subjected to surface treatments

The S-N-P (stress, number of cycles, failure probability) curves for 2024 T3 and 7075 T7351 aluminium alloys were obtained. Previously, surface treatments of degreasing and different types of anodizing were applied to samples, evaluating the influence of these treatments on the fatigue life of the alloys. The determination of the S-N-P curves was done using Maennig's method. Rotary fatigue was used because this technique produces greater stress on the sample surfaces, the zone in which it is important to evaluate fatigue resistance. Both the transition range and the finite life range were evaluated, calculating the 1, 50 and 99% fracture probability. SEM was performed in order to characterize the fracture micromechanism. The conclusions were that Maennig's method is useful to evaluate fatigue life of these materials in a fast and efficient manner. Moreover, surface treatments produce a decrease in the fatigue life of both alloys, associating this effect with the surface damage produced on each sample during the treatment.     

One parameter model for strength properties of hardenable aluminium alloys

Models for strength properties are proposed for commercially aluminium alloys. The alloy group investigated are the hardenable alloys from the 2000 (Al–Cu and Al–Cu–Mg), 6000 (Al–Mg–Si) and 7000 (Al–Zn–Mg) series. The same model for solid solution hardening that has successfully been applied to non-hardenable alloys has been used. For precipitation hardening, particle cutting and the Orowan mechanism have been considered. The same basic model is used for all strength properties. It is demonstrated that with one fitting parameter for each property, a representation with reasonable accuracy can be obtained that is applicable to a wide range of alloys. Such models are useful in materials optimisation and selection.     

The dispersion mechanism of TiB2 ceramic phase in molten aluminium and its alloys

Titanium diboride (TiB₂) ceramic particulates are dispersed in molten aluminium and its alloys for grain refining and for making cast metal–matrix composites. For producing cast MMC, the dispersion of the ceramic phase via in-situ aluminothermic reduction of K₂TiF₆ and KBF₄ flux mixture with molten aluminium and, via the addition of exogenously formed TiB₂ with the fluoride flux has been studied at 900°C. In this article, the aspects of interfacial energy that govern the dispersion and agglomeration of TiB₂ particulates are examined. The Gibbs-adsorption interface equation is particularly employed to define and to quantify the change in the surface energy as a function of the alloying element concentration and, consequently the effect of interfacial energy on the nucleation rate of TiB₂ formed via metallothermic reduction reaction and the size of the ceramic phase is also explained.     

Subzero tensile properties of 7010 aluminium alloy and Ti-6A1-4V and IMI550 titanium alloys in sheet form

Tensile properties are reported for Al-6Zn-2.5Mg-1.7Cu-0.12Zr (7010), Ti-6Al-4V and Ti-4Al-4Mo-2Sn-0.5Si (IMI550) alloy sheet, 1.7 mm thick tested at 293, 223, 173 and 77 K. The strength of these alloys increased and the reduction of area decreased with decreasing test temperature. The Young's Modulus (E), 0.1% proof stress (σ_0.1) and true tensile strength ($\text{σ}{}_{\mathrm{TS}}$) were related to temperature T in degrees absolute (in the range 293-173 K for E and 293-77 K for σ_0.1 and $\text{σ}$_TS) by     

Analysis of fatigue crack initiation and S-N response of model cast aluminium piston alloys

Fatigue crack initiation and S-N fatigue behaviour of hipped model Al7Si-Sr and Al0.7Si piston alloys have been investigated after overaging at 260 °C for 100 h to provide a practical simulation of in-service conditions. The results show that hipping did not affect the S-N behaviour of Al7Si-Sr. This is attributed to the lack of significant change in porosity distribution in this alloy because of its low porosity levels even in the unhipped state. However, hipping profoundly improved the fatigue performance of alloy Al0.7Si due to the significant reduction in porosity. In this investigation, it was observed that porosity was rendered impotent as a fatigue crack initiator in both hipped alloys. Instead, fatigue cracks were observed to originate mainly from intermetallic particles (particularly the Al₉FeNi phase) in both alloys and sometimes from oxide particles in Al0.7Si alloy. Fatigue cracking was also frequently observed at intermetallic clusters in hipped Al0.7Si. The observed scatter in fatigue life is discussed in terms of the size of fatigue crack initiating particles and the overall particle size distribution which follows a power law distribution function.     

Fracture toughness of cast aluminium alloys

An investigation was carried out to evaluate the fracture toughness of cast aluminium alloys of different microstructural complexity, brought about by alloy constitution and cooling rate of castings. In all cases the three-point bend specimens, which had a thickness of 15 mm, did not provide valid plane — strain stress intensity factor values. The fracture susceptibility at a given stress level reckoned in terms of the conditional plane strain stress intensity factor (K _Q) was found to be lowest in aluminium-4.5% copper alloy castings and the susceptibility increased with increase in microstructural complexity. Casting cooling rate in these castings is likely to affect the damage potential of a given defect at yield stress to a greater extent than the fracture susceptibility at a given stress.     

铝合金熔焊区结构稳定性的测试技术

在航空航天领域中,轻合金激光熔焊区的结构稳定性具有重要意义.因此,本文从晶界面结构视角具体审视这一问题.本研究以一种5系铝合金的激光熔焊区为研究对象,分别利用扫描电镜、电子背散射衍射(EBSD)和统计性的晶界面结构分析方法,首先实现了热影响区、等轴区和熔合区在空间上的准确划分;其次对各子区分别计算了穿过晶界面的取向差角...     

Tensile behavior of dissimilar friction stir welded joints of aluminium alloys

The heat treatable aluminium alloy AA2024 is used extensively in the aircraft industry because of its high strength to weight ratio and good ductility. The non-heat treatable aluminium alloy AA5083 possesses medium strength and high ductility and used typically in structural applications, marine, and automotive industries. When compared to fusion welding processes, friction stir welding (FSW) process is an emerging solid state joining process which is best suitable for joining these alloys. The friction stir welding parameters such as tool pin profile, tool rotational speed, welding speed, and tool axial force influence the mechanical properties of the FS welded joints significantly. Dissimilar FS welded joints are fabricated using five different tool pin profiles. Central composite design with four parameters, five levels, and 31 runs is used to conduct the experiments and response surface method (RSM) is employed to develop the model. Mathematical regression models are developed to predict the ultimate tensile strength (UTS) and tensile elongation (TE) of the dissimilar friction stir welded joints of aluminium alloys 2024-T6 and 5083-H321, and they are validated. The effects of the above process parameters and tool pin profile on tensile strength and tensile elongation of dissimilar friction stir welded joints are analysed in detail. Joints fabricated using Tapered Hexagon tool pin profile have the highest tensile strength and tensile elongation, whereas the Straight Cylinder tool pin profile have the lowest tensile strength and tensile elongation. The results are useful to have a better understanding of the effects of process parameters, to fabricate the joints with desired tensile properties, and to automate the FS welding process.     

Environmentally assisted cracking of aluminium alloys

A short review of the stress corrosion cracking (SCC) behaviour of aluminium alloys is given. Mechanisms of environmentally assisted cracking are outlined. For aluminium alloys, in which stress corrosion cracks propagate predominantly along grain boundaries, anodic dissolution and hydrogen embrittlement have been proposed. Transgranular stress corrosion cracking occurring at severe loading conditions has found particular interest concerning localised corrosion‐deformation interactions. Accelerated test methods for assessing the SCC behaviour are described, including the slow strain rate testing technique and the breaking load method. Results of recent studies on environmentally assisted cracking of aluminium alloys are summarised. Most of the work published in the last two decades has been on aluminium‐lithium based alloys and improved high strength Al‐Zn‐Mg‐Cu alloys in corrosion resistant retrogressed and re‐aged tempers.