共查询到20条相似文献,搜索用时 15 毫秒
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Y. Suzuki Z. Maekawa H. Hamada M. Kibune M. Hojo N. Ikuta 《Journal of Materials Science》1992,27(24):6782-6790
The relationship between the interphase consisting of physisorbed and chemisorbed silane on glass fibres and the resultant composite Mode I delamination fracture toughness in glass fibre fabric laminate, was studied. The Mode I interlaminar fracture toughness of the laminate specimen was obtained by using a double cantilever beam (DCB) specimen. The delamination resistance of the laminate specimen finished with two silane concentrations and washed in methanol solvent, is discussed on the basis of the interlaminar fracture toughness. In order to determine the amount of physisorbed and chemisorbed silane on the glass fibre, the amount of total carbon was determined using an analysis instrument. The physisorbed silane migrated into the resin matrix and influenced the mechanical properties and interlaminar fracture of the laminate specimen. The amount of unsaturated polyester resin blended with a silane coupling agent was measured using dynamic mechanical spectroscopy, and a DCB specimen for mechanical properties and fracture toughness. 相似文献
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To enhance the adhesion between the natural fibre and the thermoplastic matrix, a coupling agent of maleic anhydride grafted polypropylene MAPP is applied. In literature, there are different guidelines of the optimum percentage required of MAPP. Therefore, a systematic work is carried out to optimise the MAPP percent with respect to the type of the natural fibre. Different parameters are investigated namely; Coupling agent ratio to the fibre (0%, 6.67%, 10%, 13.3%, 16.67%), coupling agent source, fibre type (flax, hemp, sisal), and fibre content (30%, 50%). Composite is produced using a kneader and the resulting material is assessed mechanically, thermally, microscopically and for water absorption. For different MAPP source and the natural fibre type, optimum MAPP to fibre ratio is found in average to range between 10% and 13.3% according to the investigated property (stiffness, strength and impact). Increase of MAPP is found to decrease the melting temperature. The thermal behaviour is also linked to the copolymer molecular weight. 相似文献
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Y. Suzuki Z. Maekawa H. Hamada A. Yokoyama T. Sugihara M. Hojo 《Journal of Materials Science》1993,28(7):1725-1732
The relationship between the adhesive properties of the interphase of glass fibre/resin and the resultant composite Mode I delamination fracture toughness in glass fibre fabric laminate (GFFL) was studied. The Mode I interlaminar fracture toughness of GFFL was obtained by using a double cantilever beam (DCB) specimen. The delamination resistance of GFFLs which have two silane coupling agents and three concentration finishes is discussed on the basis of interlaminar fracture toughness. The crack propagation behaviour of DCB testing was mainly divided into stable and unstable manners. The fracture toughness and the crack propagation behaviour were dependent on the types and concentration of silane coupling agents. 相似文献
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《Composites》1994,25(7):512-515
The effect of crosslinked structure of silane condensates on the interfacial strength between silane-treated glass fibre and epoxy resin was examined using a dialkoxysilane, γ-aminopropyldimethoxymethylsilane (APDS), and a trialkoxysilane, γ-aminopropyltrimethoxysilane (APTS). Glass fibres were treated with aqueous solutions of APDS, ATPS or mixtures of both to change the silane crosslink density, and then washed with methanol to leave only chemically bonded silane at the surface. As an index of interfacial strength, the interfacial stress transmissibility was determined using a modified single-filament test. The interfacial strength decreased in the order APDS, mixtures of APTS and APDS, and APTS, showing that siloxane crosslinking of the silane condensates reduces the interfacial strength. This result suggests that the crosslinked structure depresses the penetration of the resin into the interphase and hinders reaction between silane organofunctional groups and the resin. In addition, treatment of the glass fibre with the various APDS-APTS mixtures reduced the interfacial strength in all cases, compared with the strength after APDS treatment alone. This indicates that the silane interphases formed in the present system do not lead to the formation of interpenetrating networks with the resin molecules. 相似文献
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有机硅烷偶联剂对聚丙烯酸酯/纳米SiO2复合材料性能的影响 总被引:2,自引:0,他引:2
同步采用无皂乳液聚合法和溶胶-凝胶法制备了聚丙烯酸酯/纳米SiO2复合材料,通过TEM、力学性能、DSC、TG和XRD等检测手段研究了不同有机硅烷偶联剂对聚丙烯酸酯/纳米SiO2复合材料性能的影响.结果表明,分别采用3-甲基丙烯酸氧丙基三甲氧基硅烷(MEMO)和乙烯基三甲氧基硅烷(VTMO)制备的纳米复合材料,力学性能随其用量的增加而同步增强增韧;TEM结果表明,采用MEMO和VTMO制备的聚丙烯酸酯/纳米SiO2复合材料中的纳米SiO2的粒径约20nm,且分布均匀;热性能结果表明,采用乙烯基三乙氧基硅烷(VTEO)制备的纳米复合材料的玻璃化温度(-8.1℃)和热裂解温度(350℃)最高;XRD结果表明,有机硅烷偶联剂的加入降低了纳米复合材料的结晶度. 相似文献
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为改善沥青的物理和老化性能,本文采用γ-(2,3环氧丙氧)丙基三甲氧基硅烷(KH560)对高岭土进行了表面修饰,通过熔融共混法分别制备了高岭土和表面修饰高岭土改性沥青,并对其进行了薄膜加热试验(TFOT)和压力老化容器试验(PAV),测试了高岭土和表面修饰高岭土改性沥青老化前后的物理性能,并利用傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)对高岭土和表面修饰高岭土及其改性沥青老化前后的结构进行了表征。FTIR和XRD分析表明,KH560成功接枝到高岭土表面,但未改变高岭土的晶体结构。相比未修饰高岭土,表面修饰高岭土对沥青软化点和黏度的提高幅度更大,对沥青低温延度的不利影响减弱,TFOT和PAV老化对沥青性能的负面影响降低,并有效抑制了沥青老化后羰基指数的增加,显著改善了沥青的抗热氧老化性能。随着表面修饰高岭土掺量的增加,沥青物理性能和抗老化性能的提升越来越明显。 相似文献
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《Composites Part A》2001,32(5):607-618
The properties of the interphase formed between a glass fibre and a polymer resin have been characterised based on novel techniques, including the nanoindentation and nanoscratch tests and the thermal capacity jump measurement. The variation of interphase thickness affected by differing silane coupling agents is specifically evaluated. The nanoindentation test gives an interphase thickness of approximately 1 μm with large variations between specimens, and is not sensitive enough to identify the effect of different silane agents. The effective interphase thickness measured from the nanoscratch test varies between 0.8 and 1.5 μm depending on the type and concentration of silane agent. The higher is the silane agent concentration, the larger is the interphase thickness. These values are consistent with those measured based on the heat capacity changes in terms of general trend, although the latter technique tends to present slightly higher values. The foregoing observations strongly support the usefulness of the techniques for interphase characterisation. 相似文献
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Polyester resin-quartzite aggregate composites have been investigated for the effect of two silane coupling agents (γ-aminopropyl triethoxy silane andγ-methacryloxy propyl trimethoxy silane) on the mechanical and thermal properties. The integral blend additive method of application of the coupling agent was used in the preparation of the samples. Variation of the thermal stability and the compressive strength with the nature and the content of the silane coupling agent were quite consistent. The properties showed maxima around a certain value of the coupling agent content, which is suggested as the optimum value. Results are also presented on the samples containing an additional filler, namely, the CaCO3. 相似文献
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《Composites Part A》2007,38(8):1852-1859
The influence of silane coupling agents on the microstructure and dielectric behaviour of epoxy/BaTiO3 composites was studied. Epoxy was diluted using tetrahydrofuran as solvent in order to facilitate the mixing step. Methoxy silane was applied onto ceramic particles. Different diluted aqueous solutions with 0.25, 0.35 and 0.50 wt% of silane/BaTiO3 were used. Dipping technique was utilised to obtain composite films. Dielectric measurements were performed from 25 Hz to 1 MHz and from 20 °C to 120 °C. Composites presented good dielectric properties and a strong dependence with the silane concentration. 相似文献
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Titanium nitride (TiN) nano-particles were subjected to graft modification by silane coupling agent (KH-570) via a direct blending method. The hydroxyl groups on the surface of TiN nano-particles can interact with silanol groups [-Si-OCH3] of KH-570 forming an organic coating layer. The covalent bonds (Ti-O-Si) formation was testified by Fourier transform infrared spectra (FTIR) and X-ray photoelectron spectroscopy (XPS). Through transmission electron micrograph (TEM) observations, it was found that KH-570 could improve the dispersibility of nano-TiN particles in ethyl acetate. Thermo gravimetric analysis (TGA) and contact angle measurements indicated that KH-570 molecules were adsorbed or anchored on the surface of nano-TiN particle and the net efficiency of it was 22.76 %, which facilitated to hinder the aggregation of nano-TiN particles. 相似文献
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Role of silane coupling agent and polymeric film former for tailoring glass fiber sizings from tensile strength measurements 总被引:2,自引:0,他引:2
Tensile strengths of differently sized E-glass fibres have been characterised using a bimodal Weibull two parameters cumulative distribution function. By comparing unsized fibres, pure silanes, different film formers, and silane/film former combinations, a comprehensive summary on the healing effect for surface flaws in relation to the type of sizing emulsion has been obtained. The great influence of the film former, which is the main component of the sizing by weight, was shown to affect both the healing of initially occuring flaws in the unsized fibre and the possibility of creating new defects. Besides the single influence of the film former, the synergetic effect of silane and film former polymer has been shown. In fact, the presence of sizing influences both the population of flaws on the fibre surface and the structure of the interphase, which will be created from the impregnation with a polymer matrix. Data from statistics of fracture as a function of the nature of sizings were discussed according to the literature on stress corrosion of E-glass filaments. 相似文献
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