注射成型粘结钕铁硼磁体制造工艺研究

磁体的注射成型是一种高效生产的近净成型技术。详细说明了注射成型粘结钕铁硼磁体用复合粉和磁体的制造工艺及性能测试方法。研究了粘结剂、添加剂的含量以及磁粉装载量对注射成型磁体的加工性能、磁性能及力学性能等的影响规律。并从微观上揭示了其机理。用MQP-B快淬钕铁硼磁粉和尼龙12粘结剂制备出了磁性能Br为0.539 T,Hcb为345.37 k A/m,Hci为681.02 k A/m,(BH)max为47.37 k J/m~3的注射成型钕铁硼磁体。     

流动温压成型黏结钕铁硼/锶铁氧体复合磁体的研究EI北大核心CSCD

采用流动温压成型工艺制备黏结钕铁硼/锶铁氧体复合磁体,研究温压工艺参数对钕铁硼/锶铁氧体复合磁体磁性能的影响。结果表明:随着温压温度、压制时间以及保压压力的提高,黏结复合磁体的磁性能呈现先增大后减小的趋势。流动温压成型参数的选择与黏结剂有关,采用酚醛环氧树脂BPANE8200为黏结剂时,流动温压成型的最佳工艺参数:77℃加载900MPa并保压8min,复合磁体的剩磁B_r、内禀矫顽力H_(cj)以及最大磁能积(BH)max均获得最大值,即Br=522mT,Hcj=740.48kA/m,(BH)max=39.82kJ/m^3。     

粘结剂对粘结钕铁硼/锶铁氧体复合磁体磁性能的影响

为获得磁性能适中的磁体,采用流动温压成型技术制备了各向同性粘结Nd Fe B/锶铁氧体复合磁体.利用振动样品磁强计(VSM)研究了不同粘结剂对粘结Nd Fe B/锶铁氧体复合磁体磁性能的影响.研究表明:环氧值适中的酚醛环氧树脂制备的磁体具有较好的磁性能;当采用环氧值为0.480 mol/100 g酚醛环氧树脂BPANE8200H做粘结剂时,粘结Nd Fe B/锶铁氧体复合磁体获得了最佳的磁性能:Br=0.55 T,Hcj=620.6 k A/m,(BH)max=45.6 k J/m3.在保证磁体磁性能的前提下兼顾力学性能,粘结磁体流动温压成型温度参数的设置必须考虑粘结剂的软化点温度.     

Nd—Fe—B永磁材料的粉末注射成型技术

粉末注射成型技术制备Nd-Fe-B稀土永磁体可以较好地解决Nd-Fe-B磁材的难加工问题，直接制备出具有最终形状的磁体，目前该技术已引起了世界先进的高度重视，其发展及产业化速度非常迅速，本重点介绍了目前采用的几种粉末注射成型用Nd-Fe-B磁粉的制备方法，分析了各种方法及粉末的特点；讨论了粘结剂，改性剂及磁场取向对注射成型Nd-Fe-B粘结磁体和烧结磁体最终磁性能的影响；指出了注射成型Nd-Fe-B磁体的现在和潜在的应用市场，在此基础上，指出了今后开展工作的方向并展望了其发展前景。     

NdH纳米助剂回收制备烧结钕铁硼永磁体的研究

采用NdH纳米掺杂的方法对废旧烧结钕铁硼磁体进行了回收制备。研究了不同NdH纳米粉掺杂量对再制造烧结钕铁硼磁性能的影响。随着NdH纳米粉末掺杂量的增多,烧结磁体矫顽力从926.54 kA/m增加到1 299.87 kA/m;剩磁首先相对稳定在1.296 T,在掺杂量2.0%(质量分数)后,剩磁逐渐下降。与原始磁体相比,2.0%(质量分数)NdH纳米粉掺杂磁体性能最佳,矫顽力回复97.5%,剩磁回复95.9%,磁能积回复89.7%。通过计算,掺杂3.0%(质量分数)NdH纳米粉后,再制造烧结磁体中富钕相体积分数从3.03%增加到5.70%,然而其晶粒尺寸从8.18μm增长至11.68μm。结合微观分析与磁性能,2.0%(质量分数)NdH纳米粉掺杂磁体性能最好。     

粘结NdFeB制备工艺参数的优化研究

采用正交设计法,对粘结NdFeB磁体模压成型的制备工艺参数进行了优化研究.讨论了粒度配比、粘结剂含量、偶联剂含量、成型压力及固化温度对粘结NdFeB磁体磁性能的影响,在此基础上,得出了一套较优的工艺参数.     

烧结钕铁硼磁体的组织结构及合金成分优化研究进展

烧结钕铁硼磁体因具有优异的磁性能、较好的机械加工性和低成本等优势而被广泛应用在现代工业和电子技术领域。然而,随着科技的不断进步,对烧结钕铁硼磁体的磁性能提出了更高要求,高剩磁、高矫顽力、高磁能积磁体成为今后发展的重要趋势。磁体组织结构决定了磁体性能,磁体组织结构又与磁体成分密切相关。成分优化是改善烧结钕铁硼磁体磁性能的有效途径。本文在分析烧结钕铁硼磁体组织结构的基础上,详细梳理了近几十年来烧结钕铁硼磁体组元元素替代和掺杂的研究成果。在此基础上,指出了元素替代和掺杂在改善烧结钕铁硼磁体磁性能中存在的问题及今后的发展方向,为进一步提高烧结钕铁硼磁体磁性能提供理论参考。     

采用SC工艺制备高性能烧结钕铁硼磁体的研究

研究了采用SC(strip casting)工艺制备的高性能烧结钕铁硼磁体。结果表明：速凝薄带主要由厚度约3μm的(2：14：1)相片状晶组成．片状晶之间被厚度0．2～0．5μm的富Nd相薄层隔开，没有α-Fe枝状晶存在。速凝薄带经氢破碎、气流磨、压型、烧结后磁体的永磁性能达到：Br=1．431T，jHe=1022kA／m，(BH)max=387kJ／m3。     

酚醛树脂粘结钕铁硼磁体温压制备技术研究

用温压成型工艺制备了酚醛树脂粘结钕铁硼磁体,通过对磁体密度、剩磁、矫顽力、磁能积和抗弯强度的分析,研究了耦联表面处理对磁粉抗氧化性能的影响及成型工艺对磁体性能的影响.结果表明:偶联处理可以明显提高磁粉的抗氧化能力;在压力为620MPa,温压温度为180℃且不进行二次固化条件下获得了性能最佳的磁体,其密度为6.12g/cm3,抗弯强度为59.25MPa,剩磁为0.6824T,内禀矫顽力为730kA/m,最大磁能积为78.2kJ/m3.     

粘结NdFeB磁体的制备工艺

利用NdFeB 磁粉、聚酰亚胺制备了粘结NdFeB 磁体。研究了磁粉粒度、偶联剂用量、粘结剂用量、成型压力和粘结剂性能对粘结磁体磁性能及力学性能的影响。实验结果表明,合理的粒度配比(粗∶细为33∶67) 、偶联剂用量(磁粉0. 9 %) 、粘结剂用量(磁粉3. 2 %) 、合适的压力(600 MPa) 以及以聚酰亚胺作为粘结剂,可以获得具有较好磁性能和力学性能的粘结NdFeB 磁体。      

High Energy and High Coercivity Sintered NdFeB Magnets by Low Oxygen Process

1. IntroductionSince NdFeB magnets were discovered[ll, theirmagnetic performance has been improved by many researchers. The maximum energy product of sinteredNdFeB magnets has been increased from 240 kJ/m'to 430 kJ/m' by Kaneko et al.[2] in 1993. The maximtun energy product commercially available todayis close to 358 kJ/m'. Because of this high performance of NdFeB products, the applications have increased enormously in the last decade. For example,hard disk drivers (HDD), magnetic reso…     

添加润滑剂对烧结钕铁硼磁体性能的影响

研究了烧结钕铁硼永磁材料的粉末流动性及添加润滑剂对粉末流动性与磁体取向度和磁性能的影响.结果表明:影响松装状态磁粉流动性的主要因素是粉末颗粒团聚,影响密实磁粉流动性的主要因素是颗粒间的摩擦力.添加适量的润滑剂可以防止粉末颗粒团聚、明显地减小摩擦力,改善粉末流动性,提高磁体的取向度、剩磁与磁能积.采用添加润滑剂和橡皮模等静压制成型工艺,批量生产的烧结钕铁硼磁体性能达到:Br=1.457 T,jHc=1148 kA/m(14.43 kOe),(BH)max=408 kJ/m3(51.3 MGOe).     

粉末注射成形技术在烧结NdFeB永磁体制备中的应用

全面介绍了采用注射成形技术制备烧结NdFeB永磁体的工艺过程；总结了粘结剂、磁场取向及成形、脱脂和烧结工艺对最终产品的影响；比较了注射成形和传统粉末冶金压制成形制备的NdFeB磁体的性能；在分析现状的基础上，指出了现阶段存在的问题。     

Properties improvement and structural optimization of sintered NdFeB magnets by non-rare earth compound grain boundary diffusion

Grain boundary diffusion using rare earth (RE)-containing compounds has recently become an effective approach for improving the coercivity and reducing the heavy RE content in sintered NdFeB magnets. Here we report the enhancement of magnetic properties and corrosion resistance of NdFeB magnets by a non-RE compound diffusion process. The Dy-free sintered NdFeB magnets were coated with an MgO layer by magnetron sputtering, followed by solid diffusion heat treatment. With the successful diffusion of MgO into the magnet, the coercivity increasing from 1094 to 1170 kA/m and the maximum energy product increasing from 240 to 261 kJ/m³, together with the enhanced temperature stability and corrosion resistance, have been demonstrated. The underlying mechanisms for these enhancements have been analyzed. Microstructural investigations show that MgO entered mainly into the intergranular regions and modified the composition and structure of the grain boundary phase. The intergranular Nd–O–Fe–Mg phases observed in the MgO diffused magnet contribute to the improved performance. The current non-RE compound grain boundary diffusion process has significance in further minimizing the use of rare earth (RE).     

New kind of NdFeB magnet prepared by spark plasma sintering

We have produced an anisotropic Nd/sub 15.5/Dy/sub 1.0/Fe/sub 72.7/Co/sub 3.0/B/sub 6.8/Al/sub 1.0/ magnet by the spark plasma sintering (SPS) technique and compared it with a magnet of the same composition processed by the conventional sintering method. We investigated magnetic properties, microstructure, and constituents by a B-H loop-line instrument, a scanning electron microscope, and an energy-dispersive X-ray detector, and studied the effects of processing conditions on the magnetic properties, dimensional precision, and density. We also examined the magnet's electrochemical properties in electrolytes and its corrosion behavior in oxidizing environments. We found that the microstructure of the SPS NdFeB magnet is different from that of the conventional one. In the SPS-processed magnet, the grain size is fine and uniform while the distribution of the Nd-rich phase is heterogeneous. The SPS NdFeB magnet has a maximum energy product of 240 kJ/m/sup 3/ and a coercive force of 1260 kA/m. The density of the magnet reaches 7.58 g/cm/sup 3/, and its dimensional precision is about 20 /spl mu/m. The electrochemical properties and the corrosion resistance of the SPS NdFeB magnet are better than those of the conventional one. The SPS process is a promising method for the production of NdFeB magnets with ideal overall performance.     

Magnetic Properties and Thermal Stability of Pr_(1-x)La_xCo_(5-y)Alloys

Pr1-xLaxCo5-y (x=0, 0.15. 0.25, 0.35,1.0, y=0.5, 0.7, 0.9, 1.0) alloys were investigated. The effect of the variation of x and y on magnetic properties and thermal stability of the alloys were studied. The magnetic properties for the Pr0.85La0.15Co4.3 and Pr0.75La0.25Co4.1 magnets are iHc=368 kA/m, Br=0.91 T, (BH)max=145.6 kJ/m3, αBr=-0.03%/℃ and iHc=568 kA/m,Br=0.8 T, (BH)max=127.2 kJ/m3,αBr,=-0.06%/℃, respectively The phase structures of as-cast alloys and magnets were investigated     

含Ti和C的纳米复合Nd2Fe14B／α—Fe磁体研究

研究Ti和C添加对Nd9.4Fe79.6B11合金磁性能的影响规律。结果表明:Ti和C联合添加能够在不降低合金剩磁的情况下显著提高合金的矫顽力,最佳工艺条件下制备出的Nd9.4Fe75.6Ti4B10.5C0.5合金薄带的剩磁Br=0.91T,矫顽力Hcj=975.6kA/m,磁能积(BH)max=135.4kJ/m3。在磁体密度为6.1g/cm3时,黏结Nd9.4Fe75.6Ti4B10.5C0.5磁体剩磁Br=0.68T,内禀矫顽力Hcj=975kA/m,最大磁能积(BH)max=76 kJ/m3,性能和MQ-D磁粉制备的黏结磁体性能相当,具有低价位高性能的特点。