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明艳 《现代塑料加工应用》2002,14(5):24-27
介绍了2类原位复合成纤增强体系,分别讨论了它们的成纤机理,影响成纤的条件及组分间的相互影响;并概要地叙述了目前国内外在这些领域内所取得的进展。 相似文献
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简述了热塑性聚合物共混物原位复合材料的研究进展及意义,总结了如原位复合材料的化学组成、物理特性及成型工艺对分散相“原位”成纤及其性能的影响,重点叙述了相容性对材料力学性能及拉伸、剪切作用对分散相原位成纤的影响.并提出了,磁场作用促进共混体系中分散相聚合物分子链取向及与流场协同作用的思路。 相似文献
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以高密度聚乙烯(HDPE)和回收聚对苯二甲酸乙二醇酯(r-PET)为原料,通过反应挤出、冷拉伸、退火工艺制备了HDPE/r-PET原位微纤物。研究了扫描电镜(SEM)的制样方法即用液氮冷冻、脆断样品、聚四氟乙烯带包覆、在沸腾的二甲苯中刻蚀7~10min和不同r-PET用量、不同拉伸比制备出的系列HDPE/r-PET原位微纤物的力学性能。结果表明,通过SEM可清晰地看到形成的微纤,原位微纤物的拉伸强度和冲击强度都随拉伸比的增大而增大;r-PET质量分数为15%时,原位微纤物的拉伸强度和无缺口冲击强度达到最大值;HDPE/r-PET原位微纤物的适宜注塑温度为210℃。 相似文献
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TP/TP原位微纤化共混物的研究进展 总被引:1,自引:0,他引:1
简要介绍了热塑性聚合物(TP)/热塑性聚合物原位微纤化共混物的产生、制备方法,并着重讨论了原位成纤的机理、影响微纤化共混物材料特性(形态、流变性、结晶性、力学性能等)的因素,对该材料的发展进行了展望。 相似文献
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通过与热液晶原位复合材料的对比,系统阐述了具有柔性分子链的普通热塑性树脂就地成纤增强增韧高聚物的国仙外研究进展,着重对近几年来该技术在成纤机理、控制因素以及结构与性能等方面的研究成果作了初步总结。 相似文献
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PP/UHMWPE原位成纤复合材料的混炼及成型工艺研究 总被引:13,自引:3,他引:10
采用超高分子量聚乙烯(UHMWPE)原位成纤增强、增韧聚丙烯(PP)。讨论了混炼剪切力、成型冷却方式和UHMWPE熔体熔点粘度对材料力学性能的影响。发现提高剪切力,加快冷却速度均有利于力学性能的提高,配比为90/10的PP/UHMWPE的缺口冲击强度、拉伸强度和断裂伸长率可达88.6kJ/m^2、45.1MPa和570%,分别是PP-1330的3.5倍、1.5倍和2.5倍;而UHMWPE相对分子擀 相似文献
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《Ceramics International》2017,43(9):6885-6890
The in situ elastic modulus and strength distribution of carbon fibers in C/SiC composites were studied. To obtain the in situ property data, fibers were heat treated according to the fabrication process of C/SiC composites. Tensile tests were performed on the single fibers and fiber bundles. The equivalent in situ modulus and strength were proposed considering the loose and unparallel fibers in the composites. The experimental and numerical results showed that the equivalent elastic modulus and average strength of in situ fibers are much lower than that of the original fibers. In addition, the equivalent strength distribution of in situ fibers is more dispersive. 相似文献
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Peigang He Lingyu Jia Guoru Ma Ruifei Wang Jingkun Yuan Xiaoming Duan Zhihua Yang Dechang Jia 《Ceramics International》2018,44(9):10726-10734
In this paper, phosphate-based geopolymer composites are studied and the effects of different carbon fiber felt contents (from 20?vol% to 40?vol%) on the phase composition, microstructure, mechanical properties and microwave absorbent properties from 2?GHz to 18?GHz frequency band of the composites were systematically investigated. The results indicate that with the increase in carbon fiber felt contents, flexural strength and Young's modulus of the composites gradually increased. The fracture mode of the composite changed from brittle failure to ductile failure with the presence of carbon fiber felt. It was mainly due to the micropore deformation as well as fibers pulling-out and the crack deflection, which consumed most fracture energy. However, microwave absorbent performance tended to increase at first and then decreased as the carbon fiber felt content ramping up. When the content of carbon fiber felt in the composite was 26.7?vol%, the composite showed the best microwave absorbent performance and the reflection loss reached to ??59.3?dB. It is mainly attributed to the Debye polarization of the carbon fibers and the interface polarization between fibers and the matrix. 相似文献
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The construction and examination of meso-structural finite element models of a Chemical-Vapor-Infiltrated (CVI) C/SiC composite is carried out based on X-ray microtomography digital images (IB-FEM). The accurate meso-structural features of the C/SiC composites, which are consisted of carbon fiber tows and CVI-SiC matrix, in particular the cavity defects, are reconstructed. With the IB-FEM, the damage evolution and fracture behaviors of the C/SiC composite are investigated. At the same time, an in situ tensile test is applied to the C/SiC composite under a CT real-time quantitative imaging system, aiming to investigate the damage and failure features of the material as well as to verify the IB-FEM. The IB-FEM results indicate that material damage initially occur at the defects, followed by propagating toward the fiber-tow/SiC-matrix interfaces, ultimately, combined into macro-cracks, which is in good agreement with the in situ CT experiment results. 相似文献
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Polyaniline (PANI)/epoxy composites with different polyaniline (PANI) contents were successfully developed by in situ polymerization of aniline salt protonated with camphorsulfonic acid within epoxy matrices and fully characterized. The influence of PANI loading levels on various properties was also explored. Dielectric and electrical properties of PANI/epoxy composites were studied for samples in parallel plate configuration. A PANI/epoxy composite prepared in this fashion reached a high dielectric constant close to 3000, a dielectric loss tangent less than 0.5 at room temperature and 10 kHz. The hardener type was also found as a critical parameter for the dielectric properties of PANI/epoxy composites. The distribution of the conductive element clusters within the polymer matrix was studied by SEM and correlated to the dielectric behavior of the composite films. 相似文献
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Interfacial in situ polymerization of single wall carbon nanotube/nylon 6,6 nanocomposites 总被引:1,自引:0,他引:1
An interfacial polymerization method for nylon 6,6 was adapted to produce nanocomposites with single wall carbon nanotubes (SWNT) via in situ polymerization. SWNT were incorporated in purified, functionalized or surfactant stabilized forms. The functionalization of SWNT was characterized by FTIR, Raman spectroscopy and TGA and the SWNT dispersion was characterized by optical microscopy before and after the in situ polymerization. SWNT functionalization and surfactant stabilization improved the nanotube dispersion in solvents but only functionalized SWNT showed a good dispersion in composites, whereas purified and surfactant stabilized SWNT resulted in poor dispersion and nanotube agglomeration. Weak shear flow induced SWNT flocculation in these nanocomposites. The electrical and mechanical properties of the SWNT/nylon nanocomposites are briefly discussed in terms of SWNT loading, dispersion, length and type of functionalization. 相似文献
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Ayman S. Al-Hussaini 《Polymer-Plastics Technology and Engineering》2015,54(1):61-67
Terpolymers of aniline, anthranilic acid and o-phenylenediamine/Hydrophilic bentonite composites were synthesized using a 1:1:1 molar ratio of the respective monomers with different percentages of clay via modified in situ chemical terpolymerization. The spectral characteristics upon incorporation of anthranilic acid units into the copoly(aniline o-phenylenediamine) backbone in absence and in presence of bentonite nanoparticles were investigated. Moreover, terpolymer/bentonite composites were thermally more stable than pure terpolymer under nonoxidative condition. On the basis of surface morphological studies of terpolymer composites, a platy network texture can be explained, and it can be clearly seen in the SEM photomicrographs. 相似文献