Particle launch to 19 km/s for micro-meteoroid simulation using enhanced three-stage light gas gun hypervelocity launcher techniques

Particle launch experiments were performed to study application of the enhanced hypervelocity launcher (EHVL), i.e. the third-stage addition to the two-stage gun, for launching micron to millimeter sized particulates at velocities unobtainable with a standard two-stage light gas gun launch. Three types of particles or fliers were tested along with several barrel designs. For micron scale particles fine-grain polycrystalline ceramics were impacted and fractured, launching particulate clouds at velocities of 15 km/s. Multiple titanium particles 400 μm diameter embedded in plastic were “shotgun” launched to velocities of 10 km/s. Flier plates of 3 mm diameter by 1 mm thick Ti6Al4V were launched to 19 km/s. All experiments used a second-stage projectile with graded density facing impacting a flier in an impact generated acceleration reservoir. This paper describes the modification and adaptation of the Sandia EHVL to provide micrometeoroid simulation capabilities.     

A novel gamma-ray imaging concept using “edge-on” microchannel plate detector

The “edge-on” illuminated microchannel plate (MCP) position-sensitive detector (PSD) is used for gamma-ray imaging for the first time. The superior position resolution of the MCP is combined with high detection efficiency due to the “edge-on” illumination mode. The results of imaging a 15 μCi ¹³⁷Cs source (662 keV quantum energy) are presented.     

Spectroscopic evidence of inhomogeneous distribution of Nd in YVO4, YPO4 and YAsO4 crystals

Nd³⁺ : YVO₄ is one of the most interesting laser hosts for micro and diode-pumped solid state lasers. We have studied magnetic and optical properties of Nd³⁺ in three zircon type crystals YMO₄ (M=V, As, P). In particular, Nd³⁺ ions exhibit in the three hosts a multisite character observed in the absorption and emission spectra. However, the emission and its dynamics are strongly dependant on the reabsorption mechanisms. In Nd : YVO₄, single crystals containing 7 ± 1 × 10¹⁸ Nd³⁺ ions/cm³, the lifetime is 95 ± 2 μs in good agreement with the calculated radiative lifetime. Electron Paramagnetic Resonance (EPR) measurements are performed to identify the nature of the different substitution sites for Nd³⁺ ions. Nd³⁺ ions are found to be inhomogeneously distributed in tetragonal D_2d symmetry sites, in isolated ions, “shallow clusters” and pairs. Proportions of the different local environments depend on the total neodymium concentration. For instance, 15% of the Nd³⁺ ions are gathered in Nd³⁺–Nd³⁺ pairs for 7.2 ± 0.2 × 10¹⁹ Nd³⁺ ions/cm³.     

Scaling flow fields from the impact of thin plates

A dimensional analysis is performed to obtain velocity scaling relationships for the perforation of thin plates. The approach used is an extension of Dienes and Walsh's “late-stage equivalence” and Holsapple and Schmidt's “coupling parameter” concepts, used to simplify velocity scaling of impact phenomena. The coupling parameter C for plate perforation, is shown to have the form C=dU^μδ^ν for the perforation of thick plates and the form C=dU^μδ^ν f(t/d) for the perforation of thin plates (d is the projectile diameter, t is the plate thickness, U is the impact velocity and δ is the projectile density). It is shown that μ=1/2 for momentum scaling and μ=1 for energy scaling, however, from scaled hydrocode output it is found that, for aluminum impacting aluminum, the value of μ is equal to 0.83±0.03, which is neither energy nor momentum scaling. It is also shown that velocity scaling of thick plate perforation, using the same materials in the model and prototype and the same t/d, is not possible. An example of velocity scaling hydrocode output is given where the radial particle velocity wave profiles from the model calculation at U=55.6km/s and t/d=0.675 are similar to those from the prototype calculation with U=100km/s and t/d=1.08.     

The chemistry of micrometeoroid and space debris remnants captured on hubble space telescope solar cells

Prior to the retrieval in 1993 from low Earth orbit (LEO), the “—V2” Solar Array wing of the Hubble Space Telescope was exposed to hypervelocity impacts (micrometre to millimetre scale) from both micrometeoroids and space debris. The initial survey of the damage (100–3500μm diameter sized craters) identified that micrometeoroid remnants dominated the flux in the 100–1000μm size regime, with debris dominating>1000μm. These residues were composed of remnants of silicate minerals, calcite, metal sulfides and metals that often appeared as complex poly-mineralic melts within melt pits. A further survey of 10–100μm diameter craters identified that the most common chemistry was space debris with the crossover from meteoroids to debris being at around 30μm D_CO. Residues include remnants of specialised steels and paint fragments but the dominant type is aluminium and aluminium oxide, which are almost certainly remnants of solid rocket motor operations. It is found that the relative contribution of debris as a function of size, agrees remarkably with a prediction derived using flux data from Long Duration Exposure Facility and a meteoroid model.     

X-ray imaging with “edge-on” microchannel plate detector: first experimental results

A novel scanning slit X-ray imaging system based on an “edge-on” microchannel plate detector was developed and tested. Images were acquired at 50 kV(p) X-ray tube voltage with a limiting spatial resolution of 7 lp/mm. The pixel noise was measured to be 0.3 count/pixel/s for a 50×70 μm² pixel size. This photon counting detector can be considered to be virtually noise free.     

Pyroelectric properties of BST/PLT composite thick films with addition of xPbO–(1 − x)B2O3 glass

The Ba_xSr_1−xTiO₃ (BST)/Pb_1−xLa_xTiO₃ (PLT) composite thick films (20 μm) with 12 mol% amount of xPbO–(1 − x)B₂O₃ glass additives (x = 0.2, 0.35, 0.5, 0.65 and 0.8) have been prepared by screen-printing the paste onto the alumina substrates with silver bottom electrode. X-ray diffraction (XRD), scanning electron microscope (SEM) and an impedance analyzer and an electrometer were used to analyze the phase structures, morphologies and dielectric and pyroelectric properties of the composite thick films, respectively. The wetting and infiltration of the liquid phase on the particles results in the densification of the composite thick films sintered at 750 °C. Nice porous structure formed in the composite thick films with xPbO–(1 − x)B₂O₃ glass as the PbO content (x) is 0.5 ≥ x ≥ 0.35, while dense structure formed in these thick films as the PbO content (x) is 0.8 ≥ x ≥ 0.65. The volatilization of the PbO in PLT and the interdiffusion between the PLT and the glass lead to the reduction of the c-axis of the PLT phase. The operating temperature range of our composite thick films is 0–200 °C. At room temperature (20 °C), the BST/PLT composite thick films with 0.35PbO–0.65B₂O₃ glass additives provided low heat capacity and good pyroelectric figure-of-merit because of their porous structure. The pyroelectric coefficient and figure-of-merit F_D are 364 μC/(m² K) and 14.3 μPa^−1/2, respectively. These good pyroelectric properties as well as being able to produce low-cost devices make this kind of thick films a promising candidate for high-performance pyroelectric applications.     

Semi-solid processing of ultrahigh-carbon steel castings

Semi-solid processing using cooling plate technique was developed to produce a high quality ultrahigh-carbon steel (UHCS) components. Microstructure and mechanical properties were investigated as a function of fraction of solid. The microstructure of UHCS was improved using semi-solid processing. A unique homogenized microstructure comprised of fine particles grain size (200–100 μm) was obtained which totally differs from that obtained by ordinary UHCS casting (520 μm particle grain size). Tensile strength of as-cast and heat treated semi-solid processed UHCS is relatively high compared with ordinary one. Both the tensile strength and elongation closely connect with the particle grain size and cementite network changed with fraction of solid. Increasing fraction of solid increases hardness values, which is attributed to the fine and homogenous structure by semi-solid processing.     

Relationship Between Particle Size and Dissolution Rate of Bulk Powders and Sieving Characterized Fractions of two Qualities of Orthoboric Acid

We have carried out a study of the particle size distribution and aqueous dissolution rate of two commercially available qualities of orthoboric acid, labeled “crystal” (ABC) and “powder” (ABP). In a previous work, we have shown that the two commercial qualities of orthoboric acid chosen as model compound (“powder” and “crystal”) are related to the same crystal network in spite of their dvferent names. However, these two qualities have very different size particle distributions, as previously determined by sieving and confirmed by the present laser light scattering study. Dissolution testing is performed under sink conditions and show that the bulk ABC quality dissolves far more rapidly that the bulk ABP quality, For each quality, dissolution rates of four sieved particle size fractions (0-90 μm; 90-125 μm; 125-180 μm; 180-250 μm) were compared. Concerning the ABC quality, comparisons were also done with three other particles size fractions: 250-355 μm, 355-500 μm, and 500-710 μm. This study used the dQ/dt versus t profile. Dissolution profiles of the fractions enclosing particles with a size superior to 125 μm are very close. On the other hand, fractions enclosing particles with a size smaller than 90 μm present a different profile and a slower rate of dissolution.     

Optimum thickness of carbon stripper foils in tandem accelerator in view of transmission and lifetime

Optimum thickness of charge stripper foils installed at the terminal of a tandem accelerator has been investigated from the view of (1) charge stripping effect, (2) transmission of ions through accelerator, (3) lifetime of foils for the irradiation of ions. For this purpose, measurements have been done for (a) transmission of H, Li, O, Br and Au ions, passing through 12 UD Pelletron tandem accelerator for carbon stripper foils of 1.8–19.5 μg/cm² thickness, at terminal voltages of 5 and 10 MV, and (b) lifetime of 2–15 μg/cm² thick Tanashi foils developed by Sugai by irradiating Au ions at the terminal voltage of 10 MV. The results obtained are as follows: (a) From the view of above items (1) and (2), the optimum thickness of foils is 10 μg/cm² for ions of Z=1, several μg/cm² for Z=8, and less than a few μg/cm² for heavier ions. (b) From the view of item (3), the lifetime of Tanashi foils by means of new arc-discharge method is demonstrated to be much longer than that of commercial foils for foils thicker than about 5 μg/cm² thick. This superiority rapidly decreases with decreasing foil thickness, and at around 2 μg/cm², the lifetime of Tanashi foils is at the most 2.4 times longer than that of commercial foils.     

Effects of cement size distribution on capillary pore structure of the simulated cement paste

The evolution of tricalcium silicate (C₃S) microstructure during hydration is tri-dimensionally simulated based on an “Integrated Particle Kinetics Model”. The hydration degree, the contact surfaces between the hydrated particles, the hydraulic radius and the capillary pore size distribution of the simulated cement paste at various degrees of hydration are calculated. Three examples of the C₃S microstructure development with different size distributions are presented. The effects of the cement size distribution on pore structure of cement paste are demonstrated and the results are discussed. In these examples, the cement size distribution varies between 3–40, 5–40 and 10–40 μm, respectively.     

Demonstration of feasibility of operating a silicon ZIP detector with 20 eV threshold

100-g silicon detectors (known as “ZIPs,” Z-resolving Ionization and Phonon detectors) developed by the Cryogenic Dark Matter Search Experiment have been tested at charge bias voltages of up to 200 V/cm, significantly above their usual operating range (3–6 V/cm). Thermal gain factors in excess of 50 were observed due to the primary ionization drifting in the large applied field, with only minimal increase in phonon noise. The observed thermal gain corresponds to an intrinsic threshold of 20 eV, resulting in detectors that have direct application for use in a neutrino magnetic moment measurement based on a 40-MCi tritium source.     

Growth and structure in abalone shell

The growth and self-assembly of aragonitic calcium carbonate found in the shell of abalone (Haliotis) is described. This was accomplished through the close examination of laboratory-grown flat pearl samples and cross-sectional slices of the nacreous shell. Further understanding of the sequenced assembly has been obtained. It has been confirmed that the growth of the aragonite component of the composite occurs by the successive nucleation of aragonite crystals and their arrest by means of a protein-mediated mechanism; it takes place in the “Christmas-tree pattern” [Nature 49 (1994) 371]. It is shown that the protein layer is virtually absent where plates on a same plane abut (along lateral surfaces of tiles). This suggests a mechanism of c-axis aragonite growth arrest by the deposition of a protein layer of approximately 20–30 nm that is periodically activated and determines the thickness of the aragonite platelets, which are remarkably constant (0.5 μm). This platelet size was measured for animals with shell diameters of 10, 50, and 200 mm and was found to be constant. The overall growth process is expressed in terms of parameters incorporating the anisotropy of growth velocity in aragonite (V_c, the velocity along c axis, and V_ab, the velocity in basal plane). Comparison of laboratory-raised and naturally-grown abalone indicates growth regulated by the level of proteinaceous saturation. Naturally-grown abalone exhibits mesolayers (growth bands) 0.3 mm apart; it is proposed that they result from seasonal interruptions in feeding patterns, creating thicker (10–20 μm) layers of protein. These mesolayers play a critical role in the mechanical properties, and are powerful crack deflectors. The viscoplastic deformation of the organic inter-tile layers is responsible for the significant improvement of tensile strength over the tensile strength of monolithic aragonite.     

Poly(vinyl pyridine-poly ethylene glycol methacrylate-ethylene glycol dimethacrylate) beads for heavy metal removal

Poly(vinyl pyridine-poly ethylene glycol methacrylate-ethylene glycol dimethacrylate) [poly(VP-PEGMA-EGDMA)] beads with an average size of 30–100 μm were prepared by suspension polymerization. Poly(VP-PEGMA-EGDMA) beads were characterized by swelling studies, scanning electron microscopy (SEM), elemental analysis, Fourier Transform Infrared Spectroscopy (FTIR). The beads with a swelling ratio of 65% were used for the heavy metal removal studies. Chelation capacity of the beads for the selected metal ions, i.e., Pb(II), Cd(II), Cr(III) and Cu(II) were investigated in aqueous media containing different amounts of these ions (5–80 mg/l) and at different pH values (2.0–10.0). The maximum chelation capacities of the poly(VP-PEGMA-EGDMA) beads were 18.23 mg/g for Pb(II), 16.50 mg/g for Cd(II), 17.38 mg/g for Cr(III) and 18.25 mg/g for Cu(II). The affinity order on mass basis was observed as follows: Cu(II) > Pb(II) > Cr(III) > Cd(II). pH significantly affected the chelation capacity of VP incorporated beads. Heavy metal adsorption on the poly(PEGMA-EGDMA) control microspheres was negligible. Regeneration of the chelating beads was easily performed with 0.1 M HNO₃. It was shown that these beads can be used effectively for heavy metal removal from aqueous solutions with repeatedly adsorption–desorption operations. These features show that poly(VP-PEGMA-EGDMA) beads are potential candidate sorbent for heavy metal removal.     

Microstructures, densification and mechanical properties of TiC–Al2O3–Al composite by field-activated combustion synthesis

Dense TiC–Al₂O₃–Al composite was prepared with Al, C and TiO₂ powders by means of electric field-activated combustion synthesis and infiltration of the molten metal (here Al) into the synthesized TiC–Al₂O₃ ceramic. An external electric field can effectively improve the adiabatic combustion temperature of the reactive system and overcome the thermodynamic limitation of reaction with x < 10 mol. Thereby, it can induce a self-sustaining combustion synthesis process. During the formation of Al₂O₃–TiC–Al composite, Al is molten first, and reacted with TiO₂ to form Al₂O₃, followed by the formation of TiC through the reaction between the displaced Ti and C. Highly dense TiC–Al₂O₃–Al with relative density of up to 92.5% was directly fabricated with the application of a 14 mol excess Al content and a 25 V cm⁻¹ field strength, in which TiC and Al₂O₃ particles possess fine-structured sizes of 0.2–1.0 μm, with uniform distribution in metal Al. The hardness, bending strength and fracture toughness of the synthesized TiC–Al₂O₃–Al composite are 56.5 GPa, 531 MPa and 10.96 MPa m^1/2, respectively.     

Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound: hydrazine 3-nitro-1,2,4-triazol-5-one complex

An optimized and validated spectrophotometric method has been developed for the determination of uranyl ion in the presence of other metal ions. The method is based on the chelation of uranyl ion with meloxicam via β-diketone moiety to produce a yellow colored complex, which absorbs maximally at 398 nm. Beer's law is obeyed in the concentration range of 5–60 μg/mL with apparent molar absorptivity and Sandell's sensitivity of 5.02 × 10⁴ L/mol/cm and 0.1 μg/cm²/0.001 absorbance unit, respectively. The method has been successfully applied for the determination of uranyl ion in synthetic mixture and soil samples. Results of analysis were statistically compared with those obtained by Currah's spectrophotometric method showing acceptable recovery and precision.     

Growth of lithium doped silver niobate single crystals and their piezoelectric properties

Lithium doped silver niobate (Ag_1−xLi_xNbO₃, 0 < x < 0.1) is one of the candidate materials for lead-free piezoelectric materials. In this study, Ag_1−xLi_xNbO₃ single crystals were successfully grown by a slow cooling method. Crystal structure was assigned to perovskite-type orthorhombic (monoclinic) phase. Dielectric properties were measured as a function of temperature. As a result, with increasing lithium contents, the phase transition at around 60 °C was shifted to lower temperature while the phase transition at around 400 °C was shifted to higher temperature. On the basis of these peak shifts, the lithium contents in Ag_1−xLi_xNbO₃ single crystals were determined. Moreover, P–E hysteresis measurement revealed that pure silver niobate crystal was weak ferroelectrics with P_r of 0.095 μC/cm² while Ag_0.9Li_0.1NbO₃ (ALN10) crystal was normal ferroelectrics with P_r of 10.68 μC/cm². About this ALN10 crystal, polling treatment was performed and finally piezoelectric properties were measured. As a result, high electromechanical coupling coefficient k₃₁ over 70% was observed.     

Effect of Particle Size on Deformation and Compaction Characteristics of Ascorbic acid and Potassium Chloride: Neat and Granulated Drug

Deformation and compaction characteristics of two soluble drugs, ascorbic acid and potassium chloride, were investigated. Five different particle size fractions of ascorbic acid with mean particle size (d₅₀) ranging from 30-300μm and four different particle size fractions of potassium chloride with d₅₀ ranging from 20-400 μm were selected in the study. The compaction behavior of the drug substances as neat drugs or as granulated drugs were evaluated on both a Carver press and an instrumented single-punch tablet press. The results clearly show that mean particle size of the drug substances plays an important role in their compactibility. Intrinsic compactibility of both drug substances was slightly improved with increased particle size. Granulations of the drugs with polyvinyl pyrrolidone significantly improved their compactibility. However, this effect was more pronounced in the drug substance with finer particle size. The Heckel plots indicate that deformation characteristics of both granulated drugs were related to their original mean particle sizes. The granulations prepared from the coarser particle size (d₅₀ 250 μm to 400 μm) underwent two stages of deformation, so-called “brittle fracture” and “plastic deformation”. While the granulations prepared from the finer particle size predoninantly underwent “plastic deformation”. The results indicated that the plastic deformation of both granulated drugs was progressively enhanced whilst fragmentation of particles was correspondingly reduced as the particle size of the drugs was decreased. Scanning electron photomicrographs indicated that the granulation process changed the surface morphology of the drug particles imparting more “microirregularities” or “defects”, thereby providing greater “interparticulate bonding” as compared with the neat drugs. Optimum particle size range of ascorbic acid and potassium chloride for satisfactory compactibility was found to be 30-40 μm and 20-40 μm, respectively. The present study demonstrates the importance of selecting the appropriate particle size of drug for the development of tablet dosage forms.     

Preparation and characterization of gold-coated silver triangular platelets in nanometer scale

Colloids of triangular silver platelets and the platelets coated with a layer of gold have been prepared and analyzed by dynamic light scattering (DLS), transmission electron microscopy (TEM), high-resolution electron microscopy (HRTEM), ultraviolet-visible spectroscopy (UV–vis). The particle size distribution measured by DLS indicates the Ostwald ripening process in evolution of triangles is fed by small spherical particles during light illumination. The shape of most particles is a truncated equilateral triangle and the degree of truncation decreases as the size increases. Triangular platelets are of edge length 50–60 nm and thickness 6–10 nm. The edge length increases to 60–90 nm after depositing a gold layer. To preserve the triangular geometry, a gold layer of thickness less than 5 nm is preferred. The epitaxial nature of gold grown on the 1 1 1 planes of the silver crystal is clearly illustrated in HRTEM images when the thickness of gold is less than 1 or 2 nm. A moiré fringe is usually observed when the Au thickness is higher than 5 nm. The moiré fringe is simulated by rotating two overlapped lattices of the same spacing. The peak position of in-plane dipole resonance at 680 nm is sensitive to the degree of truncation of silver triangle. It shifts towards 615 nm owing to corner rounding by the heat. The gold coating broadens and shifts the peak of in-plane resonance toward shorter wavelengths, hence the cool blue color changes into a warmer color.     

Sol–gel alumina environmental barrier coatings for SiC grit

SiO₂ surface film is insufficient to protect SiC from the oxidation at widely varying partial pressures of oxygen, in particular in the presence of water vapor (e.g. in gas turbines) and also in other environments, e.g. during brazing for hard “tipping” of turbine blades. This work demonstrates that sol–gel alumina, coated on 0.5 mm coarse SiC grit, may form an acceptable, up to 10 μm thick “environmental barrier coating” EBC for some of these applications. The sol–gel has advantages over other methods (such as CVD) is the simplicity and low cost. We have used NH₄OH pre-treatment to hydroxylate surface of SiC prior to applying alumina coating. Such modified SiC/SiO₂ surface helped to deposit the positively charged alumina sol, and thus allowed to build thick coatings on the SiC grit. There is some indication that these coatings partially convert to mullite through reaction at the interface with the native silica on SiC. Oxidation resistance tests at 1200 °C were performed to show effectiveness of such coated SiC grit.