Natural brine solar pond: an experimental study

The South East of Tunisia is a sunny region. This area contains many mineral reserves of natural brine, which currently are not well exploited. These reserves are estimated to several millions of cubic metres. The abundance of solar energy and salt has led us to test the collection and storage of solar energy by a salt gradient solar pond. A small laboratory solar pond of dimensions 2 m×2 m×1 m, excavated from the ground, has been constructed at ENIT (National School of Engineers of Tunis). The salt utilised in the pond is a natural brine which comes from south of Tunisia. Temperature and solar radiation measurements have been carried out over 8 weeks to evaluate the efficiency of this pond.     

Effects of porous media on thermal and salt diffusion of solar pond

Laboratory and field experiments were carried out along with numerical simulations in this paper to study the effects of porous media on thermal and salt diffusion of the solar ponds. From our laboratory experiments simulating heat transfer inside a solar pond, it is shown that the addition of porous media to the bottom of a solar pond could help enhance its heat insulation effect. The experiment on salt diffusion indicates that the upward diffusion of the salt is slowed down when the porous media are added, which helps maintain the salt gradient. Our field experiments on two small-scaled solar ponds indicate that when porous media are added, the temperature in the lower convective zone (LCZ) of the solar pond is increased. It is also found that the increase in turbidity is repressed by porous media during the replenishment of the salt to the LCZ. Thermal diffusivities and conductivities of brine layers with porous media such as pebble and slag were also respectively measured in this paper based on the unsteady heat conducting principles of a semi-infinite body. These measured thermal properties were then used in our numerical simulations on the effect of porous media on thermal performance of a solar pond. Our simulation results show that brine layer with porous media plays more positive role in heat insulation effect when thermal conductivity of the ground is big. On the other hand, when the ground has a very small thermal conductivity, the performance of solar pond might be deteriorated and total heat storage quantity of solar pond might be reduced by brine layer with porous media.     

Experimental study of natural brine solar ponds in Tibet

A salinity gradient solar pond (SGSP) is a simple and effective way of capturing and storing solar energy. The Qinghai-Tibet Plateau has very good solar energy resources and very rich salt lake brine resources. It lacks energy for its mineral processes and is therefore an ideal location for the development and operation of solar ponds. In China, solar ponds have been widely applied for aquaculture, in the production of Glauber’s salt and in the production of lithium carbonate from salt lake. As part of an experimental study, a SGSP using the natural brine of Zabuye salt lake in the Tibet plateau has been constructed. The pond has an area of 2500 m² and is 1.9 m deep. The solar pond started operation in spring when the ambient temperature was very low and has operated steadily for 105 days, with the LCZ temperature varying between 20 and 40 °C. During the experimental study, the lower convective zone (LCZ) of the pond reached a maximum temperature of 39.1 °C. The results show that solar ponds can be operated successfully at the Qinghai-Tibet plateau and can be applied to the production of minerals.     

A one-dimensional numerical study of the salt diffusion in a salinity-gradient solar pond

A one-dimensional transient mathematical model is used for the study of the salt diffusion and stability of the density gradient in a solar pond. A finite difference method with a diffusion coefficient dependent on both temperature and salt concentration is used to solve the salt diffusion equation. On the basis of simple considerations we analyze the influence of the salinity-gradient thickness on the useful energy which can be withdrawn from the bottom layer of the solar pond. Finally some considerations on the effect of the velocity of injected brine in rising solar ponds are presented, making use of the Rayleigh analysis of the small perturbations in order to study the stability of the system.     

磁悬浮液体密度计及其标定

改进了一种利用磁悬浮和霍耳效应的液体密度计及其标定方法，描述了该密度计的结构，给出了分段拟合二变量实验曲线的标定方法。这种密度计适用于在太阳池中连续地测量不同深度处盐水的浓度和密度。计算表明，在太阳池中可能出现的温度和盐浓度的范围内，标定结果与实验数据精确相符。     

Towards the design of low maintenance salinity gradient solar ponds

Applications of simple methods to reduce the maintenance of a small solar pond are discussed in this paper. It was found that floating rings along with continuous surface flushing could effectively control and maintain a relatively thin upper convective layer. A novel system of salt replenishment (a salt charger) is introduced. It is shown that the application of the proposed system is capable of controlling the position of the lower interface. Criteria governing the design of a salt-charger for a salinity-gradient solar pond are developed theoretically and verified experimentally. The design procedures are presented. Experiences relating to the utilization of brine shrimps to improve the transparency of the pond are described.     

The effect of thermodiffusion on the stability of a salinity gradient solar pond

A one-dimensional mathematical model is used for the study of the NaCl diffusion in a salinity-gradient solar pond. The model takes into account the effect of the thermodiffusion, or Soret effect, and also the possibility of injection of concentrated brine at the bottom of the salinity-gradient zone of the solar pond. The model results show that the thermodiffusion moves in the same direction of the molecular diffusion process, thus contributing to destabilize the salinity-gradient layer. This effect can be a significant contribution to the salt diffusion (over 10%), when the temperature gradient and salt concentration are high, like at the bottom of the salinity-gradient zone.     

Maintenance strategy for a salt gradient solar pond coupled with an evaporation pond

In a previous study, the authors presented a simple mathematical model for predicting the ratio of the evaporation pond area to that of a salt gradient solar pond area. The evaporation pond idea provides a very attractive method of salt recycling by evaporation, especially in areas of high evaporation and low rates of rain as it is the case for North Africa.In this paper, the model was elaborated upon and applied to two types of surface water flushing (fresh water and seawater) under the prevailing conditions of Tripoli, Libya (latitude=32.86°N). All the results presented were predicted for the first three years of operation. The daily variations of brine concentration in the of Tajoura's Experimental Solar pond and those based on different designs were predicted and discussed under different scenarios. The quantities of brine provided by the evaporation pond and that required by were predicted for both cases of surface water flushing (fresh water and seawater) under the different design conditions. It was predicted that the can provide 20–40% during the first year and 45–95% during the third year depending on the design selected.     

Monitoring and maintaining the water clarity of salinity gradient solar ponds

A common problem encountered in salinity-gradient solar ponds is the growth of various types of algae and bacterial populations, which affects the brine clarity and hence reduces thermal performance. Algae and bacterial populations are enhanced by the presence of organic nutrient such as nitrogen and phosphorus. A comprehensive study was undertaken on three salinity-gradient solar ponds in Australia: a 3000 m² sodium chloride solar pond at Pyramid Hill in Northern Victoria; a 50 m² sodium chloride; and 15 m² magnesium chloride solar pond at RMIT University in Bundoora, Victoria. The experimental study involved monitoring the clarity of these three ponds and testing chemical and biological treatment methods to see their effect on the brine transparency. The sources of turbidity and their impacts on clarity and efficiency of salinity-gradient solar ponds are presented in detail in this paper. The initial observation showed that the amount of sunlight is reduced due to the heavy algal growth creating instability in the solar pond as it absorbs light. Two treatment methods were applied to these solar ponds and experiments were conducted to study the turbidity reduction in the solar ponds. In the RMIT magnesium chloride solar pond, diluted hydrochloric acid was injected in the pond to reduce the pH and turbidity levels. Algal blooms were observed and found in the pond where the pH was between 5.5 and 8. It was observed from the experimental study that pH values should be kept below 4.5 to maintain low turbidity and prevent algae growth. The introduction of brine shrimps was also found to be very effective and economical to control algae, provided the oxygen has not depleted due to advanced heavy algal growth. The investigation concluded that hydrochloric acid could be used initially as a shock treatment to kill all the algae and then brine shrimps could be introduced to control the growth of algal and maintain transparency. This analysis showed that by using a combination of chemical and biological treatment methods, the pond clarity can be maintained and the thermal efficiency of the solar pond can be improved.     

Optimum thickness of the nonconvective zone in salt gradient solar ponds

The nonconvective gradient zone of a salt gradient solar pond tends to more effectively transmit incident solar energy to the storage brine below as its thickness is reduced. However, that same gradient zone tends to more effectively reduce heat loss from the warm brines as its thickness is increased. Therefore, there exists an optimum gradient zone thickness for which the net rate of energy collected and retained is a maximum. This report describes a technique for using a numerical simulation model to determine the optimum thickness of the gradient zone in ponds; provided other basic design, operating and climatic factors are specified. Significant improvements in pond efficiency may be obtained if the thickness of the gradient zone is adjusted monthly, seasonally or even if maintained at the annual average optimum thickness as compared with operating the pond with other than an optimum gradient zone thickness.     

A RECTANGULAR SOLAR POND MODEL INCORPORATING EMPIRICAL FUNCTIONS FOR AIR AND SOIL TEMPERATURES

A novel theoretical model, capable of giving the temporal temperature variation at any point inside or outside a non-insulated rectangular solar pond at any time, is presented. Incorporating the finite difference approach, the model makes use of one- and two-dimensional heat balances written on discrete regions in the brine and in the soil adjacent to the pond. These simultaneous equations are solved for the local temperatures, using a computer program. Values of hourly averaged air temperature and daily averaged soil temperature for the site were used as input parameters, and empirical functions for the time-dependence of these variables were incorporated into the theoretical model. It was found necessary to use this level of detail of the meteorological data for reliable predictions on the solar ponds. The model results are compared with measured results on an actual solar pond built in Cukurova, Turkey. The modelled and experimental temperature profiles are found to be in a very good agreement. The results indicate that the thickness of the salt gradient region of a solar pond should not be less than 1.3 m. Heat losses form the pond side-walls was found not to effect the performance of solar ponds when the surface area is greater than 100 m².     

Solar pond with honeycomb surface insulation system

A solar pond consisting of transparent compound honeycomb encapsulated with Teflon film and glass plates at the bottom and top surface respectively, floating on the body of a hot water reservoir is considered and analysed for the heat transfer processes in the system. A mathematical model is developed where the energy balance equation of the convective water is formulated by considering its capacity effects, various heat losses and solar energy gain through the surface insulation and is solved by the finite difference method. Transient rate of heat collection and storage characteristics are investigated. Explicit emphasis is laid on the effect of the thickness of the bottom encapsulation on the year-round thermal performance of the system and results seem to favour the minimum thickness. The annual average efficiency of the transparent honeycomb insulated solar pond is found to be higher than the conventional salt gradient pond by a factor of about 2.     

Heat extraction methods from salinity-gradient solar ponds and introduction of a novel system of heat extraction for improved efficiency

Heat has generally been successfully extracted from the lower convective zone (LCZ) of solar ponds by two main methods. In the first, hot brine from the LCZ is circulated through an external heat exchanger, as tested and demonstrated in El Paso and elsewhere. In the second method, a heat transfer fluid circulates in a closed cycle through an in-pond heat exchanger, as used in the Pyramid Hill solar pond, in Victoria, Australia. Based on the experiences at the El Paso and Pyramid Hill solar ponds, the technical specifications, material selection, stability control, clarity maintenance, salt management and operating strategies are presented. A novel method of extracting heat from a solar pond is to draw the heat from the gradient layer. This method is analysed theoretically and results of an experimental investigation at Bundoora East, RMIT, are presented. An in-pond heat exchanger made of polyethylene pipe has been used to extract heat for over 2 months. Results indicate that heat extraction from the gradient layer increases the overall energy efficiency of the solar pond by up to 55%, compared with conventional method of heat extraction solely from the LCZ. The experimental results are compared with the theoretical analysis. A close agreement has been found. From this small-scale experimental study, convection currents were found to be localised only and the density profiles were unaffected. An experimental study using an external heat exchanger for brine extraction and re-injection at different levels within the gradient layer still needs to be conducted to determine the effect of the heat extraction from the non-convective zone (NCZ) on the stability of the salinity gradient (both vertically and horizontally) and an economic analysis needs to be conducted to determine the economic gains from increased thermal efficiency.     

Simulation of the control of a salt gradient solar pond in the south of Tunisia

We are interested in the modeling and control of a salt gradient solar pond (SGSP) in the south of Tunisia. We developed a model of a closed cycle salt gradient solar pond (CCSGSP) that ensures successful year round operation. This model was used to study the response of the solar pond (SP) to various control techniques. It takes into account heat and salt diffusion within the pond and simulates the transient behavior of a SGSP. Furthermore, we investigated the dynamic process, which involves internal gradient stability, boundary behavior between the gradient zone and the convective zones. We thus incorporated the double diffusive processes into the SP model by using the one dimensional stability criterion produced by linear theory. The governing differential equations are solved numerically by using a control-volume scheme.The results show that successful operation of a SP requires three things: the maintenance of the storage zone temperature through heat extraction and brine injection, the use of surface washing to control the deepening of the upper mixed layer and a well designed initial salt stratification to prevent the formation of instability within the gradient. Using linear salinity profile as an initial condition, three round year simulations were run using average meteorological data with the result that adequate stability (Rρ2 throughout the gradient and Rρ10 at the interfaces) was maintained. Numerical results show also that 10–30% efficiency could have been reached if heat extraction is performed routinely especially when one considers that the storage temperature is within 40–80 °C. The model is validated against data taken from the operation of the UTEP SP. Close correlation between computed and measured data was obtained.     

Kinetics of diffusion of salt in solar ponds

In the present communication, the kinetics of diffusion of salt in a stacked layer solar pond has been investigated by using the step function for the initial state of salt distribution and a closed form solution for the salt concentration has been obtained with the boundary conditions of an operational solar pond. It has been predicted that the time required for a two layered solar pond with non-convective zone of about 1 m depth to reach equilibrium concentration gradient is about 585 days, whereas that required for a ten layered pond is only 96 days.     

Solar ponds using ammonium salts

Ammonium salts have good potential for use in salt gradient solar ponds. The environmental problems associated with NaCl are eliminated by incorporating the salt discharge from the solar pond into the fertilizer cycle of an agricultural system. Thermophysical and optical properties of several ammonium salts are sufficiently close to those of NaCl to suggest that the thermal efficiency of solar ponds using ammonium salts should be equivalent to that of a NaCl pond. Ammonia outgassing is minimal, and algae growth is curtailed by precipitating soluble phosphates. Because fertilizer is purchased for the agricultural system, the cost of salt for the solar pond is determined by the real interest for holding the fertilizer in inventory. These economics make feasible several desirable maintenance schedules for the solar pond.     

Solar ponds in alkaline lake and oil well regions

Solar ponds are probably the simplest technology available for the useful conversion of solar energy. The basic technology is proven. Solar ponds have been shown to be technically feasible and economically viable for many applications, particularly for thermal use. The electrical conversion and use of solar energy via solar ponds is still questionable, in general, for economic viability. By putting the untapped sources together in the South Plains region, it looks promising economically both for thermal and electrical conversions and applications. There are a number of alkaline lake basins randomly scattered in the South Plains region of the U.S.A. In that area, there are thousands of crude oil producing wells that produce brine in abundance. The selection of suitable alkaline lake basins as a solar pond site and as depository sites of brine from oil wells and the using of this brine and salty water from alkaline lakes makes the solar pond economically viable for both thermal and electrical demands in the area.     

Introduction of a passive method for salt replenishment in the operation of solar ponds

A passive method for the replenishment of salt in solar ponds is suggested, based on the natural circulation of water caused by density differences. Water, from a selected depth in the solar pond, is passed through a salt bed in an adjacent tank, where its salinity is increased before it is returned to the bottom region of the solar pond. The difference between the densities, at the points of intake and outlet, provide the driving force for the natural circulation. Careful system design ensures that this circulation will transport enough salt to the bottom region of the pond to compensate for its upward diffusion in salt gradient solar ponds. This method negates the need for the pumping installation normally required for salt replenishment; and it provides a simple, self-regulating, and reliable method for density control in the bottom region of solar ponds.     

Prospects and scopes of solar pond: A detailed review

Solar pond is an artificially constructed pond in which significant temperature rises are caused to occur in the lower regions by preventing convection. To prevent convection, salt water is used in the pond. Those ponds are called “salt gradient solar pond”. In the last 15 years, many salt gradient solar ponds varying in size from a few hundred to a few thousand square meters of surface area have been built in a number of countries. Nowadays, mini solar ponds are also being constructed for various thermal applications. In this work, various design of solar pond, prospects to improve performance, factors affecting performance, mode of heat extraction, theoretical simulation, measurement of parameters, economic analysis and its applications are reviewed.     

超声波法测量盐水溶液浓度

利用超声波在不同浓度、不同温度的盐水溶液中传播速度不同这一特性，测出盐浓度Ｓ、声速Ｖ和温度Ｔ之间的关系，绘制不同温度下的Ｓ－Ｖ曲线和不同浓度下的Ｖ－Ｔ曲线，用计算机对实验曲线进行拟合，给出相应的多项式回归方程，模拟计算结果十分接近实验结果，该方法测试简便，精确度高。