等离子平板显示器(PDP)红色荧光材料的研究进展

由于市场份额萎缩,日本先锋、日立、东芝、富士通、板硝子和中国台湾台塑光电、中华映管、达人科技等知名厂商纷纷宣布退出PDP产业,而中国大陆对PDP项目的投资却不断加大,继南京华显高科和四川虹欧等离子平板显示器项目开工之后,2009年7月安徽鑫昊等离子项目在安徽合肥启动,致使全球PDP制造基地和技术中心逐渐向中国大陆转移,但PDP在未来的平板显示市场竞争中能否占有一席之地、形成一支独秀的局面,备受关注.PDP主要是利用稀有气体电离放出波长为100~200nm真空紫外光用以激发三基色荧光粉进而实现彩色显示,目前存在的主要问题是发光效率低、亮度低以及作为超大屏幕显示器(例如103英寸(261.62cm))能耗高.PDP的发光效率不仅与气体放电方式和驱动电路有关,而且与荧光材料的发光效率直接相关.以红色真空紫外荧光材料为例,系统总结了近年来在PDP新型荧光材料和真空紫外激发发光机理方面取得的进展,并对未来PDP的研发提出了前瞻性建议.     

彩色PDP纳米荧光粉的研究

等离子体显示(PDP)具有超薄、高清晰、大画面等优点而被世界公认是实现壁挂式高清晰度电视(HDTV)的首选技术,而荧光粉对PDP性能起着决定性作用.着重介绍了纳米PDP荧光粉的制备方法及影响发光性能的关键因素,并提出了其研究的技术前景.     

PDP蓝色荧光粉BaMgAl10O17:Eu2+研究现状与前景

彩色等离子体平板显示(PDP)是信息显示领域重要发展方向之一,荧光粉对PDP性能起决定性的作用,红色、绿色荧光粉体技术相对成熟,蓝色荧光粉研究滞后,问题也比较多.概述了BAM蓝色荧光粉体的结构、发光机理、制备工艺、劣化机理,并提出了BAM荧光粉体研究的技术前景.     

发光材料用球形高纯氧化铝生产新工艺

球形高纯氧化铝产品主要用于铝酸盐基系列发光材料，如节能灯用三基色荧光粉、长余辉荧光粉、PDP荧光粉和LED荧光粉等，也可作为透明陶瓷、宝石单晶及高档磨料的原料。     

高清晰度投影电视及彩色等离子体平板显示(PDP)用荧光体

本课题组承担了“九五”期间863课题,在新材料领域专家委员会的指导下,经过5年的努力工作,积极开展了具有创新性的工作,出色地完成了合同中各项研究内容,研制的彩色投影电视用和彩色等离子体平板显示(PDP)用荧光粉,发光性能均达到国际先进水平。1 取得的成果与国际先进水平比较 (1)在国内首次成功地研制出彩色投影电视用红、绿、蓝三基色荧光粉,经中科院阴极射线质检中心和北京化工厂荧光粉分厂测试部检测,荧光粉的各项性能指标达到或超过国外同类样品水平。该荧光粉由信息产业部12所、天津三津公司在7英寸投     

彩色PDP用蓝色荧光粉体的纳米化工艺研究

介绍了一种彩色PDP用蓝色荧光粉体的纳米化工艺，通过此方法，可以制备出比传统的PDP蓝色荧光粉体发光效率更高的纳米级蓝色荧光粉体，同时有效的降低了制备过程的烧结温度。制备的蓝色荧光粉体完全适用于PDP显示设备中。另外，纳米化的小颗粒也为进一步的表面包覆以防止衰减奠定了基础。     

LED用荧光玻璃的制备及性能研究

以行星球磨得到的SiO₂粉体和商用Ce:YAG荧光粉为原料, 采用放电等离子体烧结技术(简称SPS)成功制备块体荧光玻璃。利用XRD、SEM、紫外/可见光分光光度计和荧光光谱仪等研究了Ce:YAG荧光玻璃的物相、显微结构、吸收和发光性能等。研究结果表明: SPS烧结制备的块体荧光玻璃样品主体是非晶相, 同时荧光粉颗粒在玻璃基质中均匀分布, 颗粒大小也未发生变化, 这表明荧光粉晶体在SPS烧结过程中没有发生化学分解反应, 在玻璃基体中得到很好地保存。该荧光玻璃吸收峰在460 nm左右, 发射波长在530 nm左右。通过对不同含量荧光粉的荧光玻璃进行发光性能表征, 发现荧光粉含量为3wt%的荧光玻璃性能最佳, 以此封装的白光LED样品在800 mA电流驱动下, 获得白光输出, 色坐标为(0.33, 0.38)。     

PDP用蓝色荧光粉的研究进展

综述了近年来等离子体平板显示器(PDP)用蓝色荧光粉的研究进展,介绍了PDP蓝色荧光粉的种类和制备方法,分析了现有PDP蓝色荧光粉存在的问题和不足,并展望了PDP蓝色荧光粉未来的发展趋势。     

等离子体显示用铝酸盐绿色荧光粉的制备及其发光性能研究

采用高温固相法合成了一系列的BaAl12O19:Mn绿色荧光粉,分析了还原气氛、Mn掺杂量、烧结温度和焙烧保温时间等因素对等离子体显示(PDP)用绿色荧光粉BaAl12O19:Mn的晶体结构、相态和发光性能的影响.结果表明,在N2、H2(H2=10%)还原气氛下烧制的样品发光强度比其在碳粉还原气氛下烧制的样品发光强度要大.当Mn掺杂比例为0.14(mol/mol),烧结温度为1350℃和保温时间为3.5h时,所制备的绿色荧光粉发光性能最佳.     

稀土发光材料进展

自1964年Y203：Eu被用于制造荧光粉以来，稀土发光材料得到了迅猛的发展，大多数稀土元素或多或少地被用于荧光材料的合成，稀土发光材料己成为显示、照明、光电器件等领域中的支撑材料，并不断地有新的稀土荧光粉出现。     

用于白光LED稀土Eu掺杂SiAlON基荧光粉的发光性能

SiAlON基荧光粉因其优异的化学和物理稳定性,成为近年来发光领域的一个研究热点,尤其在LED等领域,受到研究者的热切关注。稀土掺杂SiAlON基荧光粉体有望成为新一代照明光源。由于缺乏青色光发射,往往会造成显色性能不足。本研究通过传统高温固相法合成了β-Si₅AlON₇:Eu荧光粉,采用X射线衍射仪(XRD)、扫描电镜(SEM)、X射线光电子能谱(XPS)等研究了其结构、形貌、元素和价态。通过光谱仪表征了样品的激发光谱以及发射光谱的波长范围并测试了热猝灭性能,发现激发波长覆盖紫外至蓝色光区域,并且发射光谱显示出典型的Eu²⁺跃迁的宽谱。在300℃下,样品的发射光强度依然可达到室温强度的40%左右,热激活活化能(E_a)达到了3.7 eV,相比较商用YAG:Ce³⁺(YAG)荧光粉,热稳定性有一定的提升。在与蓝色芯片复合后成功制备了高显色(显色指数R_a=87)的白色发光LED,对应的色温也达到了暖白光范围(CCT=4501K)。本研究实现了SiAlON基青色...     

Surface modification of the (Y,Gd)BO3:Eu phosphor by dual-coating of oxide nano-particles

The surface of (Y,Gd)BO₃:Eu³⁺ phosphor, red-emitting source in the plasma display panel (PDP), was dual-coated with SiO₂ and Al₂O₃ nano-particles. The surface modification of the phosphor was performed by a modified sol-gel method using the colloidal alumina and silica as surface coating precursors. We observed the oxide nano-particles on the surface of the single coated and the dual-coated phosphors and it was found that the luminance intensity was increased in the photoluminescence (PL) by a suppression of the nonradiative recombination via surface defects. The experimental results suggest that the surface modification of phosphors with nano-particles of the oxides leads to an increase in the luminance intensity of phosphors in the PDP (plasma display panel) and the gas discharge lamps.     

Synthesis,photoluminescence properties of Sr<Subscript>1.95</Subscript>Ba<Subscript>0.05</Subscript>CeO<Subscript>4</Subscript>:Eu<Superscript>3+</Superscript> for LED applications

The Sr_1.95Ba_0.05 CeO₄:Eu³⁺ phosphors are synthesized by the solid-state reaction method. The samples are characterized using X-ray diffraction (XRD), diffuse reflectance spectroscopy and photoluminescence (PL) spectra. The XRD results reveal that the synthesized phosphors are genuine crystalline and belong to the orthorhombic structure. The intense PL emission is optimized from the PL spectra at various doping concentrations of europium ions. The results indicates that the phosphor can be effectively excited under 264 nm wavelength producing on intense emission spectrum of the synthesis material at 484 nm (blue region). The color purity of the phosphor is confirmed by CIE coordinates (x = 0.217, y = 0.265). The experimental data indicate that the prepared phosphors can be used as blue-emitting material in the field of illuminations and display devices.     

Characterization of phosphor materials for use in plasma display panel by time-resolved vacuum-ultraviolet laser spectrometry

Phosphor materials that were manufactured for use in a plasma display panel (PDP) were investigated by employing a newly designed time-resolved vacuum-ultraviolet (VUV) spectrometer, which consists of a pulsed VUV laser and a fast photodetector. The VUV spectrometer was used to collect quantum efficiency data as well as the rise and decay times for the PDP phosphor luminescence. Both the rise and decay times increased with decreasing excitation wavelength in the VUV region. This result can be explained by a change in the mechanisms of photoexcitation and luminescence, that is, from charge-transfer excitation to host-lattice excitation below 200 nm. The present instrument was also used for an evaluation of the phosphor materials (Ba(1 - x)MgAl10O17:Eu2+(x)) by changing the Eu2+ concentration. The obtained data suggest that the impurities and defects are located inside the host crystal. Thus, the VUV spectrometer constructed in this study has considerable potential for use in investigating the nature of PDP phosphor materials.     

一种新颖的白光LED荧光粉测量系统和分析方法(英文)

为获得高效率的白光LED,得到荧光粉和芯片的最佳匹配,本文提出了一种新颖的白光LED荧光粉测量系统和分析方法.该方法根据荧光粉测量原理,采用单色光激发荧光粉,获得荧光粉的激发光谱特性.由单波长激发的光谱组合可以得到荧光粉的三维光谱特性,荧光粉光谱与LED芯片光谱匹配可以模拟白光LED光谱.分析了荧光粉在单波长及光谱激发条件下的效率.实验结果表明,该测量系统和分析方法可以确定荧光粉和兰光LED芯片的最佳匹配,从而为获得高效率白光LED奠定了良好的基础.     

Electrophoretic deposition of monochrome and color phosphor screens for information displays

This paper reviews our research on the electrophoretic deposition (EPD) of phosphors for the processing of monochromatic and color screens for information displays. Our investigation began with the study of the fundamentals of the EPD process for phosphors. The processing variables which enhance the adhesion strength of phosphor deposits were determined. The optical performance of phosphors deposited by EPD was shown to be not affected by the process itself nor by the conditions which enhance phosphor adhesion. Processes developed to produce high-resolution color screens by combining EPD and photolithography techniques are described. Also, a method to electrophoretically deposit phosphor in a thermo-reversible gel from mixtures of poly(butyl methacrylate) and isopropanol was examined.     

蓝光激发红色荧光粉的研究进展及其在白光LED中的应用

蓝光LED芯片激发黄色荧光粉是目前白光LED的主要实现方式,引入红色荧光粉对调整白光LED的显色指数及色温有重要意义。重点介绍和评述了可被蓝光激发且具有宽发射带的硫化物、氮化物、铝酸盐等几种体系红色荧光粉的发光性质、最新研究成果及在白光LED中的应用。对比发现,氮化物荧光粉可被从近紫外到可见绿光有效激发,随基质组成的不同,可发出峰值波长为600～650nm的红色荧光,且由于其优良的化学稳定性、热稳定性成为最有前途的一类红色荧光粉。采用两种以上的荧光粉代替单一黄色荧光粉,有利于调整白光LED的色温,提高显色指数。     

Optically stimulated luminescence in an imaging plate using BaFi:Eu

BaFI:Eu phosphors are fabricated using a new method of synthesis: liquid phase synthesis, in which the phosphor particles are formed through the association of Ba2+ ions, F-ions and Eu2+ ions in solution. An intense optically stimulated luminescence (OSL) peak at about 410 nm is observed by stimulating X ray irradiated BaFI:Eu phosphor with about 550-750 nm light. It is found that the peak wavelength of the optically stimulation spectrum is about 690 nm. This result suggests that the semiconductor laser can be used as the stimulating light source. It is also found that the OSL intensity is increased with increasing the X ray dose. The BaFI:Eu phosphor as a photostimulable material for the imaging plate of a computed radiography system provides the following advantages; (1) high X ray absorption coefficient, (2) high monodispersion in size which would contribute to sharp images, (3) high OSL and thus low luminescence mottle and (4) high DQE (detective quantum efficiency).     

Photonic Crystal Phosphors Integrated on a Blue LED Chip for Efficient White Light Generation

Following the proof‐of‐concept experiment in the unit structure level, photonic crystal (PhC) phosphors—structurally engineered phosphor materials based on the nanophotonics principles—are integrated with a blue light‐emitting diode (LED) chip to demonstrate a compact and efficient white light source. Red‐ or green‐emitting CdSe‐based colloidal quantum dots (CQDs) are coated on a Si₃N₄ thin‐film grating to fabricate PhC phosphors. The underlying PhC structure is designed such that the photonic band‐edge modes at the zone center (k_∣∣ = 0) are tuned to the energy of the blue excitation photons. By progressively stacking the PhC phosphor plates on a blue LED chip, the blue, green, and red emission intensities can be tightly controlled to obtain white light with the desired properties. The chromaticity coordinates, (0.332, 0.341), and correlated color temperature, 5500 K, are obtained from a stack of 3 red and 11 green PhC phosphor plates; in contrast, a stack of 5 red and 16 green reference phosphor plates are required to generate a similar white light. Overall, the PhC phosphors produce 8% higher total emission intensity out of 33% less amount of CQDs than the reference phosphors.     

Advances in sulfide phosphors for displays and lighting

For traditional applications such as cathode ray tubes and fluorescent lamps, many inorganic phosphors have been optimised during decades. For new applications in display and lighting technology, novel materials are being developed. After giving a short history of sulfide phosphors, the present paper will focus on Ca_1−x Sr _x S:Eu single crystal particle phosphors. The material is grown by solvothermal synthesis, process not needing toxic gases or high temperature processing steps. This phosphor combines a broad excitation spectrum and a broad—saturated red—emission spectrum, which makes it an ideal material for wavelength conversion in LEDs for general lighting.