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Cu时效硬化钢中Cu的析出 总被引:6,自引:0,他引:6
研究了Cu在工业试制的高强度船体钢中的时效析出行为及其时效硬化规律。结果表明:500~550℃时效,硬度随时间增加很快达到峰值,然后再降低;时效温度对Cu的硬化效果起决定性作用。1.5~2h时效硬化峰值温度约为500℃。在硬化峰值温度下,大量Cu析出相在位错线和板条界上析出,尺寸小于5nm,产生强烈沉淀强化作用。过时效状态下,Cu析出相发生明显长大,析出相形态由球状颗粒转变为杆状或短棒状,沉淀强化作用也随之减弱。 相似文献
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P Monthoux 《Canadian Metallurgical Quarterly》1990,41(16):11128-11139
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采用磁控共溅射方法分别制备了含有W和Mo两种不同成分的铜系薄膜,用EDX、XRD、SEM和纳米压痕仪对薄膜成份、结构、形貌和显微硬度进行了分析。结果表明,制备出的Cu—W和Cu-Mo薄膜均呈晶态结构,Cu-W和Cu—Mo形成了均匀的固溶体;经650℃热处理1h后,Cu—W和Cu—Mo薄膜中晶粒长大,有富w和富Mo相从基体Cu相中弥散析出;Cu-W薄膜的显微硬度随W成分的增加先增加后降低;Cu—Mo薄膜的显微硬度随Mo成分的增加而持续升高,薄膜退火态的显微硬度低于沉积态。分析认为,以上结果的产生均因添加W、Mo所引起的晶粒细化效应和薄膜的热稳定性较差所致。 相似文献
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Lee-Ho Su Yee-Wen Yen Chao-Ching Lin Sinn-Wen Chen 《Metallurgical and Materials Transactions B》1997,28(5):927-934
The interfacial reactions of molten Sn and molten In with solid Cu substrate were determined by studying their reaction couples.
The annealing temperature was 300 °C. The phases formed at the interface were examined by optical microscopy, scanning electron
microscopy, and electron probe microscopy analysis (EPMA). The thickness of the reaction layers was measured using an image
analyzer. For Cu/Sn couples, two phases, ε and η, were found. Only the Cu11In9 phase was observed at the interface of the Cu/In couples. In comparison with the results of couples of solid Sn and solid
In with solid Cu substrate, their phase formation sequences were similar; however, the interfacial morphology and the reaction
rates were different. For the liquid/solid couples, the reaction rate was much faster and the interface was nonplanar. A mathematic
model was also proposed to describe the dissolution of the Cu substrate and the growth of the intermetallic compounds. Fast
dissolution of the substrate was observed in the beginning of the reaction and was followed by a relatively slow growth of
the intermetallic compounds at the interface. 相似文献
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A study has been made of the morphology of unidirectionally solidified and as-cast Cu?Cu2S eutectic alloys. The growth morphology of the eutectic is rod-like, consisting of rods of Cu2S which are circular in cross-section in a copper matrix. Following solidification, the Cu2S rods neck down, pinch off, and spheroidize in a sequence which has previously been termed “ovulation”. The spheroids subsequently coarsen rapidly by a process which is controlled by the volume diffusion of sulfur in copper. 相似文献
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John P. Hager Stanley M. Howard John H. Jones 《Metallurgical and Materials Transactions B》1970,1(2):415-422
The activities and partial molar heats of mixing have been determined in the liquid Cu?Sn system at 1320°C and the liquid Cu?Au system at 1460°C. The experimental technique consisted of the analysis of Knudsen cell effusates with a T.O.F. mass spectrometer. The ion current ratio for the alloy components was measured for each system over a range of temperature and composition and the thermodynamic values calculated by a modified Gibbs-Duhem equation. Both systems exhibited negative deviations from ideal behavior. The results can be partially represented by the equations $$\begin{gathered} \log \gamma _{Cu} = - 0.0175x^2 _{Sn} - 0.302 (0 \leqslant x_{Cu} \leqslant 0.20) \hfill \\ log \gamma _{Sn} = - 0.342x^2 _{Cu} + 1.084(0 \leqslant x_{Sn} \leqslant 0.20) \hfill \\ \end{gathered} $$ for the Cu?Sn system at 1320°C and by $$\begin{gathered} \log \gamma _{Cu} = - 0.703x^2 _{Au} - 0.083(0 \leqslant x_{Cu} \leqslant 0.52) \hfill \\ \log \gamma _{Au} = - 1.057x^2 _{Cu} + 0.098(0 \leqslant x_{Au} \leqslant 0.47) \hfill \\ \end{gathered} $$ for the Cu?Au system at 1460°C. 相似文献
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Sivaprahasam D. Sriramamurthy A. M. Bysakh S. Sundararajan G. Chattopadhyay K. 《Metallurgical and Materials Transactions A》2018,49(4):1410-1424
Metallurgical and Materials Transactions A - Nanoparticle agglomerates of passivated Fe (n-Fe) and Fe0.96Cu0.04 (n-Fe0.96Cu0.04), synthesized through the levitational gas condensation (LGC)... 相似文献