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1.
In this work, after cationic pretreatment of cotton fabric with cetylpyridinium chloride (CPC), the compound of citric acid (CA) and succinic acid (SUA) were used as crosslinking agents to dye cotton fabrics with natural madder dye to improve the dyeing and antibacterial properties and realise the multifunctional finishing of cotton fabric. The effects of mordant dyeing, CA + SUA crosslinked dyeing, and CPC/CA + SUA crosslinked dyeing on the microstructure and properties of cotton fabrics were compared. The dyeing by the three processes occurred primarily in the amorphous zone of the fibres, and all kept the original crystalline form of the cotton. CA + SUA crosslinked dyeing and CPC/CA + SUA crosslinked dyeing increased the thermal stability of the cotton fabric. CPC/CA + SUA crosslinked dyed cotton obtained excellent dyeing results with the colour depth value (K/S) of 12.3 and rubbing fastness and washing fastness of levels 4–5, and the levelness and dye permeability were acceptable. Furthermore, the antibacterial rate against Escherichia coli and Staphylococcus aureus reached 99.99%, and the ultraviolet protection factor (UPF) reached 50+. Moreover, the wrinkle recovery angle (WRA) increased by 55% compared with raw cotton. This showed that CPC/CA + SUA crosslinked dyed cotton had excellent antibacterial, anti-ultraviolet, and anti-wrinkle performances.  相似文献   

2.
In this study, polyamino carboxylic acids have been used to improve the dyeability of cotton in a salt‐free reactive dyeing process. These polyamino carboxylic acids were prepared by partial carboxylation of polyvinylamine. Cotton fabric was pretreated with polyamino carboxylic acids and dyed with reactive dyes. The colour strengths of the dyed fabrics were evaluated by measuring the K/S values. The fastness properties (washing, rubbing and light fastness) of the dyed cotton fabrics were also measured. The pretreatment of cotton with polyamino carboxylic acids creates positive charges on the fabric surface. In this way, salt‐free reactive dyeing of cotton or dyeing with only a small amount of electrolyte is possible.  相似文献   

3.
Cellulose fiber surface was modified with silk sericin (or simply, sericin). Sericin fixation on cellulose was confirmed by environmental scanning electron microscopy (ESEM) and Fourier transform infrared spectrophotometry–attenuated total reflectance (FTIR‐ATR). Sericin content in finished samples was estimated by dyeing treated fabrics with an acid dye, Supranol Bordeaux B, and determining K/S and L values of the dyed fabrics. The treated fabrics were tested for free formaldehyde content, crease recovery, tensile strength, electrical resistance, water retention, and biocidal activity. From ESEM and FTIR‐ATR results, it was found that sericin coated onto cotton surfaces as a film. Increasing sericin content in the finishing solution increased the amount of coated sericin, and a greater depth of color in dyed samples and reduced free formaldehyde content in treated samples were observed. The sericin content in samples was found to have a negligible influence on tensile strength and crease recovery angle. With increasing sericin content, electrical resistivity of the samples dramatically decreased and water retention increased, indicating that sericin‐treated fabrics may be comfortable to wear because of its maintenance of moisture balance with respect to human skin. Because cotton textile coated with sericin exhibited low formaldehyde content and no biocidal activity against Klebsiella pneumoniae and Staphylococcus aureus, the fabric may reduce skin irritation and disturbance of physiological skin flora arising from textile contact. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1421–1428, 2005  相似文献   

4.
A new approach to the dyeing of cotton fabrics using an electrostatic self‐assembly method was evaluated. Cotton fabrics were pretreated with 2,3‐epoxypropyltrimethylammonuium chloride and cationic charges were produced on the fabric surfaces. For the dyeing of cotton fabric, reactive and acid dyes were used. Oppositely charged anionic reactive/acid dyes and cationic poly(diallyldimethylammonium chloride) were alternately deposited on the surface of cationised cotton fabrics. Ten multilayer films of dye/poly(diallyldimethylammonium chloride) were deposited on the cotton fabric surfaces using a padder. The build‐up of the multilayer films and the level of colour strength (K/S) achieved are discussed. Samples of cotton fabrics were also dyed with the same dyes, but using the exhaust method, and both types of dyed samples were compared. The washing, rubbing and light fastness properties were evaluated for the dyed fabrics.  相似文献   

5.
In this study, 100% cotton knitted fabrics made from combed cotton and combed pima cotton were dyed with reactive dye, with different dye concentrations. Colour properties such as CIE L*a*b* values as well as dyeing uniformity of the dyed fabrics were measured. The relationships between colour properties and the ultraviolet protection afforded by cotton knitted fabrics were investigated. Experimental results revealed that dye concentration is the most important factor. In addition, only L* values have a direct mathematical relationship with the ultraviolet protection factor; a* and b* values and dyeing uniformity were not found to have a significant correlation with ultraviolet protection factor values. Meanwhile, knitted fabric made from combed cotton fibre has better ultraviolet protection performance than fabric made from combed pima cotton fibre.  相似文献   

6.
To achieve the goals of saving water and being salt‐free in the coloration of cotton fabric with reactive dye, nonionic reverse micelles were prepared and optimised with a surfactant, Triton X‐100, n‐octanol and isooctane by injecting a small amount of CI Reactive Red 195 aqueous solution. The adsorption, diffusion and fixation of this dye on cotton fabric in Triton X‐100 reverse micelle and bulk water were then investigated. The equilibrium and kinetic data of the dye adsorption process were evaluated. The colour strength and fixation rate of cotton fabrics dyed in the micelle and in bulk water were also examined and compared. The results indicated that the amount of dye adsorbed increased with the increasing temperature and the initial dye concentration. The dye adsorption process could be described using the Langmuir isotherm and pseudo‐second‐order kinetic equations. It was found that CI Reactive Red 195 showed a stronger adsorption property on cotton fabric in Triton X‐100 reverse micelle than in bulk water without the addition of sodium chloride. Using Triton X‐100 reverse micelle as the dyeing medium offered the reactive dye better diffusion performance within the cotton fibre as compared with bulk water. Moreover, higher fixation of the dyes absorbed on the cotton fibre was achieved when the optimum concentration of sodium carbonate was used as the alkali agent in Triton X‐100 reverse micelle.  相似文献   

7.
A series of fluorotriazine reactive dyes have been synthesized and applied to dye cotton in supercritical carbon dioxide (scCO2) with good dyeing results. The pieces of cotton to be dyed were previously presoaked in a protic solvent and cosolvents were applied during dyeing. The colour strength of the dyeings was evaluated by K/S measurements. The K/S values achieved on cotton dyed were up to 35.8 ± 4.2. Even after the cotton was subjected to a Shoxlet extraction at 358 K for 1 h, a maximum K/S value of 20.2 ± 1.8 was measured. The percentage of dye molecules chemically fixed to the cotton was on average 85%. The excellent reactivity of fluorotriazines allowed a reduction of 3 h on the dyeing time. It is noticeable that a dye concentration of 10% on weight of the fibre (owf) can be applied to dye cotton with fluorotriazines, since no damage of the cotton fibres occurred, as observed for the chlorotriazines at this high dye concentration.Dyes with fluorotriazine as reactive group were found to be the most preferable dyes for dyeing cotton in scCO2, as they were able to exceed the limitation of the reaction with the cotton.  相似文献   

8.
Turkey has a great number of hazelnut trees that possess nutritious components. However, only the inside part of the hazelnut is used as a nutrient, while the rest of it is waste. This study suggests that the waste parts of the Turkish hazelnut could be used as a natural dye for dyeing textile fabrics. The dyeing properties of the leaves, coat, shell and dice of the hazelnut were studied on wool, cotton and viscose fabric by using three different mordants: copper sulphate, iron sulphate and aluminium sulphate. The selected dyed fibre sample surfaces were observed using a scanning electron microscope. The colour strength (K/S), light, washing, rubbing, and perspiration fastness levels of the dyed fabrics were investigated. The experimental natural dyeing results indicate that waste hazelnut‐based products can be used as a natural dye for textile coloration.  相似文献   

9.
To achieve textile dyeing and functional finishing in one process, a bleach‐resistant reactive dye precursor to anti‐bacterial N‐halamine was synthesised by reacting a type of dichlorotriazine reactive dye with 4‐amino‐2,2,6,6‐tetramethylpiperidine. The synthesised compound, which can be transformed to an N‐halamine molecule by exposure to dilute bleach solution, was used to dye cotton fabrics. After exposure to a dilute sodium hypochlorite solution, dyed cotton fabrics showed excellent anti‐bacterial properties against Staphylococcus aureus and Escherichia coli O157:H7, facilitating a ca. 6‐log reduction in bacteria within a short period of contact. Compared with the dichlorotriazine reactive dye, the reactive dye precursor demonstrated comparable dyeing properties including exhaustion and fixation values. No differences in rub fastness, wash fastness or bleach fastness were detected between fabrics dyed with, respectively, dichlorotriazine reactive dye and the reactive dye precursor to N‐halamine.  相似文献   

10.
The sulfated β‐cyclodextrin (sb‐cd) was prepared from β‐cyclodextrin and the sb‐cd was crosslinked with cotton fabric using ethylenediaminetetraacetic acid (EDTA) as crosslinker. After crosslinking, the synthesized ZnO nanoparticles were padded on this fabric surface. Then, the treated fabrics were dyed with neem extract. The synthesized polymer, crosslinked and nanoparticle‐treated cotton fabrics were characterized using fourier transform infrared spectroscopy (FTIR), X‐ray diffraction (XRD), particle sized analyzer, and transmission electron microscopy (TEM) studies. The antibacterial test was done against Staphylococcus aureus and Escherichia coli bacterium. The composite coated with neem dyed cotton fabric has exhibited 71% of dye uptake with 2–3 fastness grade and it has 99% of antibacterial efficiency for S. aureus and 97% for E. coli bacterium. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013  相似文献   

11.
For the first time, the natural anthocyanin dyes (mainly consisting of cyanidine 3‐glycoside) extracted from mulberry (Morus rubra) fruits has been successfully used to dye cotton fabric, with a dyeing property performance good enough for potential commercial applications. In this study, succinic acid was firstly incorporated into cotton fabrics by esterification to the hydroxyl groups of cellulose, forming an anionic site for the dyes. The performance of the modified material was characterised by Fourier transform infrared spectroscopy and tensile strength. Results showed that the tensile strength of cotton fabrics was mostly retained after modification. The anthocyanin extracts from mulberry fruits were used to study the dyeability of the control and modified cotton fabrics. Red and deep purple (aubergine) are two main shades of cotton fabrics dyed with mulberry fruit extracts. Most importantly, aubergine shade is rare in cotton fabrics dyed with natural dyes. Modification with succinic acid clearly increased the colour strength of the dyed cotton fabric. The colour strength of dyed cotton fabric was improved from 2.7 to 5.3 in the case of dyeing without mordants, and from 3.2 to 6.9 in the case of dyeing with tin mordanting. Meanwhile, the colour fastness was improved by 0.5–2 grades with increasing succinic acid concentration in the finish solution. The colour fastness to perspiration, crocking, light, and washing of fabric dyed with simultaneous tin mordanting and modified with 30 g l?1 of succinic acid was found to be acceptable, with a grey scale grade of at least 3. As for home laundering, neutral soapy solution was more acceptable than alkaline soapy solution.  相似文献   

12.
A dyebath containing left-over CI Acid Red 249 after dyeing of wool was completely decolorised using an isolated bacteria Bacillus flexus. Optimisation was carried out by varying the pH, temperature, dye concentration, and microbial loading. Complete decolorisation of a 50 mg l−1 dye solution was achieved in 8 h at pH 7 and 37 °C with 10% v/v loading of the bacteria. The decolorised bath was utilised for dyeing of wool fabric with the same dye at 5% shade. This cycle of dyeing–decolorising–dyeing was repeated 5 times. The evaluation of dyed fabric was done using K/S, colour values, and fastness to light and washing. Comparison of a sample dyed with the conventional exhaust process showed that the dyeing quality is not affected for all five successive reuse cycles. The results are important from the viewpoint of reducing water consumption and chemicals.  相似文献   

13.
In this study, the effects of polycarboxylic acid sodium salt on the dyeing of cotton with reactive dyes were evaluated by measuring and comparing the K/S values and dyeing fastnesses of the dyed cotton fabric samples. Results showed that the K/S value and dyeing fastness of cotton fabrics dyed with polycarboxylic acid sodium salt, substituting inorganic salts as exhausting agent were close to that of with sodium chloride when dip‐dyeing process was used. While, in pad‐dry dyeing, the K/S value of cotton fabric samples dyed with polyacid salts as exhausting agent was higher than that of with sodium sulfate, and the dyeing fastnesses of these samples were nearly the same. The dyeing mechanism of cotton fabric with reactive dye, using polycarboxylic acid sodium salt as exhausting agent was analyzed. The dyeing exhausting mechanism of reactive dye seems different when the inorganic salt and polycarboxylic acid sodium salt were used as exhausting agent in the dyeing of cotton fabric with reactive dye. The polycarboxylic acid sodium salt, as weak electrolyte, increased the dye‐uptake of reactive dye on cotton fabric not only by screening negative charges on cotton surface, but also by the effect of salting‐out or hydrophobic combination. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007  相似文献   

14.
Textile fabrics were dyed with complexometric indicators (ionochromic dyes) to develop Fe(II) ionochromic fabric. Three kinds of ionochromic dye were used to dye silk fabric, and they were evaluated for colour changes triggered by Fe(II) solution. The K/S values and photos of the fabrics were then recorded. It was found that 1,10‐phenanthroline was the most suitable ionochromic dye in these dyes. Colour change from white to red could be clearly seen when 1,10‐phenanthroline‐dyed silk fabric was triggered by Fe(II) solution, but it showed no colour change when triggered by Cu(II), Mg(II), or Ca(II) solution. Moreover, 1,10‐phenanthroline‐dyed nylon, polyester, and cotton fabrics showed no obvious colour changes after triggering by Fe(II) solution. Ion concentration, pH value, and reaction time could affect the colour changes. When triggered by 8 mg l?1 of Fe(II) solution at neutral pH for about 15 min, the ionochromic fabric showed a clear colour change. In addition, three coloured fabrics in green, blue, and yellow were also dyed with 1,10‐phenanthroline. It was found that they could also show clear colour changes when triggered by Fe(II) solution. These ionochromic fabrics may find broad application in many fields, such as Fe(II) detection, magic toys, anticounterfeiting materials, and bionic silk flowers.  相似文献   

15.
为实现槐米染料的工业化应用及提高棉织物的功能性,分析了使用壳聚糖、Al3+、Fe2+媒染剂预媒染色法对棉织物染色效果的影响,重点研究了铝预媒染方法染色温度、染色时间、pH值等工艺参数对染色棉织物K/S值的影响,并测试了槐米染色棉织物的抗紫外性能。结果表明:直接使用槐米染色的效果较差;壳聚糖媒染对上染效果影响不大,使用铝、铁媒染剂,可得到不同颜色的棉织物;铝媒染剂染色棉织物为鲜艳的黄色,为较好的媒染方法;铝预媒染染色方法染色优化条件为:温度为80℃,染色时间120分钟,染浴pH值为6.8;铝预媒染染色棉织物具有较好的抗紫外性能。  相似文献   

16.
Enzymatic coloration of fabrics has received worldwide attention in recent years. In order to improve the dyeing properties of enzymatically coloured fabrics, a novel strategy using 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride (EDC), a biological coupling agent, to pretreat wool fabric was employed in this paper. Enzymatic coloration of wool fabrics with syringic acid was carried out in the presence of laccase from Trametes versicolor. The effect of different periods on laccase-catalysed polymerisation of syringic acid was examined by UV-vis spectroscopy. Enzymatic coloration results of dyed wool fabrics were evaluated by means of K/S value and colour difference (∆E*). Process parameters, including the dosages of syringic acid and incubation time, that influenced the colour depth were studied. Meanwhile, the colour fastness and levelness of dyed wool fabrics were tested. The results showed that the UV-vis absorbance of reaction solution increased as oxidation time elapsed, and a new peak appeared at 360 nm. After pretreatment, the K/S values and colour difference values of wool fabrics dyed with poly(syringic acid) improved appreciably compared with the control samples without any pretreatment. Moreover, pretreated wool fabrics showed better dyeing fastness and levelness than control samples.  相似文献   

17.
In this research, the effect of carbon dioxide laser irradiation on various properties of raw and bleached cotton fabrics, including fabric weight, bending rigidity, wetting, and air permeability, as well as dyeing, was examined and compared. The experiments were carried out at three different laser powers ranging from 4.5 to 6 W to determine the effect of laser treatment on fabric properties. In particular, the influence of laser irradiation on the dyeing properties of treated fabrics with CI Reactive Blue 198 was studied. The colour change of laser‐treated fabrics was determined by calculation of the K/S values as a function of fabric reflectance. The morphological changes in laser‐treated fabrics were observed by scanning electron microscopy. The effects of laser treatment on the properties of raw and bleached cotton fabrics were varied. For instance, the wettability of raw cotton samples was reduced after laser irradiation, whereas the wettability of bleached cotton fabrics was greater. Possible reasons for the various dyeing behaviours observed with irradiation at different laser powers are discussed.  相似文献   

18.
朱小娜  王晓  艾莎  魏菊  陈茹 《精细化工》2023,40(2):407-414
为了通过泡沫染色和光固化改善棉织物的染色性能,合成了一种含有不饱和双键的硅氧烷低聚物,设计了合适的含有聚合型黄色蒽醌染料、硅氧烷低聚物、光引发剂2,4,6-三甲基苯甲酰基-二苯基氧化膦(TPO)、表面活性剂十二烷基硫酸钠(SDS)的泡沫体系对棉织物进行泡沫染色。采用1HNMR和GPC分析了硅氧烷低聚物的化学结构和相对分子质量分布,采用FTIR表征了硅氧烷低聚物和染色棉织物的化学结构,采用SEM观察染色棉织物的表面形态。探讨了硅氧烷低聚物用量、染料用量、SDS质量浓度、TPO用量对泡沫性能和染色性能的影响,分析了硅氧烷低聚物的固色机理。结果表明,染料质量浓度30 g/L、硅氧烷低聚物用量为染料质量的2倍、SDS质量浓度2.0 g/L、TPO用量为染料质量的5%、紫外光照时间5 min时,染色织物染色深度可达5.70,耐皂洗色牢度和干/湿摩擦色牢度均为4~5级,水接触角为110.1°,紫外防护系数>50。硅氧烷低聚物通过侧基上的不饱和双键发生自由基聚合和硅醇基偶合交联实现固色,并赋予织物良好的疏水性能和抗紫外线性能。  相似文献   

19.
Novel results were obtained by selection of chitosan treatment parameters on cotton fabrics to obtain antimicrobial properties against E. coli, gram-negative bacteria. Taguchi experimental design was used in this study and microbial reduction rate was considered as the response. The signal-to-noise and the analysis of variance (ANOVA) were used to find the optimum levels to indicate the impact of treatment parameters on antimicrobial properties. The antimicrobial behavior of the fabric against bacterium as a function of each parameter was plotted. A verification test was also performed to prove the validity of Taguchi technique for this study after the determination of parameters’ optimum levels. Also the effect of chitosan and the mordanting on the dyeing properties of cotton fabrics with natural dyes such as walnut hull and safflower was investigated by measuring the color strength (K/S values) of the treated and untreated substrates at various concentrations. The results revealed that the K/S of dyed chitosan-treated cottons increased compared to untreated samples. In addition, antimicrobial properties of natural-dyed treated and untreated fabrics were determined. Walnut hull and safflower have shown antimicrobial properties. Although dyeing the chitosan-treated fabric reduced its antimicrobial effects but the results showed that chitosan-treated cotton fabrics had excellent antimicrobial properties against E. coli. Applying Taguchi experimental design for treating cotton fabrics with chitosan and utilizing these native natural dyes have never been used elsewhere.  相似文献   

20.
Cationised cotton allows the dyeing of cotton fabrics without salt and up to 100% anionic dye utilisation. The employment of cationised cotton in the dyeing of high depths of shades with reactive dyes holds marked potential for sustainable improvements through less dye consumption, decreased water usage, and zero salt utilisation, all while obtaining shade depths darker than possible with conventional reactive dyeings. This work builds upon previous work in obtaining ultradeep dyeings of cotton utilising cationised and mercerised cotton by investigating the effects of liquor ratio in dyeing and amount of dye applied. Surprisingly, for mercerised only cotton fabric, it was found that nearly equivalent depths of shade, as indicated by L*, were obtained, irrespective of the liquor ratio and the amount of CI Reactive Black 5 applied from 7% to 10% owf. However, the strengths of the dyeings, indicated by the K/S sum, show slight increases with increasing amounts of dye, but not when the liquor ratio is lowered. Similarly, for mercerised‐cationised cotton, the liquor ratio had a negligible effect on the depth of shade obtained, but increasing the amount of CI Reactive Black 5 resulted in an increase in shade depth and colour strength. Very deep shades with high colour strength were obtained with mercerised‐cationised cotton that were not obtainable with uncationised cotton, even at a very low liquor ratio and with a drastic increase in the amount of CI Reactive Black 5.  相似文献   

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