Accelerated weathering performance of Scots pine preimpregnated with copper‐based chemicals before varnish coating Part:1 coated with cellulosic and polyurethane varnishes

This study aimed to determine the effect of accelerated weathering on gloss, surface hardness and colour changes of Scots pine (Pinus sylvestris L.). Test samples were impregnated with Adolit KD‐5, Wolmanit CX‐8 and Celcure AC‐500 covered with cellulosic and polyurethane varnishes. The results showed that the values of surface hardness and gloss increased after accelerated weathering. While the surface hardness of Scots pine was increased for impregnated and polyurethane‐coated varnish, it decreased for impregnated and cellulosic varnish‐coated Scots pine after 1000 hours of accelerated weathering exposure. Copper‐based chemical impregnation and varnish coating developed the gloss of Scots pine specimens relative to the surface characteristics observed in single‐coated Scots pine specimens. While the most appropriate chemical was Celcure AC‐500 for surface hardness, it was Adolit KD‐5 for the gloss of Scots pine after 1000 hours of accelerated weathering exposure. Wood specimens impregnated prior to the application of varnish were more effective in stabilising the colour of Scots pine than Scots pine only coated with varnish. Polyurethane varnish‐treated Scots pine showed better colour stability for each partial and total accelerated weathering exposure period. The total colour changes were lowest for polyurethane varnish‐coated Scots pine impregnated with Celcure AC‐500 after 1000 hours of accelerated weathering exposure.     

The effects of tannins on adhesion strength and surface roughness of varnished wood after accelerated weathering

This study evaluated the effect of accelerated weathering on the adhesion strength and surface roughness of beech wood (Fagus orientalis) treated with mimosa and quebracho extracts and coated with polyurethane, water-based, and cellulosic varnishes. Untreated beech wood blocks and beech wood blocks treated with Tanalith-E were used as control samples. Test samples were exposed to accelerated weathering processes of 100 and 300 h. According to the test results, the mean adhesion strength of the wood samples impregnated with mimosa and quebracho tannins decreased by a maximum of 20%, while increases in the mean surface roughness (R _a) were detected. The highest adhesion strength and lowest mean surface roughness were obtained with polyurethane varnish. Moreover, the mean adhesion strength increased with the accelerated weathering up to 100 h and then decreased thereafter. As a result of the weathering process, the mean surface roughness increased and was thus negatively affected.     

Surface properties of impregnated and varnished Scots pine wood after accelerated weathering

In this study, the effect of accelerated weathering on the surface properties of Scots pine specimens impregnated with wolmanit‐CB, tanalith‐E, and adolit‐KD5 and coated with synthetic and polyurethane varnishes was investigated by measuring surface hardness, glossiness, and colour. Results showed that weathering caused an increase in the hardness of impregnated and varnished specimens, while it caused a decrease in the glossiness of specimens. Surfaces became rougher and darker after weathering in comparison with the initial surfaces of wood specimens. Positive values of the chromatic coordinates indicated that the wood surfaces changed from their original colour to a reddish and yellowish colour. The highest colour change was detected in the specimens coated with polyurethane varnish alone. Both copper‐based wood preservative treatment and varnish coating improved the surface properties of specimens in comparison with the surface properties observed on specimens coated with varnish alone.     

Impact of impregnation with boron compounds on the surface hardness and abrasion resistance of some varnished woods

This study was performed to determine the impact of impregnation with boron compounds on the surface hardness and abrasion resistance of some varnished woods. For this purpose, test specimens prepared from Oriental beech, White oak, Scotch pine, and Uludag fir, which met the requirements of ASTM D 358, were impregnated according to ASTM D 1413‐99 with boric acid (Ba), borax (Bx), and boric acid + borax (Ba+Bx) by the vacuum technique. After impregnation, the surfaces are coated with synthetic (Sn), water‐borne (Wb) and acid hardening (Ah) varnishes in accordance with ASTM D 3023. the surface hardness of specimens after the varnishing process was determined in accordance with ASTM D 4366. The abrasion resistance of specimens after the varnishing process was determined in accordance with TS 4755. According to the wood type, impregnation material and varnish type, the surface hardness was the highest for Oriental beech impregnated with borax + boric acid and acid hardening varnish and the lowest for Uludag fir impregnated with borax + boric acid and synthetic varnish. According to the wood type, impregnation material and varnish type, the abrasion resistance was the highest for Oriental beech impregnated with borax + boric acid and acid hardening varnish and the lowest for Scotch pine impregnated with borax + boric acid and synthetic varnish. Those results should be taken into account for applications like parquet, flooring etc., where the surface hardness and abrasion resistance values are very important. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Impact of impregnation with boron compounds on the surface hardness of varnished wood

This study was performed to determine the impact of impregnation with boron compounds on the surface hardness of varnished wood materials. For this purpose, test specimens prepared from Oriental beech (Fagus orientalis Lipsky) and oak (Quercus petreae Lipsky), which met the requirements of ASTM D 358, were impregnated according to ASTM D 1413 with boric acid and borax by a vacuum technique. After impregnation, the surfaces were coated by cellulosic, synthetic, polyurethane, waterborne, acrylic, and acid hardening varnishes in accordance with ASTM D 3023. The surface hardness of the specimens after the varnishing process was determined in accordance with ASTM D 4366. According to the wood type, impregnation material, and varnish type, the surface hardness was highest for the oak impregnated with borax and acrylic varnish and lowest for the oak impregnated with borax and synthetic varnish. Therefore, impregnation with boron compounds showed an increasing impact on the surface hardness of the varnished wood. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Varnish layer hardness of oriental beech (fagus orientalist L.) wood as affected by impregnation and bleaching

The impacts of impregnation and bleaching on the varnish layer hardness of Oriental beech (Fagus orientalist L.) wood were investigated. A number of bleaching combinations {[NaOH−H₂O₂], [NaOH−Ca(OH)₂−H₂O₂], [NaOH−MgSO₄−H₂O₂] [NaHSO₃−H₂C₂O₄], [NaSiO₃−H₂O₂], [KMnO₄+NaHSO₃+H₂O₃]} were applied at 18% concentration for bleaching to both impregnated and unimpregnated specimens of Oriental beech wood. Subsequently, water-based (WB) varnish was coated over the samples and the varnish layer hardness values were determined in accordance with ASTM D 4366-95. All of the chemicals used for bleaching reduced the surface hardness. However, after varnish coating, the hardness of most samples was similar to that of the varnish-coated natural (control) samples.     

The effect of zinc oxide nanoparticles on the weathering performance of wood-plastic composites

In recent years, wood-plastic composites (WPCs) have become among the most popular engineering materials. Most of their usage areas are outdoors, where they encounter various damaging factors. The weathering conditions cause significant deterioration to WPC surfaces, which negatively influences their service life. In this study, zinc oxide nanoparticles at different concentrations (1%, 3%, 5%, 10%) were added to a high-density polyethylene-based WPC matrix. The effect of zinc oxide nanoparticles on the weathering performance of WPC was evaluated after 840 hours of an artificial weathering test. The highest colour changes (∆E*) were monitored with control samples exposed for 840 hours. Adding zinc oxide nanoparticles improved the ultraviolet (UV) resistance and decreased the colour changes. The wood flour content also affected the colour changes on the WPC surface. A combination of 10% zinc oxide nanoparticles and 50% wood flour content provided the lowest colour changes. The barrier effect of nanoparticles protected the WPC surfaces from UV light. Zinc oxide nanoparticles also positively affected the load transfer, which restricted the reduction in mechanical properties after the weathering test. The degradation on the surface of WPCs was also investigated using attenuated total reflectance-Fourier Transform–infrared analysis. The changes in the characteristic bands of polymer and wood indicated that surface degradation was inevitable. Light and scanning electron microscopy images also demonstrated micro-cracks and roughness on the surface of WPCs. It is concluded that UV degradation is unavoidable, but zinc oxide nanoparticles can improve surface resistance against weathering conditions.     

Correlation and modeling between color variation and quality of the surface between accelerated and natural tropical weathering in Acacia mangium,Cedrela odorata and Tectona grandis wood with two coating

To prevent the photodegradation process, a wide range of coatings have been developed. This study evaluated wood color change (ΔE*) and the surface quality index (SQI) generated by ASTM D‐660 standards in wood protected with polyurethane and varnish finishes of three tropical species (Acacia mangium, Cedrela odorata and Tectona grandis) in two weathering conditions (natural and accelerated condition). In addition, a model was developed to predict ΔE* and SQI in natural weathering based on ΔE* and SQI from accelerated weathering. The results showed that the application of these finishes generated variations in the color parameters of wood before being exposed to the elements. Additionally, it was found that finishes generated increases in ΔE*, especially the varnish type finish, and decreasing of SQI. Finally, models were found to predict color changes or surface quality in natural weathering based on color changes or surface quality in accelerated weathering. The model algorithm was expressed by ΔE* or SQI measured (X) and time exposure (t) in accelerated weathering by equation . With these models, it is possible to predict the equivalence of exposure times in natural weathering in tropical conditions for different kinds of finishes in three tropical species. © 2013 Wiley Periodicals, Inc. Col Res Appl, 39, 519–529, 2014     

Impacts of impregnation with boron compounds on surface roughness of woods and varnished surfaces

This study determines the effects of the process of impregnation of boron compounds on the surface roughness of Oriental beech, Scotch pine, Oriental spruce, and Uluda? fir woods and varnished surfaces. For this purpose, samples are prepared according to ASTM D 358 and impregnated according to ASTM D 1413‐99 with a 5.5% solution of boric acid (Ba), borax (Bx), and Ba with Bx (Ba + Bx) and varnished with synthetic varnish (Sv) and water‐based varnish (Wb) in accordance with ASTM D 3023. The surface roughness is determined according to ISO 4287 and TS 930 standards. The results indicate that the surface roughness is the highest in Uluda? fir, Wb, and Bx and the lowest in Oriental spruce, Sv, and Ba + Bx. For the combination of wood, impregnation material, and varnish, the surface roughness is the highest in Oriental beech with Bx and Wb and the lowest in Scotch pine with Ba + Bx and Sv. The surface roughness is less in impregnated samples than unimpregnated samples and in impregnated and varnished samples than impregnated and unvarnished samples. According to these results, boron compounds decrease the surface roughness of varnishes and wood materials. Thus, impregnation of wood with boron compounds decreases the surface roughness. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4952–4957, 2006     

Colour changes of heat‐treated woods of red‐bud maple,European hophornbeam and oak

Colour evolution and colour changes were analyzed from small specimens of three heat treated wood species using the CIE L*a*b* colour space. Upon heat exposure, the wood substance became darker of species; this was accompanied by a steady reduction in lightness. As treatment conditions (e.g., time and temperature) increase, various shades of yellow were favoured for the surface of red‐bud maple wood (Δb = 1.22–9.79). For European hophornbeam wood, increased times at elevated temperatures make a blue (?b) colour the better choice. The total colour difference (ΔE) of the surfaces of wood substrates appear to be well correlated with the treatment temperature and time. The FTIR spectra suggest that the level of modification was insufficient for removing the major cell wall constituents of the wood substrates. All heat‐treated samples showed much less stability against colour difference in outdoor conditions. For red‐bud maple, the greatest improvement was achieved for samples that were treated at 150°C for 2 h (ΔE = 3.12). However, heat‐treated oak wood hadmuch less stability of colour difference for treatment conditions of 150°C for 10 h. © 2010 Wiley Periodicals, Inc. Col Res Appl, 2010.     

Impact of impregnation and bleaching on the surface hardness of oak (Quercus petraea L.) wood

The impact of impregnation and bleaching on the hardness of varnish layers on oak (Quercus petraea L.) wood was investigated. A number of solutions [sodium hydroxide (NaOH) and hydrogen peroxide (H₂O₂); NaOH, calcium hydroxide, and H₂O₂; NaOH, magnesium sulfate, and H₂O₂; sodium bisulfate and H₂C₂O₄ · 2H₂; sodium silicate and H₂O₂; and potassium permanganate, sodium bisulfate, and H₂O₂] were applied at a concentration of 18% to bleach both impregnated [Tanalith‐CBC (T‐CBC) or Imersol‐WR 2000 (I‐WR 2000)] and unimpregnated (natural) wood panels. Subsequently, a water‐based varnish (WB) was coated over the samples, and the hardness of the varnished layers was determined in accordance with ASTM D 4366. Among the samples that were varnish‐coated without bleaching, T‐CBC/WB yielded the highest hardness (59.50), whereas I‐WR 2000/WB exhibited the lowest (49.17). However, among the samples varnish‐coated after bleaching, the highest (56.50) and lowest (40.83) varnish hardness values were obtained with T‐CBC/solution 2/WB and I‐WR 2000/solution 4/WB, respectively. All the chemicals used for the bleaching process reduced the surface hardness. However, after the varnish coating, except for solutions 4 and 6, all the solutions showed hardness values similar to those of varnish‐coated natural (control) samples. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 498–504, 2004     

Thermal conductivity of oriental beech impregnated with fire retardant

This study aims to describe the effects of wood material (oriental beech) impregnated with ammonium sulfate, borax, boric acid, and zinc chloride by using two different methods (pressure and dipping) and finishes with the effects of different varnishes (polyurethane, cellulosic, synthetic) and paints (cellulosic, synthetic, industrial) on thermal conductivity. These materials were used as fire retardants. The lowest thermal conductivity of 0.143 kcal/m h°C was obtained in oriental beech control samples. The highest thermal conductivity of 0.172 kcal/m h°C was obtained in oriental beech impregnated with ammonium sulfate by using pressure and varnished with synthetic varnish. Consequently, wood impregnated with ammonium sulfate by using pressure and finished with synthetic varnish can be used as a construction material where thermal conductivity is required. Wood impregnated with borax by dipping and finished with cellulosic varnish can be used as a construction material where the insulation is required.     

Effect of microwave pretreatment on the color degradation kinetics in mustard greens (Brassica juncea)

In the present work, the impact of microwave pretreatment on the thermal degradation of color (chlorophylls) in mustard greens was studied. The drying experiments were conducted in the range of temperatures from 50 to 80°C. The degradation in the levels of chlorophylls has been quantified using Hunter color values (L*, a*, and b*) and calculating total color difference (ΔE). From the color results, the changes in color values (L*, a*, and b*) were observed as inappreciable, and changes in ΔE were found to be increased during drying. Analysis of kinetic data displayed a first-order reaction kinetics for chlorophyll degradation. Arrhenius equation was used to calculate the activation energies for rate constants, and it has been varied from 13.3 to 27.4?kJ/mol. Thermodynamic parameters, enthalpy of activation (ΔH^#), and entropy activation (ΔS^#) were found to be in the range of 1.40–2.63?J/mol and ?293 to ?305?J/mol?·?K, respectively. The data from the present work revealed that the microwave pretreatment of mustard greens remarkably influenced the retention of chlorophylls in the final dehydrated powder.     

A fallacy in the definition of ΔH*

When a color differs from the reference, it is desirable to ascribe the difference to differences in the perceptual attributes of hue, chroma, and/or lightness through psychometric correlates of these attributes. To this end, the CIE has recommended the quantity ΔH* as a psychometric correlate of hue as defined by ΔH* = [(ΔE*)² - (ΔL*)² - (ΔC*)²]^1/2, where the correlates correspond to either the 1976 CIELAB or CIELUV color spaces. Since ΔH* is defined as a “leftover,” this definition is valid only to the extent that ΔE* comprises exclusively ΔL*, ΔC*, and ΔH* and that ΔL*, ΔC*, and ΔH* are mutually independent compositionally, both psychophysically and psychometrically. It will be shown that as now defined ΔH* lacks psychometric independence of chroma and always leads to incorrect hue difference determination. Such a deficiency causes problems, especially in the halftone color printing industry, since it can suggest an incorrect adjustment for the hue of the inks. A revised definition herein of ΔH* provides a psychometric hue difference independent of chroma, valid for large and small psychometric color differences regardless of chroma. However, for small chromas, the seldom used metric ΔC might be a better color difference metric than ΔH* because complex appearance effects make the perceptual discrimination of lightness, chroma, and hue components more difficult than for high chromas.     

The colour properties of polyester/cotton knitted fabrics coated with poly(N‐vinyl‐2‐pyrrolidone)

The objective of this research was to investigate the use of crosslinked poly(N‐vinyl‐2‐pyrrolidone) (PVP) to coat polyester/cotton knitted fabric, without adversely affecting its dyeing properties. Before dyeing, the knitted fabrics were tested for bursting strength to assess the influence of the coating on their resistance. The dyeing parameters were evaluated as the exhaustion (%), K/S value, colour difference (ΔE), relative strength (RS %) and colour fastness to washing. Bursting strengths were 9.4 for coated and 9.7 kgf cm^?2 for uncoated knitted fabric samples, confirming an insignificant loss in resistance. In the evaluation of K/S, ΔE and RS%, the values for the samples with the highest concentration of PVP were the most different to those for the standard sample. The colour fastness showed satisfactory results indicating that neutralisation and washing after dyeing were effective. These results could lead to increased quality in the textile industry, adding value to products.     

Prediction of optical efficacy of vital tooth bleaching using regression analysis

Establishing a colorimetric guideline to predict the effectiveness of tooth bleaching could produce a more reliable dental treatment. The purpose of this study was to evaluate the effectiveness of tooth bleaching and to test the predictability of tooth color changes. A 10% carbamide peroxide bleaching system was used in studies at Harvard University and at Iwate Medical University in Japan. L*, a*, and b* values (CIELAB) for pre‐ and postbleaching were obtained and color differences (ΔE) were calculated. The b* and L* values of the original tooth color indicated a relatively strong to moderate correlation with ΔE values, whereas a* showed a weak correlation. The multiple‐regression equation obtained from the color data of Harvard subjects performed better than the predictive model. The predicted ΔE correlated strongly with the observed ΔE (r = 0.78). The validation of this equation on data collected from Iwate confirmed the strong correlation (r = 0.74). © 2004 Wiley Periodicals, Inc. Col Res Appl, 29, 390–394, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20048     

Some aspects of the visual scaling of large colour differences—II

In an earlier article the authors related visually‐ scaled large colour differences to ΔE* values calculated using four colour‐difference formulae. All four metrics yielded linear regressions from plots of visual colour difference against ΔE*, and ΔE gave the best linear fit, but the correlations were rather low. In an effort to clarify matters, the previous investigation is expanded to include data not hitherto examined. The link between visual colour difference and ΔE* colour metrics is further explored in terms of a power law relationship over a wide range of lightness, hue, and chroma variations within CIELAB colour space. It is shown that power‐law fits are superior to linear regressions in all cases, although correlations over large regions of the colour space are not very high. Partitioning of the experimental results to give reduced data sets in smaller regions is shown to improve correlations markedly, using power‐law fits. Conclusions are drawn concerning the uniformity of CIELAB space in the context of both linear and power‐law behavior. © 2000 John Wiley & Sons, Inc. Col Res Appl, 25, 116–122, 2000     

Comparison of Conventional Varnishes with Nanolacke UV Varnish With Respect to Hardness and Adhesion Durability

The long-term durability of varnished wooden surfaces used in either indoors or outdoors environments depends on the resistance of varnish layers on these surfaces against potential physical, mechanical and chemical effects to which they may be exposed. In this study, “Nanolacke ultraviolet varnish”, developed by a Turkish dying and varnish industry company and widely accepted as a 21^st century technology has been compared to other conventional varnish systems widely used in the industry in terms of dry film resistance properties. In this study, cellulosic, polyurethane, polyester, synthetic and Nanolacke ultraviolet varnish have been applied on beech (Fagus orientalis L.) and oak (Quercus robur L.) wood samples which had been prepared according to the industry standards. Then, the hardness and adhesion resistance of these layers have been determined according to ASTM D 4366 and ASTM D 3359-2 standards, respectively.     

Weathering,water absorption,and durability of silicon,acetylated, and heat‐treated wood

In this study, two colloidal dispersions of pure amorphous silicon dioxide particles, acetylated, and heat‐treated samples were tested for a possible application as a wood protection agents. The silicon, acetylated, and heat‐treated samples were exposed to an accelerated weathering experiment, and their dimensional stability was assessed. The weathering experiment comprised cycles of 2 h UV‐light irradiation followed by water spray for 18 min. The surface changes of the weathered samples were characterized by FT‐IR spectroscopy and color measurements. According to results, the silicon treatments showed lower color changes than untreated ones. However, acetylated and heat‐treated samples provided the lowest color changes. The resistance of the silicon, acetylated, and heat‐treated wood to decay was studied by means of brown and white rot fungi in laboratory decay tests. Decay test results revealed that acetylated and heat‐treated wood samples showed better decay resistance against P. placenta and C. versicolor than silicon treatments. Samples modified with silicon were exposed in above ground standard lap‐joint test in Ultuna, Sweden. The dispersions of pure amorphous silicon dioxide impregnated in wood did not significantly influence its hygroscopic and dimensional behavior. However, the silicon treatment reduced the color changes caused by weathering. The silicon impregnated samples showed a weak fungal discoloration similar to that of chromated copper arsenate impregnated controls in above ground standard lap‐joint test. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4506–4513, 2006     

Publications Sponsored by the Colour Measurement Committee—VIII

Methods of describing the extent of agreement between the ΔE values calculated from a colour-difference equation and the corresponding visual estimates of colour difference are discussed. Lack of agreement will be due to a combination of errors in the visual assessments, in the measurements, and in the colour-difference equation itself. If there were no error in the instrumental measurements, the equation error for a particular colour difference would be the difference between the calculated ΔE value and the mean visual assessment of a very large number of observers (ΔVtrue). Experimental data in the form of acceptances (%) can be converted to ΔV values directly proportional to the observed colour differences. The overall equation error for n colour differences can be calculated from Eqn 1. The Davidson and Friede data are considered to be the most satisfactory of those presently available for testing the suitability of equations for industrial colour-tolerance work and have been used to assess the accuracy of several well-known equations. After allowing for errors in the visual assessment and in the instrumental measurements, σ(log ΔE) for the 1964 CIE equation was 0.22. Similar values (0.16-0.23) were found for other equations. A lower a-value was found for a very simple empirical equation essentially based on the x, y chromaticity diagram rather than on any transformation of it. The usual transformations tend to be based on data covering the whole chromaticity gamut, whereas real surface colours cover only a fraction of the possible area. This fact, together with the knowledge that most equations are based on data corresponding to small fields of view or large colour differences, could account for the relative failure of the standard equations.