Performance enhancement of dye‐sensitized solar cells via cosensitization of ruthenizer Z907 and organic sensitizer SQ2

Cosensitization is a highly effective technique to enhance the photovoltaic performance of a dye‐sensitized solar cell. The main objective of this work is to improve the performance of dye‐sensitized solar cell using cosensitization approach and investigation of the effect of the organic cosensitizer concentration on the power conversion efficiency of the fabricated solar cell devices. In this work, Z907, a ruthenium dye, has been cosensitized with SQ2, an organic sensitizer, and an overall efficiency of 7.83% has been achieved. The fabricated solar cells were evaluated using UV‐Vis spectroscopy, current‐voltage (I‐V) characteristics, and electrochemical impedance spectroscopy analysis. Our results clearly indicate that the concentration of organic cosensitizer strongly affects the photovoltaic performance of fabricated solar cells. Upon optimization, the cell fabricated with 0.3 mM Z907 + 0.2 mM SQ2 dye solution demonstrated J_sc (mA/cm²) = 21.38, V_oc (mV) = 698.37, FF (%) = 52.46, and power conversion efficiency of η (%)  = 7.83 under standard AM1.5G 1 sun illumination (100 mW/cm²). It was observed that the efficiency of cosensitized solar cells is significantly superior than that of individual sensitized solar cells (Z907 [η  = 5.08%] and SQ2 [η  = 1.39%]). This enhancement in efficiency could be attributed to the lower electron‐hole recombination rate, decrease in competitive absorption of I^?/I^?₃, and less dye aggregation because of the synergistic effect in cosensitized solar cells.     

Analysis of thin silicon solar cells for high efficiency

A comprehensive theoretical analysis taking into account the contribution from both the emitter and base regions having finite surface recombination velocity has been developed for computing short-circuit current, open-circuit voltage, and efficiency of thin AR coated thin silicon solar cells with textured front surface. The dependence of efficiency on the front surface and back surface recombination velocities and on the cell parameters have been investigated in details for varying cell thickness considering the effects of bandgap narrowing and Auger recombination in the material. It is shown that efficiency exceeding 24% can be attained with silicon solar cells having thickness as low as 25 μm provided both front and back surfaces are well passivated (S < 10³cm/s) and the doping concentration in the base and emitter are in the range of 5 × 10¹⁶ to 10¹⁷cm⁻³ and 10¹⁸ to 5 × 10¹⁸cm⁻³, respectively. It is also shown that an efficiency of about 23% can be obtained for thin cells of 25 μm thickness with a much inferior quality materials having diffusion length of about 40 μm.     

An integrated system of zinc oxide solar panels,fuel cells,and hydrogen storage for heating and cooling applications

Due to the production of hydrogen, using fuel cells for energy conversion and storing encounters safety problems. Combining high-temperature solid oxide fuel cells with photovoltaic solar panels or zinc oxide solar panels can be a good candidate to produce/convert and store the energy more efficiently for using at peak times. The current paper intends to analyze the efficiency of integration of zinc oxide solar panels and fuel cells to produce hydrogen directly. Therefore, the excess step of converting electricity to hydrogen and re-converting it to electricity, which is customarily used for the integration of the photovoltaic and solid oxide fuel cells, could be skipped. The new method paves the way for providing the required energy for heating/cooling through the floor heating and ceiling cooling systems as well as generating electricity. The article also demonstrates that it is possible to have heat during the day and night for an area of 1920 m² and 542 m². It is also possible to create coolness during the day and night for an area of 925 m² and 260 m².     

A simplified electrical model of the dye-sensitised photoelectrochemical cell

This paper presents a steady-state electrical model of dye-sensitised solar cells with simplified boundary conditions. The codes are considerably concise and the sub-functions had confirmed good extensibility. This model is utilised to predict the current–voltage characteristics and the energy conversion efficiency based on various design and operating properties. The experimental data from the literature have been used to validate the theoretically fitted j?V characteristics of the presented model. Parametric simulations were conducted to analyse the effect of diffusion/drift, dye loading, and electrode thickness on dye-sensitised solar cell performance. Simulated results confirm that diffusion is the major driving force for electron and ion transport, while the drift of electrons is negligible. The model predicts optimal electrode thickness ranging between 10 and 15° μm which is consistent with the thickness (10 μm) used in general experimental studies published in the literature. Additionally, it is observed that there exists a logarithmic relation between the short-circuit current density and the amount of dye adsorption. This observation suggests that there exists a dominated recombination reaction which is responsible towards the high efficiency of DSCs.     

Highly efficient photon-to-electron conversion with mercurochrome-sensitized nanoporous oxide semiconductor solar cells

Dye-sensitized solar cells based on nanoporous oxide semiconductor thin films such as TiO₂, Nb₂O₅, ZnO, SnO₂, and In₂O₃ with mercurochrome as the sensitizer were investigated. Photovoltaic performance of the solar cell depended remarkably on the semiconductor materials. Mercurochrome can convert visible light in the range of 400–600 nm to electrons. A high incident photon-to-current efficiency (IPCE), 69%, was obtained at 510 nm for a mercurochrome-sensitized ZnO solar cell with an I⁻/I₃⁻ redox electrolyte. The solar energy conversion efficiency under AM1.5 (99 mW cm⁻²) reached 2.5% with a short-circuit photocurrent density (J_sc) of 7.44 mA cm⁻², a open-circuit photovoltage (V_oc) of 0.52 V, and a fill factor (ff) of 0.64. The J_sc for the cell increased with increasing thickness of semiconductor thin films due to increasing amount of dye, while the V_oc decreased due to increasing of loss of injected electrons due to recombination and the rate constant for reverse reaction. Dependence of photovoltaic performance of mercurochrome-sensitized solar cells on semiconductor particles, light intensity, and irradiation time were also investigated. High performance of mercurochrome-sensitized ZnO solar cells indicate that the combination of dye and semiconductor is very important for highly efficient dye-sensitized solar cells and mercurochrome is one of the best sensitizers for nanoporous ZnO photoelectrode. In addition, a possibility of organic dye-sensitized oxide semiconductor solar cells has been proposed as well as one using metal complexes.     

Modeling and simulation of solar cells quantum well based on SiGe/Si

In recent years, the development of quantum well solar cells QWSCs (Quantum Well Solar Cells) has generated a great deal of interest. These configurations have shown good promise to optimize the low conversion efficiency of conventional solar cells because of the high rate of absorption losses present in them. In this work, we are interested in modeling and simulation of two different structures of solar cells, a simple solar cell based on silicon Si and a quantum well solar cell SiGe/Si. When a solar cell is compared to 80 quantum well layers of Si_0.8Ge_0.2with a pin solar cell based on Si. The short circuit current J_sc increases from 23.55 to 37.48 mA/cm² with a relative increase of 59.15% found. In addition, the limit of the absorption band of the lower energy photons extends from 1100 nm to 2000 nm.     

Measurement of surface recombination velocity of silicon wafers under sunlight condition by novel photoluminescence surface state spectroscopy

For a successful realization of super-high efficiency solar cells, reduction of surface or interface recombination is required. Thus, it is important to know the value of the surface recombination velocity (S) for the optimization of the passivation technology and for the design of solar cells. In this paper, a photoluminescence (PL) based novel technique for the measurement of the value of S under sunlight is presented, and applied to variously passivated Si surfaces. S was found not to be constant but to depend strongly on the excitation intensity near and above 1 sun condition. The value of S is strongly reduced under concentrated sunlight indicating that concentration of sunlight or use of a thin film is effective for efficiency increase.     

Dark I–V–T measurements and characteristics of (n) a-Si/(p) c-Si heterojunction solar cells

Heterojunction solar cells have been manufactured by depositing n-type a-Si:H on p-type 1–2 Ω cm Cz single-crystalline silicon substrates. An efficiency of 14.2% has been obtained for 1 cm² solar cells by using a simple (Al/(p) c-Si/(n) a-Si:H/ITO/metal grid) structure. With an additional surface texturing, we have reached an efficiency of 15.3% for 1 cm² solar cells. We have investigated the dark IV-curves in order to contribute to a better understanding of the basis of solar cells.     

Novel solar cookers: suitable for small families

This paper presents the fabrication details and on-field experimental studies of two novel solar cookers, suitable for cooking requirements of small families; these are named as small family solar cookers (SFSC-1 and SFSC-2). Small size, good thermal performance, light weight, low-cost and short payback periods are some important features of these cookers. The values of some essential thermal performance parameters, first figure of merit (F₁), second figure of merit (F₂) and standard cooking power suggested by Bureau of Indian Standards and International Standard for box-type solar cookers, have been evaluated by experimental studies and found to be 0.116°C m²/W, 0.466, 30 W and 0.118°C m²/W, 0.488, 50 W for SFSC-1 and SFSC-2, respectively. A comparative analysis of the thermal performances of SFSCs with the solar cookers, developed by many authors, has also been presented here. The payback periods with respect to different cooking fuels for SFSCs have been found to be reasonably short.     

ELECTRODEPOSITED CdTe FOR THIN FILM SOLAR CELLS

Large area 300 mm x 300 mm CdS/CdTe solar cells with record efficiencies over 10% have been fabricated using a reproducible, safe and low cost electrodeposition route for CdTe deposition. CdS window layers have been grown using chemical bath deposition which produces uniform adherent films by a cost effective route. Electrical characterization of small area (0.02 cm²) devices confirms that the structure is p-n rather than p-i-n. Module reliability tests show efficiency stability for more than 16,000 hours outside, and very little change using indoor environmental tests.     

Effect of electrolytes on the photovoltaic performance of a hybrid dye sensitized ZnO solar cell

The efficiency of dye sensitized solar cell depends on the number of factors such as impedance due to anions in the electrolytes, oxidation–reduction process of anions and size of cations of the electrolyte. This paper reports the effect of electrolytes on the photovoltaic performance of hybrid dye sensitized ZnO solar cells based on Eosin Y dye. The size of the cations has been varied by choosing different electrolytes such as LiBr+Br₂, LiI+I₂, tetrapropylammonium iodide +I₂ in mixed solvent of acetronitrile and ethylene carbonate. The impedance of anions has been determined by electrochemical impedance spectra. It is observed that Br⁻/Br₃⁻ offers high impedance as compared to I⁻/I₃⁻ couple. The oxidation–reduction reactions of electrolytes are measured by linear sweep voltammogram. It is found that Br⁻/Br₃⁻ is more suitable than an I⁻/I₃⁻ couple in dye sensitized solar cell (DSSC) in terms of higher open-circuit photovoltage production and higher overall energy conversion efficiency. This is attributed to more positive potential of the dye sensitizer than that of Br⁻/Br₃⁻. The gain in V_oc was due to the enlarged energy level difference between the redox potential of the electrolyte and the Fermi level (E_f) of ZnO and the suppressed charge recombination as well.     

Performance evaluation of solar dryer system for optimal operation: mathematical modelling and experimental validation

An analytical moisture diffusion model which considers the influence of external resistance to mass transfer is developed. The methodology to determine constant and variable moisture diffusion coefficients, D_eff is proposed. A laboratory model of mixed-mode solar dryer is constructed to perform 16 experiments for different performance dependent variables under simulated indoor conditions. The potatoes (Solanum tuberosum) of Kufri Safed variety have been chosen as the test food product. The range of variables investigated is absorbed thermal energy (150–750 W/m²); air mass flow rate (0.009–0.022 kg/s); loading density (1.08–4.33 kg/m²) and sample thickness (5–18 mm). The efficiency results have been analysed to identify the value of each process variable leading to optimal operation of dryer. The study reveals that dryer with sample thickness of 8 mm and loading density of 4.33 kg/m² can operate optimally for absorbed energy of 450 W/m² and air mass flow rate of 0.017 kg/s.     

Electrospun Co-TiC nanoparticles embedded on carbon nanofibers: Active and chemically stable counter electrode for methanol fuel cells and dye-sensitized solar cells

Cobalt-titanium carbide nanoparticles (Co-TiC NPs) embedded on carbon nanofibers (composite) were prepared by electrospinning of a solution containing cobalt acetate tetrahydrate (CoAc), titanium (IV) isopropoxide (TIIP) and polyvinylpyrrolidone (PVP) in acetic acid and ethanol. It was then subjected to a carbonation process at a low temperature (850 °C) since the composite contains metal carbide. The obtained composite, as an efficient electrode, was used as an alternative to Pt-free counter electrode (CE) for fuel cells (FCs) and dye-sensitized solar cells (DSSCs). Cyclic voltammetry (CV) and chronoamperatory (CA) tests were used to measure the composite electrode's performance in methanol oxidation. The results showed that the introduced composite could enhance both methanol electro-oxidation and electrochemical stability as the low onset potential and high current density of the composite electrode were obtained at 189 mV and ～90 mA cm^?2 vs. Ag/AgCl, respectively. The composite also was examined in dye-sensitized solar cells as counter electrode (CE). The results showed that the composite electrode was effective, providing stable electrocatalytic activity (ECA) and conductivity, indicating the composite can improve catalytic activity in triiodide reduction. The short-circuit current density (J_sc), open circuit voltage (V_OC), fill factor (FF), and energy conversion efficiency (η) were found to be ～9.98 mA cm^?2, 0.758 V, 0.507 and 3.87%, respectively. The high ECA could be attributed to the synergic effects from all the pristine components.     

Mutual effect of extrinsic defects and electronic carbon traps of M-TiO2 (M = V,Co, Ni) nanorod arrays on photoexcited charge extraction of CdS for superior photoelectrochemical activity of hydrogen production

Understanding the photoexcited charge carrier dynamics such as separation, transportation and extraction in smart hybrid nanocomposites is the key to high performance solar cells. Nanocomposites possess advantage of broader solar absorption with their fast photoexcited charge separation and transportation but their use as photocorrosion-stable material is yet to be explored. Also, bulk and surface defects in individual components of the nanocomposites boost the efficiency of the solar cells, despite of the fact the recombination of the photoexcited charges at the interfaces lead to a substantial loss of charges and realizing a big challenge. Herein, the extrinsic defects like bulk and surface defects are induced by transition metal (M = V, Co, Ni) doping of M ? TiO₂ nanorod arrays. Consequently, the hydrothermal synthesis method offers the tuning of the carbon trapping states depending upon the type of the metal doped in M ? TiO₂ that decelerates the charge carrier dynamics in the M-TiO₂/CdS (M = V, Co, Ni) nanocomposites with the increase in the amount of carbon. Excellent charge extraction is observed in VTiO₂ (4% carbon) from its CdS sensitizer with photocurrent density of 2.06 mA/cm² than NiTiO₂ (14.6% carbon), TiO₂ (18.94% carbon) and CoTiO₂ (39.2% carbon) with photocurrent densities of 1.83, 1.46 and 1.34 mA/cm² at 0 V versus Ag/AgCl under 100 mW/cm² light intensity, respectively. This shows primary dependence of photoexcited charge dynamics upon the density of the carbon trapping states to be least while secondary dependence upon the density of the extrinsic defects in M ? TiO₂ to be maximum. This work creates a paradigm for future studies to have a broader insight of the photocatalyst's overall functioning to boost the efficiencies in solar cells by controlling the amount of electronic carbon traps during the synthesis of a large class of inorganic semiconductor photocatalysts.     

Temperature-dependent quantum efficiency analysis of graded-gap Cu(In,Ga)Se2 solar cells

Despite the high solar cell efficiencies achieved with Cu(In,Ga)Se₂ (CIGS) absorbers, key parameters such as the carrier diffusion length and recombination lifetime are still under investigation. Here, we extract lifetime and diffusion length from temperature-dependent internal quantum efficiency (IQET) spectra of state of the art high efficiency CIGS solar cells. Two-parameter fits to the measured IQE curves using a model for double-graded gap solar cells show very good agreement in the studied temperature range T=146–293 K, allowing the extraction of the electron recombination lifetime in the absorber and the collection probability in the front region of the cell. The obtained results agree with current literature values obtained by other characterization techniques. Furthermore, the temperature dependence of the recombination lifetime is explained by Shockley–Read–Hall recombination through a single bulk defect level with an activation energy of 200 meV.     

Thermal management of solar cells using a nano‐coated heat pipe plate: an indoor experimental study

With temperature increasing, the photovoltaic efficiency of solar cells is reduced significantly. Such an efficiency loss may offset the efficiency improvement because of the development of the photovoltaic technology. This paper provides a novel approach for efficiency loss recovery of solar cells. Specifically, a nano‐coated heat pipe plate was integrated with the solar panel to remove heat from the hotspots on solar cells. This study concerns the indoor experiments of a commercial solar cell thermally managed with a heat pipe plate. The temperature rise and non‐uniformity on the solar panel were quantified in different light irradiances. With thermal management by the heat pipe plate, the solar panel shows a temperature‐rise reduction of 47–50%. This implies that half of the efficiency loss of the solar cell can be recovered. In addition, the temperature variation within the solar panel is reduced to 1.0–2.5 °C, which is beneficial in prolonging the longevity of the solar cell. In the experiments, the heat pipe plate can provide a cooling flux of 380 W/m² with light irradiance below 1000 W/m². By incorporating the heat pipe plate with a water jacket, the heat removal flux could be improved to 600 W/m², leading to a solar cell temperature of a few degrees higher than the ambient. Copyright © 2016 John Wiley & Sons, Ltd.     

Preparation of semiconducting copolymer and its application in nanocrystalline TiO2 solar cells

Abstract

The past decade has witnessed increasing attention in the nanocrystalline TiO₂ solar cells (TSSCs). In this work, we have studied a novel TiO₂/PCBM/PPy solar cell based on blends of the semiconducting copolymer polypyrrole (PPy) and [6,6]-phenyl C₆₁ butyric acid methyl (PCBM) coated titanium dioxide (TiO₂) nanocrystal film to substitute the I₃^?/I^? redox electrolyte and the dye using in DSSCs. The research by incident photon to current efficiency spectra shows that the TiO₂ films had a stronger absorption in 300–500 nm light range. The performance of the resulting photovoltaic devices was investigated, and the effects of the PCBM/PPy ratio by photocurrent–voltage characteristics were researched. By the optimised PCBM/PPy ratio was 3∶1, The TSSC exhibited a short circuit current of 1·28 mA cm^?2, an open circuit voltage of 0·788 V, a fill factor of 0·654 and a light to electric energy conversion efficiency of 0·622% under a simulated solar light irradiation of 100 mW cm^?2.     

Enhanced hydrogen production over incorporated Cu and Ni into titania photocatalyst in glycerol-based photoelectrochemical cell: Effect of total metal loading and calcination temperature

The solar driven hydrogen production was successfully investigated in a glycerol-based photoelectrochemical cell (PEC) over nanostructured TiO₂ supported bimetallic Cu and Ni by adjusting total metal loading (5, 10, and 15 mol%) and calcination temperature (400, 450, 500, and 600 °C). The effects of the mentioned parameters on physicochemical and photoelectrochemical properties of prepared Cu–Ni/TiO₂ photoanodes were explored by using different characterization techniques. The hydrogen evolution was experimentally found to be affected total metal loading and calcination temperature. The calcined photocatalyst with the total metal loading of 5 mol% at 450 °C was identified as the most efficient photocatalyst by producing maximum accumulative hydrogen of 694.84 μmol. A high performance of this photocatalyst is mainly attributed to its proper particle size and great ratio of Ti³⁺:Ti⁴⁺ and Cu⁺:Cu²⁺ in TiO₂ matrix. These better physicochemical properties enhanced charge carrier separation, which retarded the charge recombination and enhanced the transportation of photo-induced electrons at the photoelectrode/electrolyte interface. The intermediates from photooxidation of glycerol were verified using high performance liquid chromatography, indicating a partial oxidation of glycerol with selective pathway in KOH (1 M) solution. This work demonstrates that optimization Cu–Ni/TiO₂ photoanode has the practical potential in PEC cell to generate hydrogen from solar and biomass energy.     

Effect of hydrogen radical annealing on SiN passivated solar cells

Remote plasma was used for PE-CVD of SiN films and it was found that hydrogen radical (H^* ) annealing of c-Si cells with SiN films improved the efficiency of the cells. Cell efficiency of 21.8% was obtained by applying a SiN/SiO₂ double-layer structure on the emitter of a PERL-type solar cell. It was found that the H^* annealing has two effects: it reduces surface recombination velocity (SRV); and it degrades bulk-lifetime of p-type c-Si. To apply SiN practically, it is effective to use a rear n-floating or a triode structure. Reducing the exposed area of the p-type substrate by using n-type diffused layer increases the efficiency of solar cells.     

Aqueous dye-sensitized solar cell based on new ruthenium diphenyl carbazide complexes

The major challenge of the operation of every solar cell based on dye including water splitting solar cell (WSSC) and dye sensitized solar cell (DSSC) is the using organic solvent medium which causes to decompose the solar cell structure, resulting environmental impact. Here, we synthesized and characterized two new ruthenium complexes with nitrogen and oxygen donor ligands for DSSC application which show good stability on TiO₂ surface in water solvent. Interestingly, the DSSC based on [Ru(dcbpy)₂(DPC)]Cl, where dcbpy = 4,4-dicarboxilic acid 2,2-bipyridin and DPC = diphenylcarbazide, was shown better efficiency in water than methanol dye loading as well as N3 as a benchmark sensitizer in the same condition. The DPC-based exhibited open circuit voltage (V_oc) of 0.63 V, short-circuit current density (J_sc) of 2.5 mA/cm² and fill factor (FF) of 70%, resulting an overall power efficiency of 1.12%. The incident-photon-to-current conversion efficiency (IPCE) value is also reached to 45% for [Ru(dcbpy)₂(DPC)]Cl in the same condition It is proposed that the ruthenium complex containing nitrogen and oxygen donor ligands is more stability on TiO₂ and prevent the decomposition of TiO₂ porous under water solvent condition.