共查询到18条相似文献,搜索用时 109 毫秒
1.
反应精馏技术的研究现状及应用 总被引:5,自引:0,他引:5
对反应精馏技术的研究现状及其应用进行了综述,介绍了反应精馏塔及催化剂,对催化剂床中传质及流体力学特征,数学模型和反应精馏塔设计方程进行了总结;同时介绍了反应精馏技术的应用现状及其可能的应用领域。 相似文献
2.
反应精馏技术的研究现状及应用进展 总被引:1,自引:0,他引:1
反应精馏是化学反应和精馏过程耦合为一体的单元操作,已成为当今的重要研究领域。本文对反应精馏技术的研究现状及其应用进行了综述,介绍了反应精馏塔及催化剂,对催化剂床中传质及流体力学特征,数学模型和反应精馏塔设计方程进行了总结;同时介绍了反应精馏技术的应用现状及其可能的应用领域. 相似文献
3.
4.
5.
综述了催化精馏技术的原理和催化精馏塔的结构,介绍了国内催化精馏技术在催化精馏塔、催化剂和数学模型方面的研究进展及其工业应用情况。 相似文献
6.
7.
8.
反应精馏技术及其应用 总被引:3,自引:0,他引:3
反应精馏技术是伴有化学反应的精馏技术,它具在可提高反应的选择性和转化率,降低能耗,节省投资等特点,本文简单介绍了的反应精馏的优点,反应精馏塔的结构及其应用。 相似文献
9.
10.
叙述了催化精馏技术的概念、优点及其作用原理,简单介绍了催化精馏技术中催化精馏塔的类型、催化剂的种类及其装填方式以及催化精馏技术在酯化、醚化、异构化、烷基化等方面的应用,以及近年来研发的一些新技术。 相似文献
11.
By means of water as an extractant, the two-feed and three-feed reactive distillation production processes of methylal are synthesized and analyzed. The effects of water on the methylal reactive distillation (RD) production is investigated. Thermally coupled two-feed and three-feed reactive dividing-wall columns are proposed and analyzed. The two-feed and three-feed RD processes are compared. The three-feed thermally coupled reactive dividing-wall column (DWC) exhibits an outstanding ability of energy and cost savings. Results from this work could be helpful for further development and application of RD or reactive DWC in methylal production. 相似文献
12.
13.
Nonlinear feedback control scheme for reactive distillation column has been proposed. The proposed control scheme is derived
in the framework of Nonlinear Internal Model Control. The product compositions and liquid and vapor flow rates in sections
of the reactive distillation column are estimated from selected tray temperature measurements by an observer. The control
scheme is applied to an example reactive distillation column in which two products are produced in a single column and the
reversible reaction A+B=C+D occurs. The relative volatilities are favorable for reactive distillation so that the reactants
are intermediate boilers between the light product C and the heavy product D. Ideal physical properties, kinetics, and vapor-liquid
equilibrium are also assumed. It is shown that the proposed control scheme keeps tight product composition control. 相似文献
14.
Liu Mo Jiang Shao-Tong Pan Li-Jun Zheng Zhi Luo Shui-Zhong 《Chemical Engineering Research and Design》2011,89(11):2199-2206
Esterification of raw lactic acid from fermentation broth and then hydrolysis of lactate ester in reactive distillation column is an effective process for purification of lactic acid. Reactive distillation for hydrolysis of methyl lactate is studied. First, the thermodynamic properties and reaction kinetics are analyzed; then the reactive distillation column is designed based on the objective function total annual cost. The effects of tray number of rectifying section, tray number of reactive section, and feed location on the total annual cost are investigated. And a dual-temperature control structure is proposed for the optimal reactive distillation column, and the results show that it works quite well for this hydrolysis system. 相似文献
15.
Ukrit Sahapatsombud Amornchai Arpornwichanop Suttichai Assabumrungrat Piyasan Praserthdam Shigeo Goto 《Korean Journal of Chemical Engineering》2005,22(3):387-392
In this work, a reactive distillation column in which chemical reactions and separations occur simultaneously is applied for
the synthesis of tert-amyl ethyl ether (TAEE) from ethanol (EtOH) and tert-amyl alcohol (TAA). A rate-based kinetic model
for liquid-phase etherification and an equilibrium stage model for separation are employed to study the reactive distillation.
The calculation is carried out using the commercial software package, Aspen Plus. Simulations are performed to examine the
effects of design variables, i.e., a number of rectifying, reaction and stripping stages on the performance of reactive distillation
column. It has been found that an optimal column configuration for the TAEE production under the study is designed with no
rectifying, 4 reaction and 8 stripping stages. With such an appropriate specification of the reactive distillation column,
the effects of various operating variables on the TAA conversion and TAEE selectivity are further investigated and the results
have shown that the reflux ratio and operating pressure are the most important factors to the operation of the reactive distillation. 相似文献
16.
17.
乙酰丙酸乙酯是一种潜在的生物质基平台化合物,在工业上具有很高的应用价值。乙酰丙酸乙酯传统的生产方法主要为间歇反应法,效率较低,产物分离困难且工艺流程较长。因此,本文提出了反应精馏工艺生产乙酰丙酸乙酯,在以中试实验结果为依据的基础上,使用Aspen Plus模拟软件建立了工艺流程,并考察了回流比、进料位置、进料摩尔比以及理论塔板数等关键参数,得到了常规单塔反应精馏工艺生产乙酰丙酸乙酯的最优配置。而后,为了得到纯度大于99.9%的乙酰丙酸乙酯,本文进一步提出了反应精馏双塔精制流程以及反应精馏隔壁塔流程,并通过对两种流程所得到的产品纯度以及能耗的对比,验证了反应精馏隔壁塔工艺生产乙酰丙酸乙酯的有效性以及在节能方面较大的优势。 相似文献
18.
Z. vandov J. Marko
. Jelemenský 《Chemical engineering journal (Lausanne, Switzerland : 1996)》2008,140(1-3):381-390
A significant part of the safety analysis of a reactive distillation column is the identification of multiple steady states and their stability. A reliable prediction of multiple steady states in a reactive distillation column is influenced by the selection of an adequate mathematical model.For modelling reactive distillation columns, equilibrium (EQ) and nonequilibrium (NEQ) models are available in the literature. The accuracy of the nonequilibrium stage model seems to be limited mainly by the accuracy of the correlations used to estimate the mass transfer coefficient and interfacial area.The binary mass transfer coefficients obtained from empirical correlations are functions of the tray design and layout, or of the packing type and size, as well as of the operational conditions and physical properties of the vapour and liquid mixtures.In this contribution, the nonequilibrium model was used for the simulation of a reactive distillation column. For prediction of the binary mass transfer coefficient for a sieve tray, four correlations were chosen to show their impact on the prediction of the reactive distillation column behaviour. As a model reactive distillation system, the synthesis of methyl tertiary-butyl ether (MTBE) was chosen. The steady-state analysis and the dynamic simulation of the model system were done. Qualitative differences between the steady states were predicted using the chosen correlations. 相似文献