共查询到19条相似文献,搜索用时 59 毫秒
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研究了铕酞菁、钕酞菁和镨酞菁配合物的合成、提纯与表征的方法。合成及表征结果表明,合成所得酞菁化合物通过元素分析可知,具有纯度高、红外光谱表征推测结构可靠。紫外分析表明铕酞菁、钕酞菁和镨酞菁配合物特征吸收峰有相似之处。 相似文献
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邻氨基苯甲酸-2,2'-联吡啶铕镧配合物的合成及表征 总被引:2,自引:2,他引:0
用氯化稀土与邻氨基苯甲酸铵和2,2′-联吡啶在水溶液中反应,合成了邻苯甲酸-2,2′-联吡啶-Eu-La固体稀土配合物,经元素分析,其化学组成式为(Eu0.5La0.5)L3L′(其中L=邻氨基苯甲酸,L′=2,2′-联吡啶),测定了配合物的红外光谱和荧光光谱,实验结果表明,两配体与稀土离子形成了配位键;用不发光的 La∧3 离子取代EuL3L′配合物中部分Eu∧3 离子可以提高Eu∧3 离子的特征荧光发射强度。 相似文献
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以苯磺酸和氧化镨为原料合成并培养得到苯磺酸镨晶体{[Pr(H2O)9](C6H5SO3)3}n,通过热重分析、红外吸收光谱和X-射线单晶衍射对其进行了表征。晶体结构表明:该配合物属于正交晶系,Pnma空间群,晶胞参数为a=29.940(4),b=7.269 8(9),c=13.866 1(17),α=90o,β=90o,γ=90o,V=3 018.1(7),Z=4,F(000)=1 580,R1=0.051 2,wR2=0.084 2。中心金属离子以水合离子[Pr(H2O)9]3+的形式存在,苯磺酸基团仅作为抗衡阴离子,并未发生配位。 相似文献
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以4-硝基邻苯二甲腈为原料合成了四叔丁氧基酞菁锌,通过IR、UV-Vis和荧光光谱进行了表征,并研究合成产物的溶解性.结果表明取代酞菁锌的具有好的溶解性,不发生二聚,紫外可见光谱发生红移. 相似文献
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溶胶凝胶法合成镨、钕硅酸锆色料的研究 总被引:6,自引:1,他引:6
采用溶胶 -凝胶法成功地制备了镨黄、钕紫色料 ,对不同的矿化剂 ,在不同的温度合成的色料进行了XRD、XPS、分光反射率和颗粒度的测试。结果表明 :和固相合成法相比 ,采用溶胶 -凝胶法合成的试样 ,其呈色更好 ,粒度分布更窄。 相似文献
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长链羧酸铕四元配合物的合成及其发光性质 总被引:5,自引:0,他引:5
合成了铕与长链羧酸、二苯甲酰甲烷、邻菲啰啉形成的四元配合物,用元素分析、红外光谱、核磁共振氢谱和紫外光谱对所合成的铕四元配合物进行了表征。由于长链羧酸的引入,铕配合物在氯仿等挥发性有机溶剂中具有良好的溶解性,这为今后与高分子基体复合创造了条件。铕配合物在342nm光波激发下,发出以铕的特征发射谱线612nm左右为主的强荧光。 相似文献
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以硝酸盐和尿素为基质,采用燃烧法在650℃合成了SrAl2O4:Eu2+,Dy3+,Pr3+长余辉发光粉体.研究了样品的晶体结构、晶粒大小及发光性能.结果表明:Eu2+,Dy3+,Pr3+共掺杂的磷光体没有改变铝酸锶的晶体结构,平均晶粒尺寸为41.5nm;激发和发射光谱分别为360nm和515nm的宽带谱,与SrAl2... 相似文献
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Richard H. Jones Alexander T. Ashcroft David Waller Anthony K. Cheetham John M. Thomas 《Catalysis Letters》1991,8(2-4):169-174
The selective partial oxidation of methane over the europium iridium pyrochlore, Eu2Ir2O7, has been studiedin situ by using powder X-ray diffraction and mass spectrometry. At a temperature of 873 K and 1 atmosphere pressure, with a CH4O2 ratio of 21 under argon dilution, high yields of synthesis gas are obtained. The pyrochlore structure of the iridate is modified during the initiation of the catalyst, giving an active solid that is shown to comprise particles of iridium metal, 30 Å in diameter, supported on europium oxide, Eu2O3. The modification of the pyrochlore structure was monitored by X-ray diffraction, and the product gases were continuously analysed by mass spectrometry. 相似文献
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采用紫外-可见分光光度计,研究了固定工艺条件下十二烷基二甲基甜菜碱(BS-12)与琥珀酸二(2-乙基己基)酯磺酸钠(SDOS)两种表面活性剂及钕离子对金属表面化学镀镍磷的影响,得到较佳的工艺条件:SDOS与BS-12摩尔比为1:1,Ni~(2+)与H_2PO_2-摩尔比为0.3,pH=8,70℃施镀并添加适量的硫酸钕.探讨了表面活性剂的作用机制.结果表明,在固定的基础镀液中加入SDOS与BS-12混合表面活性剂,镀液会产生明显的温度效应和很强的协同效应,其镀速的增加比相应的单一表面活性剂所产生的增幅要大;加入稀土金属钕离子后,镀速下降,但镀层质量得到改善. 相似文献
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Byung-Hae Jung Do-Kyung Lee Sang-Ho Sohn Hyung-Sun Kim 《Journal of the American Ceramic Society》2003,86(7):1202-1204
Because of their thermal, dielectric, and optical properties, new glass compositions and thick-filmed transparent dielectrics containing neodymium oxide (Nd2 O3 ) were studied as a source of purer images in plasma display panels. In the present study, PbO–B2 O3 –SiO2 and PbO–B2 O3 –SiO2 –ZnO–Al2 O3 were used as starting glass compositions, to which up to 25 wt% of Nd2 O3 then was added. Increased amounts of Nd2 O3 increased the glass transition temperature and dielectric constant of the bulk glasses and decreased the coefficient of thermal expansion. The fired thick films (around 30 μm) allowed selectively visible light to penetrate and showed deep absorption properties at 585 nm that were related to an extraneous gas from neon discharge. 相似文献
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John S. Preston Anna C. du Preez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1996,65(1):93-101
The chemical reduction of pure europium(III) chloride solutions was investigated using reagents comprising reactive metals (Zn and Mg), metal amalgams (Zn-Hg, Na-Hg and Eu-Hg), metal hydride (NaBH4) and nitrogenous reductants (N2H4 and NH2OH). Using 100% excess of reducing agent and of ammonium sulphate, efficient precipitation of europium(II) sulphate was obtained with the metal amalgams (99·7–99·9%) and with zinc metal (99·8%), whereas only partial precipitation was obtained with magnesium metal (69%), and no precipitation was observed with the other reagents. Application of the method to synthetic rare earth chloride solutions containing europium 7·5, neodymium 5, samarium 35 and gadolinium 20 g dm−3 gave efficient precipitation of europium(II) sulphate with zinc and europium amalgams, but no selective precipitation with sodium amalgam. Reduction of an authentic middle rare earth chloride solution with zinc amalgam gave 97·5% recovery of europium(II) sulphate containing (as a percentage of the total rare earths) europium 92, samarium 3·5, neodymium 2, cerium 1, praseodymium 0·6 and gadolinium 0·5%. Conversion of the europium(II) sulphate to europium(II) chloride, followed by re-precipitation of the sulphate increased the europium content only to 96·5%, whereas replacement of the re-precipitation by solvent extraction of the trivalent rare earth impurities into solutions of commercial organophosphorus or carboxylic acids in xylene increased the europium content to > 99·98%. The zinc ions introduced into the middle rare earth mother liquor during the reduction procedure can be removed by solvent extraction into a commercial phosphine oxide (Cyanex 925), without loss of rare earth values. 相似文献