共查询到20条相似文献,搜索用时 271 毫秒
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用不附加另外电源的DC-PCVD装置沉积Si3N4薄膜,,XRD TEM检查出这种Si3N4是非晶态、IR,AES验证这种薄膜的主要成分是Si3N4、TEM与OM研究 薄膜组织结构。 相似文献
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采用电子回旋共振等离子体化学气相沉积(ECR-PECVD)技术制备了Si3N4薄膜。利用显微硬度计测定了Si3N4薄膜的表面微硬度。由摩擦测试机对SiN4薄膜的摩擦性能进行了测试分析。结果表明,Si3N4薄膜的摩擦系数和单位时间的磨损量较小,该膜具有良好的耐磨性和耐划伤能力。 相似文献
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介绍了一种利用激光化学气相沉积技术,在平面石英玻璃衬底上沉积平凸形Si3N4球面介质膜用作微透镜,包括LCVD的实验装置及其沉积工艺,实验结果表明,只要适当控制源气体的化学配比与浓度,调节激光功率与衬底上的聚集激光光斑尺寸,选择适当的沉积时间,就可以获得不同直径、透明、表面光滑的Si3N4球面介质膜,用作微透镜。 相似文献
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以N2,CH4作为反应气体,采用微波等离子体化学气相沉积法(MPCVD)进行碳氮膜的合成研究。通过控制反应温度、气体流量、微波功率、反应气压,在Si(111)和Si(100)基底上气相合成β-C3N4晶态薄膜。扫描电子显微镜(SERM)下观察到生长在Si基底上的薄膜具有六角晶棒的密结构。EDX分析胡沉积条件的不同,六角晶棒中N/C在1.0~2.0之间。X射线衍射分析(XRD)发现薄膜中含有β-C3 相似文献
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采用(CH3)2SiCl2和N2H4反应产物为先驱体,在H2,NH3气条件下,用CVD法制备Si/C/N的纳米微粉,在制备Si/C/N纳米微粉的过程中通过高温炉-气相色谱联用技术分析了裂解逸出的气体,用化学法分析了微粉中元素组成变化,讨论了先驱体H2,NH3气体条件下的裂解机理及微粉的形成机理。 相似文献
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电沉积Ni—P,Ni—P—Si3N4非晶态合金及其结构,性能研究 总被引:2,自引:0,他引:2
研究了Ni-P、Ni-P-Si3N4非晶态合金薄膜的是沉积工艺,通过SEM-EDS,XRD,EMPA等微观分析方法,提出了获取8 ̄14wt%Ni-P和Ni-P-Si3N非晶合金镀层的镀液组成和电沉积参数。实验表明,Ni-P非晶态合金镀层在碱液中具有优越的耐蚀性能,在含Cl^-1的中性盐液中有良好的耐蚀性,且不产生点蚀;Ni-P-Si3N4非晶合金镀层,经晶化处理后,耐蚀性能提高,且与基材呈冶金结合 相似文献
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对4Cr5MoSiV1钢和3Cr2W8V钢分别进行3SNC-RE共渗加氧化、SNC共渗加氧化和SNC-RE共渗等表面处理,并对经处理的试样分别进行了热疲劳性能和铝液腐蚀性能试验研究。 相似文献
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研究了生工在硅片,合金钢片上的氮化碳薄膜的X射线衍射谱(XRD),实验结果表明在硅片上先生长Si3N4过渡层和对样品进行热处理,有利于β-C3N4晶体的生成,不同晶面的硅衬底,生长C3N4薄膜的晶面不同,合金钢片上C3N4薄膜,出现七个β-C3N4衍射峰和六个α-C3N4衍射峰,这些结果与β-C3N4和α-C3N4的晶面数据计算值相符合。 相似文献
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《Science and Technology of Advanced Materials》2003,4(4):397-402
Yttria stabilized zirconia (YSZ) can be employed as thermal barrier coatings (TBCs) on Ni-based super alloys in gas turbines and aircraft engines. The YSZ coatings have been fabricated by atmospheric plasma spraying or electron-beam physical vapor deposition. The increase in operation temperature of gas turbines demands another fabrication process to obtain high quality TBCs. Chemical vapor deposition (CVD) can be an alternative route to prepare TBCs due to excellent conformal coverage and columnar microstructure. This paper reviews the fabrication of YSZ films by conventional thermal CVD and plasma CVD intended for TBCs. A new laser CVD developed by our group with a high deposition rate of 660 μm h−1 was also briefly introduced. 相似文献
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J.R. Vargas Garcia 《Science and Technology of Advanced Materials》2013,14(4):397-402
Yttria stabilized zirconia (YSZ) can be employed as thermal barrier coatings (TBCs) on Ni-based super alloys in gas turbines and aircraft engines. The YSZ coatings have been fabricated by atmospheric plasma spraying or electron-beam physical vapor deposition. The increase in operation temperature of gas turbines demands another fabrication process to obtain high quality TBCs. Chemical vapor deposition (CVD) can be an alternative route to prepare TBCs due to excellent conformal coverage and columnar microstructure. This paper reviews the fabrication of YSZ films by conventional thermal CVD and plasma CVD intended for TBCs. A new laser CVD developed by our group with a high deposition rate of 660 µμh-1 was also briefly introduced. 相似文献
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Volkmar Hopfe 《真空研究与实践》2002,14(4):206-212
Laser activated CVD can be applied in different ways: (i) wide area coating having the potential of continuously coating temperature sensitive substrates (parallel beam), (ii) coating on shaped parts, e. g. fibres, (iii) micro structuring/ patterning, e. g. for rapid prototyping or repair of wafers, (iv) build‐up of 3‐dimensional microstructures on substrates under for designing/making microsystems, (v) forming nano‐powders with narrow size distribution, e. g. for advanced ceramics. Evaluation of the industrial potential of the most prospective developments is underway. One of these areas being covered more in detail comprises high speed coating of fibers. The fibres are used for manufacturing damage‐tolerant fiber reinforced ceramic composites. Based on a industrial 6 kW cw‐CO2 laser, an atmospheric pressure laser CVD process has been established which performs continuous coating of fiber bundles. The laser CVD method is characterized by several significant advantages, among them deposition rates of typically > 1 μm/s, small volume cold‐wall reactors, and short residence time of the fibers in the deposition chamber, which avoids fiber degradation. As another feature favoring industrial application, the process can be performed at atmospheric pressure in an open reactor with a continuous air‐to‐air coiling of the fiber bundles. The prototype laser CVD reactor established at Fraunhofer Institute is equipped with in‐situ FTIR sensorics for process monitoring and chemistry control. Cost distribution analysis is used for making preliminary efficiency assessment of the innovative coating process. 相似文献
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电感耦合等离子体CVD室温制备的硅薄膜的结构研究 总被引:3,自引:0,他引:3
用内置式单圈电感耦合等离子体化学气相沉积(ICP-CVD)方法在室温下制备Si薄膜.用傅里叶红外吸收光谱、喇曼光谱、原子力显微镜和分光椭圆偏振谱等测量分析表明,即使在室温下用ICP-CVD也获得了有纳米结晶相的Si薄膜,样品结构与源气体SiH4浓度密切相关.实验结果预示着在高电子密度的ICP-CVD过程中,活性原子集团的形成以及薄膜的生长机理与传统的等离子体CVD过程不同. 相似文献
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Y. Zhou X. Yan E. Kroke R. Riedel D. Probst A. Thissen R. Hauser M. Ahles H. von Seggern 《Materialwissenschaft und Werkstofftechnik》2006,37(2):173-177
Amorphous hydrogenated silicon oxocarbonitride (SiCNO:H) films have been deposited by plasma‐assisted chemical vapour deposition (PACVD) using bis(trimethylsilyl)carbodiimide (BTSC) as a single source precursor in a argon (Ar) radio‐frequency plasma. In this work the SiCNO:H films deposited at different deposition temperatures were studied in terms of deposition rate, refractive index, surface roughness, microstructure, and chemical composition including bonding state. The results showed that a higher deposition temperature enhanced the formation of Si‐N bonds, and disfavoured the formation of N=C=N, Si‐NCN, C‐H and Si‐CH3 bonds. A higher deposition temperature also decreased the deposition rate and increased the refractive index of the resulting SiCNO:H film. With increasing temperature a denser film was formed, indicating a change of the deposition mechanism, i.e., transformation from particle precipitation to heterogeneous surface reaction. Except for the coatings deposited at room temperature, the surface of the films was smooth with a roughness of around 4 nm at the centre in the range of 5 μm x 5 μm area. Moreover, the films contained 8 ~ 16 at.% oxygen bonded to Si, which originated from the remnant H2O in the deposition chamber. 相似文献
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K.-T. Rie A. Gebauer J. Whle G. Erker R. Mohr C. Sarter 《Materialwissenschaft und Werkstofftechnik》1994,25(11):431-434
Deposition of hard coatings type (B,C,N) at low coating temperatures by PACVD In this study the deposition of (B,C,N) layers by means of low temperature (250°C) pulsed DC plasma assisted CVD process was investigated using a metallo-organic compound as precursor being synthesized in a new way. It is shown that the deposition of (B,C,N) layers is possible with high hardness and adhesion in the investigated parameter range. 相似文献
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Amorphous hydrogenated silicon films were deposited on glass substrates at room temperature. This cold deposition process was operated in a dielectric barrier discharge CVD reactor with a fixed strip-shaped plasma matched with a moving substrate holder. The maximum film area was 300 × 600 mm2. The film deposition rate as a function of applied peak voltage of DBD power was investigated under different hydrogen-diluted silane concentrations, and the film surface smoothness, continuity, and film/glass adherence were also studied. The maximum deposition rate was 12.2 Å/s, which was performed under the applied peak voltage of 16 kV and a hydrogen-diluted silane concentration of 50%. IR measurements reveal that the silane concentration plays a key role in determining the hydrogen-silicon bonding configurations. With increasing hydrogen-diluted silane concentration, the H-Si bonding configurations shift gradually from Si-H3 to Si-H. The variation of photo/dark conductivity ratio and optical bandgap versus hydrogen-diluted silane concentration were investigated. The use of DBD-CVD for deposition of a-Si:H films offers certain advantages, such as colder substrate, faster film growth rate, and larger deposition area. However, the consumption of silane for the DBD-PECVD procedure is much greater than for the RF-PECVD process. 相似文献
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The first measurement of impedance on free-standing diamond films from 0.1 Hz to 10 MHz up to 300℃ were reported. A wide range of chemical vapour deposition (CVD) materials were investigated, but here we concentrate are well fitted to a RC parallel circuit model and the equivalent resistance and capacitance for the diamond films have been estimated using the Zview curve fitting. The results show only one single semicircle response at each temperature measured. It was found that the resistance decreases from 62 MΩ at room temperature to 4 kΩ at300℃, with an activation energy around 0.51 eV. The equivalent capacitance is maintained at the level of 100 pF up to 300℃ suggesting that the diamond grain boundaries are dominating the conduction. At 400℃, the impedance at low frequencies shows a linear tail, which can be explained that the AC polarization of diamond/Au interface occurs. 相似文献
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Qingyu Xu Hao Liu Zheng Wen Jinlong Gao Di Wu Qi Li Shaolong Tang Mingxiang Xu 《Journal of Superconductivity and Novel Magnetism》2011,24(7):2119-2122
Zn0.98Cu0.02O films have been prepared under different conditions by pulsed laser deposition. Ferromagnetism with saturate magnetization of about 7 emu/cm3 at 300 K has been observed in Zn0.98Cu0.02O film prepared in N plasma at room temperature. The concentration of oxygen vacancies was increased by N substituting O in N plasma, and the ferromagnetism originated from the aligned magnetic moments of more Cu ions mediated by oxygen vacancies. Furthermore, ferroelectricity has been confirmed by the observation of the electrical field dependent converse piezoelectric coefficient d 33 loop at room temperature, indicating the potential multiferroic applications. 相似文献