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1.
Particulate matter (PM) emitted from a dual fuel engine is characterized using thermogravimetry, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Thermogravimetric analysis (TGA) provides the mass fractions of elemental carbon and volatile materials in PM; XPS provides the possible chemical compositions in the topmost layer of PM surface and Raman analysis provides the possible structure of the carbon presented in PM. Dual fuel engine uses both liquid (diesel) and gaseous fuels simultaneously to produce mechanical power and can be switched to only diesel fueling under load. The dual fuel engine is operated with natural gas and simulated biogases (laboratory prepared) and results are compared between the dual fueling and diesel fueling under the same engine operating conditions. Significantly higher volatile fractions in PM are obtained for dual fueling compared to diesel fueling complementing the gravimetric results. The maximum contribution of the graphitic carbon or aliphatic carbon such as hydrocarbons and paraffins (C═C or C─C) are found in the topmost atomic layers of both the diesel and dual fuel PM samples. The other chemical states are found to be the carbon-oxygen functional groups indicating significant oxidation behavior in the PM surface. Lesser aromatic content is noticed in the case of dual fuel PM than diesel PM. The carbon in dual fuel PM is found to be more amorphous compared to diesel PM. These characterizations provide us new information how the PM from a diesel engine can be different from that from a dual fuel engine.  相似文献   

2.
The emission regulations for diesel particulate matter (PM) are becoming increasingly strict. The focus of regulations is turning to reducing the number of nanosized particles as well as the total mass. A more precise measurement technique for particle numbers and mass must be developed to meet these new regulations. In this study, a new method for estimating the mass weighted size distribution of diesel PM was investigated by measuring the size of primary particles and the number concentration distribution of particle aggregates. Time-resolved laser-induced incandescence was used for primary particle size measurement and a scanning-mobility particle sizer was used to quantify the number concentration of aggregates. The results from these two conventional measurement techniques were combined using fractal analysis formulas to relate the electrical mobility diameter, the number of primary particles per aggregate, primary particle size, and fractal dimension. This method, applied to single-cylinder diesel engine exhaust with various engine loads and injection pressures, successfully estimated the mass weighted size distribution of particle aggregates. The procedure is very simple and the estimations are comparable with those based on effective density, making this method a useful and reliable tool for estimating mass weighted size distribution of fractal particles such as diesel PM.  相似文献   

3.
This work provides insight into the morphology and mixing state of submicron particles in diesel exhaust from a ship engine with an exhaust gas recirculation scrubber. Particles from this low-speed ship engine on test bed were collected using a microinertial impactor with transmission electron microscopy (TEM) grids on two stages. Micro- and nanostructural characteristics of single particles were studied by TEM. Image analysis was carried out on overview and high-resolution images, revealing influence of the exhaust gas treatment (scrubber) on the particle morphology and mixing state. Soot agglomerates were found to be collapsed after scrubber, reflected by their change in fractal dimension (Df ) from 1.88 to 2.13. Soot was predominantly found internally mixed with other components, with a higher degree of internal mixing observed after scrubber. Soot nanostructural characteristics on the near atomic scale such as layer distance, lamella length, and tortuosity were not observed to be influenced by the scrubber. We also found that particles in the size range between 30 and 50 nm, which were abundant in the exhaust before and after scrubber, were not graphitic soot. Furthermore, we found indications that these particles are composed of other crystalline material (salts).

Copyright 2013 American Association for Aerosol Research  相似文献   

4.
The particulate matter (PM) emitted from a single-cylinder compression-ignition, natural-gas engine fitted with a High-Pressure Direct-Injection (HPDI) system distinctly different from a duel fuel engine was investigated, and characterized by size distribution, morphology, mass-mobility exponent, effective density, volatility, mixing state, and primary particle size using transmission electron microscopy (TEM), and tandem measurements from differential mobility analyzers (DMA) and a centrifugal particle mass analyzer (CPMA). Six engine conditions were selected with varying load, speed, exhaust gas recirculation (EGR) fraction, and fuel delivery strategy. An increase in engine load increased both the number concentration and the geometric mean diameter of the particulate. The fraction of the number of purely volatile particles to total number of particles (number volatile fraction, NVF) was found to decrease as load increased, although at the lower speed, partially premixed mode, the lowest NVF. All size distributions were also found to be unimodal. The size-segregated ratio of the mass of internally mixed volatile material to total particle mass (mass volatile fraction, MVF) decreased with load and with particle mobility-equivalent diameter. A roughly constant amount of volatile material is likely produced at each engine mode, and the decrease in MVF is due to the increase in PM number with load. Effective density and mass-mobility exponent of the non-volatile soot at the different engine loads were the same or slightly higher than soot from traditional diesel engines. Denuded effective density trends were observed to collapse to approximately the same line, although engine modes with higher MVFs had slightly higher effective densities suggesting that the soot structures have collapsed into more dense shapes—a suspicion that is confirmed with TEM images. TEM results also indicated that primary particle size first decreases from low to medium load, then increases from medium to high load. An increase in EGR was also seen to increase primary particle size. Coefficients were determined for a relation that gives primary particle diameter as a function of projected area equivalent diameter. A decrease in load or speed results in a stronger correlation.

Copyright 2015 American Association for Aerosol Research  相似文献   

5.
Two potential strategies for reducing diesel emissions are exhaust aftertreatment and the use of reformulated or alternative fuels. Little is yet known about the impact on ultrafine particle emissions of combining exhaust aftertreatment with such increasingly common fuels. This paper reports ultrafine particle size distribution measurements for a study in which the impact of such fuels on emissions from a heavy duty diesel engine employing different aftertreatment configurations was evaluated. Eight different fuels were tested: Canadian No. 1 and No. 2 diesel; low sulfur diesel fuel; two different ultra low sulfur diesel fuels (< 30 ppm S); Fischer-Tropsch diesel fuel; 20% biodiesel blended with ultra low sulfur diesel fuel; and PuriNOx?. The fuels were tested in combination with four exhaust configurations: engine out, diesel oxidation catalyst (DOC), continuously regenerating diesel particle filter (CRDPF), and engine gas recirculation with CRDPF (EGR-DPF). In general, aftertreatment configuration was found to have a greater impact on ultrafine particle size distributions than fuel composition, and the effects of aftertreatment tended to be uniform across the entire particle size distribution. Steady state tests revealed complex behavior based on fuel type, particularly for PuriNOx. This behavior included bimodal particle size distributions with modes as low as 8–10 nm for some fuels. Unlike previous results for gravimetric PM from this study, no significant correlation for ultrafine emissions was found for fuel properties such as sulfur level.  相似文献   

6.
Multiple fractal dimensions are used to characterize morphological changes that occur when an aerosol composed of irregularly shaped agglomerates is subject to condensation followed by evaporation. The agglomerates change from a branched, chainlike structure to a more regular, near-spherical or clumplike structure reflected in a decrease in the structural fractal dimension. The textural fractal dimension remains constant because the primary particles, of which the agglomerates are composed, do not change in shape. The degree of supersaturation and the number of condensation-evaporation cycles that the aerosol undergoes are major factors that influence morphological change. Even at low supersaturations, increasing the number of condensation-evaporation cycles makes the agglomerates more regular and thus decreases the structural fractal dimension. The transition point in the Richardson plot is a good indicator of the size of the primary particles in the agglomerate.  相似文献   

7.
Aerosol measurements were carried out in medium-speed diesel engines to determine the aerosol characteristics and formation in four-stroke diesel engines equipped with turbocharger(s) burning heavy fuel and high ash-content heavy fuel oil. The mass size distributions are bimodal with a main mode at 60–90 nm and a second mode at 7–10 μm. The small mode particles are formed by nucleation of volatilized fuel oil ash species, which further grow by condensation and agglomeration. The large mode particles are mainly agglomerates of different sizes consisting of the small particles. The number size distributions peak at 40–60 nm, as also observed in the SEM micrographs. Agglomerates consisting of these primary spherical particles are also found. The TEM micrographs reveal that these particles consist of even smaller structures. Based on the mass and elemental size distributions evidence of high volatility of the fuel oil ash was found. The main effect on the aerosol size distributions was caused by the engine type and fuel oil properties.  相似文献   

8.
C.H. Cheng  C.S. Cheung  T.L. Chan  S.C. Lee  C.D. Yao  K.S. Tsang   《Fuel》2008,87(10-11):1870-1879
Biodiesel is an alternative fuel for internal combustion engines. It can reduce carbon monoxide (CO), hydrocarbon (HC) and particulate matter (PM) emissions, compared with diesel fuel, but there is also an increase in nitrogen oxides (NOx) emission. This study is aimed to compare the effect of applying a biodiesel with either 10% blended methanol or 10% fumigation methanol. The biodiesel used in this study was converted from waste cooking oil. Experiments were performed on a 4-cylinder naturally aspirated direct injection diesel engine operating at a constant speed of 1800 rev/min with five different engine loads. The results indicate a reduction of CO2, NOx, and particulate mass emissions and a reduction in mean particle diameter, in both cases, compared with diesel fuel. It is of interest to compare the two modes of fueling with methanol in combination with biodiesel. For the blended mode, there is a slightly higher brake thermal efficiency at low engine load while the fumigation mode gives slightly higher brake thermal efficiency at medium and high engine loads. In the fumigation mode, an extra fuel injection control system is required, and there is also an increase in CO, HC and NO2 (nitrogen dioxide) and particulate emissions in the engine exhaust, which are disadvantages compared with the blended mode.  相似文献   

9.
Particulate matter emitted by diesel engines is mainly formed by soot agglomerates, which are composed of primary particles forming irregular clusters. The primary particles have small variations in size and shape, although a narrow distribution can be effectively found. Soot agglomerates were collected with a thermophoretic sampling device installed in the exhaust pipe of a direct-injection diesel engine, and the samples were analysed using high resolution transmission electron microscopy. The size distributions of the primary particles have been shown to be quasi-monodisperse. Their mean size was obtained from averaging 10 primary particles per image, and five images per operating mode. The sampling location, the engine speed, the air/fuel ratio and the exhaust gas recirculation were independently modified, and some variations in the primary particle size were observed, mainly when the air/fuel ratio and the engine speed were varied. A time integrated equation has been proposed for estimating the rate of growth of the particles, which provided good fitting to the measured sizes. This equation uses as input the instantaneous cylinder pressure experimental data, as well as the temperature and heat release records obtained from the analysis of the cylinder pressure data (combustion diagnostic).  相似文献   

10.
This article investigates the black carbon (BC) content of soot formed in premixed and diffusion flames and emitted by light duty gasoline and diesel vehicles. BC is measured photoacoustically and compared with particulate mass collected by filter and calculated from particle size distributions. The BC fraction of soot from rich premixed ethylene flames increases with height above the burner, but can remain well below unity in modestly sooting flames. The BC fraction produced by a propane diffusion flame soot generator (combustion aerosol standard, CAST) falls as the fuel is diluted with nitrogen, the principal means used to adjust the desired particle size. Thermally treating the soot to remove possible condensed semivolatile species does little to change these trends. Transmission electron microscopy (TEM) images show that despite low BC content, these particles display the characteristic fractal-like agglomerate morphology of soot. Particle mass spectra reveal polycyclic aromatic hydrocarbon (PAH) and fullerene fragments associated with low BC soot, which disappear as the BC fraction approaches unity. The results suggest that low BC content reflects immature solid soot that has not carbonized. Particulate matter (PM) measurements from current technology diesel and gasoline vehicles exhibit a high, >80% BC fraction. This is attributed to effective soot carbonization during the expansion and exhaust strokes of the engine, and to the substantial reductions of condensable hydrocarbons by catalytic aftertreatment. These results are discussed with respect to using light absorption-based instruments to monitor engine exhaust PM and using flame-generated soot for PM instrument calibration.  相似文献   

11.
Recently, the diesel engine particulate matter (PM) emission standard was changed from being based on mass to being based on both number and mass. However, it is difficult to determine the mass- and number-weighted distributions simultaneously because of the complex shapes of PM.We studied a new method to determine the mass-weighted distribution of PM using the primary particle density, and compared it with two conventional PM measurement methods using effective density and gravimetric filtration. In the method developed, the primary particle size was measured using transmission electron microscopy (TEM)-calibrated laser-induced incandescence (LII) to detect changes in the primary particle size in real-time. The number-weighted distribution of aggregates was measured with a scanning mobility particle sizer (SMPS). The mass–mobility exponent and the effective density were determined with an impactor and the SMPS. The differences in the mass concentrations for each technique were between 3.1% and 29.9%.  相似文献   

12.
The effect of diesel fuel and operation mode on diesel particulate matter (PM) emissions was studied using a combination of a gravimetric impactor (DGI) and SEM/EDX analysis of PM particles from 0.005 to 2.5 μm aerodynamic size. Tests were made with heavy fuel oil (HFO) and light fuel oil (LFO) with medium speed (500 rpm), turbo-charged, power per cylinder ~1 MW, multivariable large-scale diesel engines. Diesel PM was sampled from diluted and cooled exhaust gases. The sampled PM was found to be primarily made of carbon and sulphur derived from the fuel and lube oil but contain several other chemical species as well. In this paper the submicron particle size range (0.2-0.5 μm and 0.5-1.0 μm) is discussed. The EDX analysis gave reasonably accurate quantitative results featuring the important elements present in the samples, namely, C, O, Mg, Si, S, Cl, Ca, V, Fe, Ni, Zn (and Al). The results indicate that the finest particles originate primarily from the fuel while the somewhat larger particles contain also significant amounts of elements derived from the lubrication oil. As expected, the concentrations of sulphur and certain metallic elements such as V, Ni, Ca, Zn, Fe, Mg are significantly higher in diesel PM from HFO firing than for LFO firing.  相似文献   

13.
The morphology and nanostructure of soot from different engines were studied. The soot samples were collected from a 1.9 L Volkswagen light-duty diesel (LDD) engine for two different fuel types [ultralow sulfur diesel (ULSD) and B20] and six speed/load combinations, as well as from a heavy-duty engine using a pilot-ignited high-pressure direct-injection (HPDI) natural-gas combustion system for three different speed/load combinations.

Transmission electron microscopy (TEM) was employed to investigate the soot morphology by using alternative fractal measurement methods. The fractal dimensions (Df ) were computed from the scaling of the projected aggregate dimensions with the number of primary particles (“LW” method) and two-dimensional pair correlation functions. For the soot collected from the LDD, it was found that the fractal dimensions are independent of fuel type, while a higher engine load slightly decreased Df . The soot produced by the HPDI exhibited a similar correlation between Df and engine load. The fractal dimension of the engine-emitted soot was measured in a range of 1.70–1.85 and the fractal prefactor kfLW of 1.08–1.39.

Raman spectroscopy was used to characterize the soot nanostructure based on the degree of microstructural disorder. The Raman spectral analysis was done using two-band (“G” at ~1578 and “D” at ~1340 cm?1) and five-band (G, D1, D2, D3, and D4 at about 1580, 1350, 1500, 1620, and 1200 cm?1 respectively) combinations. For the soot sampled from the LDD, the results from both methods showed that B20 soot exhibited a greater structural disorder. Likewise, the Raman analysis of the soot from both engines also showed that the increase in engine load condition caused increases in the degree of the structural order of soot. The use of either D/G ratio or D1 width cannot distinguish between the HPDI and the LDD soot. However, on a plot of D/G versus D1, the data fall into distinct clusters. This may indicate the importance of using more than two spectral parameters to characterize the soot samples.  相似文献   

14.
Hu Chen  Jianxin Wang  Shijin Shuai  Wenmiao Chen 《Fuel》2008,87(15-16):3462-3468
Vegetable methyl ester was added in ethanol–diesel fuel to prevent separation of ethanol from diesel in this study. The ethanol blend proportion can be increased to 30% in volume by adding the vegetable methyl ester. Engine performance and emissions characteristics of the fuel blends were investigated on a diesel engine and compared with those of diesel fuel. Experimental results show that the torque of the engine is decreased by 6%–7% for every 10% (by volume) ethanol added to the diesel fuel without modification on the engine. Brake specific fuel consumption (BSFC) increases with the addition of oxygen from ethanol but equivalent brake specific fuel consumption (EBSFC) of oxygenated fuels is at the same level of that of diesel. Smoke and particulate matter (PM) emissions decrease significantly with the increase of oxygen content in the fuel. However, PM reduction is less significant than smoke reduction. In addition, PM components are affected by the oxygenated fuel. When blended fuels are used, nitrogen oxides (NOx) emissions are almost the same as or slightly higher than the NOx emissions when diesel fuel is used. Hydrocarbon (HC) is apparently decreased when the engine was fueled with ethanol–ester–diesel blends. Fuelling the engine with oxygenated diesel fuels showed increased carbon monoxide (CO) emissions at low and medium loads, but reduced CO emissions at high and full loads, when compared to pure diesel fuel.  相似文献   

15.
The need for diversification of energy sources and reducing various emissions including CO2 emission in diesel engine can be met with alternative diesel fuels such as gas to liquid (GTL) and GTL–biodiesel blends. But there should be a clear understanding of the combustion and engine-out emission characteristics for alternative fuels. In this respect, an experimental study was conducted on a 2.0 L 4 cylinders turbocharged diesel engine fuelled with those alternative diesel fuels to investigate the engine-out emission characteristics under various steady-state engine operating conditions. The results revealed that noticeable decreases in THC (22–56%) and CO (16–52%) emissions for GTL–biodiesel blends were observed, whereas NOx emissions for GTL–biodiesel blends increased by a maximum of 12% compared to diesel. With regard to particle size distributions (PSDs) for GTL–biodiesel blends, the particulate matter (PM) number concentration in accumulation mode decreased, as a result of the excess oxygen content in biodiesel. Contrary to the tendency in the accumulation mode, there was a slight increase in the PM number concentration in the nucleation mode under the operating conditions wherein the exhaust gas recirculation (EGR) strategy was applied. The total PM number concentration for G + BD40 decreased by a maximum of 46% compared to that for diesel. From these results of enhanced emission characteristics compared to diesel and GTL fuel, the potential for the use of GTL–biodiesel blends could be confirmed.  相似文献   

16.
The present work focuses on an experimental comparison of diesel emissions produced by three fuels: an ultra low sulfur diesel fuel (BP15), a pure soybean methyl-ester biodiesel fuel (B100), and a synthetic Fischer-Tropsch fuel (FT), practically free of sulfur and aromatic compounds, and produced in a gas-to-liquid process. The study was carried out using a 2.5 L direct injection common-rail turbodiesel engine operated at 2400 rpm and 64 N m torque (19% of maximum torque). The engine was tested with single and split (pilot and main) injections and without exhaust gas recirculation (EGR). The study has two objectives. The first objective is to investigate the impact of the start of injection (SOI) on performance and emissions of each fuel. The second objective is to study the isolated impacts of the test fuels on pollutant emissions by adjusting the injection parameters (SOI and fuel rail pressure) for each fuel, while producing practically the same combustion phasing. When the combustion phasing occurs similarly, this study has confirmed that the FT fuel can reduce all regulated diesel emissions under both single and split injection strategies. Finally, it has been confirmed that biodiesel can reduce particle mean diameter in comparison with BP15. However, higher PM mass emission for B100 has been observed under the condition of matched combustion phasing. The increase of the PM mass emission is probably due to the unburned or partially burned hydrocarbon (HC) emissions.  相似文献   

17.
H.E. Saleh 《Fuel》2008,87(13-14):3031-3039
This paper investigates the effect of variation in LPG composition on emissions and performance characteristics in a dual fuel engine run on diesel fuel and five gaseous fuel of LPG with different composition. To quantify the best LPG composition for dual fuel operation especially in order to improve the exhaust emissions quality while maintaining high thermal efficiency comparable to a conventional diesel engine, a two-cylinder, naturally aspirated, four-stroke, DI diesel engine converted to run as pilot-injected dual fuel engine. The tests and data collection were performed under various conditions of load at constant engine speed. From the results, it is observed that the exhaust emissions and fuel conversion efficiency of the dual fuel engine are found to be affected when different LPG composition is used as higher butane content lead to lower NOx levels while higher propane content reduces CO levels. Fuel #3 (70% propane, 30% butane) with mass fraction 40% substitution of the diesel fuel was the best LPG composition in the dual fuel operation except that at part loads. Also, tests were made for fuel #3-diesel blend in the dual fuel operation at part loads to improve the engine performances and exhaust emissions by using the Exhaust Gas Recirculation (EGR) method.  相似文献   

18.
M. Basinger  T. Reding  K.S. Lackner 《Fuel》2010,89(10):2925-2938
Though many plant oils have a similar energy density to fossil diesel fuel, several properties of plant oils are considerably different from those of diesel. Engine modifications can overcome some of these differences. An engine modification kit has been designed and tested for a slow speed, stationary, indirect-injection diesel engine - the Lister-type CS 6/1, common throughout the developing world. The kit allows waste vegetable oil fueling with similar performance to that of diesel fueling. The kit’s simple yet robust design is targeted for use as a development mechanism, allowing remote farmers to use locally grown plant oils as a diesel substitute.The modification kit includes a preheating system and the tuning of the injector pressure and timing to better atomize given the unique properties of straight plant oils. The design methodology for the modifications is detailed and a suite of performance test results are described including fuel consumption, efficiency, pre-combustion chamber pressure, and various emissions. The results of the study show how a combination of preheating the high pressure fuel line, advancing the injector timing and increasing the injector valve opening pressure allows this engine to efficiently utilize plant oils as a diesel fuel substitute, potentially aiding remote rural farmers with a lower cost, sustainable fuel source - enabling important agro-processing mechanization in parts of the world that needs it most.  相似文献   

19.
Kuen Yehliu  Octavio Armas 《Fuel》2010,89(2):423-437
Few factors affect diesel combustion and emissions more significantly than the composition of the fuel and the fuel injection process. In this paper, both of these factors are considered by comparing conventional, synthetic and vegetable oil-derived diesel fuels and by comparing a single pulse injection and a split (pilot and main) injection process. This paper focuses on characterization of the combustion process and emissions produced by three substantially different diesel fuels: an ultra low sulfur diesel fuel (BP15), a pure soybean methyl ester (B100), and a synthetic, practically free of sulfur and aromatic compounds, Fischer-Tropsch fuel (FT) produced in a gas-to-liquid process. The study was carried out in a direct injection (DI) 2.5 L common-rail turbodiesel engine working at four engine operation modes, spanning conditions of most interest in the engine map. In all modes the engine was tested with single and split injection (pilot and main), with constant start of injection (SOI), and without exhaust gas recirculation (EGR). Using the results from thermodynamic analysis, this study confirms that the ignition character of the fuel affects the start of the combustion process, notably for the whole combustion process when the single injection is used, and during the combustion process after the pilot injection when the split injection is used. In general, the FT fuel can reduce both NOx and PM specific emissions in all modes under both single and split injection modes, bypassing the nitrogen oxides-particulate matter (NOx-PM) trade-off. Finally, this work confirms that biodiesel can reduce the particle concentration. However, in some cases an increase of PM mass emission has been observed and this increase of the PM mass emission is due to unburned or partially burned hydrocarbon (HC) emissions.  相似文献   

20.
Partial combustion of biomass in the gasifier generates producer gas that can be used for heating purposes and as supplementary or sole fuel in internal combustion engines. In this study, the potential of coir-pith and wood chips as the feedstock for gasifier is analyzed. The performance of the gasifier–engine system is analyzed by running the engine for various producer gas–air flow ratios and at different load conditions. The system is experimentally optimized with respect to maximum diesel savings and lower emissions in the dual fuel mode operation while using coir-pith and wood chips separately. The performance and emission characteristics of the dual fuel engine are compared with that of diesel engine at different load conditions. Specific energy consumption in the dual fuel mode of operation is found to be in the higher side at all load conditions. The brake thermal efficiency of the engine while using wood chips in the dual mode operation is higher than that of coir-pith. The CO emission is higher in the case of dual fuel mode of operation as compared to that of diesel mode. In the dual fuel mode of operation, the higher diesel savings is achieved while using wood chips as compared to that of coir-pith. The comparison of the performance and emission characteristics of the dual fuel engine with diesel engine is also described.  相似文献   

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