Measurement of Metal Nanoparticle Agglomerates Generated by Spark Discharge Using the Universal Nanoparticle Analyzer (UNPA)

Nanoparticle agglomerates play an essential role in the manufacturing of many nanomaterials and are commonly found in combustion products. Conventional aerosol instruments based on equivalent spheres are not directly applicable to the measurement of nanoparticle agglomerates. The increasing interest in real-time assessment of the structure of engineered nanoparticle agglomerates and the mass concentration of potentially hazardous agglomerates (e.g., diesel soot, welding fume) makes an instrument devoted to online structure and mass measurements for nanoparticle agglomerates highly desirable. A recently developed instrument, universal nanoparticle analyzer (UNPA), utilizes the close relation between agglomerate structure and unipolar charging properties and infers agglomerate structure from measurement of the average charge per agglomerate. It was used in this study to characterize in situ the structure of metal nanoparticle agglomerates generated by spark discharge, to study the effects of sintering on the structure of these agglomerates, and to make real-time assessment of their airborne mass concentration. The primary particles sizes measured by UNPA for the gold (Au), silver (Ag), and nickel (Ni) agglomerates are in reasonable agreement with the TEM (transmission electron microscopy) sizing results, d _p = 7.9 ± 1.5, 11.8 ± 3.2, and 6.6 ± 1.0 nm, respectively. In addition, findings from the study of agglomerate structural change during sintering using the UNPA sensitivity coincide with results from TEM and mobility analyses. With regard to the mass concentration of silver agglomerates at room temperature, good agreement was found under our experimental conditions between results given by UNPA, the effective density, and the gravimetric measurement.

Copyright 2012 American Association for Aerosol Research     

Wire-in-Hole-Type Spark Discharge Generator for Long-Time Consistent Generation of Unagglomerated Nanoparticles

The electrode configuration in a spark discharge generator plays a critical role in the characteristics of the process. For instance, the rod-to-rod configuration is unable to prevent nanoparticles from agglomerating due to slow local carrier gas velocity. On the other hand, the recently developed pin-to-plate configuration is able to produce unagglomerated nanoparticles; however, the geometric mean diameter and the number concentration of produced nanoparticles change over time as the pin gets eroded. In this work, we present a novel wire-in-hole-type spark discharge generator (WH-SDG) which is able to generate unagglomerated nanoparticles with a constant size distribution over a long time. The WH-SDG, which consists of a metal wire and a grounded plate with a hole in which the metal wire is located in the center, effectively suppressed changes in the electrode morphology and the gap distance, which cause the minimal variation of the spark discharge voltage and frequency in time. Therefore, the WH-SDG was able to maintain a constant size distribution of the generated nanoparticles for 12 h. In addition, it was found that the WH-SDG could control the diameter of nanoparticles by regulating the gas flow rate into generator, and could produce nanoparticles from various metals such as copper and palladium.

Copyright 2015 American Association for Aerosol Research     

High Frequency Testing and Modeling of Silent Discharge Ozone Generators

This paper deals with high frequency modeling of silent discharge ozone generators (OGs). The electrical characteristics of two simple silent discharge OGs operated at low and high frequency are analyzed and compared. An equivalent electric model is proposed for the operation of the OG at high frequency. This model can be used to optimize the electronic power converter used to supply silent discharge OGs at high frequency. Experimental results measured in the laboratory for two particular OGs are presented to validate the proposed model.     

Physicochemical Characterization of Simulated Welding Fumes from a Spark Discharge System

This study introduces a spark discharge system (SDS) as a way to simulate welding fumes. The SDS was developed using welding rods as electrodes with an optional coagulation chamber. The size, morphology, composition, and concentration of the fume produced and the concentration of ozone (O₃) and nitrogen oxides (NO_X) were characterized. The number median diameter (NMD) and total number concentration (TNC) of fresh fume particles were ranged 10–23 nm and 3.1×10⁷ ? 6×10⁷ particles/cm³, respectively. For fresh fume particles, the total mass concentration (TMC) measured gravimetrically ranged 85–760 μg/m³. The size distribution was stable over a period of 12 h. The NMD and TNC of aged fume particles were ranged 81–154 nm and 1.5×10⁶?2.7×10⁶ particles/cm³, respectively. The composition of the aged fume particles was dominated by Fe and O with an estimated stoichiometry between that of Fe₂O₃ and Fe₃O₄. Concentrations of O₃ and NO_X were ranged 0.07–2.2 ppm and 1–20 ppm, respectively. These results indicate that the SDS is capable of producing stable fumes over a long-period that are similar to actual welding fumes. This system may be useful in toxicological studies and evaluation of instrumentation.

Copyright 2014 American Association for Aerosol Research     

Numerical Model to Characterize the Size Increase of Combination Drug and Hygroscopic Excipient Nanoparticle Aerosols

Enhanced excipient growth (EEG) is a newly proposed respiratory delivery strategy in which submicrometer or nanometer particles composed of a drug and hygroscopic excipient are delivered to the airways in order to minimize extrathoracic depositional losses and maximize lung retention. The objective of this study was to develop a validated mathematical model of aerosol size increase for hygroscopic excipients and combination excipient–drug particles and to apply this model to characterize growth under typical respiratory conditions. Compared with in vitro experiments, the droplet growth model accurately predicted the size increase of single component and combination drug and excipient particles. For typical respiratory drug delivery conditions, the model showed that the droplet size increase could be effectively correlated with the product of a newly defined hygroscopic parameter and initial volume fractions of the drug and excipient in the particle. A series of growth correlations was then developed that successively included the effects of initial drug and excipient mass loadings, initial aerosol size, and aerosol number concentrations. Considering EEG delivery, large diameter growth ratios (2.1–4.6) were observed for a range of hygroscopic excipients combined with both hygroscopic and nonhygroscopic drugs. These diameter growth ratios were achieved at excipient mass loadings of 50% and below and at realistic aerosol number concentrations. The developed correlations were then used for specifying the appropriate initial mass loadings of engineered insulin nanoparticles in order to achieve a predetermined size increase while maximizing drug payload and minimizing the amount of hygroscopic excipient.     

A High-Temperature Reducing Jet Reactor for Flame-Based Metal Nanoparticle Production

We present a new flame-based aerosol reactor configuration that combines thermal decomposition and hydrogen reduction to produce metal nanoparticles. This approach uses a fuel-rich hydrogen flame as a source of low-cost energy to initiate particle synthesis, but separates the flame chemistry from the particle formation chemistry. Hot combustion products pass through a nozzle to produce a high-temperature reducing jet. A liquid precursor solution is rapidly atomized, evaporated, and decomposed by the expanding jet, initiating particle formation. In particular, here we have produced carbon-coated copper nanoparticles from an aqueous copper formate precursor solution and characterized them by aerosol mobility distribution measurements, electron microscopy, and x-ray diffraction. Copper serves here as a prototype for non-oxide materials that are generally difficult to produce in flame-based reactors. This work demonstrates that such materials can be produced in substantial quantities with particle diameters below 50 nm in this new process.     

Simultaneous Production of Two Monodisperse Aerosols Using a Spinning-Top Aerosol Generator

A relatively simple laboratory technique for the simultaneous production of two monodisperse aerosols of different size has been developed and tested. This technique utilizes a standard May spinning-top aerosol generator that has been modified and enclosed under a special dual-cone fractionator. The fractionator efficiently separates the primary and satellite droplets. Illustrative Nacl aerosol generation data, obtained in a series of experiments, show that satellite droplets can provide an important source of the monodisperse aerosol.     

Attributes of Polymer and Silica Nanoparticle Composites: A Review

In this article, polymer microspheres and silica nanoparticles have been discussed as important filler in polymer composites. Their synthesis methods, properties, and application were particularly stressed. Silica is usually used as nucleating agent, surface enhancement mediator, and as templates and cores. Among polymer/silica composites, various categories including polyaniline, polypyrrole, polystyrene, epoxy, rubber, and acrylate polymer were discussed in detail. It was observed that silica nanoparticles enhanced mechanical strength and overall performance of composites. Furthermore, composites having carbon nanotube along with silica particles possess high electrical and mechanical performance. These composites are important in nanoelectronic devices, nanomedicines, and defense-related applications.     

茂名乙烯污水深海排放

介绍了茂名乙烯污水采用陆上处理和海洋处置结合的方案,取得了很好的环境效益,并着重介绍了排海工程的设计、施工和经验教训。     

硝酸磷肥生产的回顾与展望

简述了硝酸磷肥的发展历史,重点介绍了山西天脊煤化工集团有限责任公司在肖酸磷肥生产中存在的问题及采取的措施,开展望了硝酸磷肥的发展前景。     

制备生物柴油的固体催化剂研究进展

生物柴油是一种清洁、可再生能源。对催化油脂酯交换反应制备生物柴油的固体催化剂的研究进展进行综述,分析了各种固体催化剂的特性,并对催化油脂酯交换反应的固体催化剂今后研究方向进行讨论。     

季戊四醇生产工艺简介

简单介绍了以Tollens法为基础的几种季戊四醇的生产方法。对各种方法的优点及存在问题作了简单的分析。     

Single-Particle Fluorescence Spectrometer for Ambient Aerosols

A fluorescence particle spectrometer (FPS) for real-time measurement of the fluorescence spectra of aerosol particles in the size range 1-10 w m diameter is reported. The prototype FPS has a sufficiently high sample rate (from 5 to 28 l/min for 3.5 w m to 11 w m diameter particles) to measure aerosol within buildings at practical rates (from 1 up to 600 particle fluorescence spectra per minute). Previously reported bioaerosol prototype detectors for measurement of single particle spectra (Pan et al., Opt. Lett ., 24, 116-118 (1999); Hill et al., Field Anal. Chem. Tech ., 3, 221-239 (1999)) were unable to sample the ambient environment; air containing particles had to be forced under pressure into a sample cell. In addition, sample rates were so small (less than 0.01 l/min) as to be impractical for most applications. The present design overcomes these deficiencies by the use of an airtight cell that highly concentrates micrometer-sized particles. A virtual impactor first concentrates aerosol particles, which are then drawn under negative pressure through an aerodynamic focusing nozzle in the inlet of the instrument, through the sample region, providing further concentration. The rate of particle spectra measured by the FPS increases significantly when the particle inlet is within a few meters of some common sources of indoor biological particles, e.g., a person coughing, sneezing, or rubbing his skin, or the presence of a dog. The spectra obtained have a variety of spectral shapes. The FPS may be useful in a variety of areas, e.g., in studying and monitoring airborne particles that cause diseases or allergies.     

氮肥生产污水零排放工程总结

总结了氮肥生产污水处理工程的建设及该工程对造气、脱硫、稀氨水、废油水等工业污水进行综合处理的情况。工程实施后,氮肥生产实现了污水零排放治理目标。     

Receptor Models for Ambient Carbonaceous Aerosols

The status of receptor models for the carbonaceous fraction of the ambient aerosol is reviewed. The sources and characterization techniques for atmospheric carbonaceous compounds are outlined. Receptor models are classified in semiquantitative methods, chemical mass balances, and multivariate techniques. Requirements, limitations, and applications of receptor models as applied to carbonaceous aerosols are presented.     

氮肥生产污水零排放综合治理总结

总结了氮肥生产污水零排放综合治理环保工程项目的实施情况,介绍了工程中的部分创新点及使用效果。该工程实施后,已彻底实现了生产项目污水零排放的目标。     

芳烃加热炉节能减排技术应用

分析了芳烃装置的主要耗能设备加热炉在装置能耗中所处的地位,全面地探讨了芳烃装置加热炉节能减排的8种途径和实施对策,保证芳烃加热炉的高效运行,对芳烃装置的节能减排意义重大。     

氮肥生产污水零排放工程总结

总结了氮肥生产污水零排放环保工程项目的实施情况,介绍了工程的运行效果。工程实施后,氮肥生产实现污水零排放治理目标。     

二甲基亚磷酸生产中废水的零排放技术

介绍了二甲基亚磷酸生产中废水零排放的先进工艺,并特别讨论了以甲醇和三氯化磷为原料生产二甲基亚磷酸的工艺原理和流程.同时给出了封闭循环的流程图.     

应用超滤技术实现电泳生产废水零排放

阴极电泳涂层具有优异的防腐性能,在稀土永磁材料表面防腐上有广泛的应用,电泳生产线不论大小均存在着电泳漆和清洗水的回收和排放问题,为了实现电泳漆和电泳漆清洗水的在线回收利用,采用电泳漆超滤清洗、回收以及电泳后喷淋水超滤循环利用,达到电泳漆的100%回收,实现了电泳生产废水零排放。