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1.
Most filtration models assume that the air stream runs perpendicularly to the orientation of the filter fibers. However, cigarette filters remove aerosol particles apparently by a different filter configuration in that the fiber orientation almost parallels the air streamlines. To focus on the effect of fiber orientation, cellulose acetate filters were used in this work to facilitate the filter performance comparison. A piece of original round cigarette filter was molded to form a cube. The same piece of filter was used for both perpendicular and parallel orientations, to avoid the variability caused by the non-uniform filter media distribution. DOP aerosol particles used in the tests were generated by either a constant output aerosol nebulizer or an ultrasonic atomizing nozzle. A Po-210 radiation source was used to neutralize the challenge aerosols to the Boltzmann charge equilibrium. A scanning mobility particle sizer (for < 0.8 μm) and an aerodynamic particle sizer (for > 0.8 μm) were used to measure aerosol number concentrations and size distributions upstream and downstream of the cigarette filters. The results showed that parallel and orthogonal filters behave similarly. However, the pressure drop across parallel filter was lower than for the perpendicular filter, indicating that the airflow is more laminar passing through the parallel filters. Possibly for the same reason, aerosol penetration through parallel filter was higher than the orthogonal filter, although the difference may not be statistically significant. When a comparison of the fiber orientation is based on filter quality, orthogonal filter performs better than parallel filter, if face velocity is lower than 60 cm/s. Parallel filter performs better only when the particles are smaller than the most penetrating size and under high face velocity.  相似文献   

2.
Recently, the protection of health care workers from tuberculosis-containing aerosols has been the subject of considerable debate. An experimental apparatus and test protocol were developed to measure the collection efficiency of surgical mask and respirator filter media using a microbial aerosol challenge. Mycobacterium chelonae (M. chelonae), used as a surrogate for Mycobacterium tuberculosis, was generated from liquid suspension using a Collison nebulizer. Upstream and downstream concentrations of viable aerosol particles were measured using Andersen cascade impactors, while total particle concentrations were measured with an aerodynamic particle sizer (APS). A monodisperse polystyrene latex (PSL) sphere aerosol (0.804 μm) was used in separate experiments to measure filter efficiency; concentrations were determined with the APS. The mycobacterial aerosol ranged in size from 0.65 to 2.2 μm when measured with the cascade impactor. A similar size range was found with the APS, yielding a count median diameter of about 0.8 μm. Samples of the mycobacterial aerosol were collected on glass slides, stained M. chelonae, as determined by environmental scanning electron microscope, were found to be rod shaped with an average length of 2 μm and average width of 0.3 μm. To evaluate the apparatus over a range of filter efficiencies (10–100%), different layers of fiberglass filter paper were tested for penetration using a 0.12 μm dioctyl phthalate (DOP) aerosol measured with a light scattering photometer, in addition to the mycobacterial and PSL aerosols. For the range of efficiencies tested it was shown that filter collection of DOP was linearly related to that of both mycobacterial and PSL sphere aerosols (r2 = 0.99), demonstrating that an inert aerosol may be used to predict the collection of biological aerosols by such filter media.  相似文献   

3.
The performance of filters made of sintered submicron alumina particles was evaluated. The filter has a high collection efficiency and high pressure drop, requiring the development of a special measuring system for its evaluation. The system consists of a polydisperse NaCl particle generator, a differential mobility analyzer (DMA), an ejector to supply aerosols for testing filters with high pressure drop, and a mixing-type condensation nucleus counter (CNC) capable of obtaining a stable reading of very low concentration particles. Penetrations as low as 10−9 can be measured in the particle diameter range of 0.02-0.14 μm. Two filters made by sintering 0.60 and 0.84 μm alumina particles were evaluated. The experimental data collected served as the basis of theoretical development. Following the single fibre theory, the filter penetration is calculated by using a single sphere as the element. Both the diffusion and interception collection mechanisms were taken into account. The resulting equation gives a general trend of efficiency curves as a function of the parameters involved, e.g. the test aerosol size, packed particle size and filtration velocity. However, it is not sufficiently accurate for providing quantitative performance results.  相似文献   

4.
5.
We have developed a new, fully controlled filter testing device and have used it to measure size-resolved penetration through a typically used filtration media for (but not only) atmospheric aerosol sampling. Twenty membrane and fiber filter pieces (mixed cellulose ester filters, polytetrafluoroethylene filters, quartz fiber filters, glass fiber filters, and polycarbonate filters) of various manufacturers and filter codes were examined. High variability in the penetration curve shapes, most penetrating particle size (MPPS) (from 20 nm to 90 nm) and penetration maxima (from 0.001% to almost 100%) has been found. The dependence of pressure drop on face velocity generally agrees with theory, the comparison of penetration at various face velocities proved the theoretical equations being able to determine MPPS only partially correctly. Although the variability within an individual filter of the same code is not negligible, it is small compared to the differences between the various filter types. The results not only differed from the information provided by the manufacturers, but in many cases also provided information otherwise unavailable, although affecting the sampling and also the ability of comparison with theory. To have enough information for the proper choice of the filter for a given purpose, it would be necessary to have not only total penetration given from the DOP standard measurement, but the MPPS, penetration maximum value and pressure drop as well.

Copyright 2015 American Association for Aerosol Research  相似文献   

6.
This paper describes theoretical and experimental studies undertaken in connection with the problem of sampling carbon fiber aerosols in an ambient environment. Calculations indicate that carbon fiber aerosols with an 8-μm fiber diameter and a density of 1.8 g/cm3 can be sampled by a sampler designed to collect particles in the 10–30–μm aerodynamic diameter range if fibers up to a few millimeters in length are to be collected. An approach is then described in which carbon fiber aerosols are collected in the impactor of the inlet of a dichotomous sampler. Experimental data are presented showing that the impaction characteristics of the carbon fiber aerosol can be predicted with a reasonable degree of accuracy by approximating the shape of the fibers by a prolate ellipsoid.  相似文献   

7.
We investigate the filtration performance of composite filters composed of micrometer and nanometer fibers. The filter quality is evaluated using the figure of merit, also known as the quality factor. We use analytical expressions for the pressure drop and filtration efficiency to compute the figure of merit. The effects on the figure of merit by fiber diameter, solidity, and thickness of nanometer and micrometer fibers and face velocity are investigated. Experimental data obtained using conventional filter media and nanofiber composite filters are then used to verify the calculated results. We find that for large particles (approximately 0.1 μm and above), nanofibers can improve the figure of merit compared to conventional filters. Smaller fiber size, larger solidity, and thickness of the nanofiber layer lead to better filtration performance in this size range. For small particles (approximately below 0.1 μm), nanofibers do not improve the figure of merit compared to conventional filter media. Larger fiber size, smaller solidity, and thickness of the nanofiber layer are preferred in this size range. We demonstrate that our procedure using analytical expression is a fast and effective tool for filter media design.  相似文献   

8.
The performance of electrostatically charged blown microfiber filter media was characterized for high-volume sampling applications. Pressure drop and aerosol collection efficiency were measured at air pressures of 55.2 and 88.7 kilopascals (kPa) and filter face velocities ranging from 2.5 to 11.25 meters per second (m/s). Particle penetration was significant for particles above 0.5 micrometers (μm) in aerodynamic diameter where the onset of particle rebound was observed as low as 200 nanometers (nm). Particle retention was enhanced by treating filters in an aqueous solution of glycerol. Adding this retention agent eliminated electrostatic capture mechanisms but mitigated inertial rebound. Untreated filters had higher nanoparticle collection efficiencies at lower filter face velocities where electrostatic capture was still significant. At higher filter face velocities, nanoparticle collection efficiencies were higher for treated filters where inertial capture was dominant and particle rebound was mitigated. Significant improvements to microparticle collection efficiency were observed for treated filters at all air flow conditions. At high air pressure, filter efficiency was greater than 95% for particles less than 5 μm. At low air pressure, performance enhancements were not as significant since air velocities were significantly higher through the fiber mat. Measured single fiber efficiencies were normalized by the theoretical single fiber efficiency to calculate adhesion probability. The small fiber diameter (1.77 μm) of this particular filter gave large Stokes numbers and interception parameters forcing the single fiber efficiency to its maximum theoretical value. The adhesion probability was plotted as a function of the ratio of Stokes and interception parameter similar to the works of others. Single fiber efficiencies for inertial nanoparticle collection were compared to existing theories and correlations.

Copyright 2014 American Association for Aerosol Research  相似文献   


9.
The purpose of this study was to compare the performance efficiency of melt-blown and currently used glass fiber filter media under the same environmental conditions. To evaluate filter efficiency, filter class was determined according to ISO and European standards (EN 1822-1:2009) using an automated filter tester (0.3 μm size), taking into account particle filtration, fractional efficiency for negative pressure devices, and consumption of electrical power. The average fractional efficiency, quality factor (QF), fractional efficiency by dust loading amount, pressure by dust loading amount, and QF by dust loading amount were higher in the case of melt-blown media than in the case of glass fiber filters. The fractional efficiency of hydrocharged melt-blown filters was higher than that of uncharged media. Based on performance efficiency, melt-blown filters are more effective high efficiency particulate air filters than glass fiber media.

Copyright © 2018 American Association for Aerosol Research  相似文献   


10.
Neither the European standard nor the US standard for classification of intermediate class filters comprises testing of filter performance with respect to ultrafine particles (UFPs) or particles of the most penetrating size (MPPS). This could turn out to be a major lack in classification standards since UFPs have been pointed out as a serious health hazard. In this study, fractional efficiencies of eight new full-scale bag filters and twenty-three new filter medium samples were determined. The influence of air velocity and aerosol type was investigated, and correlations between efficiencies for UFPs (EFUFPs), MPPS-sized particles (EFMPPS) and 0.4 μm-sized particles (EF0.4μm) were established. The tested bag filters were challenged by four aerosol types: a neutralized atomized oil aerosol, the same oil aerosol but non-neutralized, a non-neutralized thermally generated oil smoke, and a “natural” indoor aerosol. The tests were carried out at different air velocities through the filter medium, ranging between 0.08 m/s and 0.22 m/s. The relationships that were observed between EFUFPs, EFMPPS, and EF0.4μm appeared to be linear within the observed filtration efficiency ranges. These relationships were similar regardless of the test aerosol type used, but somewhat different for glass fiber filters than for charged synthetic filters. Generally, EFMPPS was 10–20% lower than EF0.4μm. The influence of air velocity variations on the size resolved efficiency was determined. The glass fiber filters showed practically the same fractional efficiencies regardless of whether the test aerosol was neutralized or not. However, the charged synthetic filters showed substantially lower efficiencies when tested with the non-neutralized aerosol compared to the case when the aerosol was neutralized.

Copyright 2013 American Association for Aerosol Research  相似文献   

11.
Polyacrylonitrile (PAN) fibers with mean diameters in 270-400 nm range were prepared by electrospinning for use as a filter media. Compared to commercial filters made of polyolefin and glass, the fibers of electrospun filters were more uniform in diameter. The performance of electrospun filters was evaluated by measuring the penetration of monodisperse NaCl nanoparticles (below 80 nm in size) through the filters. It was found that electrospun filters could be made which had nanoparticle penetration values comparable to commercial filters but with substantially less filter mass. The penetration of nanoparticles through the electrospun filter media could be reduced by increasing the filter thickness, which is controlled by the collection time during the electrospinning process. Nanoparticle collection by electrostatic forces was found to be negligible for electrospun filters. Filter quality factors and single fiber collection efficiencies were found to be independent of filter thickness for electrospun filters, and the penetration of nanoparticles through electrospun filters was in better agreement with theoretical predictions than was the measured penetration through a commercial filter. This study shows that electrospinning is a promising technology for the production of high performance nanoparticle filters.  相似文献   

12.
The article presents experimental results and theoretical analysis of aerosol nanoparticle penetration through fibrous filters with a broad fiber diameter distribution. Four fibrous filters were produced using the melt-blown technique. The analysis of the filters’ SEM images indicated that they had log-normal fiber diameter distribution. Five kinds of proteins and two types of silica particles were generated by electrospraying and were then classified using a Parallel Differential Mobility Analyzer to obtain well-defined, monodisperse, singly charged challenge aerosols with diameters ranging from 6.3 to 27.2 nm. Particle penetration through the filters was determined using a water-based CPC. Experimental results were compared first with predictions derived from the classical theory of aerosol filtration. It is demonstrated that it is inappropriate to apply it to the arithmetic mean fiber diameter, as this results in turn in a huge underestimation of nanoparticle penetration. A better, but still unsatisfactory agreement is observed when that theory was used together with the pressure drop equivalent fiber diameter or when the Kirsch model of nonuniform fibrous media was applied. We show that the classical theory applied to any fixed fiber diameter predicts a stronger dependence of nanoparticle penetration on the Peclet number as compared to experimental data. All these observations were successfully explained by using our original partially segregated flow model that accounts for the filter fiber diameter distribution. It was found that the parameter of aerosol segregation intensity inside inhomogeneous filters increases with the increase in particle size, when the convective transport becomes more pronounced in comparison to the diffusive one.  相似文献   

13.
An experimental study on filtration of submicron solid and liquid aerosol particles by using a filter media composed of agglomerates or granules of nanoparticles is described. Fumed silica nanoagglomerates, carbon black granules, silica shells, activated carbon granules, glass beads and nanoporous hydrophobic aerogel were among the granular filter media tested and compared to a commercially available HEPA fiber-based filter. Other than the glass beads which were used for comparison purposes, the primary particle size of the agglomerates/granules is of nanometer scale, but they agglomerate to form porous structures of about several hundreds of microns which were customized as packed (deep bed) or fluidized bed filters and challenged against submicron solid and liquid aerosols. For packed bed filters, the size of the granules has been optimized to a range of 150-500 µm with a filter thickness of about 1-3 in. and superficial gas velocities of less than 4 cm/s. Fluidized beds required granules smaller than 150 µm and the height of the bed was in the range of 15-40 cm.The customized filters and a HEPA fiber-based filter were challenged simultaneously against the same aerosol at the same superficial gas velocities. When using carbon black or aerogel granules as filter media, collection efficiencies comparable or even higher than HEPA fiber-based filters are obtained, but with the advantage of extra filtration capacity due to the deep bed configuration and the absorption of liquids into the porosity of the media. A fluidized bed filter of aerogel granules not only provides higher collection efficiency and larger capacity than a HEPA fiber-based filter when challenged against both oil mist and solid aerosols but also has an extremely low pressure drop compared to a packed bed filter and can be operated continuously with respect to removing saturated granules and adding fresh ones.  相似文献   

14.
The collection efficiencies of commonly used membrane air sampling filters in the ultrafine particle size range were investigated. Mixed cellulose ester (MCE; 0.45, 0.8, 1.2, and 5 μm pore sizes), polycarbonate (0.4, 0.8, 2, and 5 μm pore sizes), polytetrafluoroethylene (PTFE; 0.45, 1, 2, and 5 μm pore sizes), polyvinyl chloride (PVC; 0.8 and 5 μm pore sizes), and silver membrane (0.45, 0.8, 1.2, and 5 μm pore sizes) filters were exposed to polydisperse sodium chloride (NaCl) particles in the size range of 10–400 nm. Test aerosols were nebulized and introduced into a calm air chamber through a diffusion dryer and aerosol neutralizer. The testing filters (37 mm diameter) were mounted in a conductive polypropylene filter-holder (cassette) within a metal testing tube. The experiments were conducted at flow rates between 1.7 and 11.2 l min?1. The particle size distributions of NaCl challenge aerosol were measured upstream and downstream of the test filters by a scanning mobility particle sizer (SMPS). Three different filters of each type with at least three repetitions for each pore size were tested. In general, the collection efficiency varied with airflow, pore size, and sampling duration. In addition, both collection efficiency and pressure drop increased with decreased pore size and increased sampling flow rate, but they differed among filter types and manufacturer. The present study confirmed that the MCE, PTFE, and PVC filters have a relatively high collection efficiency for challenge particles much smaller than their nominal pore size and are considerably more efficient than polycarbonate and silver membrane filters, especially at larger nominal pore sizes.  相似文献   

15.
The study presented here investigates the number weighted particle size distributions of aerosols generated in the laboratory from lead oxide and lead sulfide dusts and sampled by Institute of Occupational Medicine (IOM) and closed face cassette (CFC) samplers as determined by scanning electron microscopy (SEM). The wall deposits and filter deposits from each sampler were characterized separately. A Mann-Whitney statistical analysis revealed that differences in the number weighted distributions of particles captured by the filter and the wall were not significant over the size range (up to 20 μm aerodynamic equivalent diameter) present in these laboratory-generated aerosols. Furthermore, for these samples it was not possible to distinguish an absolute difference between the IOM and CFC filter catches. By comparing direct measurements of aerodynamic equivalent diameter (AED) made by an Aerodynamic Particle Sizer (APS) to AEDs calculated from SEM images, empirical shape factors for lead oxide and lead sulfide were determined. To validate this approach APS and SEM measurements of the AED of 2 μm and 6 μm physical diameter monodisperse glass and polystyrene microspheres were made. Using the shape factors of spheres and the known densities of these materials, it was found that the SEM determinations of AED agreed with the APS results. To demonstrate the reliability of the redeposition method of sample preparation, lead sulfide and lead oxide aerosols were briefly sampled by IOM samplers such that sufficient particles were collected for SEM examination directly on the filter but not so many that particles were likely to touch or overlap. Half of each filter was analyzed in the SEM directly; the other half was ultrasonically removed and re-deposited for analysis by SEM. There were no statistically significant differences in their number weighted size distributions, demonstrating that the sample treatment process does not change the size distribution of these particular aerosols.  相似文献   

16.
ABSTRACT

In this work, the vaporization of the ash forming constituents in circulating fluidized bed combustion (CFBC) in a full-scale 80 MWth unit was studied. Ash vaporization in CFBC was studied by measuring the fly ash aerosols in a full-scale boiler upstream of the electrostatic precipitator (ESP) at the flue gas temperature of 125°C. The fuel was a Venezuelan bituminous coal, and a limestone sorbent was used during the measurements. The fly ash number size distributions showed two distinct modes in the submicrometer size range, at particle diameters 0.02 and 0.3 μm. The concentration of the ultrafine 0.02-μm mode showed a large variation with time and it decreased as the measurements advanced. The concentration of the 0.02-μm mode was two orders of magnitude lower than in the submicrometer mode observed earlier in the bubbling FBC and up to three orders of magnitude lower than in the pulverized coal combustion. Scanning electron micrographs showed few ultrafine particles. The intermediate mode at 0.3 μm consisted of particles irregular in shape, and hence in this mode the particles had not been formed via a gas to particle route. We propose that the 0.3-μm mode had been formed from the partial melting of the very fine mineral particles in the coal. The mass size distribution in the size range 0.01–70 μm was unimodal with maximum at 20 μm. Less than 1% of the fly ash particles was found in the submicrometer size range. Ninety percent of Mg in coal was organically bound, and it was found to react with quartz and aluminosilicate minerals inside the coal particle. No Mg was found to be released to the gas phase and Mg mass fraction size distribution was size independent. A fraction of halogens CI, Br and I were found to be in the gas phase after the combustion.  相似文献   

17.
During September and October, 1998, the new Integrated Organic Gas and Particle Sampler (IOGAPS), was operated at Hazelrigg, UK, the field measurement station of the University of Lancaster. Gas/particle partition ratios of twenty-two 2–5 ring PAH were determined using both the IOGAPS (in which the gas phase is collected before the particle phase) and a low flow sampler which utilized the traditional filter-sorbent geometry. For compounds of intermediate volatility, less partitioning to the gas phase was observed when the denuder was used. The denuder (8- channel, 60 cm, 16.7 L min?1 air sampling rate) trapped small amounts of several non-volatile PAH. This result is consistent with particle diffusion losses of 5 to 10% for particles less than 0.05 μm under the flow conditions in the denuder. The 60-cm denuder was probably longer than necessary for the flow rate used. During the sampling, both glass fiber and Teflon-coated glass fiber filters were used. Without a denuder in front of a glass fiber filter, the fine particulate mass (PM 2.5) measurements showed a major positive bias that has been attributed to adsorption of gases by the filter. Teflon-coated glass fiber filters were not subject to this artifact problem, and equal masses were collected on filters from the denuded and non-denuded air flows.  相似文献   

18.
Porous foam provides an inexpensive, light-weight and effective medium to capture physiologically-relevant aerosol fractions. It can be manufactured to have a wide range of properties relevant to aerosol deposition. A series of laboratory experiments were conducted to measure particle penetration though porous foam media of varying pore size and foam length. Both solid and liquid aerosols (0.01–10 μm diameter) were tested using a Sequenzial Mobility Particle Sizer or Aerodynamic Particle Sizer to count and size particles penetrating the foam. With this data, an existing semi-empirical model was improved upon to predict particle penetration through a foam of a given fiber diameter, and thickness. The model is based on three dimensionless parameters (St, Ng, Pe) that account for inertial, gravitational, and diffusive modes of deposition, respectively.  相似文献   

19.
Two‐phase model styrene–acrylate copolymers were synthesized with a soft phase consisting of methyl acrylate, butyl acrylate, and butyl methacrylate. Besides the styrenic copolymers, copolymers containing a hard phase of methyl methacylate and methyl acrylate were also synthesized. Comonomer droplets with a narrow size distribution and fair uniformity were prepared using an SPG (Shirasu porous glass) membrane having pore size of 0.90 μm. After the single‐step SPG emulsion, the emulsion droplets were composed mainly of monomers, hydrophobic additives, and an oil‐soluble initiator, suspended in the aqueous phase containing a stabilizer and inhibitor. These were then transferred to a reactor, and subsequent suspension polymerization was carried out. Uniform copolymer particles with a mean diameter ranging from 3 to 7 μm, depending on the recipe, with a narrow particle size distribution and a coefficient of variation of about 10% were achieved. Based on the glass‐transition temperatures, as measured by differential scanning calorimetry, the resulting copolymer particles containing a soft phase of acrylate were better compatibilized with a hard phase of methyl methacrylate than with styrene with dioctyl phthalate (DOP) addition. Glass‐transition temperatures of poly(MMA‐co‐MA) particles were strongly affected by the composition drift in the copolymer caused by their substantial difference in reactivity ratios. Incorporation of DOP in the copolymer particles does not significantly affect the glass‐transition temperature of MMA‐ or MA‐containing copolymer particles, but it does affect the St‐containing copolymer and particle morphology of the copolymers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3037–3050, 2003  相似文献   

20.
The Aerodynamic Particle Sizer (APS) has been in use at the National Institute for Occupational Safety and Health (NIOSH) for over two years, beginning with a prototype model and more recently with a commercial version (Model 3300). The APS has been tested and used in a variety of laboratory and field situations. It has been a very useful instrument for testing aerodynamic sizing devices and provided a much needed means of rapid aerodynamic sizing of particles. Limits to the accuracy of the APS in determining aerodynamic diameter of particles were investigated.

The calibration of the APS was originally carried out by using monodisperse di-octyl phthalate (DOP) oil aerosol in the 3–15 μm range. Using a laser imaging system, the flattening of droplets into oblate spheroids was observed for larger particles (20–100 μm). The APS was recalibrated with solid latex particles and the DOP particles were measured to determine the effect of the droplet flattening. A 15 μm droplet is measured as being 20% smaller by the APS. A semiempirical equation was developed to fit the droplet deformation data. Particle measurement in the APS takes place largely outside the Stokes regime. Therefore, it has been predicted by Wilson and Liu (1980) that the measured diameters will be dependent on density. Monodisperse particles of density 1.15 and 2.15 were generated. In the range of 8–14 μm there was a difference of up to 8% in the measured size for particles of the same aerodynamic diameter. Particle coincidence can modify the measured size distribution in a different way than for other optical particle counters. The APS has circuitry to reduce the effects of coincidence that can also modify the meausred distribution. Calculations were carried out to simulate the effect of coincidence. Several potential problems and improvements for the APS were found.  相似文献   

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