Ozonation of Spent Reactive Dye-Baths: Effect of HCO3?/CO32? Alkalinity

The effect of carbonate and bicarbonate alkalinity (soda ash buffer as 5,180 mg/L HCO3? alkalinity at pH 7 and as 5,100 mg/L CO32? alkalinity at pH 12) on the ozonation of reactive vinylsulphone dyestuffs in a simulated spent dye-bath has been studied at varying pHs. Adsorbable organic halogen (AOX) formation due to the high chloride content of the effluent and detoxification, which was evaluated in terms of the relative toxicity index Itox determined from the ED50 values for the marine photobacteria Vibrio fischeri, were also evaluated. Highest total organic carbon (56%), chemical oxygen demand (44%), and UV254 (77%) removals were achieved at pH 7 in the presence of HCO3? alkalinity. The fastest decolorization was observed for the case pH 2, the first order decolorization rate constant found as k620 = 0.16?min?1, closely followed by the pH 12 case with soda ash (k620 = 0.12?min?1) case. No positive correlation was evident between AOX, whose maximum value (=1.3 mg/L) appeared after 40 min ozonation at pH 7 and decreased to 0.54 mg/L after 120 min treatment, and Itox, which decreased to 0.16 at t = 50?min and increased rapidly thereafter. The Itox values were more related to color abatement kinetics. The maximum relative toxicity index of Itox = 0.83 occurred after 120 min. It was also established that the presence of alkalinity in the spent reactive dye-bath had no negative impact on the oxidation rates. In contrast, its absence seriously inhibited treatment efficiency. It is speculated that, with added soda ash, the carbonate radicals HCO3? and CO3??, which are more stable and selective than OH?, were produced and promoted the oxidation process.     

Effect of Biotrickling Filter Operating Parameters on Chlorobenzenes Degradation

In this paper the effect of operating parameters on biotrickling filter performance degrading chlorobenzene and o-dichlorobenzene mixture were studied. The large laboratory scale biofilter, total volume 40 L, filled with inert packing material was used. The biomass adaptation and cultivation were performed in a batch fermentor and were used to inoculate the biotrickling filter. After a starting period, the influence of the substrate load increase, liquid recirculation flow rate, and empty bed retention time on elimination capacity and removal efficiency were found. The most important recirculation liquid parameters were analyzed every day, that is: concentration of metabolites, dissolved organic carbon, nitrate, chloride, and biomass. A good correlation was found between intermediate concentration and the removal efficiency of the biotrickling filter. The measurements of the absorbance, very easy and rapid, can be used as a control parameter of the biofiltration efficiency.     

含磷酸根离子和三价铁离子的溶液中镓的沉淀行为研究

研究了磷酸根离子对镓离子和三价铁离子沉淀过程的影响以及在含磷酸根离子的溶液中三价铁离子对镓离子沉淀过程的影响。实验结果表明磷酸根离子能促进镓离子和三价铁离子的沉淀,其沉淀率都随磷酸根离子浓度的增加而增加,直至磷酸根离子与待沉淀的金属离子摩尔比达到1∶1,进一步提高磷酸根离子浓度,镓离子和铁离子沉淀率几乎不变。在相同的磷酸根离子浓度和pH下,三价铁离子比镓离子容易沉淀。在含磷酸根的溶液中,三价铁离子对镓离子的沉淀过程具有促进作用,并且镓的沉淀率随Fe3+/Ga3+摩尔比的增加而增加,Fe3+/Ga3+摩尔比从0增加至5∶1时,镓完全沉淀所要求的pH从3.5降低到3.0。采用共沉淀法可以在较低的pH下比较完全地从溶液中回收镓。     

Effects of Iron on Chemical Sulfide Oxidation in Wastewater from Sewer Networks

Effects of iron on the kinetics and stoichiometry of aerobic chemical sulfide oxidation in wastewater from two different sites were studied at pH 8 and 20°C. Iron(III) chloride was added to the wastewater in concentrations of up to 20?g?Fe?m?3. The rate of aerobic chemical sulfide oxidation increased linearly with the iron(III) additions resulting in equal effects with wastewater from the two sites. Despite the significant effect of the iron(III) additions, the background concentrations of iron cannot explain the significant temporal and spatial variability of aerobic chemical sulfide oxidation kinetics reported in this study and in the literature. In this respect, other metals are probably also important. In addition to the impacts on the oxidation kinetics, the iron(III) additions resulted in a change of the oxidation stoichiometry. With increasing amounts of iron(III) added to the wastewater, less dissolved oxygen was required for the sulfide oxidation.     

Modeling Arsenite Adsorption on Rusting Metallic Iron

Experimental data on As(III) adsorption by rusted zero valent iron (ZVI) could be modeled using a simple Langmuir isotherm model. However, the adsorption equilibrium was observed to shift with time, as continued rusting produced additional sites on the rusted ZVI surface for potential arsenic adsorption. A modified Langmuir isotherm model was formulated taking into consideration the temporal variation in the site concentration for potential arsenic adsorption on the rusted ZVI surface. This model simulated the long-term experimental data on As(III) adsorption quite well. The model was further refined by apportioning the arsenic adsorbed on the rusted ZVI surface into labile and irreversibly adsorbed fractions. Finally, the developed model was used to simulate the performance of an adsorption column. The simulation results indicate that an adsorption column of length 0.4 m and diameter 0.056 m, i.e., containing 0.001?m3 of rusted ZVI weighing 4.76 kg, and operated at an empty bed contact time of 12 min, can treat 2,375–2,525 L of water containing 100?μg?L?1 of As(III) such that the effluent As(III) concentration from the column is less than 10?μg?L?1.     

Effect of Sand Movement on a Cohesive Substrate

Flume experiments investigated the effect of mobile sand on the erosion of cohesive beds. The fluid-induced stress alone was not enough to cause erosion, and sand motion as bed load was needed. Erosion rates and suspended sediment concentration were found to increase with increasing sand transport and to decrease with increasing median grain size. The erosion rate was found to be at a maximum during saltation, intermediate during creep, and lowest during suspension.     

Effect of Rock Strength Criterion on the Predicted Onset of Sand Production

The variation of sanding onset prediction results with the selection of one or another rock strength criterion is investigated. In this paper, four commonly used rock strength criteria in sanding onset prediction and wellbore stability studies are presented. There are Mohr–Coulomb, Hoek–Brown, Drucker–Prager, and modified Lade criteria. In each of the criterion, there are two or more parameters involved. In the literature, a two-step procedure is applied to determine the parameters in the rock strength criterion. First, the Mohr–Coulomb parameters like cohesion So and internal friction angle ?f, are regressed from the laboratory test data. Then, the parameters in other criteria are calculated using the regressed Mohr–Coulomb parameters. It is proposed that the best way to evaluate the parameters in a specific rock strength criterion is to perform direct regression of the laboratory test data using that criterion. Using this methodology, it is demonstrated that the effect of various rock strength criteria on sanding onset prediction is less dramatic than using the commonly used method. With this methodology, the uncertainties of the effect of rock strength criterion on sanding onset prediction are also reduced. Through this study, it is also demonstrated that a sanding onset prediction problem cannot be properly solved by adopting strength criteria that are not influenced by the intermediate principal stress if laboratory test data indicate rock failure is dependent on intermediate principal stress.     

Role of Bioflocculation on Chemical Oxygen Demand Removal in Solids Contact Chamber of Trickling Filter/Solids Contact Process

The trickling filter/solids contact (TF/SC) process was developed in the late 1970s to improve the quality of the final effluent from existing trickling filter plants, to be able to meet stricter Environmental Protection Agency effluent requirements. Although this process has successfully achieved this objective, it is still not completely understood, there is limited information regarding the flocculation phenomena occurring in the solids contact chamber (SCC), and no information could be found on the relationship between flocculation and organic matter removal kinetics. To better understand the kinetics of biological flocculation in a continuous flow SCC, a long-term experimental program was conducted using a TF/SC pilot plant constructed at the Marrero, La., wastewater treatment plant. This program started in January 1998 and has continued through date. The present article will focus on two major areas: (1) the kinetics of bioflocculation in the SCC; and (2) effect of bioflocculation on chemical oxygen demand (COD) removal. Analysis of the wastewater composition revealed that, on the average, only 18.7% of the total COD in the SCC influent is truly dissolved. Therefore, most of the total COD removal observed in the SCC must be due to a physical process, such as flocculation. The experimental data confirmed that flocculation of the particulate COD contained in the trickling filter effluent explains the high total COD removal observed at the SCC. Both total and colloidal COD removals are well explained by the first-order flocculation model.     

The Role of Bioflocculation on Suspended Solids and Particulate COD Removal in the Trickling Filter Process

Understanding that there is a significant presence of extracellular polymeric substances at the biofilm/wastewater interface and that the primary constituent of chemical oxygen demand (COD) in domestic wastewaters is organic particulates, this research describes the kinetics of particulate removal in a pilot-scale trickling filter (TF) and the role of bioflocculation in the removal process. Recent research has described the role of bioflocculation on particulate COD (PCOD) removal in suspended growth biological wastewater treatment systems. However, no research pertaining to PCOD removal by bioflocculation in attached growth systems was identified prior to this study. For this study, experiments were conducted using both bench- and pilot-scale biofilm reactors and provided evidence that the removal of organic and inorganic particulate matter in a TF bioreactor follows a first-order bioflocculation rate equation. The statistical analysis of data obtained from the pilot TF fits the dispersion model to suspended solids and PCOD remaining in the pilot TF.     

Method for Estimating Dynamic Compaction Effect on Sand

This paper proposes a method for estimating the degree and depth of improvement resulting from dynamic compaction on sand. The method is based on extensive two-dimensional finite element analyses, which are benchmarked using centrifuge model results. By appropriately normalizing the results from a wide range of soil properties, initial conditions and operating parameters such as momentum per blow, energy per blow, and number of blows, the results for numerous cases can be summarized into a relatively small number of plots, which can be used for predictive purposes. A preliminary assessment of the reliability of these curves was conducted using results from a centrifuge and a field study. The results of this comparative exercise indicate that the predictions using the method are reasonably realistic.     

Effect of Gravity and Initial Stress on Torsional Surface Waves in Dry Sandy Medium

This problem studies the effect of gravity and initial stress on the propagation of torsional surface waves in dry sandy medium. The mathematical analysis of the problem has been dealt with the Whittaker function. Assuming the expansion of the Whittaker function up to linear term, it is concluded that the gravity field will always allow torsional waves to propagate. The expansion of the Whittaker function up to quadratic terms shows that two such wave fronts may exist in the medium. Finally, it is concluded that the sandy medium without support of a gravity field cannot allow the propagation of torsional surface waves, where as the presence of a gravity field always supports the propagation of torsional surface waves regardless of whether the medium is elastic or dry sandy.     

Effect of Penetration Rate on Cone Penetration Resistance in Saturated Clayey Soils

In this paper, the effects of penetration rate on cone resistance in saturated clayey soils are investigated. Shear strength rate effects in clayey soils are related to two physical processes: the increase of shear strength with increasing rate of loading and the increase of shear strength as the process transitions from undrained to drained. Special focus is placed on this second effect. Cone penetration tests were performed at various penetration rates both in the field and in a calibration chamber, and the resulting data were analyzed. The field cone penetration tests were performed at two test sites with fairly homogeneous clayey silt and silty clay layers located below the groundwater table. Additionally, tests with both cone and flat-tip penetrometers in sand-clay mixtures were performed in a calibration chamber to investigate the change in drainage conditions from undrained to partially drained and from partially drained to fully drained. A series of flexible-wall permeameter tests were conducted in the laboratory for various clayey sand mixtures prepared at various mixing ratios in order to obtain values of the coefficient of consolidation, which is required to estimate the penetration rates below which penetration is drained and above which penetration is undrained. A correlation between cone resistance and drainage conditions was established based on the results of the calibration chamber and field penetration tests.     

Iron-Activated Persulfate Oxidation of an Azo Dye in Model Wastewater: Influence of Iron Activator Type on Process Optimization

The study explores the potential of iron-activated persulfate oxidation of an azo dye in model wastewater. The influence of the type of iron activator on process efficiency was investigated by using ferrous and zero valent iron. The Box-Behnken experimental design and response surface methodology were applied for the modeling of the Fe2+/S2O82- and Fe0/S2O82- processes. The combined effect of three important process parameters was investigated and presented by the means of the quadratic polynomial model. The statistical analysis of model performance was evaluated by ANOVA. The optimal process conditions giving the maximal mineralization for both processes were determined: pH 4.81, [Fe2+] = 1.64??mM, and [S2O82-] = 84.87??mM predicting 35.14% mineralization and pH 5.52; [Fe0] = 4.27??mM and [S2O82-] = 138.43mM predicting 54.38% mineralization by the Fe2+/S2O82- and Fe0/S2O82- processes, respectively. The predicted values of dye mineralization obtained by model equations were in good agreement with the experimental values. The type of iron activator was demonstrated to significantly influence both process efficiency and optimal conditions.     

Effect of Compressive Load on Uplift Capacity of Model Piles

Thirty six tests on model tubular steel piles embedded in sand were carried out in the laboratory to assess the effects of compressive load on uplift capacity of piles considering various parameters. The model piles were of 25 mm outside diameter and 2 mm wall thickness. The soil–pile friction angles were 21 and 29° in loose and dense conditions of sand. The piles were embedded in sand for embedment length/diameter ratios of 8,16, and 24 inside a model tank. They were subjected to a static compressive load of 0, 25, 50, 75, and 100% of their ultimate capacity in compression and subjected to pull out loading tests. The experimental results indicated that the presence of the compressive load on the pile decreases the net uplift capacity of a pile and the decrease depends on the magnitude of the compressive load. A logical approach, based on the experimental results, has been suggested to predict the net uplift capacity of a pile considering the presence of compressive load.     

配加梅山铁精矿对烧结生产的影响

对各种梅精配比的烧结生产进行数据统计分析，找出配加梅精对烧结各项指标的影响，并提出加强粉矿的基础特性研究、提高烧结矿相中SFCA的比例以及增加生石灰用量等措施。     

Effect of Sand Supply on Transport Rates in a Gravel-Bed Channel

In a series of flume experiments using constant discharge, flow depth, and gravel feed rate, sand feed rates were varied from 0.16 to 6.1 times that of gravel. The bed slope decreased with increasing sand supply, indicating that the gravel could be transported at the same rate, along with increasing amounts of sand, at smaller shear stresses. Prediction of river response to an increase in sediment supply requires prediction of mutual changes in bed composition and transport, and therefore a transport model defined in terms of the grain size of the bed surface. A recent model provides satisfactory prediction of the experimental observations and indicates the general response of gravel beds to increased sand supply. An increase in sand supply may increase the sand content of the river bed and the mobility of gravel fractions, which can lead to bed degradation and preferential evacuation of these sediments from the river.     

Effect of Loading Mode on Strain Softening and Instability Behavior of Sand in Plane-Strain Tests

Experimental data to study the effect of loading mode on the strain softening and instability behavior of sand under plane-strain conditions are presented in this paper. A new plane-strain apparatus was adopted to conduct K0 consolidated drained and undrained tests under both deformation-controlled and load-controlled loading modes. The drained behavior of very loose and medium dense sand and the undrained behavior of very loose sand under plane-strain conditions were characterized. The test results show that the loading mode affects the postpeak behavior and controls whether strain softening or instability will occur in the postpeak region. Shear bands occurred in tests conducted on medium dense sand, but not in tests for very loose sand. The failure line and critical state line are not affected by the loading mode. The study also shows that the concept of a unique “ultimate state” for both dense and loose sand as previously established based on conventional drained triaxial tests is not supported by the plane-strain data.     

Effect of Arching on Uplift Capacity of Pile Groups in Sand

In this paper an analytical method has been proposed to predict the net ultimate uplift capacity of pile groups embedded in sand considering the arching effect. This method takes into consideration the embedded length (L), diameter of the pile (d), surface characteristics of pile, group configuration, spacing of the pile group (3d to 6d), and the soil properties. Arching develops due to relative compressibility of sand relative to pile which activates the soil–pile friction. As piles/pile groups move up, the active state of soil is initiated. The modified value of active earth pressure coefficient considering arching effect has been derived. Typical charts for evaluation of net ultimate uplift capacity for pile groups are presented through the figures. The predicted values of ultimate uplift capacity of pile groups with different configuration and slenderness ratios are compared with the available experimental results. The predicted values considering arching effect are found to be in good agreement with the data available from the literature.     

Effect of Basicity on Persulfate Reactivity

The generation of reactive species in activated persulfate systems under different conditions of basicity was investigated using three probe compounds. Anisole was used to detect both sulfate radical and hydroxyl radical. Nitrobenzene was used to detect hydroxyl radical, and hexachloroethane was used as a reductant probe. Minimal probe compound degradation occurred in persulfate reactions conducted at pH ≤ 10, demonstrating that a low flux of reactants is generated at acidic, neutral, and slightly basic pH regimes. In persulfate reactions at pH?12, sulfate and hydroxyl radical were generated but minimal reductants were produced. Scavenging studies showed that the dominant reactive species at basic pH was hydroxyl radical. The generation of reductants increased at high molar ratios of base to persulfate; however, hydroxyl radical generation rates increased only when molar ratios of base to persulfate were >3∶1. The results of this research demonstrate that the hydroxyl radical is the dominant reactive oxygen species in base-activated persulfate formulations and that overall reactivity increases with increasing base:persulfate ratios.     

Effect of Rare Earth Oxides on Catalysts Mo-Te System

Surface compositions,structures,and acidities of the Mo-Te-Fe-Ni catalysts added with La_2O_3,CeO_2,Pr_6O_(12),Nd_2O_3 and Sm_2O_3 were measured and related with the activities of the catalysts for selective oxidationof olefins.It was found that adding rare earth elements to the Mo-Te catalysts increases obviously theirselectivities to methacrolein(MAL),and the yield percentage of MAL changes periodically with the increase ofatomic numbers of rare earth elements added,and the highest yield was obtained with the catalyst containingCeO_2.The addition of CeO_2 to 9-component Mo-Te catalyst increases not only the activity of the catalyst,but also its thermostability remarkably.The mechanism of rare earth elements in the catalysts was discussed.