Retention of a metastable bcc ε-Pu solid solution: ε-Pu(Ti)

A metastable -Pu (bcc) solid solution has been retained to room temperature by rapid quenching of Pu-rich Pu-Ti alloys from the liquid state. Until now, -Pu solid solutions were limited to high temperatures and had not been successfully quenched to room temperature without transformation. The apparatus used to quench the specimens was a modified gun-type splat-cooling unit, capable of producing extremely high cooling rates of from 10⁶ to 10⁸ ° C sec^–1. -Pu(Ti) was retained in the composition region from 20 to more than 45 at.% Ti, and extrapolation of the lattice parameter/composition curve yielded a value of a ₀ = 3.53₀ Å for -Pu at 20° C. This modification differs from the -Pu modification derived by extrapolating from high temperature to 20° C by a small valence increase of 0.1. Metastable -Pu (Ti) (fcc) solid solutions were also quenched-in with alloys containing lesser amounts of Ti, and evidence was found to indicate that the was probably a product of -Pu(Ti) solid-state decomposition.     

Dielectric Properties of Melt-Grown Cd1 – xZnxTe Crystals

The real (") and imaginary (") parts of the complex dielectric permittivity of Cd_{1 – x} Zn _x Te (x= 0.1–0.2) crystals are measured as a function of temperature and frequency. The "-vs.-temperature data show a maximum, and " rises rapidly at about the same temperature. This behavior is interpreted in terms of compositional fluctuations, structural defects, and the associated internal electric fields.     

On the analysis of tunneling data for A15 superconductors

We examine the applicability of the standard McMillan inversion of Eliashberg's equations for superconductors with a nonconstant electronic density of statesN(). We do this usign simple models forN() and a realistically shapedN() taken from recent band structure work for Nb₃Sn. It turns out that peak structure inN() near _F may lead to gross errors in the derived Eliashberg function ²F() when the energy dependence ofN() is omitted in the inversion procedure. For Nb₃Sn, this leads to a 40% overestimate of when ²F() is evaluated via the standard McMillan program.     

Dielectric properties of chemically treated wood

Dielectric properties along the grain for absolutely dried untreated and seven kinds of chemically treated Sitka spruce (Picea sitchensis Carr.) woods were measured. Cole-Cole's circular arc law was applied to the results of the relaxation due to the motions of methylol groups. The following changes were caused by chemical treatments. In polyethylene glycol (PEG) impregnation, the distribution of relaxation times became very narrow, the generalized relaxation time (_m) was considerably decreased, and the relaxation magnitude (₀ – ) was slightly increased. In acetylation, the distribution of relaxation times became very broad, _m was considerably increased, and (₀ – ) was remarkably decreased. In propylene oxide treatment, the distribution of relaxation times became slightly narrow and _m was decreased. _m was slightly decreased in formalization, phenol-formaldehyde (PF) resin treatment and wood methyl methacrylate (MMA) composite. (₀ – ) was decreased in formalization and PF-resin treatment and was hardly changed in wood-MMA composite and heat treatment. The distribution of relaxation times was almost unchanged in formalization, PF-resin treatment, wood-MMA composite and heat treatment.     

Study of the paramagnetic-antiferromagnetic transition and the γ → ε martensitic transformation in Fe-Mn alloys

The paramagnetic-antiferromagnetic transition and the martensitic transformation of Fe-Mn (Mn 15–32 wt%) alloys have been investigated by resistivity, dilatometry and X-ray diffraction (XRD). The results show that paramagnetic-antiferromagnetic transition increases the resistivity and the volume of alloys, whereas the martensitic transformation reduces the resistivity and volume of alloys. The A _f that was determined by the dilatometric method is not the temperature that martensites in the Fe-Mn alloys have reverse transformed to austenites completely. Mn additions reduce M _s, increase T _N and the lattice parameter of austenite in the Fe-Mn alloys. Both the antiferromagnetic transition and the martensitic transformation lead to an increase in the lattice parameter of austenite. The lattice parameters both above T _N and below T _N decrease linearly with temperature. The lattice parameter below M _s increases first and then decreases. Moreover, the (110) and (002) atomic planes in the Fe-15Mn-0.15C alloy are separated into two peaks: 2 for (002) is 44.16°, 2 for (110) is 44.47°.     

The role of ε-martensite in the impact toughness of an Fe-17Mn alloy

The influence of -martensite on the cryogenic toughness of an Fe-17 wt% Mn alloy was studied in this work. Alloys were tempered at various temperatures in order to systematically increase the volume fraction of -martensite. This was followed by Charpy impact testing conducted at room temperature and at–196°C. The experimental results indicated that although room-temperature toughness was not influenced by the -martensite content, the cryogenic toughness was strongly dependent on the volume fraction of -martensite. In particular, with the exception of the alloys tempered at 400 and 450°C, the impact toughness consistently increased with -martensite content. Microstructural and fractographic evaluations using SEM and TEM suggested that the toughness improvements were attributed to the stress-induced martensite transformation. No microstructural evidence was found which could be ascribed to an effect of -martensite on the low-temperature embrittlement exhibited by Fe-Mn alloys tempered at 400–450°C.     

Interaction between a dislocation and an impurity in KCl: Mg2+ single crystals

The interaction between a dislocation and the impurity in KCl: Mg²⁺ (0.035 mol% in the melt) was investigated at 77–178 K with respect to the two models: one is the Fleischer's model and the other the Fleischer's model taking account of the Friedel relation. The latter is termed the F-F. The dependence of strain-rate sensitivity due to the impurities on temperature for the specimen was appropriate to the Fleischer's model than the F-F. Furthermore, the activation enthalpy, H, for the Fleischer's model appeared to be nearly proportional to the temperature in comparison with the F-F. The Friedel relation between effective stress and average length of the dislocation segments is exact for most weak obstacles to dislocation motion. However, above-mentioned results mean that the Friedel relation is not suitable for the interaction between a dislocation and the impurity in the specimen. Then, the value of H(T _c) at the Fleischer's model was found to be 0.61 eV. H(T _c) corresponds to the activation enthalpy for overcoming of the strain field around the impurity by a dislocation at 0 K. In addition, the Gibbs free energy, G ₀, concerning the dislocation motion was determined to be between 0.42 and 0.48 eV on the basis of the following equation ln / = G ₀/(kT_p0)1 – (T/T _c)^{1/2 –1}(T/T _c)^1/2 + ln ₀/where k is the Boltzmann's constant, T the temperature, T _c the critical temperature at which the effective stress due to the impurities is zero, _p0 the effective shear stress without thermal activation, and ₀ the frequency factor.     

The Accuracy of Dielectric Measurements in a Cylindrical Cavity H01p Resonator

The error of measurements of the dielectric parameters and tan in a cylindrical cavity resonator supporting the H _01p mode by varying the length of the resonator at a constant resonance frequency is considered. The errors in measuring and tanare investigated numerically as a function of the electric thickness of the sample being investigated and its permittivity .     

The dielectric properties of alumina substrates for microelectronic packaging

The dielectric characterization of alumina substrate materials used in high-performance microelectronic packaging is described. These materials included both pure and impure polycrystalline substrates and, as a reference standard, pure and chromium-doped single crystals of alumina. For each material the permittivity () and dielectric loss () has been measured over a frequency range of 0.5 kHz to 10 MHz, at room temperature, and correlated with the structure and composition as determined by supplementary techniques. At room temperature the pure substrates show the frequency independence of both and , characteristic of pure single-crystal material. The permittivity (= 10.1) agrees closely with the average of the anisotropic values for the single crystal but the dielectric loss is an order of magnitude higher than in the single crystal, giving tan 1.5 × 10^–3. The impure substrates compared with the pure, show a small increase in and a marked, frequency-dependent increase in dielectric loss. Measurements have also been made in both the high- and low-temperature ranges (i.e. 20 to 600 ° C and 77 to 293 K, respectively) in order to establish the variation of permittivity with temperature and frequency. At temperatures below 200 °C the temperature coefficient of permittivity, [( –1)( + 2)]^–1 (/T) _p is about 9 × 10^–6 K^–1 for the pure materials but this increases rapidly with impurity addition.     

Ageing characteristics of cast Zn-Al based alloy (ZnAl7Cu3)

Microstructure and ageing characteristics of a cast Zn-Al based alloy (ZnAl7Cu3) were studied using X-ray diffraction, electron scanning microscopy and back-scattered diffraction techniques. Two stages of phase transformation, i.e., decomposition of zinc rich phase and four phase transformation, + T + , were detected during ageing at 150°C. Electron back-scattered diffraction technique was applied in distinguishing both zinc rich and phases.     

Heat exchange in two-phase flow about a surface located in a rectangular channel

Similitude equations are obtained on the basis of the principle of superposition of separate effects to calculate heat exchange between surfaces with complexshaped cross sections located in a rectangular channel during their cooling by a two-phase flow.Notation T, q temperature and heat flux - T_w mean surface temperature - I, R current and electrical resistance - V volume of the material - , , anda heat-transfer coefficients, thermal conductivity, and linear expansion of the material - relative functions - =_m; ^* = _m ^{* *} _s ^* ; temperature factor - X relative weight content of liquid phase Indices w surface - f incoming flow - v volume - m two-phase flow - angle of attack - s shape of surface - * pertains to surface with swirl vanes Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 5, pp. 780–786, May, 1980.     

Nonlinear asymptotic theory of hypersonic flow past a circular cone

Summary The hypersonic small-disturbance theory is reexamined in this study. A systematic and rigorous approach is proposed to obtain the nonlinear asymptotic equation from the Taylor-Maccoll equation for hypersonic flow past a circular cone. Using this approach, consideration is made of a general asymptotic expansion of the unified supersonic-hypersonic similarity parameter together with the stretched coordinate. Moreover, the successive approximate solutions of the nonlinear hypersonic smalldisturbance equation are solved by iteration. Both of these approximations provide a closed-form solution, which is suitable for the analysis of various related flow problems. Besides the velocity components, the shock location and other thermodynamic properties are presented. Comparisons are also made of the zeroth-order with first-order approximations for shock location and pressure coefficient on the cone surface, respectively. The latter (including the nonlinear effects) demonstrates better correlation with exact solution than the zeroth-order approximation. This approach offers further insight into the fundamental features of hypersonic small-disturbance theory.Notation a speed of sound - H unified supersonic-hypersonic similarity parameter, - K hypersonic similarity parameter, M - M freestream Mach number - P pressure - T temperature - S entropy - u, v radial, polar velocities - V freestream velocity - shock angle - cone angle - density - density ratio, /() - ratio of specific heats - polar angle - stretched polar angle, / - (), (), () gage functions     

Electrical conductivity,thermoelectric power and dielectric constant of NiWO4

The a.c. electrical conductivity ( _ac), thermoelectric power () and dielectric constant () of antiferromagnetic NiWO₄ are presented. _ac and have been measured in the temperature range 300 to 1000 K and in the temperature range 600 to 1000 K. Conductivity data are interpreted in the light of band theory of solids. The compound obeys the exponential law of conductivity = ₀ exp (–W/kT). Activation energy has been estimated as 0.75eV. The conductivity result is summarized in the following equation =2.86 exp (–0.75 eV/kT)^–1 cm^–1 in the intrinsic region. The material is p-type below 660 K and above 950 K, and is n-type between 660 and 950 K.     

The behavior of the4He viscosity near the superfluid transition

Measurements of the shear viscosity at saturated vapor pressure through the lambda transition indicate a singular behavior of the form |1 – (/)|=A ^x , (where =|1–(T/T )|, with equal values for the critical exponent on both sides of the transition.Work sponsored by Consiglio Nazionale delle Ricerche, Rome (Italy).     

The Possibility of Reproducing the Units of Complex Permittivity at High Frequencies

The results of theoretical investigations of the reproduction of the units of the components of complex permittivity and by a method based on the use of the wave properties of a coaxial line are presented. The errors in reproducing and are analyzed.     

The dielectric behaviour of single-crystal MgO,Fe/MgO and Cr/MgO

The dielectric constants and loss factors,, for pure single-crystal MgO and for Fe-and Cr-doped crystals have been measured at frequencies, , from 500 Hz to 500 kHz at room temperature. For pure MgO at 1 kHz the values of and the loss tangent, tan , (9.62 and 2.16×10^–3, respectively) agree well with the data of Von Hippel; the conductivity, , varies as ⁿ withn=0.98±0.02. In Fe-doped crystals increases with Fe-concentration (at any given frequency); for a crystal doped with 12800 ppm Fe, was about four times the value for pure MgO. At all concentrations the variation of log with log was linear andn=0.98±0.02. A decrease in with increasing Fe-concentration was also observed. A similar, although less pronounced, behaviour was found in Cr-doped crystals. The effects are discussed in terms of hopping mechanisms.     

The variation of the index of refraction in a vortex tube

Three models of a vortex tube (isentropic, isothermal, and isochoric) are considered as optical inhomogeneities. Expressions relating the index of refraction to the coordinate are obtained. The possibility of obtaining Schlieren pictures of such flows is discussed.Notation a speed of sound - n index of refraction - p pressure - r radius - T absolute temperature - v linear velocity - angular deflection of the beam - x adiabatic exponent - density - angular velocity - ¯v, ¯p etc. dimensionless parameters - v₀, ₀ values at the core bounboundary - p, etc. stagnation values - n_c index of refraction at center of vortex     

Free-convection stagnation-point boundary layers driven by catalytic surface reactions: I the steady states

The free convection boundary-layer flow near a stagnation point driven by catalytic surface heating is considered. The case without fuel consumption is treated first, and it is shown that the steady state equations admit multiple solutions. Explicit expressions can be obtained for these solution branches and it is found that a hysteresis point occurs when the activation energy parameter = 1/5. The effect of fuel consumption is seen to be characterized by the dimensionless parameter and numerical results are obtained for a range of values of and , as well as Prandtl number and Schmidt number S _c . Multiple solutions are again observed and analytic expressions for the bifurcation points can be found when = S _c . For S _c these have to be determined numerically.     

Optical thermophysical characteristics of the condensed phase of combustion products and heatproof materials

An unconventional unit for experimentally studying the optical thermophysical properties of materials over a wide temperature range is described. Results are presented of studying the temperature function and dispersion of the absorption index for the condensed phase of the combustion products of a metalbearing fuel and of the emittance of fiber fireproof materials.Notation K spectral absorption coefficient - D spectral transmission coefficient - spectral absorption index - wavelength - d sample thickness - d_s surface layer thickness - I spectral intensity of radiation - , spectral and total emittances Kirov Polytechnical Institute. Kazan Chemical Engineering Institute, Russia. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 64, No. 3, pp. 330–336. March, 1993     

An Improved Transient Calorimetric Technique for Measuring the Total Hemispherical Emittance of Nonconducting Materials (Emittance Evaluation of Glass Sheets)

For measurements of the total hemispherical emittance _h of nonconducting materials, a problem of the thermal gradient produced in a sample specimen arises. An improved transient calorimetric technique to reduce the thermal gradient is proposed in this study. Glass sheets (borosilicate), semi-transparent for radiation, are selected as the nonconducting test material. The _h values of the glass sheets for various thicknesses are measured, and their results are presented as functions of thickness and temperature. The thermal gradients in the specimens are calculated by a three-dimensional analysis, and the corner effect due to them on the measured _h is estimated. It is shown that the proposed technique is useful for measuring the emittance _h of nonconducting materials.