Optical constants of polycrystalline CuGaTe2 films

Thin films of CuGaTe₂ with thicknesses in the range, 0.1–1.0 μm were deposited on Corning 7059 glass substrates by flash evaporation. The substrate temperatures, T_s, were maintained in the range 373–623 K. The transmittance of the films was recorded in the wavelength range 900–2500 nm. The dependence of the optical band gap, E_g, on substrate temperature showed that the value of E_g varied from 1.21 eV to 1.24 eV. The variation of refractive index and extinction coefficient with photon energy was studied from which the material properties such as the limiting value of dielectric constant, ε_∞, plasma frequency, ω_p, and hole effective mass, m_h^*, were evaluated as ε_∞ = 7.59, ω_p = 1.47 × 10¹⁴ and m_h^* = 1.25 m₀.     

Residual stress fields in surface-treated silicon carbide for space industry—comparison of biaxial and triaxial analysis using different X-ray methods

Any mechanical surface treatment and machining leaves ‘footprints’ in the form of residual stress fields in the surface region of technical parts or components, which are detectable by X-ray diffraction. In the present paper, we applied different X-ray methods to investigate the residual stress state in the near-surface zone of sintered silicon carbide after mechanical surface processing. Using the sin² ψ-based ‘universal plot’ method, we found steep gradients for the in-plane components σ₁₁ and σ₂₂ in the form of high compressive stresses at the surface, which change into tensile stresses within a few microns. To gain information on the triaxial residual stress state, we applied the scattering vector method, which is based on strain depth profiling by sample rotation around the diffraction vector. For the in-plane stresses, we observed gradients similar to those obtained by the ‘universal plot’ method, but they were shifted on the absolute scale towards tensile stress. We explain this difference by ‘pseudo-macroscopic’ tensile residual stress fields σ₃₃, which act normal to the surface and therefore pretend higher in-plane compressive stresses σ_ii (i = 1, 2), if they are not regarded in the evaluation procedure.     

Deformation mechanisms in tensile fracture of Al foils containing Si precipitates

Recently, Kiritani et al. proposed a new mechanism of plastic deformation without involving dislocations in tensile fracture of metal foils. The paper reports transmission electron microscopy (TEM) study of tensile fracture of Al containing hard precipitates (Si) that are considered to act as obstacles to dislocation motion. In sawtooth-shaped thin-foils formed at the fracture tip (‘sawtooth portion’), tensile strain was as high as 10³, but only a few dislocations were pinned to precipitates. Instead, voids were formed at precipitate/matrix interface, elongated in the direction of tension, and broke up into several smaller voids, due to stress concentration around hard precipitates. The thicker area of the specimen (‘base portion’), where tensile strain was 30, did not contain voids but showed a dislocation cell structure. In tensile fracture of pre-thinned specimen, voids were formed in the sawtooth portion, despite the tensile strain also being 30. These results suggest that the sawtooth portion is formed by a new mechanism that does not involve dislocations.     

The elastically equivalent softening zone size for an elastic-softening material: II. A simple piece-wise softening law

The paper determines the elastically equivalent softening zone size R_E for an elastic-softening material when there is a semi-infinite crack in a remotely loaded infinite solid; the parameter R_E plays a central role in size effect expressions that are used to correlate the maximum loads that can be sustained by solids having different dimensions. The stress (p) versus displacement (v) softening law considered is that for which P = p_c for oc and P = ; qp_c = p_* for λδ_c< v <δ_c. Particular attention is focussed on the case where the parameters λ and q are both small. Such a softening law simulates the softening behaviour of plain concrete, where there is an initially rapid softening to a low stress value at a small displacement, followed by a long tail that is associated with a low stress. The paper shows that the behaviour of a material with such a softening law can be conveniently analysed by assuming that there is a non-zero stress intensity (K_IC) at the crack tip followed by a constant stress p_* within the softening zone; , where E_o is the reduced modulus and G_{I = λpcδc} is the contribution to the specific fracture energy arising from the initially rapid softening region. Analysis of a specific model demonstrates the viability of this approach by showing that there is consistency with the proposed size effect expressions based on R_E.     

Analysis of the temperature dependence of the fracture stress of sharp notched bending specimens of a structural steel with respect to intermediate transitions

The flow and fracture stresses, σ_y^g and σ_f^g (δ = crack tip displacement), of sharply notched bending specimens of a structural steel U St 37-1 are measured in the temperature range from full scale to small scale yielding. The best adaption of the experimental results for σ_f^g is obtained by a curve which exhibits an intermediate transition, i.e. which follows in a temperature range between an upper, T_tM¹ and a lower, T_tl¹, transition temperature to the curve σ_y^g(T) for the flow stress with a constant δ = δ₁. This transition corresponds to that of the slip to the twin nucleated fracture. Two analyses [3,5] according to the local fracture stress, σ_f^*, concept show that the amount and the temperature dependence of σ_f^* are somewhat different for both methods, but that both exhibit an increase of σ_f^* in the transition range. It is concluded that each transition in the nucleation mode of the fracture is connected with such a transition in the fracture stress. It may, however, become indistinct or even be covered by the scatter of the experimental points.     

Magneto-mechanical properties evolution of Fe–C alloy during precipitation process

Evolution of magneto-mechanical properties of 160 ppm Fe–C alloy due to carbides precipitation during isothermal annealing at 473 K (up to t=50×10³ s) was studied by means of classical Barkhausen noise (HBN) and mechanical Barkhausen noise (MBN) effects. The MBN was measured for the torsion mode of load with a torque motor. Also the B(H) hysteresis loop and the coercive field H_c were evaluated using a low-frequency magnetisation set. Magnetic hysteresis losses ΔW₁ were compared with the integral ΔW₂ of HBN intensity over one period of magnetisation and the integral ΔW₃ of MBN intensity over one period of the mechanical load. The internal stress distribution function and the resulting mean level of internal stress parameter σ_i were evaluated from the MBN ‘first load’ data. It was revealed that a correlated increase of ΔW₁ and ΔW₂ parameters exists. However, the relative increase of ΔW₃ is much lower than the relative increase of ΔW₁. The relationship between H_c and σ_i was found to be parabolic. This dependence explained by Néel’s model of the impact of the residual stress level on H_c. The presence of precipitates of type was confirmed by scanning electron microscopy.     

Optical properties of Nd:NaLa (WO4)2 single crystal

Nd³⁺-doped NaLa(WO₄)₂ single crystal with a dimension of 20 mm × 40 mm and a good optical quality was grown by Czochralski method. The polarized absorption spectra and emission spectra were measured at room temperature. The absorption cross-section and emission cross-section were presented. The Judd–Ofelt theory, extended to anisotropic system, has been applied to evaluate the intensity parameters Ω_t (t = 2, 4, 6), radiative transition rates A, radiative lifetimes τ_R and fluorescent branching ratios β. The calculated radiative lifetime was compared with the experiment data for the ⁴F_3/2 emitting level. All spectral features are strongly affected by an inhomogeneous broadening connected with the ‘disordered crystal’ character of the title compound.     

Development of a cryogenic detection concept for GNO

The Gallium-Neutrino-Experiment at GNO measures solar neutrinos radiochemically via the reaction ⁷¹Ga(ν,e)⁷¹Ge. In order to reduce statistical and systematic uncertainties in detecting the decay of ⁷¹Ge to ⁷¹Ga, a favourable way could be the use of high-resolution cryogenic detectors instead of the presently integrated miniaturized proportional counters. After the successful development of a highly efficient 4π-detector, optimization of thermal Ge-deposition and decoupling of deposition and detection, present activity concentrates on low background considerations, enhancement of external and internal shielding of the cryostat and a long-term run with artificially activated ⁷¹Ge to prove the feasibility of ‘cryoGNO’ in our Underground Laboratory in Garching.     

Review of the fracture mechanics approach to creep crack growth in structural alloys

The application of the fracture mechanics approach to time-dependent high temperature crack growth has been reviewed. Available data on several structural alloys indicate that depending on the environmental sensitivity and creep ductility of the material, creep crack growth can be characterized by either linear elastic parameter, K, non-linear elastic-plastic parameter, J^*-integral, or reference stress, σ_ref. In particular for materials that are significantly sensitive to environment, K can adequately characterize the growth rate, and for materials that are significantly creep ductile, σ_ref can be used to predict creep life of a cracked body. Finally, for materials that are relatively ductile and wherein crack growth occurs predominantly by a deformation process, J^* integral appears to be the characterizing parameter for the growth rate. Data for several materials indicate that under steady state crack growth conditions, there may be a unique growth rate-J^* relation independent of temperature and material. This would have a profound impact in terms of the utility of fracture mechanics approach to predict creep crack growth rate and needs to be examined further. Conditions under which K, J^* or σ_ref is applicable are discussed in detail.     

Strength of carbon/epoxy laminates with countersunk hole

The aim of this study is to predict the static strength of carbon/epoxy laminates with countersunk hole. Also, three-point bend (TPB) specimens with the same lay-up were analysed. For this purpose, the notched strength of the laminates was analysed by a damage zone model (DZM), where damage around the notch is represented by an ‘equivalent crack’ with cohesive forces acting between the crack surfaces. The DZM requiring only basic properties of the laminate such as unnotched tensile strength, δ₀, fracture energy, G_c^*, and stiffnesses of the laminate. However, the complex geometry around the countersunk hole implies that both δ₀ and G_c^* will vary in this area, and in order to avoid this problem an approximate geometry of the countersunk hole is used in the DZM-calculations. With this approximation, good agreement between experimental and calculated strength was observed for the laminates with countersunk hole. This was also the case for the TPB specimens.     

Treatment of nondetects in multivariate analysis of groundwater geochemistry data

Principal components analysis (PCA) is used to evaluate similarities in the trace element chemistry of groundwaters. Many of the trace elements, however, occur at concentrations below the detection limits (DL), which presents problems for statistical analyses. Since the optimal methods for dealing with the ‘

In this study, a new approach was developed to determine the best substitution methods when dealing with the ‘DL’ values for a given data set. Monte Carlo simulation experiments, using a mixture multivariate model, were performed to test the effects of substitution of the ‘

When ‘相似文献   

In situ RHEED control of self-organized Ge quantum dots

In situ registration of high-energy electron diffraction patterns was used for constructing the diagram of structural and morphological states of the Ge film on the Si(100) surface. The following regions identified in the diagram: two-dimensional (2D)-growth, ‘hut’- and ‘dome’-clusters, ‘dome’-clusters with misfit dislocations at the interface. Variations in the lattice constants of the Ge film during the MBE growth on the Si(100) surface were determined. An increase in the lattice constant at the (100) surface was attributed to the elastic deformation at the stage of 2D growth and formation of ‘hut’-clusters and to the plastic relaxation for the ‘dome’-clusters. As a result, epitaxial silicon structures with germanium quantum dots of 15 nm base size at the density of 3×10¹¹ cm⁻² were synthesized. The total electron structure of the hole spectrum of Ge quantum dots in Si was established.     

Standing-wave solutions of the Enneper (sine-Gordon) equation

The present paper investigates the real solutions of the partial differential equations (∂²ω/∂u²) − (∂²ω/∂ν²) = sin ω (Enneper or sine-Gordon equation) that are of the FORM = F(|₁(u) · |₂(ν)). In the application of the Enneper equations to crystal physics such solutions may represent standing waves. A complete classification of these solutions and its degenerate cases is given.     

Anomalous elastic response of amorphous alloys suggesting collective motions of many atoms

The dynamic Young’s modulus, E, of amorphous (a-) Zr₆₀Cu₃₀Al₁₀ (numbers indicate at.%) alloy was measured as a function of frequency, f, with a strain amplitude, _t, of 10⁻⁶, E(10⁻⁶,f), and also as a function of _t for f near 10² Hz, E(_t,10² Hz), by means of the vibrating reed methods. The elasticity study under the passing of electric current (PEC) was carried out too. E(10⁻⁶,f) is lower than E₀ for f between 10 and 10⁴ Hz showing local minima near 5×10, 5×10² and 5×10³ Hz, which are indicative of the resonant collective motion of many atoms, where E₀ is the static Young’s modulus. E(_t,10² Hz) increases showing saturation with increasing _t. Qualitatively, the outlines of E(10⁻⁶,f) and E(_t,10² Hz) observed for a-Zr₆₀Cu₃₀Al₁₀ are similar to those reported for various a-alloys. Quantitatively, a change in E(_t,10² Hz) for a-Zr₆₀Cu₃₀Al₁₀ is smallest among that reported for various a-alloys, presumably reflecting that the crystallization volume, (ΔV/V)_x, is smallest for a-Zr₆₀Cu₃₀Al₁₀. The effective charge number, Z^*, estimated from the change in E(10⁻⁶,10² Hz) due to PEC is 3.0×10⁵, which is comparable with Z^* reported for various a-alloys. We surmise that the number of atoms in the collective motions excited near 10² Hz is similar among various a-alloys. The E(10⁻⁶,f) data suggest that the spatial sizes of the density fluctuations may show a distribution.     

The CPLEAR electromagnetic calorimeter

A large-acceptance lead/gas sampling electromagnetic calorimeter (ECAL) was constructed for the CPLEAR experiment to detect photons from decays of π⁰s with momentum p_π⁰ ≤ 800 MeV/c. The main purpose of the ECAL is to determine the decay vertex of neutral-kaon decays K⁰ → π⁰π⁰ → 4γ and K⁰ → π⁰π⁰π⁰ → 6γ. This requires a position-sensitive photon detector with high spatial granularity in r−, −, and z−coordinates. The ECAL - a barrel without end-caps located inside a magnetic field of 0.44 T - consists of 18 identical concentric layers. Each layer of 1/3 radiation length (X₀) contains a converter plate followed by small cross-section high-gain tubes of 2640 mm active length which are sandwiched by passive pick-up strip plates. The ECAL, with a total of 6X₀ has an energy resolution of and a position resolution of 4.5 mm for the shower foot. The shower topology allows separation of electrons from pions. The design, construction, read-out electronics, and performance of the detector are described.     

Incorporating Runs Rules into Hotelling's χ2 Control Charts

This paper illustrates a simple and effective method of incorporating runs rules into Hotelling χ² control charts. A Markov chain will be used to obtain a desired in-control average run length (ARL). Comparisons between the basic multivariate χ² control chart and the multivariate χ² control chart, which incorporates the various runs rules, are based on their respective ARL performances. All multivariate χ² control charts that incorporate the various runs rules have shown better ARL performance compared to the basic multivariate χ² control chart for small shifts in distance λ from the in-control mean vector μ₀ to the out-of-control mean vector μ_s. An example of the application, based on the proposed method, is also given.     

Optical properties, fluorescence mechanisms and energy transfer in Tm, Ho and Tm -Ho doped near-infrared laser glasses, sensitized by Yb

The optical properties of the rare elements Tm³⁺, Ho³⁺ and Yb³⁺ were systematically investigated in various glasses. The Tm³⁺ doped aluminozircofluoride glass shows higher quantum efficiency, longer lifetime and stronger fluorescence intensity than Tm³⁺ doped YSGG crystal and other Tm³⁺ doped glasses for the ³H₄ → ³H₆ transition. Similar quantum efficiency, longer lifetime and stronger fluorescence intensity were also found in Ho³⁺ doped aluminozircofluoride glass for the ⁵I₇ → ⁵I₈ transition. The higher quantum efficiencies of Tm³⁺ and Ho³⁺ in aluminozircofluoride glass are due to the longer lifetime and the lower phonon energy. The fluorescence mechanisms and energy transfer in the Yb³⁺ -Tm³⁺ system, Yb³⁺ -Ho³⁺ system and Yb³⁺ - Tm³⁺ -Ho³⁺ system were studied. The very strong fluorescence intensities in the Yb³⁺ -Tm³⁺ system for Tm³⁺ and the Yb³⁺ -Tm³⁺ -Ho³⁺ system for Ho³⁺ which are 1.68 times that of Tm³⁺ doped YSGG crystal and 2.25 times that of Tm³⁺---Ho³⁺ codoped YSGG crystal are attributed to the efficient Yb³⁺ → Tm³⁺, Yb³⁺ → Ho³⁺ and Tm³⁺ → Ho³⁺ energy transfer processes. The fluorescence processes are described by cross relaxations of ²F_5/2 → ³H₅ → ³H₄ → ³H₆ → ²F_7/2 and²F_5/2 → ³H₅ (or ²F_5/2 → ⁵I₆ → ³H₅) → ³H₄ → ⁵I₇ → ⁵I₈ → ³H₆ → ²F_7/2.     

Evaluation of neutron thermalization parameters and benchmark reactor calculations using a synthetic scattering function for molecular gases

Using a synthetic incoherent scattering function which describes the interaction of neutrons with molecular gases we provide analytical expressions for zero- and first-order scattering kernels, σ₀(E₀ → E), σ₁(E₀ → E), and total cross section σ₀(E₀). Based on these quantities, we have performed calculations of thermalization parameters and transport coefficients for H₂O, D₂O, C₆H₆ and (CH₂)_n at room temperature. Comparison of such values with available experimental data and other calculations is satisfactory. We also generated nuclear data libraries for H₂O with 47 thermal groups at 300 K and performed some benchmark calculations (²³⁵U, ²³⁹Pu, PWR cell and typical APWR cell); the resulting reactivities are compared with experimental data and ENDF/B-IV calculations.     

Fracture mechanisms of ceramic coating during wear

A typical buckling phenomenon of the coating on the wear groove caused by the residual compressed stress was analyzed by the interface fracture mechanics and the buckling theory. It has been found that there is a critical thickness of coating on the wear groove for the buckling. The critical thickness can be calculated by t_b/c_d = [12(1 − v²_f)σ_R/π²E_f]1/2 (here t_b is the coating thickness, c_d the length of the interfacial crack, v_f the Poisson's ratio of the coating, σ_R the residual compressed stress in the coating, and E_f the elastic modulus of the coating).     

Magnetic and electrical characterization of heavily boron-doped diamond

For a heavily boron-doped diamond (BDD) film, temperature variations of the electrical conductivity σ and magnetic susceptibility χ are reported. The room temperature σ 143 (Ω-cm)⁻¹ corresponds to a carrier concentration 10³ ppm, and its temperature variation yields an activation energy E_a 28 meV from 140 to 300 K and E_a0.88 meV from 40 to 80 K. It is argued that larger boron doping leads to lower magnitudes of E_a. The χ vs. T data (1.8–350 K) fits the Curie–Weiss law, with the concentration of paramagnetic species 120 ppm and a diamagnetic susceptibility −0.4×10⁻⁶ emu/g Oe. The results obtained from the measurements of σ and χ are discussed and compared.