缝合对碳纤维复合材料性能影响研究

利用芳纶纤维对碳纤维增强环氧树脂复合材料进行缝合,研究了缝合密度、缝合方向和缝合线直径等缝合参数对复合材料拉伸性能、弯曲性能和层间剪切性能的影响。结果表明,缝合密度和缝合方向对材料性能影响较大,材料经缝合后拉伸性能和弯曲性能下降,层间剪切性能提高。     

Resin infusion of triaxially braided preforms with through‐the‐thickness reinforcement

Vacuum assisted resin transfer molding (VARTM) has shown potential to significantly reduce the manufacturing cost of high‐performance aerospace composite structures. In this investigation, high fiber volume fraction, triaxially braided preforms with through‐the‐thickness stitching were successfully resin infiltrated by the VARTM process. The preforms, resin infiltrated with three different resin systems, produced cured composites that were fully wet‐out and void free. A three‐dimensional finite element model was used to simulate resin infusion into the preforms. The predicted flow patterns agreed well with the flow patterns observed during the infiltration process. The total infiltration times calculated using the model compared well with the measured times.     

缝合增强泡沫夹芯结构复合材料力学性能研究

采用机械缝合设备连续制备了"X"型构型缝合增强泡沫夹芯结构预成型体,并采用真空导入模塑工艺(VIMP)整体成型了缝合增强泡沫夹芯结构复合材料。实验研究了面板纤维布层数、面板纤维布穿透缝合层数、缝合角度、缝合针距及纱线股数对缝合增强泡沫夹芯结构复合材料弯曲性能和平压性能的影响规律。实验结果表明:与未缝合结构相比,缝合结构在质量未明显增加的情况下,弯曲性能和压缩性能得到了显著提高,其弯曲刚度最大提高了4.66倍,破坏载荷最大提高了13.8倍;压缩强度和压缩模量最大分别提高了26.2倍和15.2倍。     

Experimental compaction characterization of unidirectional stitched noncrimp fabrics in the vacuum infusion process

In this study, experimental test equipment developed in‐house was used to study the compaction behavior of stitched quasi‐unidirectional (UD) non‐crimp fabrics (NCF) during the pre‐filling, filling, and post‐filling stages of the vacuum infusion (VI) process. The effects of the stitch pattern, stitch tension, and fiber sizing of reinforcements, as well as the effect of nesting of fiber bundles in neighboring layers, were studied. Moreover, the effects of cyclic compaction, resin viscosity, and different post‐filling strategies were studied. The developed experimental test equipment provided an applicable measuring method for characterizing the compaction behavior of both the dry and resin‐impregnated reinforcements. The effects of the stitching parameters and fiber nesting of reinforcements were found. The stitch pattern and post‐filling strategies were noted to have an effect on the preform and laminate thickness. POLYM. COMPOS., 37:2692–2704, 2016. © 2015 Society of Plastics Engineers     

Polyester composites reinforced with noncrimp stitched carbon fabrics: Mechanical characterization of composites and investigation on the interaction between polyester and carbon fiber

The primary purpose of the study is to investigate the anisotropic behavior of different noncrimp stitched fabric (NCF) reinforced polyester composites. Carbon fiber composite laminates were manufactured by vacuum infusion of polyester resin into two commonly used advanced noncrimp stitched carbon fabric types, unidirectional and biaxial carbon fabric. The effects of geometric variables on composite structural integrity and strength were illustrated. Hence, tensile and three‐point bending flexural tests were conducted up to failure on specimens strengthened with different layouts of fibrous plies in NCF. In this article an important practical problem in fibrous composites, interlaminar shear strength as measured in short beam shear tests, is discussed. The fabric composites were tested in three directions: at 0°, 45°, and 90°. Extensive photomicrographs of multilayered composites resulting from a variety of uniaxial loading conditions were presented. It was observed that broken fibers recede within the matrix in composites with weak interfacial bond. Another aim of the present work was to investigate the interaction between carbon fiber and polyester matrix. The experiments, in conjunction with scanning electron photomicrographs of fractured surfaces of composites, were interpreted in an attempt to explain the instability of polyester‐resin–carbon‐fiber interfaces. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4554–4564, 2006     

捆绑纱对预定向经编织物性能的影响

通过用玻璃纤维／涤纶捆绑纱及不同经编组织结构,研究捆绑纱对预定向经编织物性能的影响。结果表明,玻纤可用于捆绑纱组织中,其编织后强度比涤纶纱高33．3％。玻纤捆绑纱可改善树脂对织物的浸渍性,降低最终复合材料的孔隙率,提高复合材料的拉伸和剪切等力学性能。不同的捆绑纱组织结构对复合材料的力学性能影响显著,玻纤做捆绑纱时,经平组织比编链组织复合材料的经向拉伸强度高7．97％,弯曲强度高约5％。     

Vacuum‐assisted resin transfer molding using tackified fiber preforms

A low cost composite fabrication process—tackified SCRIMP—is described for fabricating aerospace‐grade composites based on tackification and vacuum‐assisted resin transfer molding (VARTM). Tackification based on a commercial tackifier (FT 500 from 3M) was used to make the net‐shape fiber preform. It was found that tackifier concentration and application conditions play important roles in governing the moldability of tackified fiber preforms. An epoxy resin (PR 500 from 3M) was used in the VARTM process‐SCRIMP at high temperatures. Experimental results show that composites with high fiber content (> 60% by volume) can be manufactured at low cost using tackification. Effects of tackification methods on composite dimension control, void content and mechanical properties were investigated and compared in both RTM and SCRIMP.     

Enhancement of resin transfer molding using articulated tooling

Mold articulation is introduced in this concept for resin transfer molding (RTM) to increase mold fill times and potentially allow for the use of high viscosity, hot melt resin systems, or thermoplastics. Following a brief review of conventional RTM and a discussion of the limitations on the factors that control fluid flow through porous media, the articulated concept is described. This is followed by an explanation of the sequence of motion of an articulated segmented mold necessary for consolidation, void removal and accelerated fluid flow through a fibrous preform. An analysis of the process using a fiber preform with orthotropic permeability is outlined from which mold fill time is obtained. This is compared with conventional RTM mold fill times using typical resin properties and fiber volume fractions. For the conservative assumptions used, an improvement by a factor of ten in mold fill time is achieved using the articulated process relative to conventional RTM.     

Processing models and characterization of thermoplastic composite wound parts

Squeezing flow was adopted to model the processing of thermoplastic composites in filament winding. It is found that the resin flow is facilitated as a result of the slip condition, thus reducing the process times. An apparatus with a constant dead weight was employed to characterize the rheology of the thermoplastic composite in filament winding. The system is carbon fiber (AS4) reinforced with the polyetherketone-ketone (PEKK) thermoplastic matrix. It is found that resin flow is dominant in the transverse fiber direction and there is insignificant flow along the fiber direction. An empirical equation of viscosity for AS4/PEKK as a function of temperature was obtained based on the model. For mechanical properties, either in a 4-point bending test or a short beam shear test, most of the hoop wound rings failed at the inside radius or on the compression side. Insufficiently applied heat and a cold mandrel in the beginning of the winding process may result in low degree of consolidation on the compression side. The average void content of the hoop wound ring is lower than that of the preimpregnated tow because of void compression through resin flow during the winding process.     

Elevated‐temperature vacuum‐assisted resin transfer molding process for high performance aerospace composites

Vacuum‐assisted resin transfer molding (VARTM) is commonly used for general temperature applications (<150 °C) such as boat hulls and secondary aircraft structures. With growing demands for applications of composites in elevated temperature environments, significant cost savings can be achieved by employing the VARTM process. However, implementation of the VARTM process for fabricating elevated temperature composites presents unique challenges such as high porosity and low fiber volume contents. In the present work, a low cost and reliable VARTM process is developed to manufacture elevated temperature composites for aerospace applications. Modified single vacuum bagging infusion and double vacuum bagging infusion processes were evaluated. Details of the method to obtain high quality composite parts and the challenging issues related to the manufacturing process are presented. Density and fiber volume fraction testing of manufactured panels showed that high quality composite parts with void content less than 1% have been consistently manufactured. A property database of the resin system and the composites was developed. A three‐dimensional mathematical model has also been developed for flow simulation and implemented in the ABAQUS finite element package code to predict the resin flow front during the infusion process and to optimize the flow parameters. The results of the present study indicate that aircraft grade composite parts with high fiber volume fractions can be manufactured using the developed elevated temperature VARTM process. © 2013 Society of Chemical Industry     

Resin flow monitoring inside composite laminate during resin film infusion process

In this article, a novel method of measuring resin flow front under vacuum condition is presented. The in situ monitoring system with metal hollow probe based on gas flow balance can be used in resin film infusion (RFI) process, where resin film is used and transverse flow is dominated along thickness direction of fiber preform. The diameter of the probe was chosen to increase the measuring accuracy, and the reliability of the method was evaluated by comparison of visualization experiment. Experimental results demonstrate that the method is suitable for monitoring resin flow in RFI process with and without autoclave, and can obtain the information about resin filling time, nonuniform flow front, and the permeability of fiber preform. Furthermore, by means of the established monitoring system, the influences of pressure and lay‐up sequence of carbon fiber fabric on epoxy resin flow during RFI process were investigated. In addition, resin flow pattern with changing viscosity of epoxy resin was studied. POLYM. COMPOS., 35:681–690, 2014. © 2013 Society of Plastics Engineers     

Modeling of resin infusion in vacuum assisted resin transfer molding

Resin infusion was modeled and analytic solutions were obtained for vacuum assisted resin transfer molding (VARTM). Compaction behavior of the fiber preform was examined experimentally and the influence of compressibility of the preform on the resin infusion was investigated mathematically. Flow front advancement through the preform was predicted by the analytic model proposed in the present study. The model provided pressure and thickness distributions of the region impregnated by the resin. For verification of the analytic solutions, a resin infusion experiment and a mold filling simulation for VARTM were performed and compared with the analytic ones. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers.     

A phenomenological model for fiber tow saturation of dual scale fabrics in liquid composite molding

Advanced composites are manufactured by liquid composite molding by impregnating a thermoset resin into a stationary woven or stitched preform. For a successful injection, the manufactured part should fill all the empty spaces between the fiber tows and inside the fiber tows with the resin. The fiber tows in such preforms have orders of magnitude lower permeability than the regions between the fiber tows, which makes them difficult to fill and hence susceptible to formation of microvoids. Numerical simulations can address the filling of fiber tows but it is difficult to capture the essential physics of their filling in a model created entirely from first principles due to the complexity of the flow which involves anisotropic permeability of flow along and across a fiber tow, uneven packing, fiber sizing, capillarity and the treatment of entrapped air. Hence, in this article we adopt a phenomenological approach in which we compare some of the possible models with an experimental procedure. The experimental procedure provides a quantitative measure of the filling of fiber tows during the impregnation process. A numerical simulation based on the dual scale flow was developed with different constitutive models that described the filling of the fiber tows. The predictions of the different models are compared with the experimental results under different processing conditions to select the model that most accurately describes the tow filling behavior. POLYM. COMPOS., 31:1881–1889, 2010. © 2010 Society of Plastics Engineers.     

不同缝合方式的缝合复合材料无损检测及微观状态研究

缝合技术作为整体成型低成本制造技术已在航空领域得到广泛应用。缝合过程中引入缝线,缝线对缝合复合材料的无损检测结果和制件内部的微观状态都会有所影响。不同的缝合方式,缝线在制件内部的状态不同,因此对制件的无损检测结果和微观状态会产生不同的影响。通过实验研究了临缝、链式缝合和锁式缝合三种不同的缝合方式对缝合复合材料的超声A扫描和超声C扫描无损检测结果的影响,以及对制件内部缝线与树脂的结合等的影响。     

In situ sensor monitoring and intelligent control of the resin transfer molding process

An intelligent closed-loop expert control system has been developed for automated control of the resin transfer molding process of a graphite fiber preform using an epoxy resin, E905L. The sensor model system has been developed to make intelligent decisions based on the achievement of landmarks in the cure process, such as full preform impregnation, the viscosity, and the degree of cure of the resin rather than time or temperature. In-situ frequency dependent electromagnetic sensor (FDEMS) and the Loos resin transfer model are used to monitor and control the processing properties of the epoxy resin during RTM impregnation and cure of an advanced fiber architecture stitched preform. Once correlated with viscosity (η) and degree of cure (α), the FDEMS sensor monitors and the RTM processing model predicts the reaction advancement of the resin, viscosity and the impregnation of the fabric. This provides a direct means for monitoring, evaluating, and controlling intelligently the progress of the RTM process in situ in the mold throughout the fabrication process and for verification of the quality of the composites.     

Comparison of mechanical properties of epoxy composites reinforced with stitched glass and carbon fabrics: Characterization of mechanical anisotropy in composites and investigation on the interaction between fiber and epoxy matrix

The primary purpose of the study is to evaluate and compare the mechanical properties of epoxy‐based composites having different fiber reinforcements. Glass and carbon fiber composite laminates were manufactured by vacuum infusion of epoxy resin into two commonly used noncrimp stitched fabric (NCF) types: unidirectional and biaxial fabrics. The effects of geometric variables on composite structural integrity and strength were illustrated. Hence, tensile and three‐point bending flexural tests were conducted up to failure on specimens strengthened with different layouts of fibrous plies in NCF. In this article, an important practical problem in fibrous composites, interlaminar shear strength as measured in short beam shear test, is discussed. The fabric composites were tested in three directions: at 0°, 45°, and 90°. In addition to the extensive efforts in elucidating the variation in the mechanical properties of noncrimp glass and carbon fabric reinforced laminates, the work presented here focuses, also, on the type of interactions that are established between fiber and epoxy matrix. The experiments, in conjunction with scanning electron photomicrographs of fractured surfaces of composites, were interpreted in an attempt to explain the failure mechanisms in the composite laminates broken in tension. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers     

Effect of packing on void morphology in resin transfer molded E‐glass/epoxy composites

Effects of applying a packing pressure on void content, void morphology, and void spatial distribution were investigated for resin transfer molding (RTM) E‐glass/epoxy composites. Packing pressures of zero and 570 kPa were respectively applied to center‐gated composites containing 17.5% randomly oriented, E‐glass fiber preform. Radial samples of these disk‐shaped composites were utilized to evaluate voidage via microscopic image analysis. Two adjacent surfaces were cut from each molded disk in order to evaluate void presence from both through‐the‐thickness and planar views. The packed composite was found to contain almost 92% less void content than the unpacked composite. While void fractions of 2.2 and 2.6% were measured, respectively, from the through‐the‐thickness and planar surfaces of the unpacked composite, only 0.2% void content was observed in the packed composite from both surfaces. Digital images obtained from through‐the‐thickness surface showed that average void size dropped from 59.3 μm in the unpacked composite to 31.7 μm in the packed composite. A similar reduction in average void size from 66.7 to 41.1 μm was observed from the planar surfaces. Circular voids were found to experience higher removal rates at 99%, followed by cylindrical and elliptical voids at 83 and 81%, respectively; while irregular voids show slightly lower void removal rates at 67%. Void proximity to fiber bundles was also observed to affect void reduction as voids located inside fiber tows experience lower void reduction rates. Along the radial direction of the molded disks, removal of voids with different proximities to fibers seems to depend on their arrangement at the end of the filling stage. These findings are believed to ascertain packing as an effective void removal method for RTM and similar liquid composite molding processes. POLYM. COMPOS., 26:614–627, 2005. © 2005 Society of Plastics Engineers     

不同增强方式下泡沫夹芯复合材料三点弯曲性能研究

研究了缝合及加强筋增强方式下泡沫夹芯复合材料的三点弯曲性能.采用万能试验机分别进行了缝合与未缝合碳纤维、玻璃纤维、玻碳混杂纤维泡沫夹芯复合材料的三点弯曲实验,分别得出各自的载荷-挠度曲线,再引入加强筋的方式进一步研究缝合碳纤维泡沫夹芯复合材料的弯曲性能.结果表明,玻碳混杂纤维泡沫夹芯复合材料较玻璃纤维泡沫夹心复合材料性...     

Highly conductive polymer composites based on controlled agglomeration of carbon nanotubes

This paper reports an innovative approach to enhance electrical conductivity of fiber composites based on non-conductive fiber and polymer matrix. The dispersion of carbon nanotubes (CNTs) is carried out using a fiber sizing agent which contains uniformly distributed CNTs. The infusion of the sizing agent into the fiber preform prior to resin infusion gives rise to high agglomeration of CNTs on the fiber surface and results in electrical conductivities of 2-3 orders of magnitude higher than those of specimens prepared by a calendering approach.     

Optimization Study of C/SiC Threaded Joints

The influences of fiber preform structure and thread engagement length on the mechanical properties of Carbon fiber reinforced silicon carbide matrix (C/SiC) threaded joints were studied. The results show that stacking 3K carbon fiber cloth followed by stitching is a good preform for preparing a C/SiC nut because of its high bearing ability. Stacking 1K carbon fiber cloth followed by stitching is a preferred preform to prepare a C/SiC bolt, and its minimum thread engagement length resulting in bolt rupture instead of thread spalling failure is 4 mm, which is obviously smaller than those of other bolts.