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高变质无烟煤催化气化动力学及补偿效应 总被引:1,自引:0,他引:1
以碳酸钠为催化剂,利用热天平研究了福建建欣高变质无烟煤常压下水蒸气气化反应动力学,在800~950℃测定了碳酸钠加载量从0~18%时该无烟煤气化反应特性,确定了实验条件下碳酸钠催化剂加载饱和浓度,结果表明,加载催化剂后建欣无烟煤气化反应活化能大幅降低.得到了建欣无烟煤与水蒸气气化反应动力学缩芯模型,并给出相应的动力学参数.分析表明,该催化气化反应体系活化能E与频率因子A0之间存在动力学补偿效应,得出其补偿效应方程为ln,A0=8.66×10-5E-0.2827,等动力学温度为1 389 K. 相似文献
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典型农业生物质催化气化反应动力学特性研究 总被引:2,自引:0,他引:2
以CaO、MgO和Fe2O3为催化剂,用程序升温热重法对典型农业生物质催化气化特性及反应动力学进行了研究.利用均相反应模型和缩核反应模型对转化率与温度的关系进行了拟和计算,得到了谷壳样在4种不同二氧化碳气化条件下热解阶段及焦炭气化阶段的活化能和指数前因子.结果表明,在820~1000℃区间内,添加CaO的谷壳样表观活化能比谷壳的大;而添加MgO和Fe2O3的谷壳样表观活化能与谷壳的相比,分别下降了32.6%和17.9%以上,可以看出3种催化剂催化活性大小顺序为MgOFe2O3CaO,活化能区间范围为15.25~123.74kJ/mol.研究表明在低温区间(热解阶段),反应机理更趋向于均相反应模型,而在高温区间(气化阶段),反应机理更趋向于缩核反应模型.最后给出了谷壳在热解阶段及焦炭气化阶段的反应动力学方程. 相似文献
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《动力工程学报》2016,(9):690-696
混合准东煤原煤与催化剂K_2CO_3、Ca(OH)_2并制成煤样,在化学反应动力学控制条件下研究其气化反应特性,分析了煤样质量、CO_2体积流量和颗粒直径对气化过程中内、外扩散阻力的影响,获得不同反应温度下均相模型、未反应芯收缩核模型和修正体积模型的拟合曲线,利用等转化率法计算气化反应活化能,并通过催化活性指数验证了该方法计算活化能的准确性.结果表明:在转化率为0.2、0.4、0.6和0.8时对应的活化能为100.1~130.2kJ/mol,3种模型计算所得活化能分别为128.97kJ/mol、140.33kJ/mol和139.43kJ/mol;均相模型为较合适的气化反应动力学模型. 相似文献
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生物质催化热解气化热重分析研究 总被引:3,自引:0,他引:3
采用热重分析与气相色谱分析(TG-GC)相结合的方法,开展了以麦秸为主要研究对象的生物质催化热解气化实验研究,探讨了以NiO和CaO为催化剂,水蒸气气氛下的麦秸挥发分析出特性、半焦的气化特性、气化反应动力学特性以及催化剂对麦秸气化产物的影响.实验结果表明麦秸水蒸气气氛下的反应活性明显提高,气化反应过程中热解阶段视为一级反应,半焦气化视为缩核反应.非催化条件下麦秸的半焦气化在800℃以上才进行,添加NiO与CaO均促进了麦秸与水蒸气的气化反应,提高了气化过程的碳转化率和反应速率,但二者对半焦气化的促进机理以及气体产物的催化选择性有明显差异.添加NiO时H2产率最大,达到34mol/kg麦秸,且使气化反应温度明显降低.添加CaO不仅促进了H2和CO的生成,而且CH4产率也明显提高,表明CaO更有利于大分子碳氢化合物的裂解. 相似文献
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《International Journal of Hydrogen Energy》2022,47(63):26789-26797
The issues related to the reliability of hydrogen engines of unmanned vehicles and increasing the efficiency of using hydrogen as fuel when using the method of its production during the decomposition of hydrogen-containing molecules of liquid-phase organic compounds in a plasma discharge under the action of intense ultrasonic exposure are considered. Experiments have shown that as a result of decomposition in the acoustoplasma discharge of liquid hydrocarbons, solid-phase carbon-containing products are formed, chemical transformations occur in the liquid phase and hydrogen-containing combustible gas is formed. Hydrogen-containing gas can be used as fuel immediately after synthesis, i.e. it does not require separation, since in addition to hydrogen it contains only impurities of CO2 and water vapor. The purpose of the study is to formalize the basic conditions for tightening the control of mutual compliance with the efficiency of hydrogen engines of the same series in the conditions of their mass production. Methods of mathematical statistics and hardware-software modeling were used in the study. The term “unerroric of quality mutual compliance control” is introduced to describe a set of hardware and software tools for such control. The principle of in-depth testing of the technical condition of such engines of one series is described in a multidimensional formulation of the quality control problem for three of their operating parameters at once. The conditions for increasing the mutual correspondence of the measured values of such parameters in the conditions of serial production of hydrogen engines are formalized. 相似文献
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Linear and nonlinear analyses of the instabilities and distortion of liquid streams injected into a gaseous media are discussed. The various fundamental mechanisms and the predictive capabilities for the distortions are emphasized. Round jets, planar sheets, annular sheets, and conical sheets are discussed in detail. The balance between capillary and inertial forces is primarily examined. The method for simplifying the analyses in the case of thin liquid sheets is discussed. The capabilities for representing the droplet size distribution that follows the stream disintegration are outlined. 相似文献
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基于《水工混凝土掺用氧化镁技术规范》中的Ⅰ型氧化镁(MgO),研究了该型MgO膨胀剂(MEA)细度对掺粉煤灰水泥浆体膨胀性能的影响。即采用X射线衍射分析(XRD)及同步热分析(TG DSC)分析了掺MEA水泥浆体中MgO的水化性。结果表明,养护温度相同时,MEA的细度对水泥浆体内MEA中MgO的水化和水泥浆体的膨胀无显著影响,产生的膨胀均能补偿水泥浆体的收缩;MEA的细度可从试验设计采用的45 μm筛筛余15%左右增加到30%左右,这将有利于MEA生产企业的节能降耗。 相似文献
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使用ANSYS8.0软件对高速列车车轮进行了三维有限元分析,计算出车轮在直线、曲线和道岔条件下牵引、制动共6种工况时孔边薄弱部位的应力,分别通过Mises等效平均应力方法、Sines平均主应力方法和应力分量中考虑平均应力方法计算出应力在极值位置时的等效应力幅、等效平均应力,从而进一步算出车轮的安全系数,对其疲劳强度进行评定,并对3种方法进行了比较研究。 相似文献
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M.R. Salimpour M. SharifhasanE. Shirani 《International Communications in Heat and Mass Transfer》2011,38(1):93-99
This paper documents the geometric optimization of an array of circular and non-circular ducts. The optimization was carried out numerically using finite volume method. As optimal dimensions were independent of the array configuration, the numerical simulation was performed on a unit cell. Numerical optimization for circular, square and isosceles right triangle cross-sections of channels was performed. Based on the results of this investigation, some correlations were proposed to predict the optimal hydraulic diameter and dimensionless heat transfer per unit volume. In addition to examining the effect of pressure drop on these parameters, it was showed that among the different geometries of this study, square cross-section has the most efficiency for a given volume. The numerical results of the present study were compared with approximate results reported in the literature which a good agreement was observed. 相似文献
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本文对漫灰均温物体在常物性条件下对外辐射传热的Yong值计算建立了数学模型。通过与物体内能Yong公式的数值计算比较,得出了辐射能量的Yong值不大于内能Yong值的结论。从初步的热射Yong值计算公式发现。Yong与物体表面辐射率有关。 相似文献
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《International Journal of Hydrogen Energy》2022,47(83):35515-35526
The main purpose of this work is to propose a new method to evaluate the concentration distribution of the hydrogen jet by using a He–Ne laser through the jet. This research attempts to apply the expression of concentration Gaussian distribution, the refraction formula of inhomogeneous refractive index medium, and the concentration inversion function to disclose the displacement of the center of the laser spot at different heights in the gas jet. The spot images of the laser beam passing through the gas jet at three vertical heights z = 10d, 20d, 30d, and different radial positions are obtained. The radial spatial asymmetry of the gas jet is also found in the experiment. Finally, the calculated concentration distribution curve and the fluent simulation curve, it is found that the two results are very similar. Our findings show that the error between the concentration distribution of this method and the simulated concentration distribution reaches 2.43%. 相似文献
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General expressions for the heat of vaporization of mixtures at constant pressure; at constant temperature; and at constant pressure, temperature, and composition are proposed. The last one is related to the liquid-vapor interface where steady vaporization or condensation is taking place. Numerical examples by the proposed expressions are shown for binary mixtures of HCFC22(R22) and (HCFC123(R123) © 1997 Scripta Technica, Inc. Heat Trans Jpn Res, 25(1): 12–24, 1996 相似文献