Effect of annealing temperature on the electrical characteristics of Platinum/4H-SiC Schottky barrier diodes

Pt/4H-SiC Schottky barrier diodes have been fabricated to investigate the effect of annealing on the electrical characteristics of the fabricated devices. The parameters such as barrier height, ideality factor and donor concentration were deduced from the current–voltage (I–V) and the capacitance–voltage (C–V) measurements at room temperature. Diodes showed non-ideal behaviour like high value of ideality factor and lower value of barrier height. A barrier height of 1.82?eV was obtained from C–V measurements and it was 1.07?eV when obtained from the I–V measurements with ideality factor 1.71 for as-deposited diodes at room temperature. The diodes, therefore, were annealed in the temperature range from 25°C to 400°C to observe the effect of annealing temperature on these parameters. Schottky barrier height and ideality factors were found to be temperature-dependent. After rapid thermal annealing upto 400°C, a barrier height of 1.59?eV from C–V measurements and the value of 1.40?eV from I–V measurements with ideality factor 1.12 were obtained. Barrier heights deduced from C–V measurements were consistently larger than those obtained from I–V measurements. To come to terms with this discrepancy, we re-examined our results by including the effect of ideality factor in the expression of the barrier height. This inclusion of ideality factor results in reasonably good agreement between the values of barrier height deduced by the above two methods. We believe that these improvements in the electrical parameters result from the improvement in the quality of interfacial layer.     

Electrical properties of nickel-low-doped n-type gallium arsenide Schottky-barrier diodes

The forward current characteristics of nickel-low-doped n-type gallium arsenide Schottky-barrier diodes are measured over the temperature range 90.5-434 K. The ideality factor and its temperature dependence is determined and found to decrease with increasing temperature according to the relationshipn(T) = 11.4T^{-1/2}+0.444 to within ±4 percent. This is in agreement with the theoretical analysis of Strikha, who predicted a temperature dependence law between T^-1andT^{-1/2}. The barrier height is determined from both the saturation current and the capacitance methods. A modification is made to the forward current expression, which results in good agreement between the values of the barrier height obtained from both methods over a wide temperature range. The barrier height is found to decrease with increasing temperature at a rate of 5.8 × 10-4V/K. Comparison with the dependence of the energy gap on temperature in GaAs suggests that the observed change in the barrier height is equal to that of Eg.     

Investigation of Al Schottky junction on n-type CdS film deposited on polymer substrate

A systematic study has been made on the behavior of Al/n-CdS thin film junction on flexible polymer substrate (polyethylene terephthalate, PET) grown using thermal evaporation method. Temperature dependence of I-V measurements for this junction has been done which closely follow the equations of Schottky barrier junction dominated by thermionic emission mechanism. Intrinsic and contact properties such as barrier height, ideality factor and series resistance have been calculated from I-V characteristics. The barrier height of Al/n-CdS junction is found to increase with increase in temperature whereas ideality factor and series resistance decrease with increase in temperature.     

Temperature dependent current-voltage characteristics of the Zn/ZnO/n-Si/Au-Sb structure with ZnO interface layer grown on n-Si substrate by SILAR method

This is the first time; it was employed Successive Ionic Layer Adsorption and Reaction (SILAR) method in order to prepare Zn/ZnO/n-Si/Au-Sb sandwich structure. The ZnO interface layer was directly formed on n-type Si substrate using SILAR method. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies were showed that the film is covered well on n-type Si substrate and have polycrystalline structure. An Au-Sb electrode was used as an ohmic contact. The Zn/ZnO/n-Si/Au-Sb sandwich structure demonstrated clearly rectifying behavior by the current-voltage (I-V) curves studied at room temperature. The sample temperature effect on the current-voltage (I-V) characteristics of Zn/ZnO/n-Si/Au-Sb structure was investigated in temperature range 80-320 K by steps of 20 K. The parameters such as barrier height, ideality factor and series resistance of this structure were calculated from the forward bias I-V characteristics as a function of sample temperature. It was seen that the ideality factor and series resistance were decreased; the barrier height were increased with increasing temperature. The experimental values of barrier height and ideality factor for this device were calculated as 0.808 eV and 1.519 at 320 K; 0.220 eV and 4.961 at 80 K, respectively. These abnormal behaviors can be explained by the barrier inhomogeneities at the metal-semiconductor (M-S) interface.     

Barrier height and ideality factor dependency on identically produced small Au/p-Si Schottky barrier diodes

Small high-quality Au/P-Si Schottky barrier diodes (SBDs) with an extremely low reverse leakage current using wet lithography were produced. Their effective barrier heights (BHs) and ideality factors from current-voltage (Ⅰ-Ⅴ) characteristics were measured by a conducting probe atomic force microscope (C-AFM). In spite of the identical preparation of the diodes there was a diode-to-diode variation in ideality factor and barrier height parameters. By ex-trapolating the plots the built in potential of the Au/p-Si contact was obtained as Vbi = 0.5425 V and the barrier height value φB(C-V) was calculated to be φB(C-V) = 0.7145 V for Au/p-Si. It is found that for the diodes with diameters smaller than 100 μm, the diode barrier height and ideality factor dependency to their diameters and correlation between the diode barrier height and its ideality factor are nonlinear, where similar to the earlier reported different metal semi-conductor diodes in the literature, these parameters for the here manufactured diodes with diameters more than 100μm are also linear. Based on the very obvious sub-nanometer C-AFM produced pictures the scientific evidence behind this controversy is also explained.     

The current-voltage-temperature characteristics of Al/NPB/p-Si contact

The current-voltage (I-V) characteristics of the Al/NPB/p-Si contact shows rectifying behavior with a potential barrier formed at the contact interface. The barrier height and ideality factor values of 0.65 eV and 1.33 are measured at the forward bias of the diode. The barrier height of the Al/NPB/p-Si diode at room temperature is larger that (∼0.58 eV) of conventional Al/p-Si diode. It reveals the NPB organic film control the carrier transport of the diode at the contact interface. The temperature effect on the I-V measurement is also performed to reveal the junction characteristics. The ideality factor of the Al/NPB/p-Si contact increases with decreasing temperature. And the barrier height decreases with decreasing temperature. The effects are due to the existence of the interface states and the inhomogeneous of the barrier at the junction.     

p型Al/6H-SiC肖特基二极管特性研究

研究了 p型 Al/6H- Si C肖特基二极管的基本制作工艺及其电学参数。采用电流 -电压法 ( I-V)测试了肖特基二极管的理想因子 n和肖特基势垒高度b。对其基本电学参数 n和b 的温度特性进行了研究 ,并分析了串联电阻对 I- V特性的影响。     

肖特基接触的机理及不均匀性研究

对一般情况下肖特基接触的机理和肖特基势垒高度的影响因素做了系统分析,研究了肖特基接触特性的不均匀性及其原因,指出多晶界面势垒高度比同种材料的要低。通过实验,研究了金属/n-poly-Si0.83Ge0.17肖特基结的I-V-T特性,得到了势垒高度及影响因子与测试温度和外加偏压的依赖关系。研究发现:随着测试温度升高,表观理想因子变小,肖特基势垒高度变大;外加偏压增大,表观势垒高度和理想因子均变大。基于肖特基接触的不均匀性进行建模,得到了退火样品的表观势垒高度和理想因子近似为线性负相关的结论。     

A fully planarized 4H-SiC trench MOS barrier Schottky (TMBS)rectifier

A fully planarized 4H-SiC trench MOS barrier Schottky (TMBS) rectifier has been designed, fabricated and characterized for the first time. The use of a TMBS structure helps improve the reverse leakage current by more than three orders of magnitude compared to that of a planar Schottky rectifier. We have achieved a low reverse leakage current density of 6×10^-6 A/cm² and a low forward voltage drop of 1.75 V at 60 A/cm² for the TMBS rectifier. The static current-voltage (I-V) and switching characteristics of the TMBS rectifier have been measured at various temperatures. A barrier height of 1.0 eV and an ideality factor of 1.8 were extracted from the forward characteristics. The switching characteristics do not change with temperature indicating the essential absence of stored charge     

Series resistance calculation for Ag contacts on single crystal layered p-SnS and p-SnSe compound semiconductors in the wide temperature range

This paper summarizes the first results of characteristics parameters obtained from current-voltage (I-V) measurements for Ag/p-SnS and Ag/p-SnSe structure. The reverse and forward bias current-voltage characteristics of Ag Schottky contacts on a Bridgman-Stockbarger grown p-SnS and p-SnSe layered semiconducting material have been measured at various temperatures. We have tried to determine contact properties such as apparent barrier heights Φ_B0, ideality factor n and series resistance R_s. The apparent barrier height and ideality factor calculated by using thermionic emission theory were found to be strongly temperature dependent. Evaluating forward I-V data reveals a decrease at the apparent barrier height, but an increase at the ideality factor with decrease in temperature. It is shown that the values of R_s estimated from Cheung’s method were strongly temperature dependent and decreased with increasing temperature. It has been found that both contacts are of Schottky type.     

GaAs surface plasma treatments for Schottky contacts

The properties of different rectifying metallizations (Al, Ti/Pt, WN_x) on GaAs have been investigated for various surface preparation procedures. In particular, in situ hydrogen plasma treatments were used to remove residual surface contamination (mainly O and C) and a nitrogen plasma to grow a thin mixed nitride layer. Al and Ti/Pt Schottky diodes with an ideality factor very close to 1, but with reduced barrier height, were found after the H₂ plasma as a consequence of H diffusion into GaAs. The Schottky barrier height was further reduced if a H₂ + N₂ plasma was performed. The N content in the sputtering environment during the WN_x deposition affects the diode properties of plasma-treated WN_x contacts. By increasing the N₂ partial pressure, the diode barrier height is reduced, probably due to nitridization of the GaAs surface. Such differences disappear after annealing the diodes in arsine overpressure at 800°C. WN_x contacts deposited under different conditions on H₂ plasma treated substrates also show a similar Schottky barrier height after such annealing.     

Effect of KOH treatment on the Schottky barrier inhomogeneity in Ni/n-GaN

The effect of KOH treatment on the Schottky barrier inhomogeneity in Ni/n-GaN Schottky diodes was investigated. It was observed that both the barrier heights and ideality factors varied from diode to diode with a linear relationship between barrier height and ideality factor, indicating the presence of a lateral inhomogeneity in the Schottky barrier. Simple extrapolation of the straight line obtained from the linear fitting to the barrier height versus ideality factor plot to the image-force controlled ideality factor produced the lateral homogeneous barrier heights, which were higher than those from current–voltage measurements. Furthermore, Gaussian fitting to the distribution of barrier heights exhibited the increased barrier height with the smaller standard deviation after KOH treatment, implying the improved barrier homogeneity. A possible explanation for this behavior can be an improvement of the Ni/n-GaN interface intrinsic properties, e.g., through a reduction of the surface states acting as low barrier region.     

One micrometre scale self-aligned cobalt disilicide Schottkybarrier diodes

CoSi₂/n-type silicon(111) Schottky barrier diodes on a 1 μm scale have been fabricated using a self-aligned silicide process incorporating magnetron sputtering and rapid thermal processing, in an industrial environment. Anneal temperatures in the range 700-1100°C have been used, and ideality factors of 1.06-1.07 were obtained in the range 700-900°C with larger values for higher temperatures. The consistency in the values of the ideality factor indicates that a wide annealing temperature window exists for the successful fabrication of CoSi₂/silicon diodes     

Numerical analysis of inhomogeneous Schottky diode with discrete barrier height patches

The potential profile inside the semiconductor at the metal–semiconductor contact is simulated by numerically solving the Poisson equation and the drift diffusion equations for inhomogeneous Schottky diode. From the simulated potential and the electron and hole concentrations, the drift-diffusion current as a function of bias is calculated. The simulation is carried out for various distribution patterns of barrier height patches at the metal–semiconductor contact to study the effect of barrier inhomogeneities on the Schottky diode parameters, namely barrier height and ideality factor and their temperature dependence. It is found that barrier height decreases and ideality factor increases with increase in the deviation of discrete barrier height patches in the distribution. The resulting barrier parameters are studied to understand the effect of barrier inhomogeneities on the current–voltage characteristics of inhomogeneous Schottky contact.     

Temperature dependence of barrier height parameters of inhomogeneous Schottky diodes

We have shown by numerical simulations of I-V-T curves that the ideality factor of inhomogeneous Schottky diodes does not increase for decreasing temperature to such extent as is commonly observed for Schottky diodes in experiment. The main consequence of such a result is that in spite of the fact that the barrier height inhomogeneities fullfil the conditions for barrier height lowering for decreasing temperature they might not be a general or the only reason for occuring of this effect in experimental structures. We found out much slower ideality factor temperature dependence than reported in the literature and the dependence was even not monotonous for simulation conditions used. We conclude that some other reason as barrier inhomogeneity is responsible for ideality factor temperature dependence.     

Characteristics of LPCVD WSi2/n-Si Schottky contacts

Detailed current-voltage and capacitance-voltage characteristics of low-pressure chemical vapor deposited (LPCVD) WSi₂/n-Si Schottky contacts are reported in the temperature range of 21 to 170°C. The diode ideality factor n was found to decrease from a value of 1.46 to 1.15 as temperature was increased. Schottky barrier height φ_B, on the other hand, was found to increase from 0.72 to 0.86 V with temperature. These results suggest that diode characteristics are affected by surface and bulk effects, especially at lower temperatures. High-resolution transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy analyses revealed isolated regions of oxynitride at the silicide/silicon interface that are predominantly located where silicide grain boundaries intersect the silicon surface     

Schottky Barrier Height of Erbium Silicide on $ hbox{Si}_{1 - x}hbox{C}_{x}$

In this letter, the Schottky barrier height of erbium silicide contacts formed on $hbox{Si}_{1 - x}hbox{C}_{x}$ alloys was measured. The alloys were pseudomorphically grown on Si wafers with 0% to 1.2% C occupying the substitutional sites. Schottky barrier diodes were fabricated with an ideality factor of 1.13 or less. The hole barrier height was found to be 0.73 eV independent of the C concentration. This suggests that the electron barrier height should decrease with increasing C concentration due to the reduction in the semiconductor bandgap. For 1.2% C, the electron barrier is estimated to be 0.29 eV.      

无凹槽AlGaN/GaN肖特基势垒二极管正向电流输运机制

研究了无凹槽AlGaN/GaN肖特基势垒二极管(SBD)的正向电流输运机制。分别采用Ni/Au和TiN作为阳极金属材料制备了无凹槽AlGaN/GaN SBD,对比了两种SBD的直流特性。并通过测量器件的变温I-V特性,研究了器件的正向电流输运机制。结果表明,TiN-SBD(0.95 V@1 mA·mm^-1)与Ni/Au-SBD(1.15 V@1 mA·mm^-1)相比实现了更低的开启电压,从而改善了正向导通特性。研究发现两种SBD的势垒高度和理想因子都强烈依赖于环境温度,通过引入势垒高度的高斯分布模型解释了这种温度依赖性,验证了正向电流输运机制为与势垒高度不均匀分布相关的热电子发射机制。     

Schottky diode performance of an Au/Pd/GaAs device fabricated by deposition of monodisperse palladium nanoparticles over a p-type GaAs substrate

Au/Pd/p-GaAs Schottky diodes were fabricated by simple assembly of monodisperse Pd nanoparticles on a p-type GaAs semiconductor. Monodisperse 5-nm Pd nanoparticles were synthesized via reduction of palladium(II) acetylacetonate in oleylamine using a borane tert-butylamine complex. The Au/Pd/p-GaAs Schottky diodes provided a barrier height of 0.68 eV, which is higher than room-temperature values reported in the literature. A double distribution was observed for the barrier height for the Schottky diodes from I–V–T measurements. A decrease in temperature lowered the zero-bias barrier height and increased the ideality factor. These observations were ascribed to barrier height inhomogeneities at the interface that altered the barrier height distribution. Values of the series resistance obtained by the Norde method decreased with increasing temperature. Understanding the temperature dependence of the current–voltage characteristics of Au/Pd/p-GaAs devices might be helpful in improving the quality of Pd deposited on GaAs for future device technologies.     

Schottky barriers on n-GaN grown on SiC

Characteristics of Schottky barriers fabricated on n-type GaN were investigated. The barriers were formed by vacuum thermal evaporation of Cr, Au, and Ni. Current-voltage (I-V) and capacitance-voltage (C-V) characteristics of the barriers were measured in a wide temperature and current density range. Fundamental parameters (barrier height and built-in potential) of the Schottky barriers were determined. The dependence of the barrier ideality factor on doping concentration in GaN was measured. Correlation between the barrier height and metal work function was observed. The electron affinity for GaN was determined using both C-V and I-V characteristics. The current flow mechanism through the barriers is discussed.