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1.
MnO2对0.85Pb(Zn1/3Nb2/3)O3—0.15BaTiO3陶瓷弛豫现象的影响   总被引:2,自引:0,他引:2  
王晓莉  姚熹 《硅酸盐学报》1994,22(4):381-386
研究了MnO2掺杂对0.85Pb(Zn1/3Nb2/3)O3-0.15BaTiO3陶瓷电介电、热释电以及铁电弛豫等性能的影响。添加MnO2使PZN-BT陶瓷的介电常数ε下降,室温老化率明显增大。随着MnO2含量的增加,PZN-BT陶瓷介电常数与温度的关系中所表现出来的频率弛豫现象逐渐减弱,直到消失,但其扩散相变现象仍然十分明显。  相似文献   

2.
用湿化学法制备了钙钛矿相的含量为99%的0.95Pb(Mg_(1/3)Nb_(2/3))O3-0.05PbTiO_3(简称0.95PMN-0.05PT)微粉,SEM显示其粒度为0.2~0.3μm。通过XRD确定了合成0.95PMN-0.05PT前驱物的最佳条件为:溶液的pH值为1.5,反应温度为60℃。制备0.95PMN-0.05PT陶瓷时,预烧温度为800℃(2h),烧结温度为1250℃(1h)。粉末烧结后制得纯钙钛矿相的0.95PMN-0.05PT铁电陶瓷,其密度为理论密度的95%,介电常数为14800(800Hz)。  相似文献   

3.
在合成的(Ba0.65Pb0.35)TiO3中分别掺入了Al2O3,SiO2,La2O3,MnO2和TiO2.讨论了每种掺杂物与烧成气氛和升温制度对常温电阻率的影响,找出了PTC陶瓷的最佳组成;1mol(Ba0.65Pb0.35)TiO3,0.002molAl2O3,0.004molSiO2,0.01molTiO2,0.003molLa2O3,0.0002molMnO2.这种PTC陶瓷的表面温度为270℃,常温电阻率为5~8×103Ω·cm,时任性为240v/mm.  相似文献   

4.
用普通合成法制备了纯钙钛矿结构相的Pb(Fe_(1/2)=Ta_(1/2))O_3(PFT)陶瓷,并进行了900℃退火热处理。对其介电性质测试结果表明,未热处理与热处理过的PFT陶瓷在0.1~100kHz频率下均表现出介电弥散性转变。未热处理的PFT陶瓷最大介电常数对应的温度(T_0)不随测量频率变化;热处理过的PFT陶瓷在此频率范围T_0值表现出明显的频率依赖性(频率色散),即ΔT_0=5℃。由此可以认为PFT是弛豫铁电体。XRD结果表明,未热处理的PFT陶瓷无超晶格衍射;而热处理过的PFT陶瓷则有较弱的(111)超晶格衍射。利用有序-无序转变理论及超顺电结构模型对其结构与性质进行了探讨。  相似文献   

5.
用普通合成法制备了纯钙钛矿结构相的Pb(Fe1/2Ta1/2)O3(PFT)陶瓷,并进行了900℃退火热处理。对其介电性质测试结果表明,未热处理与热处理过的PFT陶瓷在0.1 ̄100KHz频率下均表现出介电弥散性转变。未热处理的PFT陶瓷最大介电常数对应的温度(T0)不随测量频率变化;热处理过的PFT陶瓷在此频率范围T0值表现出明显的频率依赖性(频率色散),即△T0=5℃。由此可以认为PFT是弛豫  相似文献   

6.
将尖晶石型NiMn_2O_4及钙钛矿型LaCrC_3这二者电阻个较高的半导体陶瓷热敏材料复合并经高温烧结后,其复合体电阻率大幅度降低。应用XRD,XPS,TEM和SEM对复合体结构进行较为系统的研究,结果表明:NiMn_2O_4与LaCrO_3按一定比例复合后,在烧结过程中两者之间有离子迁移发生,离子迁移的结果使钙钛矿结构的LaCrO_3转变为高导电相的La[Cr_(1-x-y)Ni_xMN_y]O_3(0<y<0,0<x+y<0),它使复合体电阻率大幅度降低。  相似文献   

7.
以乙酸和氢氧化钾为辅助原料,通过Ti(O ̄nBu)_4-Ba(OAc)_2水解法合成BaTiO_3粉体。借助SEM、TEM、XRD和EPMA等分析手段,研究了pH值对BaTiO_3粉体性能的影响。论述了合成BaTiO_3的反应机理,同时探讨了pH值对其反应机理的影响。  相似文献   

8.
考察了丙烯在M_xO_y固体超强酸催化剂上的齐聚过程。实验表明,催化剂的活性顺序为Z_rO_2>TiO_2,而Fe_2O_3催化剂几乎无活性。FT-IR表明,ZrO_2催化剂具有超强酸的3个特征吸收峰,即1050、1130和1220cm ̄(-1)。XRD分析表明,ZrO_2为非结晶态,而未浸H_2SO_4的ZrO_2没有上述3个特征吸收峰,且以晶态存在。在T=130℃、P=4.0MPa、LHSV=1.0h ̄(-1)和丙烯浓度为50%的条件下,100h的稳定性试验表明,丙烯平均转化率为69.5%,壬烯选择性为45.5%和十二烯选择性为41.6%。  相似文献   

9.
研究了ZrN在Si_3N_4-ZrO_2复相陶瓷中的形成及其对材料性能的影响,结果表明:在1.5MPaN2气压烧结条件下,ZrN的形成温度约为1600℃,提高N_2的压力有利于抑制ZrN的生成,以稳定的t-ZrO_2加Si_3N_4基体中,对抑制ZrN的生成有明显作用。当复相陶瓷中生成一定量的ZrN时,力学性能明显下降,而ZrO_2分布均匀且以t-ZrO_2,c-ZrO_2形式存在时,复相陶瓷具有较高的强度(740MPa)和断裂韧性(8.8MPa·m ̄(1/2))。  相似文献   

10.
BaTiO3系陶瓷电压非线性特性研究   总被引:2,自引:0,他引:2  
对BaTiO3-BaZrO3,BaTiO3-BaSnO3,BaTiO3-SrTiO3非线性陶瓷材料的介电性能(ε,tanδ)与外BaZr0.13Ti0.87O3,BaSn0.06Ti0.94O3在直流偏压下ε可变化1.5 ̄2.7倍;在交流电压下ε可变化2 ̄2.5倍,且具肮介电常数、较高抗电强度,可用作开关电源RCD保护电路的非线性陶瓷电容器和荧光灯无触点起辉器材料,Ba1-xSrxTiO3在直流偏  相似文献   

11.
Microstructures of ordered Ba(Cd1/3Ta2/3)O3 perovskite dielectric ceramics with and without a boron additive have been observed by atomic resolution transmission electron microscopy (TEM). The selected area electron diffraction and lattice image show a well-ordered structure with hexagonal symmetry (lattice constants of a ∼5.8 Å and c ∼7.1 Å) in the ordered Ba(Cd1/3Ta2/3)O3 with a boron additive, which is similar to those in ordered Ba(Zn1/3Ta2/3)O3 and Ba(Mg1/3Ta2/3)O3 ceramics. Ordered domains with a twin crystallographic relationship and high-density domain interfaces induced by ordering were observed in the ordered Ba(Cd1/3Ta2/3)O3 without a boron additive sintered at a relatively high temperature. Atomic resolution TEM further revealed the conservative twin boundaries along (001) and (110) planes and non-conservative antiphase boundaries with a projected displacement vector of the type [001] in the ordered Ba(Cd1/3Ta2/3)O3 without a boron additive. Finally, the energetics of different domain interfaces are discussed with the interfacial structures in ordered Ba(Cd1/3Ta2/3)O3 ceramics revealed by an electron microscope.  相似文献   

12.
Since the electromechanical devices move towards enhanced power density, high mechanical quality factor (Qm) and electromechanical coupling factor (kp) are commonly needed for the high powered piezoelectric transformer with Qm≥2000 and kp=0.60. Although Pb(Mn1/3Nb2/3)O3–PbZrO3–PbTiO3 (PMnN–PZ–PT) ceramic system has potential for piezoelectric transformer application, further improvements of Qm and kp are needed. Addition of 2CaO–Fe2O3 has been proved to have many beneficial effects on Pb(Zr,Ti)O3 ceramics. Therefore, 2CaO–Fe2O3 is used as additive in order to improve the piezoelectric properties in this study. The piezoelectric properties, density and microstructures of 0.07Pb(Mn1/3Nb2/3)O3–0.468PbZrO3–0.462PbTiO3 (PMnN–PZ–PT) piezoelectric ceramics with 2CaO–Fe2O3 additive sintered at 1100 and 1250 °C have been studied. When sintering temperature is 1250 °C, Qm has the maximum 2150 with 0.3 wt.% 2CaO–Fe2O3 addition. The kp more than 0.6 is observed for samples sintered at 1100 °C. The addition of 2CaO–Fe2O3 can significantly enhance the densification of PMnN–PZ–PT ceramics when the sintering temperature is 1250 °C. The grain growth occurred with the amount of 2CaO–Fe2O3 at both sintering temperatures.  相似文献   

13.
李楠  谢志鹏  易中周  翟凤瑞 《硅酸盐通报》2020,39(12):3729-3742
氧化铈稳定的四方氧化锆多晶陶瓷(Ce-TZP)具有良好的抗低温老化性和很高的断裂韧性(KIC>20 MPa·m1/2),但是弯曲强度较低(500 MPa左右)。如何在保留Ce-TZP陶瓷的抗低温老化性和高断裂韧性的同时,提高其强度,是本领域研究人员共同关心的问题。大量研究表明,通过添加其他固溶离子(如Y3+)达到共稳定效果和引入第二相(如Al2O3)获得细晶Ce-TZP基的复相陶瓷,可以显著提高材料的断裂强度,综合改善其力学性能。本文对CeO2与其他氧化物共稳定的ZrO2陶瓷及Ce-TZP/Al2O3复相陶瓷的研究进展进行了综述,并以义齿种植和增材制造为例介绍了其应用现状。  相似文献   

14.
Mn-Fe-Ce/TiO2低温NH3选择性催化还原NO   总被引:1,自引:0,他引:1  
采用浸渍法制备了MnO2-Fe2O3-CeO2/TiO2催化剂用于低温NH3选择性催化还原烟气中NO,考察了Mn, Fe, Ce含量及焙烧温度对NH3选择性催化还原NO的活性和抗水性能的影响. 在气体体积空速(GHSV)=24000 h-1, NH3/NO=0.8(j), 350℃煅烧和烟气含3%(j) O2的条件下,该系列催化剂的脱硝活性为MnO2-Fe2O3-CeO2/TiO2>MnO2- Fe2O3/TiO2>MnO2/TiO2,且在200℃时MnO2(10)-Fe2O3(5)-CeO2(5)/TiO2的脱硝率为95%. 对含10%(j)水蒸汽的烟气,MnO2(10)-Fe2O3(5)-CeO2(5)/TiO2的脱硝活性维持在87%;在10%(j)水蒸汽和100′10-6 SO2共存条件下,短时间内脱硝活性维持在55%.  相似文献   

15.
秦媛  刘毅  胡林  张羽琴 《硅酸盐学报》2011,(10):1581-1584
采用溶胶-凝胶的方法制备了Bi0.75Sr0.25MnO3化合物,并对其结构、磁性质、铁电性进行了研究。X射线衍射结果显示样品为单相钙钛矿结构,电阻率和差热实验证实了样品在590K的温度附近发生了电荷有序相变。磁性质测量表明样品在低温下(5K)为铁磁性。电滞回线测量显示样品在室温下最大的剩余极化强度Pr为4.47×10...  相似文献   

16.
<001> oriented xBi(Mg1/2Ti1/2)O3-(0.7-x)Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (BMT-PMN-PT) textured ceramics are successfully fabricated by the template grain growth method using BaTiO3 platelets as template. BMT-PMN-PT textured ceramics with different BMT contents are studied in terms of crystal structure, microstructures, dielectric and ferroelectric properties, and electric field induced strain. The as-fabricated BMT-PMN-PT textured ceramics were found to have a strong orientation along <001> direction. The frequency dispersion of dielectric constant of BMT-PMN-PT textured ceramics increases gradually and its relaxability becomes stronger with increasing BMT content. A large electric-field induced strain (0.42 % at 4 kV/mm) is obtained in 0.25BMT-0.45PMN-0.3PT textured ceramics with Lotgering factor 0.94, which is about 83 % enhancement than that of the randomly oriented ceramics (0.23 % at 4 kV/mm). The strain of 0.25BMT-0.45PMN-0.3PT textured ceramics have a relatively high thermal stability, with a slight decrease from 0.42 % to 0.28 % in the temperature range of 20−100 °C. Our research suggests that 0.25BMT-0.45PMN-0.3PT textured ceramics have a greatly potential for actuator devices applications owing to its advantages of large electric field induced strain response.  相似文献   

17.
(1-x)Ba(Mg1/3Nb2/3)O3-xBaSnO3陶瓷的微波介电性能   总被引:1,自引:0,他引:1  
用传统陶瓷制备方法制备了(1-x)Ba(Mg1/3Nb2/3)O3-xBaSnO3[0.0≤x≤0.3,(1-x)BMN-xBS]体系微波介质陶瓷,研究了该陶瓷的微观结构和微波介电性能.用X射线衍射仪研究陶瓷的晶体结构.用扫描电镜观察陶瓷的显微结构.用网络分析仪测试陶瓷的微波介电性能.结果表明:晶格常数c和a均随x值的增加而增加;晶格常数比(c/a)随x值的增加而减小.当x≥0.1时,1∶2有序衍射峰消失.陶瓷的平均晶粒尺寸在0.7~2 μm之间.随x值的增加,陶瓷的相对介电常数(εr)和谐振频率温度系数(τr)呈线性减小;品质因数与谐振频率的乘积(Qf)呈非线性变化.当x=0.15时,Qf达到最大值,为86 200 GHz.当x=0.3时,在此体系中可以获得τf接近零的微波介质陶瓷Ba(Sn0.3Mg0.233Nb0.467)O3,其微波介电性能如下:εr=26.1;Qf=42 500GHz;τr=4.3×10-6/℃.  相似文献   

18.
0.24Pb(In1/2Nb1/2)O3-0.42Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 transparent ceramics were fabricated by a conventional sintering technique. Through optimization of sintering conditions of calcination and sintering temperatures and time, the obtained ceramics showed high optical transmittance of 53% and 71% at light wavelengths of 1300 and 2000 nm, respectively. The ceramics showed a rhombohedral to tetragonal phase transition at ~120°C and a tetragonal to cubic phase transition at 222°C. These transition temperatures were higher than those of 0.67Pb(Mg1/3Nb2/3)-0.33PbTiO3 ceramics. In addition, the ceramics had a ferroelectric hysteresis loop, a large piezoelectric constant d33 of 407 pC/N, and a planar electromechanical coupling factor kp of 52%. These results suggest that the transparent ceramics may be used as a temperature-stable, linear electro-optic material.  相似文献   

19.
汪跃群  项光磊  高亮 《硅酸盐通报》2022,41(4):1433-1439
本文通过一步反应合成法制备了铌镁-锆钛酸铅(Pb(Mg1/3Nb2/3)O3-Pb(Zr,Ti)O3,PMN-PZT)压电陶瓷,研究了稀土元素钐(Sm)掺杂对PMN-PZT(x%(摩尔分数)Sm-PMN-PZT)结构与电学性能的影响规律,得到了具有高压电性、高机电耦合系数和高居里温度的压电陶瓷。当x=2.0时,压电常数d33=611 pC/N,机电耦合系数kp=0.68,介电损耗tan δ=1.65%,相对介电常数εr=2 650,居里温度TC=283 ℃。测试压电陶瓷电致应变性能,在3 kV/mm下单极电致应变达到0.20%,显示出其大应变材料的特征。结果表明,Sm掺杂PMN-PZT压电陶瓷具有优异的综合电学性能,有望在换能器、传感器以及致动器等领域广泛应用。  相似文献   

20.
采用固相合成法制备了Ba1-3x/2Lax(Mg1/3Ta2/3陶瓷,研究了La掺杂对钽镁酸钡的结构和微波介电性能的影响.结果表明:A位取代能改进其烧结性能.在x≤0.02时,烧结样品为单相的钙钛矿结构,B位离子1:2有序;当x>0.02时出现第二相Ba0.5TaO3.B位离子有序度随着x的增大先增加后减小,在x=0.04时出现最大值.x≤0.02时介电常数变化较小,而后其值逐渐增大.品质因数与谐振频率的乘积(Q×f)值随着x的增大先增大后减小,在x=0.02时取得最大值;谐振频率温度系数(τf)值随着x增大而增大.  相似文献   

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