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1.
聚苯醚与含有机硅嵌段共聚物共混的研究   总被引:1,自引:0,他引:1  
利用差热扫描量热计(DSC)、动态粘弹谱仪(DDV)和力学性能测试等手段研究了PPO/PHS-PDMS、PPO/PPO-PHS-PDMS和PPO/PS/PPO-PHS-PDMS3个共混体系的形态结构和性能。结果表明,PPO/PHS-PDMS为一相容体系。当PPO分子量与PPO-PHS-PDMS中PPO分子量相同时,PPO/PPO-PHS-PDMS与PPO/PS/PPO-PHS-PDMS是两个相容体  相似文献   

2.
本文对B位二元复合钙钛矿型复合氧化物LaMyM1-y’O3(M、M’=Mn、Fe、Co;y=0.0~1.0)的结构和红外光谱进行了研究.B位元素复合对B-O键强度有较大影响,B位离子之间的相互作用及BO6八面体畸变所导致的晶体结构的改变在红外光谱上有明显的反映,晶体结构的改变和红外光谱的变化有一定的对应关系.在Fe-Mn和Fe-Co体系中,几何因素对B-O键伸缩振动频率的变化起主导作用,在Mn-CO体系中电子因素起主导作用.  相似文献   

3.
利用DSC和DMA研究了一种新的含有机硅三元多嵌段共聚物PPO-PDMS-PHS与均聚物PPO共混体系的相容性,结果表明,均聚物PPO与PPO-PDMS-PHS中的两种嵌段(PPO和PHS)有相容性,两种嵌段协同作用的结果提高了共混相容性的临界值,当均聚物PPO的Mn为20000时,PPO嵌段的Mn为20000,PHS嵌段的Mn为5160时,PPO-PDMS-PHS/PPO共混物为一相容体系。  相似文献   

4.
钙钛矿型复合氧化物LaMyM‘1—yO3的结构与红外光谱研究   总被引:9,自引:2,他引:7  
本对B位二元复合钙钛矿型复合氧化物LaMyM'1-yO3(M、M'=Mn、Fe、Co;y=0.0·1.0)的结构和红外光谱进行了研究。B位元素复合对B-O键强度有较大影响,B位离子之间的相互作用及BO6八面体畸变所导致的晶体结构的改变在红外光谱上有明显的反映,晶体结构的改变和红外光谱的变化有一定的对应关系。在Fe-Mn和Fe-Co体系中,几何因素对B-O键伸缩振动频率的变化起主导作用,在Mn-C  相似文献   

5.
导了一种新的共混增容体系,以均聚物PPO作为不相容共混体系PPO-PDMS-PHS/PS的增容剂。DSC和DMA的研究结果表明,PPO对PPO-PDMS-PHS/PS共混体系确有增容作用,PPO的含量在13.5%以下时,PS、PPO和PPO-PDMS-PHS中的硬段相容为一相;PPO的含量在23.8%以上时,PPO分布在PS相和PPO-PDMS-PHS中的硬段相中,经PPO增容后,材料的拉伸性能明显提高。  相似文献   

6.
利用DSC和DMA研究了一种新的含有机硅三元多嵌段共聚物(PPO-PDMS-PHS)n与均聚物PPO共混体系的相容性,结果表明,均聚物PPO与(PPO-PDMS-PHS)n中的两种嵌段(PPO和PHS)有相容性,两种嵌段协和的结果提高了共混相容性的临界值,当均聚物PPO的Mn为20000时,PPO嵌段的Mn为20000,PHS嵌段的M国5160时(PO-PDMS-PHS)n共混物的一相容体系。  相似文献   

7.
PPO作为[PPO—PDMS—PHS]n/PS增容剂的研究   总被引:2,自引:0,他引:2  
报导了一种新的共混增容体系,以均聚物PPO作为相容共混体系「PPO-PDMS-PHS」m/PS的增容剂,DSC和DMA的研究结果表明,PPO对「PPO-PDMS-PHS」n/PS共混体系确有增容作用,PPO的含量在13.5%以下时,PS,PPPO「PPO-PDMS-PHS」n中的硬段相容为一相;  相似文献   

8.
应用量子化学研究Ca2Fe2—xAl2O5的水化活性   总被引:4,自引:0,他引:4  
用量子化学SCC-DV-Xα方法分析了Ca2Fe2-xAlxO5体系听a2Fe2O5,Ca2F31.43Al0.57O5和Ca2F31.28Al0.72O5,认为它们的水化活性随Al的增加而提高的原因是:(1)Al的净电荷比Fe高,易吸收水分子的弧对电子;(2)Al-O键比Fe-O键弱,易断裂而容易与水反应。  相似文献   

9.
采用示差扫描量热法研究了相同硬段及含量的3种不同类型软段的聚氨酯与聚氯乙烯(PVC)、氯化聚氯乙烯(CPVC)的相容性。结果表明,多嵌段聚氨酯与PVC、CPVC的相容性次序为:PCL-PUPTMO-PU>PPO-PU,而PVC和CPVC在共混体系中具有相似的相容行为  相似文献   

10.
多嵌段聚氨酯与PVC与CPVD共混体系相容性的研究   总被引:1,自引:0,他引:1  
采用示差扫描量热法研究了相同硬段及含量的3种不同类型软段的聚氨酯与聚氯乙烯(PVC)、氯化聚氯乙烯(CPVC)的相容性。结果表明,多嵌段聚氨酯与PVC、CPVC的相容性次序为:PCL-PU〉〉PTMO-PU〉PPO-PU,而PVC和CPVC在共混体系中具有相似的相容行为。  相似文献   

11.
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method.  相似文献   

12.
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.……  相似文献   

13.
14.
We associate a variety of innovations with the term "Industry 4.0". The pioneer of many 4.0 modifications forms the basisfor the trend towards the integrated di...  相似文献   

15.
A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa.  相似文献   

16.
On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.……  相似文献   

17.
Zusammenfassung Bei der Gestaltung von Ernteprozessen — beispielsweise des Prozesses Mähdrusch, Körnertransport und -abnahme — als transportverbundene Fließarbeitsverfahren mit mindestens zwei verschiedenen Arbeitsmitteln gibt es einen großen Optimierungsspielraum. Solche Prozesse sind mehrstufige Bedienungsprozesse mit gemischter Anordnung der Bedienungseinrichtungen. Außerdem besitzen sie stark ausgeprägte räumliche Aspekte. Es wird vor allem gezeigt, welche Merkmale solcher Prozesse in Simulationsmodellen abgebildet sein müssen, welche Zielgrößen in Abhängigkeit von welchen Einflußgrößen unter Berücksichtigung welcher Prozeßbedingungen ermittelt werden sollten und wie der Bewertungsprozeß zur Ermittlung der gewünschten Informationen gestaltet werden muß.  相似文献   

18.
ABSTRACT

The production of ferrous metal increased during the Roman Late Republican period, Principate and Empire. The direct bloomery process was used to extract the metal from its ores using slag-tapping and slag-pit furnaces. The fuel was charcoal and an air blast was introduced by bellows-operated tuyères. Iron formed as a bloom, often as a spongy mass of metal, which contained impurities from the smelting process, including unreacted ore, fuel, slag and fragments from the furnace walls, while the metal was often inhomogeneous with varied carbon contents. Blooms were either smithed directly into bars or ingots or they were broken up, which also allowed the removal of gross impurities and a selection of pieces with similar properties to be made. These could then be forge-welded together and formed into characteristically shaped ingots. Making steel in the furnace seems to have been achieved: it depended on the ore and the furnace and conditions within it. Surface carburization was also carried out. Iron and steel were used extensively in construction and for tools and weapons. Fire welding was often used to add pieces of steel to make the edges of tools and weapons, which could be heat-treated by quenching to harden them.  相似文献   

19.
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill.  相似文献   

20.
正Responding to ISO’s appeal for survey for the to-be-developed ISO Strategy Plan for 2016-2020,SAC hosted a special workshop over the needs and comments of various fi elds on June 8 in Beijing.The workshop was attended by ISO President-elect and Ansteel General Manager Zhang Xiaogang,SAC Vice-Administrator Yu Xinli,and 30 experts from  相似文献   

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