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电脉冲对不锈钢形变马氏体及其耐蚀性的影响 总被引:2,自引:0,他引:2
亚稳奥氏体不锈钢冷变形后产生形变诱发马氏体,影响其物理和化学性能.对打磨后的亚稳奥氏体不锈钢进行了阳极60s~280s 阴极30s~280s,9h电脉冲处理,用X射线衍射分析、显微硬度测量、自腐蚀电位测量和金相分析等方法分析处理前后的马氏体含量、表面硬度、耐腐蚀性.结果表明处理后表面马氏体均减少.随脉冲宽度的不同。电脉冲处理可以诱发电化学退火,也可以导致马氏体优先腐蚀,当发生电化学诱导退火时,不锈钢不仅在马氏体减少后仍可以保持高硬度,而且在含Cl^-介质中的耐蚀性也提高。 相似文献
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《材料热处理学报》2015,(Z1)
通过金相、SEM和TEM观察,表面粗糙度测试和电化学实验方法,对经过不同温度淬火和回火的国产Cr13型马氏体不锈钢的微观组织演变及其对材料硬度,表面光洁度和耐蚀性能的影响进行了分析研究。结果表明,马氏体是基体中的主要相,当回火温度为650℃时,铁素体变成基体中的主要相,随着回火温度的提高,不锈钢基体组织发生了由回火马氏体到回火索氏体的演变。回火后,材料的硬度降低,当回火温度达到650℃,材料硬度降至22 HRC,其表面光洁度大幅度降低。同时,回火材料的耐点蚀性能低于淬火态材料,且随着回火温度的提高,马氏体不锈钢的点蚀电位降低,并在500℃时达到最差。 相似文献
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热处理对含钼2Cr13马氏体不锈钢组织与性能的影响 总被引:1,自引:1,他引:1
对在2Cr13马氏体不锈钢中添加Mo的钢进行不同温度热处理工艺试验,研究了热处理温度对含钼2Cr13不锈钢组织、硬度与耐蚀性能的影响。结果表明,含钼2Cr13马氏体不锈钢在1080℃淬火后的硬度最高,当在400~550℃回火时,硬度值存在一个明显的上升区域,这是由于析出的合金碳化物弥散强化作用,使合金出现二次硬化现象。回火后含钼2Cr13不锈钢的耐蚀性能比2Cr13不锈钢明显提高,主要是由于含钼2Cr13不锈钢淬、回火后析出相M2X抑制了M23C6相的产生。 相似文献
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通过真空电弧熔炼方法制备了Fe-13Cr-3.5Ni不锈钢,并系统研究了不同热处理工艺对其微观组织以及硬度的影响。结果表明:熔炼态Fe-13Cr-3.5Ni不锈钢为典型的板条状马氏体组织;经过不同温度固溶和回火处理(600 ℃)后,其组织结构由板条状马氏体和少量残留奥氏体组成,残留奥氏体含量随着固溶温度的升高先增加后减少,而硬度值先降低后升高,硬度最低值为101.5 HRB;在1000 ℃淬火并在不同温度回火后其组织结构由回火板条状马氏体以及残留奥氏体组成,在650 ℃以下回火时,随着回火温度的升高奥氏体含量逐渐增多,当回火温度达700 ℃时,残留奥氏体含量下降,其洛氏硬度值随着回火温度的升高先降低后升高,其硬度值在99~107 HRB范围内。 相似文献
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In this study, the effects of tempering temperature on the microstructure, hardness, antibacterial performance and corrosion resistance of Cu-bearing 5Cr15MoV martensitic stainless steel (5Cr15MoV-Cu MSS) were investigated using an optical microscope, a scanning electron microscope, X-ray diffraction, a transmission electron microscope, an antibacterial test, electrochemical measurements, and the salt spray test. The results showed that the hardness curve had a saddle shape and its values reached the peak value after tempering at 500°C, due to the secondary hardening effect by the precipitation of tiny secondary carbides and Cu-rich precipitates. In addition, the antibacterial results also showed excellent antibacterial performance against Escherichia coli at 500°C because of the formation of Cu-rich precipitates. Results of corrosion tests indicated that the corrosion resistance decreased gradually with an increase of the tempering temperature. In particular, the passivation did not occur when the tempering temperature was above 500°C, which may be related to the Cu-rich precipitates and Cr depletion. 相似文献
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ABSTRACTTo investigate the influence of nitrogen on structure and corrosion resistance of Cr15 super martensitic stainless steels (SMSS), two types (N-free and N-0.12%) of specimens were quenched at 1050°C and tempered at different temperatures, and then, optical microscope, transmission electron microscopy, X-ray diffraction, potentiodynamic polarisation, immersion experiments and Kelvin Probe Force Microscope were used to characterize its microstructures and corrosion properties. The experimental results show that the microstructure in the N-free Cr15 super martensitic stainless steel is a biphasic tissue with alternating martensite and austenite distribution while quenched at 1050°C and tempered between 600 and 700°C. The nitrogen addition increases the content of austenite, and changes the austenite morphology significantly into the coarse block and strip distribution. What’s more, micro-galvanic corrosion is formed between austenite and martensite, which deteriorates the corrosion resistance of the SMSS. 相似文献
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焊接及热处理工艺对0Cr18Ni9Ti不锈钢耐蚀性的影响 总被引:4,自引:1,他引:3
通过草酸电解结合组织观察、动电位扫描法和交流阻抗测试研究了直流焊、脉冲焊和固溶处理、稳定化处理对0Cr18Ni9Ti不锈钢的抗晶间腐蚀性和耐点蚀性的影响.结果表明,脉冲焊比直流焊对晶间腐蚀的不利影响更大;固溶处理可以明显改善焊后材料的耐晶间腐蚀以及耐点蚀性,并增大钝化膜的稳定性. 相似文献