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针对燃煤过程排放的CO2的捕集问题,以N-甲基咪唑为主要原料,合成了含—NH2官能团的离子液体1-(1-氨基丙基)-3-甲基咪唑溴盐(即[NH2p-mim] Br),在常温常压下考察了其对CO2的吸收性能和再生后对CO2的吸收负荷,并对[NH2p-mim]Br和[bmim]Br进行了比较实验,研究了哌嗪的加入对[NH2p-mim]Br吸收CO2的影响.结果表明:胺基的引入增加了对CO2的吸收负荷,且合成的离子液体经再生后,仍具有较高的CO2吸收负荷;哌嗪可促进[NH2p-mim]Br吸收CO2的反应;[NH2p-mim]Br对CO2的吸收负荷远大于[bmim]Br,这可能是因为-NH2官能团的存在实现了[NH2p-mim]Br对CO2物理吸收和化学吸收的并存. 相似文献
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针对燃煤过程排放的CO2的捕集问题,以N-甲基咪唑为主要原料,合成了含—NH2官能团的离子液体1-(1-氨基丙基)-3-甲基咪唑溴盐(即[NH2p-mim]Br),在常温常压下考察了其对CO2的吸收性能和再生后对CO2的吸收负荷,并对[NH2p-mim]Br和[bmim]Br进行了比较实验,研究了哌嗪的加入对[NH2p-mim]Br吸收CO2的影响.结果表明:胺基的引入增加了对CO2的吸收负荷,且合成的离子液体经再生后,仍具有较高的CO2吸收负荷;哌嗪可促进[NH2p-mim]Br吸收CO2的反应;[NH2p-mim]Br对CO2的吸收负荷远大于[bmim]Br,这可能是因为—NH2官能团的存在实现了[NH2p-mim]Br对CO2物理吸收和化学吸收的并存. 相似文献
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CO2制冷系统的技术进展 总被引:2,自引:0,他引:2
CO2作为制冷工质在环保、安全性及容积制冷量等方面具有明显的优势,是一种比较理想的环保制冷剂.介绍了CO2用作制冷工质的发展历史和作为制冷剂的相关热物理特性以及3种CO2制冷循环的过程及其特点;提出了带回热器、膨胀机代替节流阀等几种可以提高CO2制冷效率的有效途径. 相似文献
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《动力工程学报》2017,(9)
以0.5%PdZrO_2/γ-Al_2O_3为催化剂,在所搭建的比例积分微分控制(PID)多功能实验装置上进行CO催化燃烧基础特性实验,分析了H_2O对CO转化率的影响,以及H_2O体积分数的变化对CO转化率和CO催化燃烧反应时间的影响.结果表明:H_2O的加入大幅提升了CO在催化剂上的起燃温度和燃尽温度,增大了CO催化燃烧反应所需的活化能,且随着H_2O体积分数的增大,CO起燃温度和燃尽温度逐步升高;CO转化率随H_2O体积分数的增加逐渐降低;CO反应稳定所需时间随H_2O体积分数的增大而增加;H_2O的存在降低了催化剂的活性,抑制了催化燃烧的进行. 相似文献
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IGCC系统控制CO_2排放的研究进展 总被引:1,自引:1,他引:0
整体煤气化联合循环(IGCC)作为一种被验证的具有发展前景的洁净煤发电技术,如何实现IGCC中CO2的零排放,已经成为国内外学者研究的热点。概述了目前国内外控制IGCC系统中CO2排放的研究进展,归纳总结了IGCC系统中CO2分离和回收的四类途径:燃烧后分离与回收、燃烧前对燃料气进行处理与分离、以IGCC为基础的煤基动力化工多联产系统以及燃烧与CO2分离一体化途径。并引入控制CO2排放科技创新一体化理论,指出未来控制CO2排放的方向。 相似文献
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TiO_2/SiO_2双层减反膜在太阳电池上的应用 总被引:2,自引:0,他引:2
利用二氧化硅(SiO_2)对太阳电池表面的钝化作用,对传统的二氧化钛(TiO_2)单层减反膜进行了改良.基于理论模拟分析了光反射率随膜层(TiO_2/SiO_2)厚度变化规律,结合实验上SiO_2最佳厚度经验值,制备了晶体硅太阳电池(即TiO_2/SiO_2/Si),并和SiN_x/Si结构的晶体硅太阳电池相比较.分别测试了少子寿命、反射率、电性能参数等,结果表明这种改良后的TiO_2减反膜也可以取得很好的减反效果和钝化效果.镀有TiO_2,SiO_2双层膜与SiN_x减反膜绒面晶体硅片的积分反射率分别为4.9%和3.9%;使用以上两种不同减反膜制备的太阳电池的开路电压均可达到0.62V.可见这种TiO_2双层膜有望在将来的生产中得到具体应用. 相似文献
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在管式炉上进行徐州烟煤的燃烧试验,采用电感耦合等离子体光谱质谱联用仪(ICP-MS)对燃烧剩余灰渣进行测定.研究了不同温度和不同燃烧气氛(空气气氛和O2/CO2气氛)下痕量元素的迁移特性.结果表明,煤燃烧过程中,痕量元素Cr、Mn、Ni、Zn、Cd、Pb在灰渣中富集,As挥发率达70%以上.随着温度的升高,大部分痕量元素在灰渣中的含量降低,Mn、Ni、Cr在灰渣中的含量相对比较稳定.O2/CO2气氛下,各元素随温度的变化趋势并未受到影响,但整体上O2/CO2气氛下各痕量元素在灰渣中的含量要大于空气气氛下的,随着温度的升高,O2/CO2气氛和空气气氛下痕量元素在灰渣中的含量越来越接近,说明燃烧气氛对痕量元素迁移的影响随温度升高而减弱. 相似文献
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Zhe Kong Jun Zhang Hongbo Wang Bo Cui Jinghui Zeng Xuan Chen Penghui Tian Guozhou Huang Junhua Xi Zhenguo Ji 《国际能源研究杂志》2020,44(2):1205-1217
Although the traditional metal oxide catalyst has high activity and strong degradation ability, the forbidden bandgap is generally larger, and the utilization rate of sunlight is much low. Moreover, the high internal resistance inhibits carrier transfer, so the photoelectrochemical performance needs to be improved. Selenides with narrow bandgap and low internal resistance are promising candidates for photocatalysts. A new type of 1D/2D selenide heterojunction was constructed by compositing MoSe2 and FeSe2, two kinds of narrow bandgap metal selenides. In this 1D/2D heterojunction, MoSe2 presents a three-dimensional network structure, which can effectively collect and transport optical carriers, and it is an ideal heterostructure as a substrate loaded with 1D FeSe2 nanorods. Moreover, this heterojunction has good light absorption characteristics and can achieve full spectrum absorption of ultraviolet and visible light. This FeSe2/MoSe2 composite has photocatalytic performance more than 3.4 times that of MoSe2, and its photoelectrochemical performance is more than 2 times. The experimental results show that FeSe2/MoSe2 is an ideal composite system with great potential in photocatalysis. 相似文献
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采用溶胶—凝胶法制备Ce掺杂TiO2光催化剂,借助XRD、HRTEM对其进行表征,分析了Ce含量、煅烧温度等因素对光催化降解偶氮废水活性的影响。结果表明,铈掺杂在提高了TiO2光催化剂催化活性的同时也抑制了相转变。当Ce的掺杂量为3%时,对偶氮废水的处理率可高达92.3%。 相似文献
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Mutual diffusion coefficients of hydrogen gas (H2) into air and its component gases (N2 and O2) have been measured in the temperature range of 30 to 180°C and at atmospheric pressure via the Taylor dispersion method. For a H2–N2 system, the composition dependence of the mutual diffusion coefficient has been studied with both H2 and N2 as the carrier gas. The mutual diffusion coefficients for the H2–air and H2–N2 systems are almost the same and smaller than that for the H2–O2 system by about 5%. The present data for the H2–N2 system, corrected to an equimolar composition, agree well with the accurate data reported by the groups of P. J. Dunlop and of R. J. J. Van Heijningen. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(3): 182–193, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10025 相似文献
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Md. Ashraful Islam Molla Mai Furukawa Ikki Tateishi Hideyuki Katsumata Satoshi Kaneco 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2018,40(20):2432-2441
The photocatalytic decomposition of Probenazole in water using TiO2/H2O2 under sunlight illumination is studied. The addition of H2O2 is effective for the improvement of photocatalytic decomposition of Probenazole with TiO2. Furthermore, the operating conditions, such as photocatalyst dosage, temperature, pH, sunlight intensity and illumination time are also optimized. The kinetics of photocatalytic decomposition follow a pseudo–first–order kinetic law, and the rate constant is 0.129 min?1. The activation energy (Ea) is 11.34 kJ/mol. The photocatalytic decomposition mechanism is discussed on the basis of molecular orbital (MO) simulation for frontier electron density. 相似文献
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