STM tunneling spectroscopy on high Tc superconductors

STM tunneling spectroscopy has been performed on the bulk single crystals of BiSrCaCuO (BSCCO) and the epitaxial thin films of YBaCuO (YBCO) at cryogenic temperatures. The STM images and tunneling spectra observed on the (001) surfaces can be classified into three cases; 1) Atomic image is visible. However, the tunneling spectrum shows semiconducting or smeared superconducting gap structures, depending on the tip-sample distance. 2) Clear atomic image can not be obtained. But, the tunneling spectrum shows flat bottom region with quite low zero bias conductance. 3) Tunneling spectra demonstrate gapless behavior, independent of the tip-sample separation. These observations support the quasi-2D electronic picture in whichs-wave like 2D superconducting layers are coupled with each other through the Josephson effect.     

Andreev Bound States and Josephson Coupling in YBa2Cu3O7−δ/Pb tunnel junctions

We have made in-situ [103] and [110]YBCO/Pb junctions, which display an hysteretic behaviour with both a well-defined Quasi-Particule branch and a Josephson current. A zero energy conductance peak is observed in the tunneling conductance — which is a signature of Andreev Bound States (ABS) at a surface of a d-wave superconductor — which splits at low temperature. This may confirm the existence of a surface state which breaks time-reversal symmetry. However, up to now, we have not seen any evidence of a coupling between Josephson current and the zero-energy ABS, predicted by Y. Tanaka and S. Kashiwaya ¹ .     

Charge-carrier injection into pentacene thin film formed on Si(111) probed by STM spectroscopy

The injection of charge carriers into a pentacene thin film formed on a Si substrate was investigated by scanning tunneling microscopy (STM). Tip height versus bias voltage (z-V) spectroscopy reveals the characteristic charge transport properties of the molecular film, i.e., the conductivity and the threshold energy of charge injection. The abrupt descent of the tip into the film owing to the transition of film conductance, which depends on the degree of charge carrier injection, was observed for crystallized pentacene thin films. The lower film conductance at around zero bias voltage is still higher than that of a vacuum. This indicates that the carrier injection barrier between the pentacene and the semiconducting substrate is extremely low. The convergence of the carrier injection endpoints into a narrow range of electric-field intensity implies that the main factor contributing to barrier formation and collapse is not the bias voltage but the electric field.     

Characterization and tunneling conductance spectra of N,N′-bis (9H-fluoren-9-ylidene)benzene-1,4-diamine thin films on graphite

N,N′-bis(9H-fluoren-9-ylidene)benzene-1,4-diamine was synthesized via the acetic acid-assisted Schiff base reaction between 9-fluorenone and p-phenylenediamine. The thin films were deposited from solution and characterized by contact angle measurements (CAM), X-ray photoelectron spectroscopy (XPS) and tunneling conductance spectroscopy (TCS). The tunneling conductance spectra, related to the potential and distance between the tip and substrate, were acquired at different tip–substrate separations and depicted significant trend under the action of electric field. Systematic analysis shows more information about electron transport through medium layers. The electric field plays an important role in tunneling conductance spectra. The tunneling conductance spectra data indicate the electric field dependence of electron transport.     

Macroscopic Quantum Phenomena in High Critical Temperature Superconducting Josephson Junctions

YBa₂Cu₃O_7?δ grain boundary bi-epitaxial Josepshon junctions (JJs) allow a very clear demonstration of Josephson current variation with the misorientation angle, consistent with the d-wave symmetry of the superconducting order parameter in cuprate, high temperature superconductors. Our bi-epitaxial junctions show a strong suppression of the first harmonic, I ₁ sin ø, of the current phase relation when tunneling from a lobe into a node of the superconducting gap function. In these configurations, the contribution of the second harmonic, I ₂ sin 2ø, becomes of the same magnitude as the first one, giving rise to a characteristic two-well Josephson potential as a function of phase ø instead of the usual single well. This characteristic intrinsic property has suggested proposals of a new class of qu-bit named “quiet” because of the existence a spontaneously degenerate fundamental state without the need of applying an external field. Our experiments probe the macroscopic quantum properties in a d-wave Josephson junction by measuring macroscopic quantum tunneling and energy level quantization. The switching current out of the zero voltage state is measured as a function of temperature down to 20 mK. The temperature variation of the width of an ensemble of switching events goes over from one, which is characteristic of a thermal activation of phase fluctuations to a temperature independent width which is a token of quantum tunneling of the phase. The transition regime is affected by the two-well potential in a 45^° misorientation junction as the second harmonic term gives rise to additional thermal transitions. The difference between quantized energy levels in the harmonic potential was determined by microwave spectroscopy. From the broadening of energy levels, it was possible to extract a Q-value of about 40 for the phase oscillations. The relatively high Q indicates quantum coherence over a sizeable time in d-wave junctions and gives hopes for a realization of a “quiet” high-T _c qu-bit. The contributions of V. L. Ginzburg to several different fields of physics are impressive and long standing. In superconductivity the Ginzburg–Landau theory, for instance, still represents a very powerful approach to model a huge number of different physical systems. High Temperature Superconductors (HTS) have strongly influenced research of the last 20 years and their d-wave order parameter symmetry represents one of the most intriguing features from both the fundamental point of view and some types of innovative long-term applications.     

Ballistic transport and electrostatics in metallic carbon nanotubes

We calculate the current and electrostatic potential drop in metallic carbon nanotube wires self-consistently by solving the Green's function and electrostatics equations in the ballistic case. About one-tenth of the applied voltage drops across the bulk of a nanowire, independent of the lengths considered here. The remaining nine-tenths of the bias drops near the contacts, thereby creating a nonlinear potential drop. The scaling of the electric field at the center of the nanotube with length (L) is faster than 1/L (roughly 1/L/sup 1.25-1.75/). At room temperature, the low bias conductance of larger-diameter nanotubes is larger than 4e/sup 2//h due to occupation of noncrossing subbands. The physics of conductance evolution with bias due to Zener tunneling in noncrossing subbands is discussed.     

Charge Transport in Unconventional Superconductor Junctions

We report two remarkable recent topics about zero-bias conductance peak (ZBCP) in normal-metal/unconventional superconductor junctions. We show that the roughness at a surface of superconductors strongly suppresses the ZBCP when the transparency of the interface is sufficiently low. In a numerical simulation at a zero-magnetic field, we confirm the split of the ZBCP owing to the interfacial roughness in realistic band structures of the high-T _c superconductors. We also study the influence of a magnetic field H on the zero bias conductance peak (ZBCP). For p-wave junctions, ZBCP does not split into two by H even for sufficiently low transparent junctions, where ZBCP clearly splits for d-wave. This unique property originates from the fact that for p-wave superconductors, perpendicularly injected quasiparticle form ZES, which contributes most dominantly on the tunneling conductance. We propose that tunneling spectroscopy in the presence of magnetic field, i.e., magnetotunneling, is a promising method to determine the pairing symmetry of unconventional superconductors.     

Low Temperature Scanning Tunneling Spectroscopy Studies of High J c NdBa2Cu3O7 − δ Single Crystals

We report low temperature scanning tunneling spectroscopy (STS) studies on NdBa₂Cu₃O_{7 ? δ} (Nd123) single crystals. Two characteristic spectra with a nearly ohmic background spectrum and a V-shaped background are observed on the cleaved surfaces. The former spectum shows an inhomogeneous distribution of a superconducting energy gap (2Δ) for STS differential conductance map. The latter shows a homogeneous distribution. It is probable that those differences are attributed to a tunneling current from different surface layers. The temperature dependence of tunneling conductance spectrum with a V-shaped background reveals that the superconducting gap disappears around T _c, and no pseudogap behavior exists above T _c.     

Electronics and chemistry: varying single-molecule junction conductance using chemical substituents

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling or superexchange, with the molecular junction conductance depending on the alignment of the metal Fermi level to the closest molecular level. Electron-donating substituents, which drive the occupied molecular orbitals up, increase the junction conductance, while electron-withdrawing substituents have the opposite effect. Thus for the measured series, conductance varies inversely with the calculated ionization potential of the molecules. These results reveal that the occupied states are closest to the gold Fermi energy, indicating that the tunneling transport through these molecules is analogous to hole tunneling through an insulating film.     

A Self-consistent Calculation and an Anisotropic Wavelength Cutoff Energy of Spin-wave Spectrum in Magnetic Tunnel Junctions

Temperature dependence of tunnel magnetoresistance (TMR) ratio, resistance, and coercivity from 4.2 K to room temperature (RT), applied de bias voltage dependence of the TMR ratio and resistances at 4.2 K and RT, tunnel current I and dynamic conductance dI/dV as functions of the de bias voltage at 4.2 K, and inelastic electron tunneling (IET) spectroscopy, d(2)I/dV(2) versus V, at 4.2 K for a tunnel junction of Ta(5 nm)/Ni79Fe21(25 nm)/Ir22Mn78(12 nm)/Co75Fe25(4 nm)/Al(0.8 nm)-oxide/Co75Fe25(4 nm)/Ni79Fe21(25 nm)/Ta(5 nm) were systematically investigated. High TMR ratio of 59.2% at 4.2 K and 41.3% at RT were observed for this junction after annealing at 275℃ for an hour. The temperature dependence of TMR ratio and resistances from 4.2 to 300 K at 1.0 mV bias and the de bias voltage dependence of TMR ratio at 4.2 K from 0 to 80 mV can be evaluated by a comparison of self-consistent calculations with the experimental data based on the magnon-assisted inelastic excitation model and theory. An anisotropic wavelength cutoff energy of spin-wave spectrum in magnetic tunnel junctions (MTJs) was suggested, which is necessary for self-consistent calculations, based on a series of IET spectra observed in the MTJs.     

Observation of current reversal in the scanning tunneling spectra of fullerene-like WS2 nanoparticles

Current-voltage characteristics measured using STM on fullerene-like WS2 nanoparticles show zero-bias current and contain segments in which the tunneling current flows opposite to the applied bias voltage. In addition, negative differential conductance peaks emerge in these reversed current segments, and the characteristics are hysteretic with respect to the change in the voltage sweep direction. Such unusual features resemble those appearing in cyclic voltammograms, but are uniquely observed here in tunneling spectra measured in vacuum, as well as in ambient and dry atmosphere conditions. This behavior is attributed to tunneling-driven electrochemical processes.     

Tunneling Conductance Dependence of the Tunneling Spectra in Bi2Sr2CaCu2O8

We have measured the tunneling spectra in Bi₂Sr₂CaCu₂O₈ with a scanning tunneling microscope(STM) at various tip-sample distances by changing the tunneling conductance in a controlled manner. When the tunneling conductance is increased from 1×10^–9 to 1×10^–5 S, the spectra do not show changes in particular. However, the gap value decreases steeply and the asymmetric back ground density of states turns inverted V-shaped one above 6×10^–4 S. The changes in the tunneling spectra at the high tunneling conductances are explained by the enhancement of the local carrier density induced by the pressure that the STM tip applied to the sample.     

Superconductivity Within the Pair-Tunneling Model Close to the Metal-Insulator Transition

We have considered the problem of s-wave and d-wave superconductivity in the two-layer Hubbard model close to the metal-insulator transition. To mimic the formation of the insulating gap, the Coulomb correlations have been taken into account within the Hubbard I approximation. The interlayer momentum-conserving Josephson tunneling between the layers has been included on the mean-field level. We demonstrate that the interlayer tunneling may contribute to the occurrence of mixed d + s wave symmetry of the superconducting state with a dominating d-wave component at a low concentration of holes. The problem of the validity of the pair-tunneling model is also briefly discussed.     

Co-tunneling enhancement of the electrical response of nanoparticle networks

A co-tunneling charge-transfer process dominates the electrical properties of a nanometer-sized "slice" in a nanoparticle network, which results in universal scaling of the conductance with temperature and bias voltage, as well as enhanced spintronics properties. By designing two large (10 μm) electrodes with short (60 nm) separation, access is obtained to transport dominated by charge transfer involving "nanoslices" made of three nanoparticles only. Magnetic iron oxide nanoparticle networks exhibit a magnetoresistance ratio that is not reachable by tunneling or hopping processes, thereby illustrating how such a size-matched planar device with dominant co-tunneling charge-transfer process is optimal for realizing multifunctional devices with enhanced change of conductance under external stimulus.     

Low-temperature electronic transport in single K(0.27)MnO(2)·0.5H(2)O nanowires: enhanced electron-electron interaction

The current-voltage (I-V) characteristics and electrical resistivity of isolated potassium manganese oxide (K(0.27)MnO(2)·0.5H(2)O) nanowires prepared by a simple hydrothermal method were investigated over a wide temperature range from 300 to 4?K. With lowering temperature, a transition from linear to nonlinear I-V curves was observed around 50?K, and a clear zero bias anomaly (i.e., Coulomb gap-like structure) appeared on the differential conductance (dI/dV) curves, possibly due to enhanced electron-electron interaction at low temperatures. The temperature dependence of resistivity, [Formula: see text], follows the Efros-Shklovskii (ES) law, as expected in the presence of a Coulomb gap. Here we note that both the ES law and Coulomb blockade can in principle lead to a reduced zero bias conductance at low temperatures; in this study we cannot exclude the possibility of Coulomb-blockade transport in the measured nanowires, especially in the low-temperature range. It is still an open question how to pin down the origin of the observed reduction to a Coulomb gap (ES law) or Coulomb blockade.     

Andreev Bound-State Tunneling and ESR Spectroscopy of High-Temperature Superconductors and Observations of Broken Time-Reversal Symmetry

An emphasis on reliable materials growth and development of new fabrication techniques has allowed us to investigate the electronic structure of high-temperature superconductors by planar quasiparticle tunneling and electron paramagnetic resonance (EPR) spectroscopies. The quasiparticle (QP) density of states (DoS) is investigated by tunneling into oriented thin films of Y₁Ba₂Cu₃O₇ (YBCO) and single crystals of Ba₂Sr₂Ca₁Cu₂O₈ (BSCCO). Data are obtained as a function of crystallographic orientation, temperature, doping, damage, and applied magnetic field. These data demonstrate that the observed zero-bias conductance peak (ZBCP) is composed of Andreev bound states (ABS) which intrinsically form at a symmetry-breaking interface of an unconventional superconductor, for example, a (110)-surface of d-wave YBCO. Tunneling into doped or ion-damaged YBCO provides a measure of the QP scattering rate below T _c. An applied field causes Doppler shift of the ABS, arising from the scalar product between the QP velocity and the superfluid momentum, v _F·P _s, observed as a splitting in the ZBCP. Magnetic hysteresis of the splitting is consistent with the effects of strong vortex pinning near the interface. The directional field dependence shows that the ABS is highly anisotropic in its transport. These results, plus in-plane crystallographic orientational dependence on single-crystal BSCCO, demonstrate the d-wave symmetry of this superconductor. Below 8 K and in zero applied field, the ZBCP splits, indicating a transition into a superconducting state with spontaneously broken time-reversal symmetry (BTRS). EPR experiments are used to detect directly the spontaneous formation of the magnetic moments in the BTRS state.     

Spin-Resolved STM for a Kondo Impurity

We investigate the bias dependence of the tunneling conductance between a spin-polarized (SP) tip of a scanning tunneling microscope (STM) and a metallic surface with a magnetic impurity. The Fano–Kondo interference between the conduction channels tip-host and tip-impurity is considered. We pay particular attention to the interplay between the lateral tip-impurity distance R and the ferromagnetism of the tip. We observe a strong dependence of the conductance with respect to both R and the tip magnetization degree. In particular, for small values of R, a conductance plateau around the Fermi energy is observed, due to the interplay between Kondo effect, quantum interference, and ferromagnetism of the tip. For full polarized tip, we find a shift of the Fano–Kondo profile toward negative bias voltages.     

Tunneling Spectra for Quasi–One-Dimensional Organic Superconductors

The tunneling conductance spectra of a normal metal/insulator/quasi–one-dimensional superconductor is calculated using the Blonder-Tinkham-Klapwijk formulation. The pairing symmetry of the superconductor is assumed to be p or d, and f-wave. It is found that there is a well-defined zero-bias peak in electron tunneling along the direction parallel to the chains or normal to these when the transmitted quasiparticles feel different sign of the pair potential. The actual line shape of the spectra is sensitive to the nodes of the pair potential on the Fermi surface.     

Tuning the bipolar conductance of an alkali-doped C(60) layer sandwiched between two tunneling barriers

Resonant tunneling through a C(60) monolayer doped with single Na, K, Rb, and Cs atoms was measured between the tip of a scanning tunneling microscope and a NiAl(110) substrate. By supporting the monolayer on a thin aluminum oxide film grown on the substrate, a double barrier tunnel junction is formed, consisting of the vacuum and oxide. This geometry enables conductance through an electronic state of the alkali-C(60) complex at both positive and negative sample bias. The positions of the conductance peaks can be varied by tuning the vacuum barrier. An opposite variation is found for Na and K as compared to Rb and Cs, suggesting the influence of bonding on nanoscale transport.