Evaluation of the mechanical properties and diffusion coefficients of osmodehydrated melon cubes

The objective of this work was to evaluate the influence of osmotic agents, their concentration and temperature, on the mass transfer kinetics and mechanical properties of osmodehydrated melon cubes. Samples were immersed in a hypertonic solution of sucrose or maltose up to 8 h under controlled temperature and agitation. Water loss, sugar gain and mechanical properties were analysed throughout the process. Mass transfer kinetics was modelled according to Peleg and Fick equations. Higher water loss, lower sugar uptake and stress at rupture values more similar to fresh fruit were observed in samples treated with maltose solutions. Peleg’s model showed the best adjustment to all the experimental data, however the k₁ and k₂ parameters did not show a clear trend with the solution concentration or temperature increase. The effective diffusivity obtained using Fick’s equation varied from 3.93 × 10^?9 to 6.45 × 10^?9m² s^?1 for water loss and from 7.57 × 10^?10 to 3.14 × 10^?9m² s^?1 for sugar gain.     

Effects of genotype and cultivation environment on lycopene content in red‐ripe tomatoes

Lycopene, a natural red pigment found in tomato, is correlated with reduced incidence of some cancers. Forty tomato varieties, including cluster F₁ hybrid tomatoes, round breeding line tomatoes (Lycopersicon esculentum Mill) and cherry tomato types (L esculentum var cerasiforme), grown under greenhouse and field conditions were evaluated for their lycopene content using high‐performance liquid chromatography (HPLC) and spectrophotometry. Lycopene content varied significantly among the tomato varieties, with cherry tomato types having the highest lycopene content. Greenhouse‐grown cluster and round tomatoes contained more lycopene (mean = 30.3 mg kg^?1) than field‐grown tomatoes (mean = 25.2 mg kg^?1), whereas cherry tomato types had a higher lycopene content in field‐grown (mean = 91.9 mg kg^?1) than in greenhouse‐grown (mean = 56.1 mg kg^?1) fruits. HPLC analysis of lycopene isomeric forms revealed a higher content of all‐trans isomers in all tomato genotypes examined. However, the cis isomeric form was exceptionally higher in the field‐ and greenhouse‐grown cherry tomato L esculentum var cerasiforme cv Gardener's Delight, which contained ～9.3 and 9.9 mg kg^?1 cis isomers respectively. Results indicate that genetics and choice of cultivation environment may have a strong influence on tomato lycopene content. Copyright © 2005 Society of Chemical Industry     

Application of inverse methods in the osmotic dehydration of acerola

This work presents a study of the mass transfer of osmotically dehydrated West Indian cherry, also known as acerola. The experiments were performed by immersing the fruits in a sucrose solution at 65ºBrix for 12 h at ambient temperature (27 °C), using three different fruit:solution ratios (1:4; 1:10 and 1:15 (w:w)). The kinetics of water loss, solids gain and weight reduction was determined. Effective mass diffusivity was calculated by the inverse method, using the Levenberg‐Marquardt minimisation algorithm. The mathematical model used to describe the physical phenomenon of osmotic dehydration was based on Fick’s Second Law, considering the fruits as geometrically perfect spheres. The influence of the fruit:solution ratio was not significant in the range of this study. Diffusivity ranged from 1.558 × 10^?10 to 1.760 × 10^?10 m² s^?1.     

Mass transfer during the osmotic dehydration of West Indian cherry

The main purpose of this work was to study water loss, solids gain, and weight and moisture reduction during the osmotic dehydration process of the West Indian cherry (Malpighia punicifolia). The diffusion coefficient of West Indian cherry was estimated by the inverse method using average moisture contents. Osmotic dehydration was examined for 12 h in a 65°Brix solution at temperature of 27 °C, without agitation, using a fruit:solution mass ratio of 1:4, 1:10, and 1:15. The kinetics and internal changes occurring during the osmotic dehydration of West Indian cherry are reported. The product’s drying kinetics was simulated using the diffusion model, and two optimization methods, Levenberg–Marquardt and Differential Evolution algorithm, were used to predict the diffusion coefficient. The results indicated that the two optimization methods performed similarly in estimating the diffusion coefficient adequately. The average calculated diffusion coefficient was 1.663 × 10^?10 m²s^?1, which is consistent with values reported in the literature.     

Mass transfer modelling in ultrasound assisted osmotic dehydration of kiwi fruit

In this study, the effect of ultrasonic pre-treatment on osmotic dehydration of kiwi slices was investigated. Kiwi fruit slices were subjected to ultrasonic pre-treatment in a sonication water bath at a frequency of 25 kHz for 20 min. Osmotic dehydration of ultrasonic pre-treated samples were conducted for a period of 300 min in 60 Brix sucrose solution. The kinetics of moisture loss and solute gain during osmotic dehydration were predicted by fitting the experimental data with Azuara's model and Weibull's model. The effects of ultrasound application on water loss, sugar gain, effective moisture diffusivity and solute diffusivity of the samples were analysed. The osmotic dehydration process showed a rapid initial water loss followed by a progressive decrease in the rates in the later stages. From the Azuara's model, the predicted equilibrium water loss value for ultrasound pre-treated sample was 58.4% (wb) at 60°C that was nearly 16% higher than the samples treated under atmospheric conditions. Fitting of Weibull model showed that the ultrasound pre-treated and untreated samples had shape parameter (β_w) ranging between 0.570–0.616 and 0.677–0.723 respectively. The lower values of shape parameter indicated that sonication caused accelerated water loss resulting faster dehydration rate. Results indicated that the effective moisture diffusivity and solute diffusivity was enhanced in ultrasonic pre-treated samples. The effective moisture diffusivity during osmotic dehydration of ultrasonic pre-treated samples was ranged between 5.460×10⁻¹⁰–7.300×10⁻¹⁰ m²/s and solute diffusivity was varied between 2.925×10⁻¹⁰–3.511×10⁻¹⁰ m²/s within the temperature range 25–60 °C. The enhanced moisture and solute diffusivity in ultrasound pre-treated kiwi slices was due to cell disruption and formation of microscopic channels.     

Mass transfer kinetics during osmotic dehydration of bananas (Musa sapientum,shum.)

Osmotic dehydration is used widely to partially remove water from plant tissues by immersion in a hypertonic solution. In this work, the influence of temperature (25–55 °C), sugar concentration (30–60%) and salt concentration (0–10%) of the osmotic solution was investigated during osmotic dehydration of banana (Musa sapientum, shum.). Mass transfer kinetics were modelled according to Peleg’s equation. Kinetic parameters were evaluated using response surface methodology. Peleg’s equation showed to be suitable for modelling the water removal and solute uptake. Initial rate of water loss and water concentration at equilibrium were influenced by linear factors of the three independent variables. Initial rate of sucrose uptake and sucrose uptake at equilibrium were affected by all factors and interactions. Initial rate of salt uptake and salt concentration at equilibrium showed a positive correlation with temperature and NaCl concentration and a negative correlation with sucrose concentration.     

Development of a Novel Image Analysis Technique to Detect the Moisture Diffusion of Soybeans [<Emphasis Type="Italic">Glycine max</Emphasis> (L.)] During Rehydration Using a Mass Transfer Simulation Model

The change in the moisture content of soybeans during a rehydration process at 25 °C was investigated. Peleg’s equation was suitable for describing the soaking characteristics of the soybean with a R² value of 0.98. The soaking time to achieve the target moisture content of soybeans (33.33%) was estimated to be 14.59 min by the Peleg model. The mass transfer coefficient (k) for the mass transfer simulation was determined with two calculation steps using the Omoto model and the simulation models. The most suitable k value for the simulation was determined to be 6.0?×?10^?7 m²/s, which is higher than the apparent k value obtained from the Omoto model. The diffusion simulation for the internal diffusion of the soybean after soaking was conducted for 180 min and the cross-section of soybeans was analyzed using an image processing technique during the diffusion process. The image analysis detected a moving layer during the diffusion process and the moisture content at the layer was determined to be 32.08% (±?0.34) based on the results of the simulation model.     

Osmotic Dehydration of Nectarines: Influence of the Operating Conditions and Determination of the Effective Diffusion Coefficients

The aim of the present work is to study the kinetics of osmotic dehydration of Caldesi nectarines (Prunus persica var. nectarina) evaluating the effect of osmotic solution concentration, type of solute, temperature, fruit/solute ratio and process time on moisture content, water loss, soluble solids content and solids gain. The process analysis was carried out experimentally and numerically through the mathematical modelling of mass transfer. Hypertonic solutions of glucose syrup and sorbitol (40 and 60 % w/w) were used for dehydration, during 2 h of process at temperatures of 25 and 40 °C, with fruit/osmotic agent ratio of 1:4 and 1:10. Water loss and solids gain showed significant differences depending on the type and concentration of the osmotic agent, process time and fruit/solution ratio. The concentration interacted significantly with all variables; in addition, there was an interaction between the type of osmotic agent and the relationship between fruit and the osmotic agent. The effective diffusion coefficients were obtained from the analytical solution of Fick’s second law applied to flat-plate geometry and by solving the mass transfer microscopic balances by finite element method, taking into account the real geometry of the nectarine pieces. The values obtained from Fick’s law varied between 1.27?×?10^?10 and 1.37?×?10^?08?m²?s^?1 for water and from 1.14?×?10^?10 to 1.08?×?10^?08?m²?s^?1 for soluble solids, while the values calculated by finite elements method ranges were between 0.70?×?10^?09 and 4.80?×?10^?09?m²?s^?1 for water and between 0.26?×?10^?09 and 1.70?×?10^?09?m²?s^?1 for soluble solids. The diffusion coefficients values obtained from the numerical solution are consistent with those published in literature.     

Temperature dependent hydration kinetics of Cicer arietinum splits

This study on hydration kinetics of chickpea (Cicer arietinum) in water at different temperature was conducted to assess the adequacy of models to describe absorption phenomena during soaking. The diffusion coefficient values calculated using two different forms of Fick’s second law were all of the order of 10^?9 m²/s. Peleg, Weibull and Exponential models were fitted to the soaked sample data. Adequacy of models was determined using coefficient of determination (R²), root mean square error (RMSE) and chi-square (χ²). The variation in moisture content of chickpea splits at different temperatures during hydration depicts an initial high rate of moisture absorption in the primary phase followed by slower absorption during the relaxation or secondary phase of hydration. The linearity in the curve during the initial stages of moisture absorption showed the uptake process was diffusion controlled. The results of non-linear regression analysis of fitting the models revealed that the Peleg model described the process of hydration better than did the other two models with R² ? 99.06%, RMSE ? 2.95 and χ² ? 0.001 for all the fitted models. Temperature had a positive and significant effect on the water absorption capacities and absorption was an endothermic process.     

Moisture Diffusivity Coefficient and Convective Drying Modelling of Murta (Ugni molinae Turcz): Influence of Temperature and Vacuum on Drying Kinetics

In this study, murta (Ugni molinae Turcz) or murtilla berries were dried in single layer at air temperatures of 50, 60 and 70 °C under vacuum and atmospheric pressure conditions. The effect of drying air temperature and vacuum on the basic dehydration characteristics of murta was determined. For the kinetic modelling, ten mathematical expressions were fitted to the experimental data. Kinetic parameters and diffusion coefficients as evaluated by an Arrhenius-type equation, showed temperature dependency. Fick’s second law was used to calculate the effective moisture diffusivity that varied from 3.10 to 11.27?×?10^?10 m²/s and from 5.50 to 11.30?×?10^?10 m²/s with activation energy values of 59.27 and 34.30 kJ/mol for atmospheric pressure and vacuum drying, respectively. According to the statistical tests applied, the Midilli–Ku?uk model obtained the best-fit quality on experimental data, followed closely by the Weibull distribution model, the Page and the modified Page models.     

Variability in the content of soluble sugars and cell wall polysaccharides in red‐ripe cherry and high‐pigment tomato cultivars

BACKGROUND: Soluble sugars and cell wall polysaccharides are well known for contributing to a range of ‘quality’ characteristics of fresh vegetables such as flavour, texture and healthy properties. Red‐ripe berries of 14 cultivars of cherry tomatoes and four cultivars of high‐pigment tomato hybrids, cultivated in the south of Italy, were analysed for their content of these important qualitative parameters. RESULTS: Sakura appeared to be the cultivar with the highest amount of soluble sugars (53 g kg^?1 fresh weight (f.w.)), mainly glucose and fructose, and, hence the ‘sweetest’ among cherry tomatoes. High‐pigment tomatoes, especially HLY02 and HLY13, showed a soluble sugar content much lower than cherry tomatoes, as expected for industrial, normal‐size tomatoes. Variations in the fructose/glucose ratio, of between 0.68 and 1.48, were evidenced among the different tomato cultivars. Cell wall polysaccharides isolated from whole fresh red‐ripe berries of each cultivar were analysed chemically. The amount of matrix polysaccharides (0.9–3.4 g kg^?1 f.w.) and cellulose (0.16–1.86 g kg^?1 f.w.), as well as their glycosidic composition, showed significant differences among the different cultivars. Cellulose to matrix polysaccharide ratio was highly variable and ranged between 0.06–1.44 and 0.17–0.77 in cherry and high‐pigment tomato cultivars, respectively. CONCLUSION: The differences evidenced in the total soluble sugar and cell wall polysaccharide composition, not only among different types of tomatoes but also different cultivars within the same typology, may play a fundamental role in the quality of tomatoes and deserve further investigations. Copyright © 2008 Society of Chemical Industry     

Mass transfer kinetics and regressional‐desirability optimisation during osmotic dehydration of pumpkin,kiwi and pear

Mass transfer kinetics and optimisation of osmotic dehydration (OD) of fruits and vegetables with diverse structures were studied. Different concentrations of sucrose (20–60 °Brix) and process times (0–24 h) were used. Magee’s model was appropriate for predicting water loss (WL), while Azuara’s model fitted well solids gain (SG) data and represented more accurately the evolution of the complete process close to equilibrium. Polynomial equations for each kinetic variable [WL, SG and weight reduction (WR) – for pumpkin, kiwi and pear] using multiple linear regression were fitted for a selected range of experimental data (30–240 min, 20–60 °Brix). A complete solution algorithm for desirability function was coded in Matlab^® 7.2 (Mathworks, Natick, MA, USA) with the aim to optimise osmotic dehydration process in terms of WL, SG and WR; optimal conditions were found for each fruit. Besides, an optimal common zone was identified for OD corresponding to process time from 114 to 240 min and sucrose concentration from 54 to 60 °Brix.     

Rehydration process of Boletus edulis mushroom: characteristics and modelling

Rehydration of air‐dried Boletus edulis mushrooms was investigated at six temperatures (25, 30, 40, 50, 60 and 70 °C). To describe the rehydration kinetics, two empirical equations, Peleg and Weibull, and a diffusion model for a slab were considered. The empirical models described the rehydration process properly, while the diffusion model also described experimental data adequately when considering the moisture‐dependent effective diffusion coefficient. The equilibrium moisture content increased in line with temperature up to 60 °C, then decreased. The kinetics constants of the Peleg and Weibull models, k₁ and β respectively, were affected by temperature. This influence of temperature can be expressed in term of an Arrhenius relationship, with an average activation energy of 19.2 kJ mol^?1. Copyright © 2005 Society of Chemical Industry     

Influence of Moisture Content and Temperature on Thermal Conductivity and Thermal Diffusivity of Rice Flours

The thermal conductivity and thermal diffusivity for four types of rice flours and one type of rice protein were determined at temperatures ranging from 4.8 to 36.8?°C, bulk densities 535 to 875.8 kg m^?3, and moisture contents 2.6 to 16.7% (w.b.), using a KD2 Thermal Properties Analyzer. The thermal conductivity of rice flours and rice protein increased with the increase in temperature, moisture content as well as with increase in bulk density. Thermal diffusivity decreased with increase in moisture content, increase in temperature and bulk density. The thermal conductivities values obtained were within the range of 0.045 to 0.124 W m^?1 K^?1 whereas the thermal diffusivity values were in the range of 0.094 to 0.138 mm² s^?1.     

Numerical Simulation of Variable Water Diffusivity during Drying of Peeled and Unpeeled Tomato

Abstract: A mathematical model was formulated for the estimation, in conjunction with experimental measurements, of water diffusivity parameters during convective drying of peeled and unpeeled tomatoes. Fick's 2nd law of diffusion was solved numerically for a sphere, by explicit finite differences, considering shrinkage effect, variable diffusivity, and constant boundary conditions. Experiments were performed in a laboratory tunnel dryer. The equivalent radius of tomato decreased by 50% until the end of the process, which explains the necessity for shrinkage inclusion in the mass transfer model. The mean estimated diffusivities varied between 2.03 × 10^?10 and 15.1 × 10^?10 m²/s for peeled tomatoes and 0.59 × 10^?10 and 15.2 × 10^?10 m²/s for unpeeled tomatoes. The estimated water diffusivities and their variation with the tested drying temperatures (45, 55, and 65 °C) provide an insight of peeling effect during air‐drying. Peeling was beneficial since yielded greater drying rates and shortened significantly drying times, thus saving energy during drying. In all the studied cases, good agreement was found between experimental and predicted drying curves (≥ 0.99, mean relative deviation [MRD]≤ 0.12, and root mean square error [RMSE]≤ 0.03). In overall, the proposed methodology provides a reliable and easy estimation of temperature and moisture‐dependent mass transfer properties and drying simulation of shrinkable food products such as tomato. Practical Application: Water diffusivity is a food property, difficult in estimation but essential in drying processing optimization. This property was estimated as a function of moisture content and drying temperature employing a numerical simulation procedure. The peeling effect was also studied and found beneficial for lower temperature drying (<55 °C) which is useful in the energy optimization of the drying process as well as the retention of the end‐product quality.     

Drying behaviour of hazelnuts

A diffusion-based drying model has been used to model the single-layer drying of whole hazelnuts (hull, air-gap and kernel). The drying of whole hazelnut was simulated by means of the numerical solution of Fick's second law for a composite solid consisting of an air gap which is between two solid bodies. The Crank–Nicholson implicit numerical method has been applied to solve the diffusion equation with variable mass diffusivity for whole hazelnut. The numerical data so obtained has been presented in the form of a series of curves which represent the drying characteristics of a whole hazelnut. Experimental results from whole hazelnuts were correlated with the theoretical results. A correlation describing the diffusivity of the whole hazelnut with moisture content and temperature was established, when the expression of diffusivity for hazelnut was used. Predicting the drying behaviour of the hazelnut for a known value of initial moisture content, equilibrium moisture and equivalent radius, a good agreement was obtaind between the experimental data and prediction. Whole hazelnut diffusivity was determined at 25–45°C, air velocity 0·2–0·3 ms⁻¹, 60% relative humidity of air, using the theoretical curves that best fit the data. The diffusivity of whole hazelnut was determined as a function of drying air temperature and velocity. © 1998 SCI.     

Equilibrium moisture content and heat of desorption of saffron

The equilibrium moisture contents of saffron (Crocus sativus L.) stigmas were determined experimentally using the standard gravimetric method at temperatures 30, 45 and 60 °C and water activity ranging from 11% to 83%. The sorption isotherm curves of saffron were sigmoidal in shape and decreased with increased temperature at constant relative humidity. Five selected isotherm models GAB, modified Henderson, modified Chung‐Pfost, modified Halsaey and modified Oswin were tested to fit the experimental isotherm data. Modified Oswin and modified Henderson models were found acceptable for predicting desorption moisture isotherms and fitting to the experimental data, respectively. The isosteric heats of desorption, determined from equilibrium data using the Clausius‐Clapeyron equation, were found to be a function of moisture content. The net isosteric heat of desorption of saffron varied between 1.38 and 5.38 kJ mol^?1 at moisture content varying between 2% and 20% (d.b).     

基于反演法计算不同温度下小麦面团的水分扩散系数

水分扩散系数是食品加工过程中重要的物理参数。估算水分扩散系数的主要方法是基于第二菲克定律,但在应用这些定律的方式上存在显著差异。本研究采用Peleg、Weibull、双指数这三种常用的食品水分吸附动力学模型拟合了冻干面团在20、30及40℃时的吸湿曲线。在此基础上,通过COMSOL软件分别建立了瞬时平衡、对流、平行指数边界三种条件下的面团吸湿模型,并通过反演法计算出对应模型下的水分扩散系数。结果表明,Weibull模型和双指数模型决定系数均在0.999以上,较为适合冻干面团吸湿曲线的拟合;平行指数边界模型能较好的模拟出不同温度条件下冻干面团的吸附水分变化规律。同时证明了水分扩散系数随温度升高而变大,且不能被当作一个常数。     

Partial dehydration of cherry tomato at different temperature, and nutritional quality of the products

This study concerns the partial dehydration of cherry tomatoes (Lycopersicon esculentum, var. Shiren) to obtain a product with 25% initial water content. Two kinds of dried tomatoes were obtained using a forced air oven at 40, 60 and 80 °C for different lengths of treatment. The first type was dehydrated after immersion of the fresh tomatoes in an aqueous solution of citric acid, sodium and calcium chloride (10:10:24 g/l); the second was obtained with no pre-treatment. The products were characterised by measuring their CIE L*a*b* colour parameters and levels of l-ascorbic acid, lycopene and β-carotene to evaluate thermal damage during processing under the different conditions. Moreover, water activity and the formation of 5-hydroxymethylfurfural were also determined as an index of sugar heat degradation. Treatment with a dipping solution protected both the nutritional and chemical qualities of the partially dried cherry tomatoes. Temperature was directly related to browning, ascorbic acid loss and HMF formation, while no clear influence could be found for carotenoid degradation.     

Effect of different rehydration temperatures on the moisture,content of phenolic compounds,antioxidant capacity and textural properties of edible Irish brown seaweed

The effect of temperature (20, 40, 60, 80 and 100 °C) on the rehydration kinetics and phytochemical constituents of dried edible Irish brown seaweed, Himanthalia elongata, were studied. The moisture content of fresh and dried seaweed was 4.07 and 0.07 g water/g dry basis, representing a 98.1% reduction in water content. All rehydration moisture curves had a clear exponential tendency, and it was observed that the rehydration time decreased when temperature was increased. Although restoration of the product to its original moisture content was achieved, rehydration resulted in losses in phytochemical content. Moisture equilibrium was achieved fastest at 100 °C (40 min) with losses of 83.2 and 93% in the total phenol and total flavonoid contents, respectively. The moisture content was fitted to empirical kinetic models; Weibull, Peleg’s, first-order and exponential association. Activation energies of 4.03, 4.28 and 3.90 kJ/mol were obtained for the parameters of Peleg’s, first-order and exponential models, respectively.