Fe-Mn-Si形状记忆合金的记忆性能分析

铁基形状记忆合金由于具有优良的形状记忆效应、价格低廉以及加工性能好等优点引起了广泛重视。对Fe-Mn-Si形状记忆合金的形状记忆机制、形状记忆效应的影响因素以及应用进行了评述。     

Martensitic stabilization and defects induced by deformation in TiNi shape memory alloys

Martensitic stabilization caused by deformation in a TiNi shape memory alloy was studied.Special attention was paid to the deformed microstructures to identify the cause of martensitic stabilization.Martensitic stabilization was demonstrated by differential scanning calorimetry for the tensioned TiNi shape memory alloy.Transmission electron microscopy revealed that antiphase boundaries were formed because of the fourfold dissociation of [110]B19' super lattice dislocations and were preserved after reverse t...     

Influences of 2.5wt% Mn addition on the microstructure and mechanical properties of Cu-Al-Ni shape memory alloys

The influences of 2.5wt%Mn addition on the microstructure and mechanical properties of the Cu-11.9wt%Al-3.8wt%Ni shape memory alloy(SMA) were studied by means of scanning electron microscopy(SEM),transmission electron microscopy(TEM),and differential scanning calorimeter(DSC).The experimental results show that Mn addition influences considerably the austenite-martensite transformation temperatures and the kind of martensite in the Cu-Al-Ni alloy.The martensitic transformation changes from a mixedβ_1→β'_1...     

Surface properties of nitrogen-ion-implanted TiNi shape memory alloy

X-ray diffraction （XRD）, auger electron spectroscopy （AES）, and X-ray photoelectron spectroscopy （XPS） were used to characterize the surface properties of the N^ ＋-ion-implanted TiNi alloy. There is a high nitrogen content region at the outermost surface of the N^＋-ion-implanted TiNi alloy. The detected nitrogen exists mainly in the form of TiN. Small amounts of Ti305 and TiO2 also exist on the surface of the N^＋-ion-implanted TiNi sample. The modified layer of the N^＋-ion-implanted sample can work as an obstacle layer of the nickel＇s dissolution, which obstructs Ni dissolving from the TiNi surface effectively.     

Phase transformation behaviors and shape memory effects of TiNiFeAl shape memory alloys

Measurements of electrical resistivity, X-ray diffraction, and tensile test at room temperature and ?196°C were performed to investigate the effects of Al addition substituting Ni on the phase transformation behaviors, the mechanical properties, and the shape memory effects of Ti50Ni47Fe2Al1 and Ti50Ni46.5Fe2.5Al1 alloys. It is found that 1at% Al addition dramatically decreases the martensitic start transformation temperature and expands the transformation temperature range of R-phase for TiNiFeAl alloys. The results of tensile test indicate that 1at% Al improves the yield strength of Ti50Ni47Fe2Al1 and Ti50Ni46.5Fe2.5Al1 alloys by 40% and 64%, but de- creases the plasticity to 11% and 12% from 26% and 27% respectively. Moreover, excellent shape memory effect of 6.6% and 7.5% were found in Ti50Ni47Fe2Al1 and Ti50Ni46.5Fe2.5Al1 alloys, which results from the stress-induced martensite transformation from the R-phase.     

磁控形状记忆合金执行器迟滞非线性模型

针对磁控形状记忆合金执行器的迟滞非线性,利用PI模型建模思想,采用线性Play算子建立磁控形状记忆合金执行器迟滞非线性模型。根据其模型结构与神经网络结构十分相似的特点,引入神经网络进行权值训练。为了提高系统的实时性,采用遗忘因子递推最小二乘法训练权值。试验结果显示:本文方法对输出位移的最大预测误差为0.0015mm,均方差为2.2931×10-4,最大误差率为0.1593%,表明该方法能够有效地建立磁控形状记忆合金(MS-MA)执行器的迟滞非线性模型,并可以获得较高的模型精度。     

Microstructure and shape memory effect of Cu-26.1Zn-4.8Al alloy

The influence of processing parameters on the microstructure and shape memory effect of Cu-26.1Zn-4.8Al alloy was investigated. The treated specimens were characterized by metallography, X-ray diffraction （XRD） and transmission electron microscopy （TEM） to explain the mechanism of shape memory effect in Cu-26.1Zn-4.8Al alloy. The results reveal that the shape memory effect is markedly increased by appropriate quenching and ageing process. XRD shows that γ phase precipitates from martensite when aged at higher temperature and γ precipitates impair the shape memory effect. TEM analysis indicate that the substructure of plate-like martensite consists of twins and stacking faults.     

Fe—Mn—Si基形状记忆合金及其应用

介绍了形状记忆合金的简要发展史,Fe-Mn-Si合金的形状记忆机理以及合金的主要元素组成,各成分的作用,提高记忆的方法,分析了其应用情况和前景。     

Effect of chemical component on shape memory effect of Fe-Mn-Si-Ni-C-RE shape memory alloy

Effect of chemical component on shape memory effect (SME) of Fe-Mn-Si-Ni-C-RE shape memory alloys was studied by bent measurement, thermal cycle training, SEM etc. Results of study indicate that the alloys with high Mn content (25%) appeare better SME, especially in lower strain. SME improves evidently when Si is higher content, especially it‘s range firm 3% up to 4%.But brittleness of Fe-Mn-Si-Ni-C-RE alloy increases by increasing the Si content. SME of the alloy is weakening gradually as carbon content increases under small strain (3%). But in the condition of large strain (above 6%), SME of the alloy whose carbon content ranges from 0.1% to 0.12% shows small decreasing range, especially of alloy with the addition of compound RE.     

Cooling rate effects on the structure and transformation behavior of Cu-Zn-Al shape memory alloys

Different fragments of a hot-rolled and homogenized Cu–Zn–Al shape memory alloy（SMA） were subjected to thermal cycling by means of a differential scanning calorimetric（DSC） device. During thermal cycling, heating was performed at the same constant rate of increasing temperature while cooling was carried out at different rates of decreasing temperature. For each cooling rate, the temperature decreased in the same thermal interval. During each cooling stage, an exothermic peak（maximum） was observed on the DSC thermogram. This peak was associated with forward martensitic transformation. The DSC thermograms were analyzed with PROTEUS software： the critical martensitic transformation start（Ms） and finish（Mf） temperatures were determined by means of integral and tangent methods, and the dissipated heat was evaluated by the area between the corresponding maximum plot and a sigmoid baseline. The effects of the increase in cooling rate, assessed from a calorimetric viewpoint, consisted in the augmentation of the exothermic peak and the delay of direct martensitic transformation. The latter had the tendency to move to lower critical transformation temperatures. The martensite plates changed in morphology by becoming more oriented and by an augmenting in surface relief, which corresponded with the increase in cooling rate as observed by scanning electron microscopy（SEM） and atomic force microscopy（AFM）.     

A free-cutting and ductile CuAlMnZnTiB shape memory alloy

The mechanical properties and cutting performance of the designed Cu Al Mn Zn Ti B shape memory alloy were studied by tensile test and microstructure observation. Using X-ray diffractometry, differential scanning calorimetry(DSC) and semi-quantitative shape memory effect test, the microstructure and shape memory effect were analyzed. It is found that lots of βphase and few α phase are formed in the quenching of Cu-7.5Al-9.7Mn-3.4Zn-0.3Ti-0.14B(mass fraction, %) alloy, a great deal of martensite and few α phase are formed in the aging alloy, while the annealing alloy is composed of a great deal of α phase and few βphase. The tensile strength and elongation of the annealed alloy are 649 MPa and 17.1%, respectively. Some tiny and dispersion distributed second phase particles are generated in Ti and B precipitates, greatly improving the alloy machinability.     

NiTi形状记忆合金应变传感特性分析

阐述了形状记忆合金丝的应变传感原理.在Brinson建立的形状记忆合金一维本构模型的基础上,引入Ikuta提出的电阻率与马氏体百分含量之间的关系并对其进行简化,建立了形状记忆合金应变传感特性的理论分析模型.分析了不同温度条件、不同初始状态的形状记忆合金电阻相对变化率与应变之间的关系.并与已有试验结果进行比较,验证了该模型的有效性.结果表明,形状记忆合金可以作为应变传感元件使用,温度对形状记忆合金的传感特性有影响,设计时要根据使用温度来确定形状记忆合金的相变温度.     

NiTi形状记忆合金拉伸变形失稳研究

介绍镍钛形状记忆合金发生应力诱发马氏体相变时的宏观失稳现象,研究微观晶粒内相变(材料失稳)因自催化效应逾渗到宏观水平所表现的类L櫣ders变形带演化(变形失稳),同步测量应力-应变响应、表面形貌和表面温度,跟踪了不同热-机械复合加载条件下构件力学行为的变化.从能量学角度对观察到的变形失稳现象进行理论分析.实验结果表明,宏观变形带的相貌演化与力学响应密切相关,探讨了建立该类材料的本构关系.     

Reverse Transformation Behavior of TiNi Shape Memory Alloys Prestrained in the Parent Phase

1 IntroductionShape memory alloys (SMAs) prestrained at a tem-perature belowAs(the reverse martensitic transformationstartingtemperature) can generate a large stress or me-chanical energy when constrainedly heated at aboveAf(the reverse martensitic transformation finishing tempera-ture) ,therefore they are regarded as one of the most im-portant actuatorsinsmart composites[1-4].The relationshipbetweenthe prestrain level and the reversible martensitictransformationof TiNi SMAs has beenstudie…     

Influence of stresses on martensitic transformation in ferromagnetic shape memory Ni_(50)Mn_(19)Fe_6Ga_(25) ribbons

~~Influence of stresses on martensitic transformation in ferromagnetic shape memory Ni_(50)Mn_(19)Fe_6Ga_(25) ribbons1. Ullakko, K., Huang, J. K., O'Handley, R. C. et al., Large magnetic-field-induced strains in Ni2MnGa single crystals, Appl. Phys. Lett., 1996, 69(13): 1966-1968. 2. James, R. D., Wuttig, M., Magnetostriciton of martensite, Philos. Mag., 1998, A 77: 1273-1275. 3. Wu, G. H., Yu, C. H., Meng, L. Q. et al., Giant magnetic-field-induced strains in H…     

钽对NiTi形状记忆合金影响的研究

本文研究了钽对ＮｉＴｉ形状记忆合金的马氏体相变特征及Ｘ射线可视性的影响．结果表明,当钽含量从０增加到４ａｔ％时,其相变温度迅速增加,钽含量超过４ａｔ％时,则趋于缓慢;含钽合金可降低ＮｉＴｉ合金相变温度对ＮｉＴｉ相对含量变化的敏感性;钽的加入可改善ＮｉＴｉ双相合金的Ｘ射线可视性．     

Effect of Ageing on Martensitic Transformation and Shape Memory Effect of Fe-Mn-Si-Co-Mo Alloy

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