Accurate experimental (p, ρ, T) data of natural gas mixtures for the assessment of reference equations of state when dealing with hydrogen-enriched natural gas

The GERG-2008 equation of state is the approved ISO standard (ISO 20765-2) for the calculation of thermophysical properties of natural gas mixtures. The composition of natural gas can vary considerably due to the diversity of origin. Further diversification was generated by adding hydrogen, biogas, or other non-conventional energy gases. In this work, high-precision experimental (p, ρ, T) data for two gravimetrically prepared synthetic natural gas mixtures are reported. One mixture resembled a conventional natural gas of 11 components (11 M) with a nominal mixture composition (amount-of-substance fraction) of 0.8845 for methane as the matrix compound with the other compounds being 0.005 for oxygen, 0.04 for nitrogen, 0.015 for carbon dioxide, 0.04 for ethane, 0.01 for propane, 0.002 each for n- and isobutane, and ultimately 0.0005 each for isopentane, n-pentane, and n-hexane. The other mixture was a 13-component hydrogen-enriched natural gas with a low calorific value featuring a nominal composition of 0.7885 for methane, 0.03 for hydrogen, 0.005 for helium, 0.12 for nitrogen, 0.04 for carbon dioxide, 0.0075 for ethane, 0.003 for propane, 0.002 each for n- and isobutane, and 0.0005 each for neopentane, isopentane, n-pentane, and n-hexane. Density measurements were performed in an isothermal operational mode at temperatures between 260 and 350 K and at pressures up to 20 MPa by using a single-sinker densimeter with magnetic suspension coupling. The data were compared with the corresponding densities calculated from both GERG-2008 and AGA8-DC92 equations of state to test their performance on real mixtures. The average absolute deviation from GERG-2008 (AGA8-DC92) is 0.027% (0.078%) for 11 M and 0.095% (0.062%) for the 13-component H₂-enriched mixture, respectively. The corresponding maximum relative deviation from GERG-2008 (AGA8-DC92) amounts to 0.095% (0.127%) for 11 M and 0.291% (0.193%) for the H₂-enriched mixture.     

高速铰削双层合金材料的硬质合金铰刀

阐述叶片叶轮两种不同性能合金钢装配后的铆钉孔铰削问题,论述了加工铆钉孔用铰刀材料选择及刀具结构和几何角度设计,给出加工铆钉孔的工艺参数,说明了使用效果。     

Forest biomass and Armington elasticities in Europe

The purpose of this paper is to provide estimated Armington elasticities for selected European countries and for three forest biomass commodities of main interest in many energy models: roundwood, chips & particles and wood residues. The Armington elasticity is based on the assumption that a specific forest biomass commodity is differentiated by its origin. The statistically significant estimated Armington elasticities range from 0.52 for roundwood in Hungary to approximately 4.53 for roundwood in Estonia. On average, the statistically significant Armington elasticity for chips & particles over all countries is 1.7 and for wood residues and roundwood 1.3 and 1.5, respectively. These elasticities can provide benchmark values for simulation models trying to assess trade patterns of forest biomass commodities and energy policy effects for European countries or for the EU as a whole.     

Comparative studies on Ar and He closed-cycle MHD power plants combined with fossil fuel

Comparative studies on Ar and He closed-cycle MHD power plants combined with fossil fuel are performed. The sizes of a regenerative heat exchanger and a boiler are expected to be smaller for He than for Ar. The pressure loss of a working gas in a regenerative heat exchanger is reduced for He. The purification subsystem for He is expected to be more compact and economical than that for Ar; but a larger compressor is required for He than for Ar.     

The impact of household consumption on energy use and CO2 emissions in China

In this paper, the consumer lifestyle approach is applied to analyze the impact of consumption by urban and rural households on energy use and CO₂ emissions for different regions and income levels in China. Grey Model is used to compare the relationship between energy consumption, consumption expenditure and CO₂ emissions for different lifestyles. The results show that direct energy consumption is diverse for urban households and simple for rural households in China. Direct energy consumption and CO₂ emissions are increasing faster for urban than for rural households. Indirect energy consumption and CO₂ emissions for urban households are much greater than the direct consumption values. The total indirect energy consumption and CO₂ emissions differ by regions and the structures are different, but the latter differences are not obvious. The impact of household income is enormous. Indirect energy consumption and CO₂ emissions are higher for high-income than for low-income households. The structural difference for indirect energy consumption and CO₂ emissions for households with different income levels is significant. The higher the income, the more diverse is the energy consumption and CO₂ emission structure. The structures for indirect energy use and CO₂ emissions are diverse for urban households, but simple for rural households.     

Comparative impacts of wind and photovoltaic generation on energy storage for small islanded electricity systems

This paper addresses the annual energy storage requirements of small islanded electricity systems with wind and photovoltaic (PV) generation, using hourly demand and resource data for a range of locations in New Zealand. Normalised storage capacities with respect to annual demand for six locations with winter-peaking demand profiles were lower for wind generation than for PV generation, with an average PV:wind storage ratio of 1.768:1. For two summer-peaking demand profiles, normalised storage capacities were lower for PV generation, with storage ratios of 0.613:1 and 0.455:1. When the sensitivity of storage was modelled for winter-peaking demand profiles, average storage ratios were reduced. Hybrid wind/PV systems had lower storage capacity requirements than for wind generation alone for two locations. Peak power for storage charging was generally greater with PV generation than with wind generation, and peak charging power increased for the hybrid systems. The results are compared with those for country-scale electricity systems, and measures for minimising storage capacity are discussed. It is proposed that modelling of storage capacity requirements should be included in the design process at the earliest possible stage, and that new policy settings may be required to facilitate a transition to energy storage in fully renewable electricity systems.     

Thermoelastic Equilibrium of Some Semi-Infinite Domains Subjected to the Action of a Heat Source

By using the integral representations for main thermoelastic Green's functions (MTGFs) we prove a theorem about new structural formulas for MTGFs for a whole class of boundary value problems (BVPs) of thermoelasticity for some semi-infinite Cartesian domains. According to these new structural formulas many MTGFs for a plane, a half-plane, a quadrant, a space, a quarter-space and an octant may be obtained by changing the respective well-known GFPE and their regular parts. The crucial moment of our investigation consists of elaboration of a new technique for calculating some generalized integrals containing products of two different GFPEs. Also, the types of boundary conditions for volume dilatation considered and GFPE for temperature differ on a single boundary only. As example of application of the obtained new structural formulas, the new MTGFs for a concrete BVP of thermoelaesticity for an octant are derived in elementary functions. The MTGFs obtained are validated on a known example for a BVP for half-space. Graphical computer evaluation of the derived in elementary functions new MTGFs is included.     

Development of methods for evaluating hydrogen compatibility and suitability

The embrittlement of metals exposed to hydrogen environments is well documented. With the deployment of hydrogen fuel cell vehicles in the consumer sector, there is a need to improve the engineering basis for the selection of materials of construction for equipment that stores and distributes high-pressure gaseous hydrogen. This brief overview summarizes publicly available guidance for evaluating materials compatibility with high-pressure gaseous hydrogen. Additionally, a new standard for measuring engineering data in gaseous hydrogen and evaluating materials suitability for service in gaseous hydrogen is introduced: the CHMC1 standard provides a general framework for qualifying materials for hydrogen service. The CHCM1 standard is unique in its broad scope and performance-based strategy for quantitatively assessing materials in their service environment and for the intended structural requirements.     

Alternative energy facilities based on site matching and generation unit sizing for remote area power supply

This paper presents the decision support technique and influencing factors in the design of an integrated solar-wind power system for stand-alone applications. Results of investigations on application of alternative energy facility like wind, photovoltaic (PV), and Integration of wind–PV power generating systems for Remote Area Power Supply have been presented. A weather model-based site matching of equipment and a simple numerical algorithm for generation unit sizing have been presented. The program has been used to determine the optimum generation capacity and storage needs for a stand-alone Wind, PV, and integrated wind–PV system for a remote site in India (Sukhalai situated near Suktawa in Hoshangabad district of Madhya Pradesh) that satisfies a typical load. Generation and storage units for each system are properly sized in order to meet the annual load demand for the above three scenarios. Annual average hourly values for load, wind speed, and insolation have been used for analysis. The results are used to justify the use of renewable energy source as a reliable option for remote areas.     

Bimaterial problems with an interfacial cavity for some boundary conditions subjected to uniform heat flux normal to the interface

Abstract

Stress analysis is carried out for a bimaterial infinite plane with an interfacial cavity. Uniform heat flux applies to the normal to the interface. Four combinations of boundary conditions are considered, that is, isothermal and adiabatic boundary conditions for heat flux analysis, and external force and displacement boundary conditions for stress analyses. The infinite plane consists of two bonded dissimilar materials of a half plane with a single notch. To achieve analytical solutions, a rational mapping function and a complex variable method are used. By changing the mapping function, other geometries for the notch can be analyzed. Complex stress functions for isothermal and external boundary conditions can be only achieved for stress calculation. The stress intensities of debonding are investigated for various debonding lengths for some elliptical holes, and for the debonding extensions. Complex stress functions for isothermal and displacement boundary conditions can be expressed by an infinite series and stress components et al. cannot be calculated. However, a solution of interfacial rigid inclusion can be solved. Complex stress functions for the adiabatic boundary are achieved by the integral forms for external force and displacement boundary conditions, and the integral cannot be carried out, and therefore, stress components cannot be achieved.     

ND5型机车主轴瓦碾瓦前的光谱数据分类及其应用

通过对机车出现故障前的光谱数据分析,总结和归纳数据异常的特征,并对其进行分类,明确各类型的特征和扣检时机,形成数据分析的参照样本,从而指导数据分析,以减少漏报和误报的发生,是光谱分析标准的细化和重要补充。     

Blind-prediction: Estimating the consequences of vented hydrogen deflagrations for homogeneous mixtures in 20-foot ISO containers

This paper summarises the results from a blind-prediction study for consequence models used for estimating the reduced explosion pressure and structural response in vented hydrogen deflagrations. The work is part of the project Improving hydrogen safety for energy applications through pre-normative research on vented deflagrations (HySEA). The scenarios selected for the blind-prediction entailed vented explosions with homogeneous hydrogen-air mixtures in a 20-foot ISO (International Organization for Standardization) container. The test program included two configurations and six experiments, i.e. three repeated tests for each scenario. The comparison between experimental results and model predictions reveals reasonable agreement for some of the models, and significant discrepancies for others. The results from the first blind-prediction study in the HySEA project should motivate developers to improve and validate their models, as well as to update documentation and guidelines for users of the models.     

锅炉参数变化时汽轮机系统的仿真算法

采用实时仿真算法对锅炉-汽轮机系统动态特性进行了整体性模拟。首先建立了详尽的汽轮机各部件动态数学模型和热力系统流量网络计算模型，特别是除氧器、表面加热器和凝汽器的通用动态数学模型；然后，将汽轮机系统动态模型与锅炉系统动态模型连接为整体仿真模型，并进行仿真。该文还列出了锅炉某些参数变化时汽轮机系统几个关键基本参数仿真结果。对电站锅炉-汽轮机系统的整体性模拟可以对运行人员进行更加全面的指导，并且为进行单元机组的瞬态性能计算，进而修正稳态性能计算结果奠定了基础。图12参3     

Transient heat conduction in an infinite medium subjected to multiple cylindrical heat sources: An application to shallow geothermal systems

In this paper, we introduce analytical solutions for transient heat conduction in an infinite solid mass subjected to a varying single or multiple cylindrical heat sources. The solutions are formulated for two types of boundary conditions: a time-dependent Neumann boundary condition, and a time-dependent Dirichlet boundary condition. We solve the initial and boundary value problem for a single heat source using the modified Bessel function, for the spatial domain, and the fast Fourier transform, for the temporal domain. For multiple heat sources, we apply directly the superposition principle for the Neumann boundary condition, but for the Dirichlet boundary condition, we conduct an analytical coupling, which allows for the exact thermal interaction between all involved heat sources. The heat sources can exhibit different time-dependent signals, and can have any distribution in space. The solutions are verified against the analytical solution given by Carslaw and Jaeger for a constant Neumann boundary condition, and the finite element solution for both types of boundary conditions. Compared to these two solutions, the proposed solutions are exact at all radial distances, highly elegant, robust and easy to implement.     

Direct application of geothermal energy: 2005 Worldwide review

This paper is a review of worldwide direct applications of geothermal energy. It attempts to update the surveys presented at and after the World Geothermal Congresses of 1995, 2000 and 2005. Seventy-two countries report direct utilization of geothermal energy. In May 2005, the direct-use projects had an estimated installed thermal capacity of 28,268 MWt. The thermal energy usage is 273,372 TJ/year (75,943 GWh/year), a 43% increase over 2000; the annual compound growth rate is 7.5%.The distribution of thermal energy used by category is approximately 32% for geothermal heat pumps, 30% for bathing and swimming (including balneology), 20% for space heating (of which 83% is for district heating), 7.5% for greenhouse and open-ground heating, 4% for industrial process heat, 4% for aquaculture pond and raceway heating, <1% for agricultural drying, <1% for snow melting and cooling, and <0.5% for other uses. The equivalent annual savings in fuel oil amounts to 170 million barrels (25.4 million tonnes) and 24 million tonnes in carbon emissions to the atmosphere.     

Understanding the fingerprint region in the infra-red spectra of perfluorinated ionomer membranes and corresponding model compounds: Experiments and theoretical calculations

We present an ATR-FTIR study of three major perfluorinated ionomers that are used as proton exchange membranes in fuel cells (FCs) and that differ in their side chains: Nafion, Aquivion and 3M membrane. The choice of the following low-molecular-weight model compounds (MCs) that mimic the membrane side chains was essential for FTIR band assignment: perfluoro(3-methyl-2,4-dioxahexane)sulfonic acid for Nafion, perfluoro(2-ethoxyethane)sulfonic acid for Aquivion, and perfluoro(2-ethoxybutane)sulfonic acid for the 3M membrane. The major goal was to identify spectral bands that can be used for recognizing bonds involved in membrane fragmentation. A major focus was on the signals from the C-O-C bonds, which were assigned in some papers for Nafion and Aquivion membranes. Our ATR-FTIR results for 3M membranes did not conform to these assignments, and DFT calculations of the vibrational frequencies for the MCs were used to resolve this conundrum. The ATR-FTIR spectra of membranes and MCs and the DFT calculations led to an understanding of the fingerprint region of all membranes, and to a re-examination and re-assignment of results for Nafion and Aquivion membranes. The low intensity of the spectral bands for the ether link connected to the backbone (for all membranes) and also in the side chain (for Nafion) suggests that these bands cannot be used for the determination of the extent of degradation.     

Entropy optimized MHD fluid flow over a vertical stretching sheet in presence of radiation

The present article describes the influence of radiation on two-dimensional laminar magnetohydrodynamic fluid flow passing over a convective surface. The behavior of the thermal equation is explored through Joule heating, heat generation/absorption, and viscous dissipation. The aim of this study is to examine the physical behavior of the entropy optimization rate. The Cartesian coordinates system is used to model the flow equations. Using similarity variables, a system of partial differential equations is converted into a system of ordinary differential equations. The problem is solved using HAM. The influence of various pertinent parameters on fluid characteristics is graphically explored. Velocity decreases for an increased amount of magnetic parameter, suction parameter, and velocity slip parameter, while behaves the opposite for Grashof number. Temperature increases for a large amount for Brinkman number, magnetic parameter, and radiation parameter, while decreases for Prandtl number. Entropy generation rate increases for Brinkman number, magnetic parameter, and temperature difference parameter. Bejan number decreases for Brinkman number while behaves the opposite for magnetic parameter and temperature difference parameter. Skin friction decreases for large values of magnetic parameters while behaving the opposite for a large amount of velocity slip parameter. Nusselt number decreases for a large amount of Brinkman number. For a better understanding of the study, comparison between numerical outcomes of entropy generation rate and Bejan number for different values of Prandtl number has been done through tables. Also, numerical outcomes of skin friction and Nusselt number are discussed using pertinent parameters through tables.     

Design modeling of lithium-ion battery performance

A computer design modeling technique has been developed for lithium-ion batteries to assist in setting goals for cell components, assessing materials requirements, and evaluating thermal management strategies. In this study, the input data for the model included design criteria from Quallion, LLC for Gen-2 18650 cells, which were used to test the accuracy of the dimensional modeling. Performance measurements on these cells were done at the electrochemical analysis and diagnostics laboratory (EADL) at Argonne National Laboratory. The impedance and capacity related criteria were calculated from the EADL measurements. Five batteries were designed for which the number of windings around the cell core was increased for each succeeding battery to study the effect of this variable upon the dimensions, weight, and performance of the batteries. The lumped-parameter battery model values were calculated for these batteries from the laboratory results, with adjustments for the current collection resistance calculated for the individual batteries.     

Availability growth models and verification of power equipment

The general availability growth models for large scale complicated repairable system such as electric generating units, power station auxiliaries, and transmission and distribution installations are presented. The calculation formulas for the maintenance coefficient, mathematical expressions for general availability growth models, ways for estimating, and fitting on checking the parameters of the model are introduced. Availability growth models for electric generating units, power station auxiliaries, and transmission and distribution installations are given together with verification examples for availability growth models of 320–1000 MW nuclear power units and 1000 MW thermal power units, 200–1000 MW power station auxiliaries, and 220–500 kV transmission and distribution installations. The verification results for operation availability data show that the maintenance coefficients for electric generating units, power station auxiliaries, transmission and distribution installations conform to the power function, and general availability growth models conform to rules of availability growth tendency of power equipment.