华烁科技股份有限公司(湖北省化学研究院)

<正>国家气体净化剂重点工业基地工业气体精制与利用湖北省重点实验室WHB煤制聚合级乙二醇新技术煤制聚合级乙二醇的先锋最早提出"煤制聚合级乙二醇",最早同时达到国家优等品与美国聚合级指标拥有脱氢、合成、加氢3项关键催化剂通过小试与中试鉴定,拥有以22项发明专利为核心的全套自主知识产权中试时间最长,国内唯一进行工程放大补充试验国内唯一科研(华烁)——工程(五环)深度战略组合,会战攻关     

WHB煤制乙二醇断技术

中国五王不工程有限公司、华烁科技股份有限公司（原湖北省化学研究院）和鹤壁宝马实业有限公司联合开发的WHB煤制聚合级乙二醇新技术,目前已经取得了新突破,该技术生产的乙二醇产品已完成聚合、纺丝和染整等应用试验,以这种乙二醇为原料生产的PET切片及纺丝染整性能已完全达到、部分指标甚至优于以石油乙烯法乙二醇为原料的对比样品。此前业内专家对煤制乙二醇项目_还存在诸多担心和质疑,其焦点之一就是产品能否达到聚合级,以及能否用于生产PET。中国五环、华烁科技与中国纺织科学研究院及其江南分院进行合作,将WHB新技术生产的乙二醇产品与石油乙烯法乙二醇产品同时进行聚合、纺丝和染整对比试验,PET切片经纺织工业化纤产品质量监督中心检测,以该乙二醇为原料的PET切片性能包括特性黏度、色度、羧基含量、水分、灰分等指标已达到纤维级PET切片国标优等品指标;同时该PET经纺丝染整后其K／S值、上染率、摩擦牢度和皂洗牢度等指标达到石油乙烯法乙二醇为原料的对比样水平,特剧是K／S值和上染率还优于对比样。结果表明,用WHB新技术生产的乙二醇完全可用于生产PET。     

WHB煤制乙二醇新技术

<正>中国五环工程有限公司、华烁科技股份有限公司(原湖北省化学研究院)和鹤壁宝马实业有限公司联合开发的WHB煤制聚合级乙二醇新技术,目前已经取得了新突破,该技术生产的乙二醇产品已完成聚合、纺丝和染整等应用试验,以这种乙二醇为原料生产的PET切片及纺丝染整性能已完全达到、部分指标甚至优于以石油乙烯法乙二醇为原料的对比样品。此前业内专家对煤制乙二醇项目还存在诸多担心和质疑,其焦点之一就是产品能否达到聚合级,以及能否用于生产PET。     

煤制聚合级乙二醇新技术取得新进展

正由中国五环工程有限公司、华烁科技股份有限公司(原湖北省化学研究院)和鹤壁宝马实业有限公司联合开发的WHB煤制聚合级乙二醇新技术取得新进展。用该技术生产的乙二醇产品已完成聚合、纺丝和染整等应用试验,以这种乙二醇为原料生产的聚酯切片及纺丝染整性能完全达到、部     

动态报道

<正>煤制乙二醇生产PET采用WHB煤制聚合级乙二醇技术建设的乙二醇装置生产的优等品乙二醇已经100%用于PET长丝领域,引领煤制乙二醇技术进入新阶段。2017年2月23日浙江双兔新材料有限公司给采用WHB煤制聚合级乙二醇技术的阳煤集团深州化工有限公司发去产品品质证明"我公司采购阳煤集团深州化工有限公司以煤为原料生产的乙二醇产品,用于生产PET长丝。经使用,该乙二醇产     

煤制合成气生产聚合级乙二醇新技术现场交流会在鹤壁顺利召开

<正>2012年11月12日,由中国五环工程有限公司、华烁科技股份有限公司(湖北省化学研究院)和鹤壁宝马集团实业有限公司三家联合主办的"煤制合成气生产聚合级乙二醇新技术(WHB新技术)现场交流会"在鹤壁煤制聚合级乙二醇中试现场召开。会议小范围邀请已有煤制乙二醇技术合作意向的煤化工企业领导、专家二十余人(另有阳煤集团和兖矿集团的领导在会前到现场交流考察),实地考察了该中试装置的运行情况,并现场取样分析检测产品质量,与会代表还与开发单位就有关技术问题进行了充分交流。     

深州化工有限公司200kt/a煤制乙二醇装置开车成功

正阳煤集团深州化工有限公司200 kt/a煤制乙二醇装置于2016年4月15日开车成功,并实现90%~100%高负荷稳定运行,产品质量经国家石油化工产品质量监督检验中心检验,达到GB/T 464—2008《工业用乙二醇》优等品的指标要求。该装置的乙二醇合成技术采用由中国五环工程有限公司、华烁科技股份有限公司(原湖北省化学研究院)和鹤壁宝马集团实业有限公司联合开发的WHB煤制聚合级乙二醇新     

煤基乙二醇合成聚酯的可行性研究

由于原料、工艺路线不同,煤基乙二醇和石油基乙二醇产品在杂质构成上会存在一些差异,安阳化学工业集团有限责任公司近年来开展了煤基乙二醇合成聚酯的可行性研究,5 L聚合试验和50 L聚合试验结果表明,煤基乙二醇与石油基乙二醇所制得的聚酯切片产品质量没有明显差异,均达到国标要求,煤基乙二醇完全可替代石油基乙二醇合成纤维级聚酯切片和瓶级聚酯切片。安化公司于2014年建成投产了世界上首套全部以煤基乙二醇为原料的300 kt/a瓶级聚酯装置,按照聚合试验所提供的原辅料配比、反应温度、反应压力、反应时间、添加剂种类及数量等工艺参数,经反复调试,生产出合格的瓶级聚酯切片,瓶级聚酯切片制作的瓶胚、塑料瓶得到国内知名饮料企业的认可和使用,完全打通了煤制聚酯的产业链。     

液相加氢提高聚酯级煤制乙二醇收率的工业化应用

为了提高煤制乙二醇聚酯级产品的收率、降本增效,选择了乙二醇液相加氢技术对煤制乙二醇工艺进行改造。设计了液相加氢工艺流程、乙二醇液相加氢与乙二醇精馏耦合流程。通过工业化运行表明,液相加氢效果明显,极大地提高了工业级乙二醇的紫外透光率;通过液相加氢后工业级乙二醇的循环,使聚酯级乙二醇收率达到100%。     

煤制乙二醇的内在质量及市场应用

简介安阳永金化工有限公司200 kt/a煤制乙二醇装置工艺路线和运行情况,结合《工业用乙二醇》(GB/T 4649—2008)设定的12项质量指标,分析与探讨以煤制乙二醇为原料对下游聚酯产品质量的影响;通过对比安阳永金化工有限公司煤制乙二醇与石油制乙二醇的质量指标,得出煤制乙二醇质量可达到石油制乙二醇产品的质量水平的结论,并通过总结安阳永金化工有限公司煤制乙二醇在聚酯厂及300kt/a瓶级聚酯项目等的市场应用经验,再次验证煤制乙二醇完全能达到GB/T 4649—2008优级品要求且品质稳定,可应用于大型聚酯生产装置,满足下游聚酯厂家的使用要求。     

Insect antifeedant properties of anthranoids from the genusVismia

Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria.     

Direct observation of freeze-thaw instability of latex coatings via high pressure freezing and cryogenic SEM

Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively. There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized. High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing, and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually preserves suspension stability during freezing. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago, IL. Tied for first place in The John A. Gordon Best Paper Competition.     

Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US

In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures (release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species (Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles from the southeastern region of the US.     

Methyl 2,4,6-decatrienoates Attract Stink Bugs and Tachinid Parasitoids

Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed.     

2007～2008年世界塑料工业进展

收集了2007年7月～2008年6月世界塑料工业的相关资料,介绍了2007～2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍.     

2005～2006年国外塑料工业进展

收集了2005年7月～2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂（聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂）、工程塑料（聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚）、通用热固性树脂（酚醛、聚氨酯、不饱和树脂、环氧树脂）、特种工程塑料（聚苯硫醚、液晶聚合物、聚醚醚酮）的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。