Electron spin coherence exceeding seconds in high-purity silicon

Silicon is one of the most promising semiconductor materials for spin-based information processing devices. Its advanced fabrication technology facilitates the transition from individual devices to large-scale processors, and the availability of a (28)Si form with no magnetic nuclei overcomes a primary source of spin decoherence in many other materials. Nevertheless, the coherence lifetimes of electron spins in the solid state have typically remained several orders of magnitude lower than that achieved in isolated high-vacuum systems such as trapped ions. Here we examine electron spin coherence of donors in pure (28)Si material (residual (29)Si concentration <50 ppm) with donor densities of 10(14)-10(15) cm(-3). We elucidate three mechanisms for spin decoherence, active at different temperatures, and extract a coherence lifetime T(2) up to 2 s. In this regime, we find the electron spin is sensitive to interactions with other donor electron spins separated by ~200 nm. A magnetic field gradient suppresses such interactions, producing an extrapolated electron spin T(2) of 10 s at 1.8 K. These coherence lifetimes are without peer in the solid state and comparable to high-vacuum qubits, making electron spins of donors in silicon ideal components of quantum computers, or quantum memories for systems such as superconducting qubits.     

Spin qubits with electrically gated polyoxometalate molecules

Spin qubits offer one of the most promising routes to the implementation of quantum computers. Very recent results in semiconductor quantum dots show that electrically-controlled gating schemes are particularly well-suited for the realization of a universal set of quantum logical gates. Scalability to a larger number of qubits, however, remains an issue for such semiconductor quantum dots. In contrast, a chemical bottom-up approach allows one to produce identical units in which localized spins represent the qubits. Molecular magnetism has produced a wide range of systems with properties that can be tailored, but so far, there have been no molecules in which the spin state can be controlled by an electrical gate. Here we propose to use the polyoxometalate [PMo12O40(VO)2]q-, where two localized spins with S = 1/2 can be coupled through the electrons of the central core. Through electrical manipulation of the molecular redox potential, the charge of the core can be changed. With this setup, two-qubit gates and qubit readout can be implemented.     

Probing Single-Electron Spin Decoherence in Quantum Dots using Charged Excitons

We propose to use optical detection of magnetic resonance (ODMR) to measure the decoherence time T₂ of a single-electron spin in a semiconductor quantum dot. The electron is in one of the spin 1/2 states and a circularly polarized laser can only create an optical excitation for one of the electron spin states due to Pauli blocking. An applied electron spin resonance (ESR) field leads to Rabi spin flips and thus to a modulation of the photoluminescence or, alternatively, of the photocurrent. This allows one to measure the ESR linewidth and the coherent Rabi oscillations, from which the electron spin decoherence can be determined. We study different possible schemes for such an ODMR setup, including cw or pulsed laser excitation. An erratum to this article is available at .     

Quantum measurement and orientation tracking of fluorescent nanodiamonds inside living cells

Fluorescent particles are routinely used to probe biological processes. The quantum properties of single spins within fluorescent particles have been explored in the field of nanoscale magnetometry, but not yet in biological environments. Here, we demonstrate optically detected magnetic resonance of individual fluorescent nanodiamond nitrogen-vacancy centres inside living human HeLa cells, and measure their location, orientation, spin levels and spin coherence times with nanoscale precision. Quantum coherence was measured through Rabi and spin-echo sequences over long (>10 h) periods, and orientation was tracked with effective 1° angular precision over acquisition times of 89 ms. The quantum spin levels served as fingerprints, allowing individual centres with identical fluorescence to be identified and tracked simultaneously. Furthermore, monitoring decoherence rates in response to changes in the local environment may provide new information about intracellular processes. The experiments reported here demonstrate the viability of controlled single spin probes for nanomagnetometry in biological systems, opening up a host of new possibilities for quantum-based imaging in the life sciences.     

Decoherence rates in large-scale quantum computers and macroscopic quantum systems

Markovian regime decoherence effects in quantum computers are studied in terms of the fidelity for the situation where the number of qubits N becomes large. A general expression giving the decoherence time scale in terms of Markovian relaxation elements and expectation values of products of system fluctuation operators is obtained, which could also be applied to study decoherence in other macroscopic systems such as Bose condensates and superconductors. A standard circuit model quantum computer involving three-state lambda system ionic qubits is considered, with qubits localized around well-separated positions via trapping potentials. The centre of mass vibrations of the qubits act as a reservoir. Coherent one and two qubit gating processes are controlled by time-dependent localized classical electromagnetic fields that address specific qubits, the two qubit gating processes being facilitated by a cavity mode ancilla, which permits state interchange between qubits. With a suitable choice of parameters, it is found that the decoherence time can be made essentially independent of N.     

Hole spin relaxation in Ge-Si core-shell nanowire qubits

Controlling decoherence is the biggest challenge in efforts to develop quantum information hardware. Single electron spins in gallium arsenide are a leading candidate among implementations of solid-state quantum bits, but their strong coupling to nuclear spins produces high decoherence rates. Group IV semiconductors, on the other hand, have relatively low nuclear spin densities, making them an attractive platform for spin quantum bits. However, device fabrication remains a challenge, particularly with respect to the control of materials and interfaces. Here, we demonstrate state preparation, pulsed gate control and charge-sensing spin readout of hole spins confined in a Ge-Si core-shell nanowire. With fast gating, we measure T(1) spin relaxation times of up to 0.6 ms in coupled quantum dots at zero magnetic field. Relaxation time increases as the magnetic field is reduced, which is consistent with a spin-orbit mechanism that is usually masked by hyperfine contributions.     

Transition to classical behavior in mesoscopic magnetic systems and quantum decoherence

A mesoscopic CrNi₆ system is used to demonstrate the possibility of transitions from quantum to classical behavior in thermally stimulated tunneling processes. The main mechanism responsible for these transitions is assumed to be quantum decoherence produced as a result of thermal interaction between the spin system and its neighborhood. Results are presented of calculations of the disruption probability for a mesoscopic system as a function of temperature. It is shown that the main characteristic which can reveal the decoherence effect is the nonmonotonic behavior of the disruption probability at low temperatures. Pis’ma Zh. Tekh. Fiz. 25, 1–5 (August 26, 1999)     

Atomic-scale magnetometry of distant nuclear spin clusters via nitrogen-vacancy spin in diamond

The detection of single nuclear spins is an important goal in magnetic resonance spectroscopy. Optically detected magnetic resonance can detect single nuclear spins that are strongly coupled to an electron spin, but the detection of distant nuclear spins that are only weakly coupled to the electron spin has not been considered feasible. Here, using the nitrogen-vacancy centre in diamond as a model system, we numerically demonstrate that it is possible to detect two or more distant nuclear spins that are weakly coupled to a centre electron spin if these nuclear spins are strongly bonded to each other in a cluster. This cluster will stand out from other nuclear spins by virtue of characteristic oscillations imprinted onto the electron spin decoherence profile, which become pronounced under dynamical decoupling control. Under many-pulse dynamical decoupling, the centre electron spin coherence can be used to measure nuclear magnetic resonances of single molecules. This atomic-scale magnetometry should improve the performance of magnetic resonance spectroscopy for applications in chemical, biological, medical and materials research, and could also have applications in solid-state quantum computing.     

Quantum information in cavity quantum electrodynamics: logical gates,entanglement engineering and 'Schrödinger-cat states'

In cavity-quantum-electrodynamics experiments, two-level Rydberg atoms and single-photon microwave fields can be seen as qubits. Quantum gates based on resonant and dispersive atom-field effects have been realized, which implement various kinds of conditional dynamics between these qubits. We have also studied the interaction between a single atom and coherent fields stored in the cavity. By progressively increasing the number of photons in these fields, we have explored various aspects of the quantum-classical boundary. We have realized a complementarity experiment demonstrating the continuous evolution of an apparatus from a quantum to a classical behaviour. We have also prepared 'Schr?dinger-cat'-like states of the field made of a few photons, and observed their decoherence. We present a brief review of these experiments along with a proposal to study larger systems, i.e. coherent fields with more photons. Fundamental limits to the size of mesoscopic superpositions of field states in a cavity will be briefly discussed.     

Quantum Entanglement and Correlations in Superconducting Flux Qubits

We report on the quantum correlations dissipative dynamics followed by coupled superconducting flux qubits. The coupling between the superconducting quantum register and the reservoir is described by two different mechanisms: collective and independent decoherence. By means of the Bloch?CRedfield formalism, we solve the quantum master equation and show that coupling under collective quantum noise is more robust to decoherence. This result is demonstrated for different flux qubit initial preparations, taking into account the influence due to external fields and temperature. Furthermore, we compute the entanglement and the quantum discord dissipative dynamics as controlled by external parameters. We show that the discord is more robust against decoherence effects. This fact could be harnessed in the realization of quantum computing tasks that do not need to invoke entanglement in their implementation.     

Entanglement-induced population trapping by Schrödinger's cat

Abstract

We propose an experiment that is a variation of the Schrödinger's cat ′paradox' wherein the entanglement between a microscopic system and a macroscopic system is of primary interest. The experiment involves tunable entanglement and serves as a model for controllable decoherence in the context of cavity quantum electrodynamics where atoms interact dispersively with a cavity field initially in a coherent state. The interaction produces an entanglement between the atom and the field, and the degree of entanglement can be probed by subjecting the atom to resonant classical radiation after it leaves the cavity. The amplitude of the resulting Rabi oscillations reflects the degree of the entanglement, there being no Rabi oscillations when the entanglement is maximum. We show that the cavity damping does not affect the experiment.     

Materials Physics and Quantum Coherence in Superconducting Qubits

Nonidealities of real superconductors in the form of residual rf losses and conductance below the superconducting energy gap in tunneling Josephson junctions are discussed as possible sources of decoherence in Josehphson junction flux qubits. The purpose of the paper is pedagogical and aimed at taking a first step in a unified view of the quantum behavior of superconducting qubits and the realities of the materials out of which they are constructed. The need for a dialog between the quantum physicist and the materials physicist is stressed. Residual rf losses and localized states in junction barriers are identified as important subjects for this dialog.     

Recent Progress in Quantum Simulation Using Superconducting Circuits

Quantum systems are notoriously difficult to simulate with classical means. Recently, the idea of using another quantum system—which is experimentally more controllable—as a simulator for the original problem has gained significant momentum. Amongst the experimental platforms studied as quantum simulators, superconducting qubits are one of the most promising, due to relative straightforward scalability, easy design, and integration with standard electronics. Here I review the recent state-of-the art in the field and the prospects for simulating systems ranging from relativistic quantum fields to quantum many-body systems.     

Decoherence of nuclear spin quantum memory in a quantum dot

Recently, an ensemble of nuclear spins in a quantum dot have been proposed as a long-lived quantum memory. A quantum state of an electron spin in the dot can be faithfully transfered into nuclear spins through controlled hyperfine coupling. Here we study the decoherence of this memory due to nuclear spin dipolar coupling and inhomogeneous hyperfine interaction during the storage period. We calculated the maximum fidelity of writing, storing, and reading operations. Our results show that nuclear spin dynamics can severely limit the performance of the proposed device for quantum information processing and storage based on nuclear spins.     

Experimental Evaluation of the Intrinsic Dissipation from Energy-Level Quantization in Josephson Devices

The main problem in realizing an experiment of macroscopic quantum coherence, namely, an experiment where the nonclassical behavior of a macroscopic system must be detected, is the fulfillment of many experimental constraints, in principle very difficult to achieve. One of the most critical parameters is the decoherence time of the system. The Rabi oscillations of a two-level system, in fact, are canceled if the quality factor associated with the oscillation is less than unity. In particular, it can be shown that the decoherence time for a SQUID system, once the temperature is given, depends only on the effective resistance. To evaluate the effective resistance of our system we have measured the energy-level quantization (ELQ) under stationary conditions at a temperature between 13 and 35 mK, for a Josephson junction and for an rf SQUID using the same type of junction. For both systems we can clearly see ELQ, because of the very low level of the intrinsic dissipation. From these measurements we can then set a lower limit for the effective system dissipation and then infer the decoherence time related to the overall setup of our experiment.     

Scalable solid-state qubits: challenging decoherence and read-out

We review some basic facts about qubits and qubit processing. After a brief survey of solid-state qubits, we focus on quantized electrical circuits and superconducting qubits based on Josephson junctions. We review the general framework and indicate how the various qubits, such as the superconducting Cooper pair box charge qubit, the persistent current flux qubit, the hybrid charge-phase qubit, and the Andreev-level qubit, can be seen to appear due to different choices of design parameters. Finally, we consider multi-qubit systems and discuss some aspects of decoherence.     

Quantum oscillations in magnetically doped colloidal nanocrystals

Progress in the synthesis of colloidal quantum dots has recently provided access to entirely new forms of diluted magnetic semiconductors, some of which may find use in quantum computation. The usefulness of a spin qubit is defined by its Rabi frequency, which determines the operation time, and its coherence time, which sets the error correction window. However, the spin dynamics of magnetic impurity ions in colloidal doped quantum dots remain entirely unexplored. Here, we use pulsed electron paramagnetic resonance spectroscopy to demonstrate long spin coherence times of ～0.9 μs in colloidal ZnO quantum dots containing the paramagnetic dopant Mn(2+), as well as Rabi oscillations with frequencies ranging between 2 and 20 MHz depending on microwave power. We also observe electron spin echo envelope modulations of the Mn(2+) signal due to hyperfine coupling with protons outside the quantum dots, a situation unique to the colloidal form of quantum dots, and not observed to date.     

Entangling a single NV centre with a superconducting qubit via parametric couplings between photons and phonons in a hybrid system

We propose an efficient scheme for generating entangled states between a single nitrogen-vacancy (NV) centre in diamond and a superconducting qubit in a hybrid set-up. In this device, the NV centre and the superconducting qubit couple to a nanomechanical resonator and a superconducting coplanar waveguide cavity, respectively, while the microwave cavity and the mechanical resonator are parametrically coupled with a tunable coupling strength. We show that, highly entangled states between the NV centre and the superconducting qubit can be achieved, by means of the Jaynes–Cummings interactions in the NV-resonator and qubit-cavity subsystems which transfer the entanglement between the vibration phonons and the cavity photons to the NV centre and the superconducting qubit. This work may provide interesting applications in quantum computation and communication with single NV spins and superconducting qubits.     

Conservation of Angular Momentum in a Flux Qubit

Oscillations of superconducting current between clockwise and counterclockwise directions in a flux qubit do not conserve the angular momentum of the qubit. To compensate for this effect the solid containing the qubit must oscillate in unison with the current. This requires entanglement of quantum states of the qubit with quantum states of a macroscopic body. The question then arises whether slow decoherence of quantum oscillations of the current is consistent with fast decoherence of quantum states of a macroscopic solid. This problem is analyzed within an exactly solvable quantum model of a qubit embedded in an absolutely rigid solid and for the elastic model that conserves the total angular momentum. We show that while the quantum state of a flux qubit is, in general, a mixture of a large number of rotational states, slow decoherence is permitted if the system is macroscopically large. Practical implications of entanglement of qubit states with mechanical rotations are discussed.     

One-step generation of Greenberger–Horne–Zeilinger states of multi solid-state spin qubits

We propose a one-step scheme for the generation of Greenberger–Horne–Zeilinger states of multi solid-state qubits and the implementation of quantum phase gates in a system consisting of N spatially separated nitrogen-vacancy centers coupled to the whispering-gallery mode (WGM) of a microsphere cavity. The proposed scheme is based on the effective electronic dipole–dipole interaction between electron spins associated with the NV centers, which is mediated by the WGM and applying external driving laser fields. As the spontaneous emission of the excited states of the NV centers is highly suppressed and the cavity mode is only virtually excited, the scheme is insensitive to decoherence.