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1.
Mengqi Li Chengfa Wang Zhijian Liu Yongxin Song Dongqing Li 《Advanced functional materials》2021,31(36):2104341
Bioinspired ionic diodes are widely explored to mimic the controllable ion transport of biological ion channels. However, due to their vertical structures, the integration of conventional ionic diodes into complex ionic circuits is still a challenge. Here, a horizontal ionic diode is developed based on an asymmetric nanochannel network membrane (NCNM) constructed from carbon black nanoparticles. The rectification of ionic current is achieved through the asymmetric concentration polarization of ions at two ends of the asymmetric NCNM. The rectification ratio of the NCNM ionic diode can be modified flexibly by changing the working fluid and the geometry of the NCNM. It is found that with the presence of cationic surfactant in the working fluid, the rectification ratio increases more than 30 times from 3.03 to 109.77. Advanced functions of the developed ionic component, including working as an ionic transistor for current switching and integrating into an ionic diode bridge on a single nanofluidic chip for rectifying alternating current signals, are also demonstrated in this paper. The horizontally arranged NCNM ionic diode possesses the advantages of easy fabrication and integration that can be practically applied in the development of ionic electronics and biocomputing. 相似文献
2.
J. Luo Y.J. Xing J. Zhu D.P. Yu Y.G. Zhao L. Zhang H. Fang Z.P. Huang J. Xu 《Advanced functional materials》2006,16(8):1081-1085
A one‐dimensional heterojunction is fabricated and characterized. This heterojunction comprises a Ni nanowire, a multiwalled carbon nanotube (MWCNT), and an amorphous carbon nanotube (a‐CNT). The three components are in an end‐to‐end configuration, and form two MWCNT contacts, namely a Ni/MWCNT and an MWCNT/a‐CNT contact. The interfacial structures of the two contacts show that multiple outer walls in the MWCNT simultaneously contact the Ni nanowire and the a‐CNT, and can simultaneously participate in electrical transport. By investigating the electrical‐transport properties of the heterojunctions, the two contacts to the MWCNT in every heterojunction are found to behave as two diodes connected in series face‐to‐face, at least one of which exhibits the characteristics of a nearly ideal Schottky diode and obeys thermionic‐emission theory, wherein only the image force lowers the Schottky barrier. The appearance of this type of nearly ideal diode is attributed to the good contacts to the multiple outer walls of the MWCNTs realized by the heterojunctions' structures. 相似文献
3.
Huacheng Zhang Xu Hou Jue Hou Lu Zeng Ye Tian Lin Li Lei Jiang 《Advanced functional materials》2015,25(7):1102-1110
Synthetic stimuli‐gated nanodevices displaying intelligent ion transport properties similar to those observed in biological ion channels have attracted increasing interests for their wide potential applications in biosensors, nanofluidics, and energy conversions. Here, bioinspired asymmetric shaped nanodevices are reported that can exhibit symmetric and linear pH‐gating ion transport features based on polyelectrolyte‐asymmetric‐functionalized asymmetric hourglass‐shaped nanochannels. The pH‐responsive polymer brushes grafted on the inner channel surface are acted as a gate that open and close in response to external pH changing to linearly and symmetrically regulate transmembrane ionic currents of the channel. A complete experimental characterization of the pH‐dependent ion transport behaviors of the nanodevice and a comprehensive discussion of the experimental results in terms of theoretical simulation are also presented. Both experimental and theoretical data shown in this work demonstrate the feasibility of using the asymmetric chemical modification method to achieve symmetric pH gating behaviors inside the asymmetric nanochannels, and lay the foundation to build diverse stimuli‐gated artificial asymmetric shaped ion channels with symmetric gating ion transport features. 相似文献
4.
Yanbing Zhang Fengyu Li Xian Kong Tangyue Xue Dan Liu Pan Jia Lili Wang Liping Ding Huanli Dong Diannan Lu Lei Jiang Wei Guo 《Advanced functional materials》2020,30(4)
2D‐material‐based membranes with densely packed sub‐nanometer‐height fluidic channels show exceptional transport properties, and have attracted broad research interest for energy‐, environment‐, and healthcare‐related applications. Recently, light‐controlled active transport of ionic species in abiotic materials have received renewed attention. However, its dependence on inhomogeneous or site‐specific illumination is a challenge for scalable application. Here, directional proton transport through printed asymmetric graphene oxide superstructures (GOSs) is demonstrated under full‐area illumination. The GOSs are composed of partially stacked graphene oxide multilayers formed by a two‐step direct ink writing process. The direction of the photoinduced proton current is determined by the position of top graphene oxide multilayers, which functions as a photogate to modulate the horizontal ion transport through the beneath lamellar nanochannels. This transport phenomenon unveils a new driving mechanism that, in asymmetric nanofluidic structures, the decay of local light intensity in depth direction breaks the balance of electric potential distribution in horizontal direction, and thus generates a photoelectric driving force for ion transport. Following this mechanism, the GOSs are developed into photonic ion transistors with three different gating modes. The asymmetrically printed photonic‐ionic devices provide fundamental elements for light‐harvesting nanofluidic circuits, and may find applications for artificial photosynthesis and artificial electric organs. 相似文献
5.
Osmotic Power Generation with Positively and Negatively Charged 2D Nanofluidic Membrane Pairs
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Jinzhao Ji Qian Kang Yi Zhou Yaping Feng Xi Chen Jinying Yuan Wei Guo Yen Wei Lei Jiang 《Advanced functional materials》2017,27(2)
In nature, hierarchically assembled nanoscale ionic conductors, such as ion channels and ion pumps, become the structural and functional basis of bioelectric phenomena. Recently, ion‐channel‐mimetic nanofluidic systems have been built into reconstructed 2D nanomaterials for energy conversion and storage as effective as the electrogenic cells. Here, a 2D‐material‐based nanofluidic reverse electrodialysis system, containing cascading lamellar nanochannels in oppositely charged graphene oxide membrane (GOM) pairs, is reported for efficient osmotic energy conversion. Through preassembly modification, the surface charge polarity of the 2D nanochannels can be efficiently tuned from negative (?123 mC m?2) to positive (+147 mC m?2), yielding strongly cation‐ or anion‐selective GOMs. The complementary two‐way ion diffusion leads to an efficient charge separation process, creating superposed electrochemical potential difference and ionic flux. An output power density of 0.77 W m?2 is achieved by controlled mixing concentrated (0.5 m ) and diluted ionic solutions (0.01 m ), which is about 54% higher than using commercial ion exchange membranes. Tandem alternating GOM pairs produce high voltage up to 2.7 V to power electronic devices. Besides simple salt solutions, various complex electrolyte solutions can be used as energy sources. These findings provide insights to construct cascading nanofluidic circuits for energy, environmental, and healthcare applications. 相似文献
6.
Organic/Inorganic Hybrid Nanochannels Based on Polypyrrole‐Embedded Alumina Nanopore Arrays: pH‐ and Light‐Modulated Ion Transport
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Qianqian Zhang Zhaoyue Liu Kefeng Wang Jin Zhai 《Advanced functional materials》2015,25(14):2091-2098
Inspired by the asymmetric structure and responsive ion transport in biological ion channels, organic/inorganic hybrid artificial nanochannels exhibiting pH‐modulated ion rectification and light‐regulated ion flux have been constructed by introducing conductive polymer into porous nanochannels. The hybrid nanochannels are achieved by partially modifying alumina (Al2O3) nanopore arrays with polypyrrole (PPy) layer using electrochemical polymerization, which results in an asymmetric component distribution. The protonation and deprotonation of Al2O3 and PPy upon pH variation break the surface charge continuity, which contributes to the pH‐tunable ion rectification. The ionic current rectification ratio is affected substantially by the pH value of electrolyte and the pore size of nanochannels. Furthermore, the holes (positive charges) in PPy layer induced by the cooperative effect of light and protons are used to regulate the ionic flux through the nanochannels, which results in a light‐responsive ion current. The magnitude of responsive ionic current could be amplified by optimizing this cooperation. This new type of stimuli‐responsive PPy/Al2O3 hybrid nanochannels features advantages of unique optical and electric properties from conducting PPy and high mechanical performance from porous Al2O3 membrane, which provide a platform for creating smart nanochannels system. 相似文献
7.
Hashimoto T. Nakasuga Y. Yamada Y. Terui H. Yanagisawa M. Akahori Y. Tohmori Y. Kato K. Suzuki Y. 《Lightwave Technology, Journal of》1998,16(7):1249-1258
A two-step bonding technique for optical device assembly on a planar lightwave circuit platform was developed, which consists of a chip-by-chip thermo-compression prebonding step and a simultaneous reflow bonding step. The technique was used to realize multichip optical integration on the platform. The characteristics of the bonding technique were examined by investigating its strength and accuracy. The bonding accuracies in the horizontal and vertical directions were 1.1 and 0.8 μm, respectively, with high bonding strength. The technique was first applied to a 3 chip integrated transceiver module and the 136 fabricated modules exhibited good performance. The average coupling loss between the laser diodes and the waveguide was estimated to be 4.1 dB and stable characteristics were observed during 1200 cycle thermal shock tests between -40 and 85°C. Next, the two-step bonding technique was used for a 4 channel laser diode module on which 8 optical device chips were integrated and a low coupling loss was achieved of better than 4.2 dB which is as good as that of the 3 chip integrated optical modules 相似文献
8.
Cheng‐Yong Li Feng‐Xiang Ma Zeng‐Qiang Wu Hong‐Li Gao Wen‐Ting Shao Kang Wang Xing‐Hua Xia 《Advanced functional materials》2013,23(31):3836-3844
A new ionic current rectification device responsive to a broad range of pH stimuli is established using highly ordered nanochannels of porous anodic alumina membrane with abrupt surface charge discontinuity. The asymmetric surface charge distribution is achieved by patterning the nanochannels with surface amine functional groups at designed positions using a two‐step anodization process. Due to the protonation/deprotonation of the patterned amine and the remaining intrinsic hydroxyl groups upon solution pH variation, the nanochannel‐array‐based device is able to regulate ion transport selectivity and has ionic current rectification properties. The rectification ratio of the device is mainly determined by the nanochannel size, and the rectification ratio is less sensitive to the patterned length of the amine groups when the nanochannels size is defined. Thus, the isoelectric point of nanochannels can be easily estimated to be the pH value with a unit rectification ratio. The present ionic device is promising for biosensing, molecular transport and separation, and drug delivery in confined environments. 相似文献
9.
This paper reports the realization and RF modeling of flexible microwave P-type-Intrinsic-N-type (PIN) diodes using transferrable single-crystalline Si nanomembranes (SiNMs) that are monolithically integrated on low-cost, flexible plastic substrates. With high-energy, high-dose ion implantation and high-temperature annealing before nanomembrane release and transfer process, the parasitic parameters (i.e. resistance, inductance, etc.) are effectively reduced, and the flexible PIN diodes achieve good high-frequency response. With consideration of the flexible device fabrication, structure and layout configuration, a RF model of the microwave single-crystalline Si nanomembrane PIN diodes on plastic substrate is presented. The RF/microwave equivalent circuit model achieves good agreement with the experimental results of the single-crystalline SiNM PIN diodes with different diode areas, and reveals the most influential factors to flexible diode characteristics. The study provides guidelines for properly designing and using single-crystalline SiNMs for flexible RF/microwave diodes and demonstrates the great possibility of flexible monolithic microwave integrated systems. 相似文献
10.
介绍采用混合贴装倒扣二极管技术制造的新型24GHz平衡混频器,并对该混频器进行设计、仿真、加工和测试,它能提供中频100kMz时小于10dB的变频损耗,本振与信号之间优于35dB的隔离度,其结构特点利于大批量、低成本生产,适合汽车电子系统的需求。 相似文献
11.
Cédric Martin Olivier Crosnier Richard Retoux Daniel Bélanger Donald M. Schleich Thierry Brousse 《Advanced functional materials》2011,21(18):3524-3530
Multi‐walled carbon nanotube (MWCNT)/silicon nanocomposites obtained by a grafting technique using the diazonium chemistry are used to prepare silicon negative electrodes for lithium‐ion batteries. The covalent bonding of the two compounds is obtained via mono‐ and multi‐layers of phenyl bridges, leading to an ideal dispersion of MWCNTs and silicon nanoparticles that are bound together. The presence of MWCNTs close to silicon nanoparticles enhances the electronic pathway to the active material particles and probably helps to prevent silicon decrepitation upon repeated lithium insertion/extraction by improving the mechanical stability of the electrode at a nanoscale level. This effect results in the enhancement of cycling ability and capacity, which are demonstrated by comparing the nanocomposite electrode to a simple mixture of the two compounds. This technique can be applied to other carbon conductive additives together with silicon or other nanosized active compounds. 相似文献
12.
In Situ Synthesis of Bipyramidal Sulfur with 3D Carbon Nanotube Framework for Lithium–Sulfur Batteries
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Lina Wang Yu Zhao Morgan L. Thomas Hye Ryung Byon 《Advanced functional materials》2014,24(15):2248-2252
A one‐pot synthesis of three‐dimensional carbon nanotube frameworks with bipyramidal sulfur particles and the application of these materials for a cathode in lithium–sulfur (Li–S) battery are reported. By simple mixing of multi‐walled carbon nanotubes (MWCNTs), sulfur powder, and capping agents in water/tetrahydrofuran, micrometer bipyramidal sulfur particles enclosed with MWCNTs are synthesized. The MWCNTs spontaneously form a 3D conducting network inside and outside the sulfur particle. Along the edge of MWCNT framework, a sulfur particle‐free region is present, which comprises ≈35 vol% based on the total volume. These sulfur‐MWCNT bipyramidal particles are mixed with conductive carbon additive to prepare binder‐free cathode for Li–S cells. The Li–S cells deliver a specific discharge capacity of ≈1600 mAh g?1 at 0.05 C on the first cycle. In particular, these Li–S cells show high rate stability and Coulombic efficiency with deep discharge and charge (1.0–3.0 V vs Li/Li+). This resultant performance can arise from 1) homogeneous distribution of the conducting MWCNT framework and the carbon additive coating layer on the sulfur particle, which allow rapid Li+ ion/electrolyte diffusion and mitigation of polysulfide shuttle, respectively, and 2) the sulfur‐free buffer space accommodating volume expansion. It is expected that this new cathode design with the simple synthetic process can reduce the number of preparation steps, thus allowing the construction of a low‐cost Li–S battery. 相似文献
13.
Liuxuan Cao Feilong Xiao Yaping Feng Weiwei Zhu Wenxiao Geng Jinlei Yang Xiaopeng Zhang Ning Li Wei Guo Lei Jiang 《Advanced functional materials》2017,27(9)
Recent advances in materials science and nanotechnology have lead to considerable interest in constructing ion‐channel‐mimetic nanofluidic systems for energy conversion and storage. The conventional viewpoint suggests that to gain high electrical energy, the longitudinal dimension of the nanochannels (L) should be reduced so as to bring down the resistance for ion transport and provide high ionic flux. Here, counterintuitive channel‐length dependence is described in nanofluidic osmotic power generation. For short nanochannels (with length L < 400 nm), the converted electric power persistently decreases with the decreasing channel length, showing an anomalous, non‐Ohmic response. The combined thermodynamic analysis and numerical simulation prove that the excessively short channel length impairs the charge selectivity of the nanofluidic channels and induces strong ion concentration polarization. These two factors eventually undermine the osmotic power generation and its energy conversion efficiency. Therefore, the optimal channel length should be between 400 and 1000 nm in order to maximize the electric power, while balancing the efficiency. These findings reveal the importance of a long‐overlooked element, the channel length, in nanofluidic energy conversion and provide guidance to the design of high‐performance nanofluidic energy devices. 相似文献
14.
15.
Light‐Gating Titania/Alumina Heterogeneous Nanochannels with Regulatable Ion Rectification Characteristic
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Qianqian Zhang Ziying Hu Zhaoyue Liu Jin Zhai Lei Jiang 《Advanced functional materials》2014,24(4):424-431
Bioinspired artificial nanochannels exhibiting ion transport properties similar to biological ion channels have been attracting some attention for biosensors, separation technologies, and nanofluidic diodes. Herein, an easily available artificial heterogeneous nanochannel shows both ion gating and ion rectification characteristics when irradiated by ultraviolet light. The fabrication of heterogeneous nanochannels includes the coating of an anatase TiO2 porous layer on an alumina porous supporter, followed by a chemical modification with octadecyltrimethoxysilane (OTS) molecules. The irreversible decomposition of OTS molecules by TiO2 photocatalysis under ultraviolet light results in a change of surface wettability and an asymmetric distribution of surface negative charges simultaneously, which contributes to the ion gating and ion rectification. The asymmetric distribution of negative charges in the TiO2 porous layer can be controlled by the irradiation time of ultraviolet light, which regulates the ion rectification characteristic. 相似文献
16.
Defa Wang Jayanta K Baral Haiguang Zhao Belete Atomsa Gonfa Vo‐Van Truong My Ali El Khakani Ricardo Izquierdo Dongling Ma 《Advanced functional materials》2011,21(21):4010-4018
A solution‐processed nanoarchitecture based on PbS quantum dots (QDs) and multi‐walled carbon nanotubes (MWCNTs) is synthesized by simply mixing the pre‐synthesized high‐quality PbS QDs and oleylamine (OLA) pre‐functionalized MWCNTs. Pre‐functionalization of MWCNTs with OLA is crucial for the attachment of PbS QDs and the coverage of QDs on the surface of MWCNTs can be tuned by varying the ratio of PbS QDs to MWCNTs. The apparent photoluminescence (steady‐state emission and fluorescence lifetime) “quenching” effect indicates efficient charge transfer from photo‐excited PbS QDs to MWCNTs. The as‐synthesized PbS‐QD/MWCNT nanoarchitecture is further incorporated into a hole‐conducting polymer poly(3‐hexylthiophene)‐(P3HT), forming the P3HT:PbS‐QD/MWCNT nanohybrid, in which the PbS QDs act as a light harvester for absorbing irradiation over a wide wavelength range of the solar spectrum up to near infrared (NIR, ≈1430 nm) range; whereas, the one‐dimensional MWCNTs and P3HT are used to collect and transport photoexcited electrons and holes to the cathode and anode, respectively. Even without performing the often required “ligand exchange” to remove the long‐chained OLA ligands, the built nanohybrid photovoltaic (PV) device exhibits a largely enhanced power conversion efficiency (PCE) of 3.03% as compared to 2.57% for the standard bulk hetero‐junction PV cell made with P3HT and [6,6]‐Phenyl‐C61‐Butyric Acid Methyl Ester (PCBM) mixtures. The improved performance of P3HT:PbS‐QD/MWCNT nanohybrid PV device is attributed to the significantly extended absorption up to NIR by PbS QDs as well as the effectively enhanced charge separation and transportation due to the integrated MWCNTs and P3HT. Our research results suggest that properly integrating QDs, MWCNTs, and polymers into nanohybrid structures is a promising approach for the development of highly efficient PV devices. 相似文献
17.
Subharmonically Pumped Millimeter-Wave Mixers 总被引:1,自引:0,他引:1
《Microwave Theory and Techniques》1978,26(10):706-715
The two-diode subharmonically pumped stripline mixer has a pair of diodes shunt mounted with opposite polarities in a stripline circuit between the signal and local oscillator inputs. The circuit has low noise and conversion loss and substantial AM local oscillator noise cancellation.The local oscillator frequency is about half the signal frequency. A novel diode chip, the notch-front diode, which has ohmic contacts on the chip faces adjacent the face containing the diode junctions, was developed for these circuits. The notch-front diode permits the low parasitic reactance of the waveguide diode mount to be achieved in stripline circuits. The best performance for a two-diode subharmonically pumped mixer with notch-front diodes was a 400 K mixer noise temperature, obtained at 98 GHz which is comparable to the best fundamental mixers in this frequency range. The performance over a 47-110-GHz frequency range for this circuit with commercial beam-lead diodes is also presented. 相似文献
18.
Rong Wu Junran Hao Yanshuai Cui Jiale Zhou Danying Zhao Shangtao Zhang Jian Wang Yahong Zhou Lei Jiang 《Advanced functional materials》2023,33(4):2208095
Biomimetic smart nanochannels can regulate ion transport behavior responsive to the external stimuli, having huge potential in nanofluidic devices, sensors and energy conversion. Field-effect nanofluidic diodes or transistors based on electric-responsive nanochannels are emerging owing to their advantages such as non-invasiveness, in situ, real time, and high efficiency. However, simultaneously realizing the voltage-control of the ion conductance and ion current rectification (ICR) properties is still a big challenge. Here, a field-effect iontronic device is developed based on ionomer/anodic aluminum oxide/conducting polymer sandwich-structured nanochannel to realize the multi-control of ion transport behaviors including ion conductance, ICR magnitude, and ICR direction by modulating the surface charge, wettability, and morphology of the nanochannel. The electroactive conducting polymer carries tunable surface charges responsive to the electric stimuli, leading to the regulation of ICR values. The complex three-segment structures lead to the reverse of ICR direction by reconfiguring the charge distribution along with the whole channel. The switching wettability between hydrophilic and hydrophobic results in the regulation of ion conductance. Furthermore, the field-effect iontronic device functions in a wide salinity range especially in hypersaline environment, due to the salinity-adaptive properties of the membrane. A new route is provided for designing more functional field-effect nanofluidic devices. 相似文献
19.
Size‐Scalable and High‐Density Liquid‐Metal‐Based Soft Electronic Passive Components and Circuits Using Soft Lithography
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Min‐gu Kim Hommood Alrowais Spyridon Pavlidis Oliver Brand 《Advanced functional materials》2017,27(3)
The use of conducting liquids with high electrical conductivity, such as eutectic gallium–indium (EGaIn), has great potential in electronics applications requiring stretchability and deformability beyond conventional flexible electronics relying on solid conductors. An advanced liquid metal thin‐line patterning process based on soft lithography and a compatible vertical integration technique are presented that enable size‐scalable and high‐density EGaIn‐based, soft microelectronic components and circuits. The advanced liquid metal thin‐line patterning process based on poly(dimethylsiloxane) (PDMS) substrates and soft lithography techniques allows for simultaneous patterning of uniform and residue‐free EGaIn lines with line width from single micrometers to several millimeters at room temperature and under ambient pressure. Using this fabrication technique, passive electronic components and circuits are investigated under elastic deformations using numerical and experimental approaches. In addition, soft through‐PDMS vias with high aspect ratio are demonstrated for multilayer interconnections in 2.5D and 3D integration approaches. To highlight the system‐level potential of the patterning technique, a chemical sensor based on an integrated LC resonance circuit with a microfluidic‐tunable interdigitated capacitor and a planar spiral inductor is fabricated and characterized. Finally, to show the flexibility and stretchability of the resulting electronics, circuits with embedded light emitting diodes (LEDs) are investigated under bending, twisting, and stretching deformations. 相似文献
20.
Zhenxian Liang Bing Lu van Wyk J.D. Lee F.C. 《Power Electronics, IEEE Transactions on》2005,20(3):679-686
A Si CoolMOS field effect transistor and SiC diode assembly with gate driver in boost configuration (ratings at 600V/12A), for power factor correction application, has been fabricated in a version of an integrated power electronic module. It uses the so-called embedded power technology, to form a three-dimensional multiple chip/component interconnection with the embedded chips in a co-planar ceramic substrate with thin-film metallization bond/interconnection added on top. In this paper, the switching parameters of this module and their effects on the performance of a converter have been analyzed and experimentally characterized. The procedures adopted for the defined fabrication process of planar metallization interconnects are presented. In addition to the improvement of structural electrical properties, compared to a conventional discrete version, the characteristics of the planar process integration have also been demonstrated. 相似文献