Composites were prepared by impregnating commercial nonwoven and unidirectional flax fibers mats, with a mimosa tannin/hexamine resin without addition of NaOH as it was described in previous papers and with improved results. The influence of various parameters was observed: the curing cycle including temperature, time, pressure, the moisture content, and the number of fiber mats the composites were made of. A new two-step method was investigated: full drying of the pre-impregnated mats for storage first and then rehydratation just before pressing. The composites obtained gave good modulus of elasticity and tensile strength in traction as well as a good resistance to water swelling for composites prepared with 50% matrix resin/50% natural fibers. Best results appear to be obtained using a slow curing at low temperature (130?°C for 35?min) with moisture content of 20% on dry material. 相似文献
The parameters affecting the packing stress of fiber mats for melt impregnation, resin transfer molding and compression molding are systematically investigated. An analytical equation based on local bending of fibers, which was previously derived for non‐impregnated networks, is applied to composite mats of dispersed planar bundles impregnated with molten polypropylene. It is shown that many simultaneous mechanisms interact during packing of impregnated bundle mats, in particular when the mats are needled. These include in‐plane bending of the bundles, compaction of the fibers within a bundle, and buckling, slippage or breakage of the out‐of‐plane fibers. In order to identify and decouple these features, aspect ratio of the bundles, lubrication, needling intensity and packing history are varied. A microstructural experiment is also developed to evaluate the extent of bundle spreading. It is found that dispersed fibers or bundles roughly follow the equation based on local bending, but that needled bundle networks deviate from the power law behavior. Three regions were identified. The first is attributed to self‐loading of the mats and to buckling of the out‐of plane fibers. The second region is due to slippage and breakage of the out‐of‐plane fibers and depends on the loading history and on the needling intensity. The third region is due to packing of the in‐plane bundles, which do not really bend, or spread under load, but are locally compressible, owing to misalignment and waviness of the individual fibers forming the bundles. In compression molding, the influence of the in‐plane reorientation of the initially out‐of‐plane bundles on the packing stress is observed. 相似文献
Process simulation forms an important part of the design loop for parts manufactured by liquid composite molding. Critical to this is the determination of accurate permeability data. While constitutive models and test methods for determination of in-plane permeability of mats and fabrics exist, these do not take account of the effects of changes in fiber architecture during preform manufacture. The deformation behavior of mats and fabrics is reviewed, leading to fiber architecture predictions based upon deformed geometry. Existing models are applied to estimate the distribution of in-plane permeabilities within the preform based upon the predicted fiber architecture. The predictions are compared with test results for pre-stretched and pre-sheared reinforcements, and the method is demonstrated for two prototype automotive parts. 相似文献
The use of natural fibers as reinforcing filler in thermoplastics is a relatively new application and has great potential in replacing glass fiber products in automotive industry. However, most of the research in this area has been focused primarily on flax fiber. In the first part of the work presented here, hemp fiber non‐woven mats are used exclusively in combination with a poly(propylene) matrix to study the mechanical properties of natural fiber mat thermoplastics (NMT) in the absence of binder. Film stacking was used as the method of preparation. The results show that hemp‐based NMT have comparable or even higher strength properties as compared with conventional flax‐based thermoplastics. A value of 63 MPa for the flexural strength is achieved at a fiber content of 64 wt.‐%. The influence of the compression ratio on the mechanical properties and density of NMT is also reported. A definite increase in strength is observed with increasing compression together with a much more uniform density profile. In the second part of this study, a unique combination of random hemp fibers, non‐woven mats and poly(propylene) films was employed in film stacking to evaluate strength properties and economic implications. The same fiber content (64 wt.‐%) was maintained in the final NMT by replacing 78 wt.‐% of the mats by random fibers. Preliminary tests reveal better mechanical properties especially in terms of impact energy, which is 50 to 100% higher, as compared with different mats‐only/poly(propylene) combinations. Further, a net saving of 40% in fiber cost is anticipated by replacing 78% non‐woven mats with an equivalent amount of random fibers. Overall results of this study indicate that hemp‐based NMT are promising candidates in automotive applications where high specific stiffness is required.
This work presents the results of numerical simulation and experimental visualization of the mold filling process in resin injection molding with preplaced fiber mats. The mold filling experiments were conducted with various mat stacks consisting of continuous random glass fiber mats and bidirectional stitched glass fiber mats. The use of two different mat types in the mat stack created porosity and permeability variations. The effect of these permeability variations was studied by taking flow pressure measurements and observing the progress of the flow front of a non-reactive fluid filling a clear acrylic mold that contained the reinforcement mat stack. Numerical simulation corresponding to each experiment was also carried out. The numerical results were compared to the experimental measurements. 相似文献
Solid preceramic polyaluminasilazane was synthesized through the reaction between liquid cyclosilazane and aluminum tri-sec-butoxide at 160°C. Electrospinning of polyaluminasilazane/polyethyleneoxide (1/0.0001 mass ratio) in chloroform solutions generated smooth fibers while the electrospun fibers from the chloroform/ N,N -dimethylformamide solutions had submicrometer structures on the fiber surfaces. Smooth and rough SiCNO ceramic fibers were obtained by the pyrolysis of the green fibers with an 80% yield. Superhydrophobic mats of ceramic fibers were fabricated via a chemical vapor deposition of perfluorosilane onto the rough fibers. These superhydrophobic mats possess good chemical and thermal stability. 相似文献
The effects of oxyen plasma treatment on the surface chemistry of Spectra 1000® high modulus polyethylene fibers and on the mechanical properties of fiber-reinforced composites of the fibers in a Bis-GMA based acrylic resin have been studied. X-ray photoelectron spectroscopy and diffuse reflectance FTIR spectroscopy have been used to show that the majority of oxygen on the fiber surface exists mostly in the form of ether and/or epoxy linkages, with carbonyl-, carboxylic- and ester-containing compounds accounting for less than 10 percent of the total. While the untreated and plasma-treated fibers have similar chemical compositions, the surfaces of the plasma-treated fibers are more polar and the oxygen is chemically bonded instead of being merely physisorbed. The interfacial shear strength between the fibers and the acrylic resin is increased by a factor of 2.3 by the plasma treatment indicating the presence of a weak boundary layer on the surface of the untreated fibers. The hydrolytic stability of the composite interfaces was investigated for fibers sized with several Bis-GMA-based adhesives. Maximum stability was attained by sizing with Bis-GMA containing a peroxide catalyst or an amine accelerator. The flexural properties of composites utilizing plasma-treated and untreated fibers were compared in three-point bending. The ultimate bending loads for composites using treated fibers were much higher than those for composites with untreated fibers, but only a fraction of that for glass or Kevlar®-reinforced materials. 相似文献
Thin coatings of poly(acrylic acid) (PAA) and poly(hydroxyethylmethacrylate) (PHEMA) were deposited onto carbon fibers by means of the electrospray ionization (ESI) technique in ambient air. These high-molecular weight polymer layers were used as adhesion promoters in carbon fiber–epoxy resin composites. Within the ESI process, the carbon fibers were completely enwrapped with polymer in the upper 10 plies of a carbon fiber roving. As identified with scanning electron microscopy also shadowed fibers in a bundle as well as backsides of fiber rovings were pinhole-free coated with polymers (‘electrophoretic effect’). Under the conditions used, the layers have a granular structure. Residual solvent was absent in the deposit. PAA and PHEMA films did not show any changes in composition and structure in comparison with the original polymers as analyzed by X-ray photo-electron spectroscopy and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Single-fiber pullout tests of coated fibers embedded in epoxy resin showed significantly increased interfacial shear strength. It is assumed that chemical bonds between carbon fiber poly(acrylic acid) and epoxy resin contribute significantly to the improved interactions. 相似文献
A process has been developed which allows the preparation of some solid ceramic fibers. In this process, activated carbon fibers which are porous throughout their entire diameter are impregnated with metal-containing solutions such as silicon tetrachloride. Calcination and sintering result in the formation of solid SiO2 fibers. Use of woven mats or nonwoven felts of activated carbon fibers results in the formation of woven mats or nonwoven felts of silica fibers. 相似文献