Removal of Zn2+ from Electroplating Wastewater Using Modified Wood Sawdust and Sugarcane Bagasse

This paper describes the preparation of new adsorbents derived from sugarcane bagasse and wood sawdust (Manilkara sp.) to remove zinc (II) ions from electroplating wastewater. The first part deals with the chemical modification of sugarcane bagasse and wood sawdust, using succinic anhydride to introduce carboxylic acid functions into the material. The obtained materials (modified sugarcane bagasse MB2 and modified wood sawdust MS2) were then characterized by infrared spectroscopy (IR) and used in adsorption experiments. The adsorption experiments evaluates Zn2+ removal from aqueous single metal solution and real electroplating wastewater on both batch and continuous experiments using fixed-bed columns prepared in laboratorial scale with the obtained adsorbents. Adsorption isotherms were then developed using Langmuir model and the Thomas kinetic model. The calculated Zn2+ adsorption capacities were found to be 145?mg/g for MS2 and 125?mg/g for MB2 in single metal aqueous solution, whereas for the industrial wastewater these values were 61?mg/g for MS2 and 55?mg/g for MB2.     

Analisys of Electric Arc Furnace Slag

The black slag produced during the melting process in electric arc furnace can be used as adjunct in the operation of land filling, building operation of road grounds, and production of concrete. Their use limitation is due to the presence of polluting chemical elements, including Cr, Ba, V, Mo, etc, that can be dangerous for human and environment, resulting by using of polluted scraps (i.e., painted, lubricated, or polymeric compound scraps). The release extent of polluting elements appears to behave as a function of the constituent phases, i.e., CaO, SiO₂, Al₂O₃, MgO, etc. The main tools employed in the characterization of the black slag consists in optical basicity calculation, SEM‐EBS and SEM‐EDS analysis. The combination of the data coming from chemical analysis, micro‐structural examination and releasing tests allows to identify the correct chemical range avoiding dangerous chemical release and to develop a working disposal procedure for the investigated slag.     

Methodological Aspects of Using Blast Furnace Slag for Wastewater Phosphorus Removal

Blast furnace (BF) slag is a by-product of steel plants. The objective of this study was to evaluate experimental methods to determine the phosphorus sorption capacity of BF slag. The handling of BF slag, before usage and clogging were also considered, as well as estimating the phosphorus retention capacity. Agitation and pilot-scale experiments were performed using both wastewater and phosphate solutions. This investigation showed that sorption capacities derived by wastewater experiments were considerably lower compared to those by phosphate solutions. Fresh BF slag briefly exposed to rainfall had a higher phosphorus sorption than weathered BF slag, indicating the importance of handling the slag carefully before usage. The risk for leakage of sulfuric compounds is considerable, especially during the initial operation phase of BF slag filters. Locations of BF slag filter beds for wastewater treatment must be carefully chosen from an environmental point of view.     

Enhanced Biological Phosphorus Removal Performance and Microbial Population Changes at High Organic Loading Rates

A laboratory-scale sequencing batch reactor was operated and the dynamics of Rhodocyclus-related phosphorus-accumulating organisms (PAOs) population was monitored. After the system reached a steady state and showed a stable enhanced biological phosphorus removal status, the organic loading rate was increased from 160 to 1,020?g?COD?m?3?cycle?1 in five steps. When the P storage capacity reached maximum at 330?g?COD?m?3?cycle?1, the system lost the stability and the effluent phosphorus concentration fluctuated. As the organic loading rate increased from 160 to 1,020?g?COD?m?3?cycle?1, the PAO population decreased from 83.8±4.9 to 32.2±16.2% and internal polyphosphate content decreased from 0.20 to 0.03?mg?P?mg?VSS?1. Phosphate-accumulating metabolism was weakened as the organic loading rate increased and PAO population decreased concomitantly, whereas glycogen-accumulating metabolism increased at high organic loading rates as supported by the increased intracellular glycogen content and production of a higher fraction of intracellular poly-β-hydroxyl valerate.     

Escherichia coli Removal Efficacy of a Marshland Upwelling System

The Marshland Upwelling System (MUS), a decentralized wastewater treatment strategy for coastal dwellings, was examined to assess its ability to remove Escherichia coli from raw sewage as a step towards total treatment. Wastewater was intermittently injected down a 4.6-m injection well into the surrounding salt marsh at 0.9, 1.9, and 3.8 lpm over the 13-month evaluation period. Optimal E. coli removal and hydraulic performance was achieved at the 1.9-lpm flow rate with influent concentrations of 260,000±370,000 E. coli/100 mL reduced to a mean effluent count of 0.4±10.6 E. coli/100 mL. Escherichia coli concentrations declined exponentially with only 0.9-m travel distance needed to reduce influent concentrations by 1 order of magnitude. Predicted surface concentrations were less than 1 E. coli/100 mL. The probability of effluent counts exceeding the U.S. Environmental Protection Agency standard of 126 E. coli/100 mL for recreational waters was 5.5×10?12%. Increasing flows to 3.8 lpm initiated localized hydraulic dysfunction as indicated by elevated injection pressures and transient increases in bacterial counts. Based on these findings, the MUS can provide an effluent of acceptable bacterial quality under specified operating parameters and the site-specific hydrogeological conditions analyzed.     

Optimization of Biological Nutrient Removal in a Membrane Bioreactor System

The main objective of the present study is to develop a modified membrane bioreactor (MBR) system for the treatment of municipal wastewater for the enhanced biological removal of nitrogen (N) and phosphorus (P) simultaneously with the ultimate goal of optimizing the two processes. The paper will address the implementation and optimization of the MBR process with respect to biological characteristics, operational performance, and effluent quality. The system utilizes anoxic P uptake and nitrification–denitrification in a MBR. Following optimization, the system achieved 99% chemical oxygen demand (COD), 98.4% NH3–N, 77.5% TN, and 96.3% P removal producing effluent biological oxygen demand, COD, NH3–N,NO3–N,NO2–N, and P of <3, 3, 0.4, 5.8, 0.050, and 0.18?mg/L, respectively.     

Laboratory Study of Successive Soil Saline Leaching and Electrochemical Lead Recovery

This research is related to a laboratory study on the performance of a successive soil saline leaching and electrochemical lead recovery process for soil decontamination. Erlenmeyer leaching assays showed that the addition of 5.5 mol NaCl/L in 25% (w/w) of soil pulp density maintained at pH 3.0 was found the most effective condition for Pb leaching. Under these conditions, 65% of Pb was leached from soil. Electrochemical treatment using an iron–monopolar electrode system operated at a current intensity of 3.0 A was able to reduce Pb content in soil leachate from 650 to 0.15 mg/L and this without production of metallic residue. Then, a leaching tank reactor and electrolytic cell coupled in a closed loop showed that the Pb mass balance of extrants/intrants ratio indicated 99.0±1.6% of Pb was recovered. Likewise, 94.1% of chloride ions were reused in the leaching tank reactor after electrochemical treatment.     

钢渣热态改质技术在电炉中的应用

采用热态改质的方法,在电炉渣排放源头对其进行改质试验,试验结果表明,原渣碱度降低后,改质渣的上磁率得到显著提高,促进了其铁质组分的回收;同时,磁选后尾渣中游离氧化钙的含量也降低,满足钢渣应用在水泥混凝土行业的国标要求。     

Pretreatment by Fenton Oxidation of an Amoxillin Wastewater

Relatively few reported works have dealt with wastewaters arising from amoxillin manufacture. To develop a treatment process for one such wastewater, several physicochemical methods such as coagulation, ultrafiltration, and Fenton oxidation (FO), have been investigated. Among these methods, FO proved effective. Consequently the method was further investigated to identify the appropriate H2O2/FeSO4 ratio, FeSO4 and H2O2 concentrations, and reaction pH and temperature. In relation to the wastewater, a suitable H2O2/FeSO4 weight ratio was 5:1 (molar ratio: 22.4:1) with H2O2 and FeSO4 concentrations at 20?g/L, 4?g/L, respectively. The corresponding pH range was 2.0–4.0 while the reaction temperature was 60°C. Given these conditions, wastewater total organic carbon was reduced by 48.8–49.4%. After FO treatment, reverse osmosis (RO) effectively reduced the dissolved salt content. The contribution of FO and RO pretreatment improved the wastewater’s biodegradability thus making a downstream biotreatment polishing process viable.     

Removal of Immiscible Contaminants from Sandy Soils Monitored by Means of Dielectric Measurements

The main objective of this paper is to explore the potential application of electromagnetic waves to evaluate the effect of contaminant removal in granular soils. Thus, various specimens of saturated silica sand were prepared using paraffin oil and lubricant oil as contaminants. Four flushing fluids were used to remove the contaminants from sand columns: Deionized water, water-detergent, water-detergent-alcohol solution, and water vapor. Dielectric permittivity was measured at different stages of the removal process at the frequency from 20?MHz?to?1.3?GHz. The measured permittivity was compared with that determined for clean and fully contaminated specimens. A theoretical mixture formula was calibrated and implemented to estimate the volume fraction of contaminant present in the pore fluid. It is concluded in this work that dielectric parameters reflect the contamination level of the soil for the nonpolar organic compounds used here. Measurement of permittivity allows us to determine that the inclusion of alcohol and detergent in the displacing fluid improved the removal efficiency. However, water vapor was the most efficient removal agent.     

Simultaneous Organic and Nutrient Removal in a Naturally Ventilated Biotower Treating Presettled Municipal Wastewater

The performance of a down-flow hanging sponge (DHS) system was continuously evaluated for 1 year for enhancement of organic matter and nutrient removal in the treatment of presettled municipal wastewater. A pilot-scale DHS (24 L) was installed at a wastewater-treatment site and operated at an ambient temperature of 25°C. This paper reports on the results of a long-term monitoring of the system. The DHS system was operated at three different hydraulic retention times (HRTs), i.e., 6, 4, and 2 h. The available results showed that increasing the HRT significantly improved the removal of chemical oxygen demand (COD) fractions. The removal efficiencies of COD were 89, 80, and 56% at HRTs of 6, 4, and 2 h, respectively. Also, ammonia (NH4–N) concentration significantly decreased by increasing the HRT. Ammonia removal percentages of 99, 90, and 72% were achieved when the DHS system was operated at HRTs of 6, 4, and 2 h, respectively, but decreasing HRT exerted a slightly negative effect on the removal of total phosphorous. Scanning electron microscopy observation revealed no clogging of the sponge pores after 12 months of continuous operation. Accordingly, the results suggested that the proposed system may be a competitive solution for municipal wastewater treatment under variable conditions.     

电弧炉的泡沫渣冶炼技术及应用

泡沫渣埋弧操作是电弧炉炼钢的一项新技术．与传统的冶炼工艺相比，该技术具有冶炼时间短、炉衬使用寿命长及电耗低等优点．极具推广价值。     

Optimization of Internal Bypass Ratio for Complete Ammonium and Phosphate Removal in a Dephanox-Type Two-Sludge Denitrification System

The capacity of complete simultaneous ammonium and phosphate removal was studied in a laboratory scale Dephanox system in relation to its internal bypass ratio (BPR). In this configuration, most of the ammonium detected in the effluent is ammonium bypassed by the system’s internal settler. Therefore, this research studies the possibility of complete simultaneous ammonium and phosphate removal by means of the balance of bypassed ammonium with ammonium requirement for growth of denitrifying phosphorus accumulating organisms in the anoxic tank. During these experiments, ammonium removal was governed by internal BPR and limited by sludge settleability. The predominant anaerobic-anoxic sludge developed a high settleability, allowing the application of drastic low BPRs. The system studied under many BPRs proved to achieve almost complete simultaneous ammonium and phosphate removal for BPRs ranging from 0.08 to 0.13 of the influent. A BPR lower than the inferior limit produced extreme accumulation of sludge into the internal settler, interfering in the distribution of sludge and consequently in removal efficiency. A positive effect of the internal settler was the extension of anaerobic contact time and anaerobic solids retention time. The increased phosphorus release suggests that a higher volatile fatty acids production might have occurred when raw wastewater was used as influent.     

Modeling of Nitrate Adsorption and Reduction in Fe0-Packed Columns through Impulse Loading Tests

A conventional tracer study using Li+ and Cl? was conducted on four Fe0-packed column reactors for nitrate removal. Both Li+ and Cl? showed strong adsorption onto iron media and thus were not ideal tracers for the study. Tests using an impulse loading of nitrate were then innovated to investigate the transport and reduction of nitrate in the reactors. The impulse loading was superposed on a continuous constant feeding of nitrate which generated a steady effluent baseline. A multivariable model incorporating hydraulic dispersion, adsorption/desorption, and reduction of nitrate was developed and numerically solved. Both Langmuir adsorption and linear adsorption isotherms were separately applied to describe nitrate adsorption on the reactive surface. The parameters of the model were estimated by fitting the model with the response curves from the impulse loading tests. These estimated parameters were consistent with previous studies. Specifically, the modeling results suggest a significant adsorption of nitrate by the iron media, causing an evident retardation effect. The research may lead to new methods for studying the fate of contaminants in porous reactive environments.     

Seasonal Operation of Ponds for Chemical Precipitation of Wastewater

Wastewater precipitation ponds (fellingsdams) are conventional stabilization ponds adapted to cold climate by the use of chemical precipitation to attain sufficient removal efficiency of impurities, primarily phosphorus. The objective with this investigation was to study the influence of an interruption of the dosage of coagulant during summer periods at two fellingsdam systems (Orrviken and Lockne) in the middle of Sweden. The investigation took place over two years characterized by unusual precipitation conditions; 2001 was intense in precipitation whereas summer 2002 represented a dry season. The results showed that there is a potential to utilize the summer biological activity in fellingsdams. At Orrviken the effluent quality measured as organic matter and phosphorus in the effluent was just slightly above the values that were reached by chemical precipitation. At Lockne the performance was lower. The organic matter reduction at Orrviken in the summers of 2001 and 2002 were 71 and 67%, respectively, compared to previous years using precipitant when the average was 78%. At Lockne, however, the values in the summers of 2001 and 2002 were 36 and 18%, respectively, compared to previous years using precipitant when the average was 55%. The phosphorous reduction at Orrviken in the summers of 2001 and 2002 were 85 and 89%, respectively, compared to previous years using precipitant when the average was 95%; at the Lockne plant, the phosphorous reduction during the summers of 2001 and 2002 were 60 and 66%, respectively, compared to the previous years' average of 86%. The nitrogen reduction varied considerably over the two summer periods. The reduction at Orrviken was 13% in 2001 and 58% in 2002; the reduction at Lockne was 13% in 2001 and 33% in 2002. Reference values of nitrogen reduction during normal operations were not available.     

Phosphorus Treatment Capability of Marshland Upwelling System under High Background Salinity Conditions

The marshland upwelling system (MUS) is an alternative onsite wastewater treatment system developed for coastal communities. The phosphorus treatment efficiency of the MUS operated under high background salinity conditions ( ～ 32?ppt) was examined over the course of a one-year field study. Five individual studies were investigated by intermittently injecting wastewater at a depth of 3.8?m using flow rates/injection frequency regimes of 1.9?L/min (30?min/3?h), 5.5?L/min (30?min/3?h), 2.8?L/min (30?min/3?h), and 2.8?L/min (15?min/h). There were two studies conducted within the 2.8?L/min (30?min/3?h) flow regime: (1) with normal influent and (2) with high strength synthetic wastewater. Over the course of the study, no signs of phosphorus saturation were observed. The overall system efficiency for the entire study was estimated to be >98%. Removal rate coefficients ranged from 0.73–1.25?m?1 and 0.66–1.08?m?1 for total phosphorus and orthophosphate, respectively. Upon completion of the final 2.8?L/min (15?min/h) study, it was determined that a travel distance of only 9.4?m would be needed to reduce influent concentrations below 0.1?mg?P/L.     

70 t电弧炉热兑转炉液态渣的工艺实践

转炉液态渣的碱度(CaO/SiO₂)一般为2.8～4.2,热容2.5 kJ/(kg·℃),进入渣罐后的炉渣温度约为1 540℃,有良好的导电性,可以利用其热能和氧化钙。当70 t电弧炉兑加120 t转炉液态渣8 t,可使平均冶炼周期由52 min降至47 min,电耗由400 kWh/t降至355 kWh/t,石灰加入量由3.6 t降至1.0 t,氧气消耗由28 m~3/t降至25 m~3/t,可有效地节约资源和减少炉渣的排放。     

Contribution of the Estrogen-Degrading Bacterium Novosphingobium sp. Strain JEM-1 to Estrogen Removal in Wastewater Treatment

This study aimed to investigate the contribution to estrogen removal from the activated sludge of an estrogen-degrading bacterium, Novosphingobium sp. Strain JEM-1, isolated by the writers from the activated sludge. The cell numbers of the Strain JEM-1 were investigated in two full-scale wastewater-treatment plants using real-time PCR. Strain JEM-1 appears to be commonly distributed in the activated sludge. The cell numbers of Strain JEM-1 in the oxidation ditch process were higher than those in the conventional activated sludge (CAS) process, and the effluent concentrations of E1 in the CAS process tended to decrease with increased cell numbers of Strain JEM-1. In a bench-scale experiment to investigate bioaugmentation with Strain JEM-1, there was a significant difference in the effluent concentrations of estrogens between the experimental series and the control series. Linear relationships were observed between cell numbers of Strain JEM-1 and the efficiency of removal of estrogens. These results suggest that Strain JEM-1 contributes to the estrogen removal in the activated sludge.     

Simultaneous Removal of Carbon and Nitrogen from Swine Wastewater Using an Immobilized-Cell Reactor

A single-stage phosphorylated polyvinyl alcohol immobilized-cell reactor with three operation modes was employed to investigate the efficiency of simultaneous carbon/nitrogen removal from raw swine wastewater. In continuous aeration mode, the removal efficiency of chemical oxygen demand (COD) and total nitrogen (T-N) exceeded 70 and 8%, respectively, at hydraulic retention time of 10?days. In intermittent aeration (IA) mode, the removal efficiency of COD and T-N was more than 85 and 46%, respectively, when the reactor was set at 50% aeration duration to cycle time to operate at three aerobic-anoxic cycles per day. When oxidation-reduction-potential control was adopted to control the duration of the anoxic period in the real-time controlled (RTC) IA mode for a 4?h aeration period, the total cycle time was reduced by about 20% with a slight increase in removal efficiency of COD (87%) and T-N (47%). The system with no extra chambers required is efficient in simultaneous carbon/nitrogen removal.