Performance of a Bioretention Area and a Level Spreader-Grass Filter Strip at Two Highway Sites in North Carolina

The pollutant removal efficiency of a bioretention area and a level spreader-grass filter strip implemented at North Carolina highway facilities was assessed. The assessment consisted of monitoring inflow, outflow, and on-site rainfall for at least 13 storm events. Monitoring included continuous discharge measurement and collecting and analyzing flow-proportional samples for each event. All samples were analyzed for solids, turbidity, and nitrogen and phosphorus forms and selected samples were analyzed for metals. The level spreader-grass filter strip had the best overall efficiency with load reduction efficiencies in all pollutants ranging from 24 to 83% and the highest reduction for total suspended solids (TSS). Much of the efficiency of this best management practice can be attributed to the 49% reduction in runoff volume from inflow to outflow. Pollutant reduction efficiencies for the bioretention area ranged from ?254 to 76% with the highest reduction for TSS. The lowest or large negative efficiency was for nitrate+nitrite nitrogen (NO2+3–N). The increase in NO2+3–N likely resulted from a combination of nitrogen additions within the cell and conversion of other forms of nitrogen to NO2+3–N. Statistical analyses suggested that all of the mass reductions for the grass filter strip and many of those for the bioretention area were significant.     

Urban Particle Capture in Bioretention Media. I: Laboratory and Field Studies

Bioretention is a novel stormwater best-management practice that uses a mixture of soil/sand/mulch as adsorptive filtration media that can capture both urban particulates and dissolved pollutants while promoting infiltration. This study conducted a series of laboratory column experiments and field observations, which showed that: (1) bioretention media stratification occurs with runoff percolation due to particulate deposition; (2) bioretention filter media are clogging limited, instead of breakthrough limited; and (3) both depth filtration and cake filtration significantly contribute to urban particle capture. Because of the fine size of bioretention media, incoming suspended solids cannot significantly penetrate below 5–10?cm of the media in the column tests and approximately 20?cm in the monitored field facility. Bioretention filters under intermittent flow conditions exhibited higher solids loading capacity (in kg/m2) before clogging than under continuous flow conditions. The clay components in incoming total suspended solids assume critical responsibility for bioretention media clogging. The media resistance due to solids deposition was estimated through Darcy’s law. The hydraulic conductivity of two media types decreased from 54±23 and 72±46?cm/h to less than 10?cm/h due to particle capture. Experimental results suggest that a 20-cm media depth is sufficient for bioretention design and maintenance procedures (media replacement) for runoff particle capture.     

Evaluation and Optimization of Bioretention Media for Treatment of Urban Storm Water Runoff

Bioretention is a relatively new urban storm water best management practice. The objective of this study is to provide insight on media characteristics that control bioretention water management behavior. Eighteen bioretention columns and six existing bioretention facilities were evaluated employing synthetic runoff. In columns, the runoff infiltration rate through different media mixtures ranged from 0.28 to 8.15?cm/min at a fixed 15 cm head. For pollutant removals, the results showed excellent removal for oil/grease (>96%). Total lead removal (from 66 to >98%) decreased when the total suspended solids level in the effluent increased (removed from 29 to >96%). The removal efficiency of total phosphorus ranged widely (4–99%), apparently due to preferential flow patterns, and both nitrate and ammonium were moderate to poorly removed, with removals ranging from 1 to 43% and from 2 to 49%, respectively. Two more on-site experiments were conducted during a rainfall event to compare with laboratory investigation. For bioretention design, two media design profiles are proposed; >96%?TSS, >96%?O/G, >98%?lead, >70%?TP, >9%?nitrate, and >20%?ammonium removals are expected with these designs     

Water Quality Improvement through Reductions of Pollutant Loads Using Bioretention

As an increasingly adopted storm-water best management practice (BMP) to remedy hydrology and water quality impairment from urban development, bioretention facilities need rigorous investigation to quantify performance benefits and to allow design improvements. This study examines water quality improvements [total arsenic, total cadmium, chloride, total chromium, total and dissolved copper, E. coli, fecal coliform, lead, mercury, nitrogen species, oil and grease, phosphorus, total organic carbon (TOC), total suspended solids, and total zinc] via monitoring for a 15-month period at two bioretention cells in Maryland. Both bioretention cells effectively removed suspended solids, lead, and zinc from runoff through concentration reduction. Runoff volume reduction promotes pollutant mass removal and links BMP water quality benefits with hydrologic performance. From a load perspective (kg/ha?year), all but TOC at one cell showed pollutant reduction. Bioretention effluents exhibited good water quality for all significant pollutants except for nitrate, copper, and phosphorus in one cell, the latter two of which may be attributed to media organic matter dissolution. Copper dissolved/particulate analyses showed that significant changes in copper speciation behavior result from transport through the bioretention media.     

Effect of Organic Surface Load on Process Performance of Pilot-Scale Algae and Duckweed-Based Waste Stabilization Ponds

Removal efficiencies in pilot scale algae-based ponds (ABPs) and duckweed-based ponds (DBPs) were assessed during two periods of 4 months each. During Periods 1 and 2, the effect of low and high organic loading was studied. A linear correlation between ponds organic surface loading rates and the corresponding biochemical oxygen demand (BOD) removal rates was observed in both systems. For both periods, higher BOD and total suspended solids (TSS) removal efficiencies were found in DBPs compared to ABPs. Nitrogen removal rates (λr) in ABPs were linearly correlated with BOD surface loading rates (λs,BOD) and nitrogen loading rates (λs,N), while in DBPs, N removal rates were almost constant irrespective of λs,BOD or λs,N. Overall N removal rate in the algae system was significantly higher than that in duckweed system. Organic loading had no effect on total phosphorus removal efficiency in both systems. Higher P removal efficiency was achieved in the duckweed system than in the algae system. In ABPs as well as DBPs, fecal coliforms were better removed during low organic loading in comparison with high organic loading. During the two operational periods, higher fecal coliform removal efficiency in the algae system than in the duckweed system was observed.     

Operational Optimization and Mass Balances in a Two-Stage MBR Treating High Strength Pet Food Wastewater

A two-stage membrane bioreactor (MBR) system was evaluated for the treatment of high strength pet food wastewater characterized by oil and grease, chemical oxygen demand (COD), biochemical oxygen demand (BOD)5, total suspended solids (TSS), total Kjeldahl nitrogen (TKN), NH4–N, and TP concentrations of 2,800, 25,000, 10,000, 4,500, 1,650, 1,300, and 370?mg/L, respectively, to meet stringent surface discharge criteria of BOD5, TSS, and NH4–N of <10?mg/L, and TP of <1?mg/L. Pretreatment of the dissolved air flotation effluent with FeCl3 at a dose of 3.5?g/L, corresponding to a Fe:P molar ratio of 1.3:1 affected TP, TSS, volatile suspended solids (VSS), COD, BOD5, and TKN reductions of 88, 72, 75, 11, 11, 36, and 17%, respectively. The two-stage MBR operating at a total hydraulic retention time of 5.3?days comprising 2.5?days in the first stage and 2.8?days in the second stage, and solids retention time of 25?days in the first stage consistently met the criteria despite wide variations in influent characteristics. Very high COD and BOD5 removal efficiencies of 97.2 and 99.8% were observed in the first stage, with an observed yield of 0.14?gVSS/gCOD. A modular approach for the quantification of simultaneous nitrification denitrification (SND) in the first-stage MBR was developed and verified experimentally. The model indicated that on average, 21% of the influent nitrogen was removed by SND and predicted nitrogen loss with an accuracy of 72%. Complete nitrification of the residual organic nitrogen and ammonia was achieved in the second-stage MBR.     

Effect of In-Lake Water Quality on Pollutant Removal in Two Ponds

An extensive field study examined pollutant removal in two regional wet detention ponds near High Point, N.C. Substantial differences in influent pollutant concentrations between the ponds caused significant differences in pond water quality and pollutant removal efficiency. In Davis Pond, influent fecal coliform and nutrient concentrations were high because of several large dairy farms in the watershed, resulting in hypereutrophic conditions as evidenced by high chlorophyll-a concentrations, high midday pH values and supersaturated midday oxygen concentrations. In Piedmont Pond, influent fecal coliform and nutrient concentrations were much lower, resulting in mesotrophic to slightly eutrophic conditions. Both ponds thermally stratified and developed an anaerobic hypolimnion. In Davis Pond, annual pollutant removal efficiencies for total suspended solids, volatile suspended solids, total organic carbon, total phosphorus, dissolved phosphorus, nitrate∕nitrite, total ammonia nitrogen, and total nitrogen were 56%, 32%, 15%, 41%, 54%, 16%, 2%, and 11%, respectively. In Piedmont Pond, annual pollutant removal efficiencies were 20%, 30%, 27%, 40%, 15%, 66%, ?64%, and 36%, respectively.     

Impacts of Media Depth on Effluent Water Quality and Hydrologic Performance of Undersized Bioretention Cells

Fill media and excavation volume are the main costs in constructing bioretention cells, but the importance and impact of media depth in these systems is relatively unknown. Two sets of loamy-sand-filled bioretention cells of two media depths (0.6?m and 0.9?m), located in Nashville, North Carolina, were monitored from March 2008 to March 2009 to examine the impact of media depth on their performance with respect to hydrology and water quality. Construction and design errors resulted in the surface storage volume being undersized for the design event (2.5?cm). The actual surface storage volume was only 28% and 35% of the design volume for the 0.6-m and 0.9-m media depth cells, respectively. Overflow (bypass) occurred at least three times more frequently than intended. The exfiltration volume was much higher in the deeper media cells, presumably because of greater storage volume in the media and more exposure to side walls. Evapotranspiration (ET) plus exfiltration accounted for 42% of the inflow runoff in the 0.9-m media cells, while ET and exfiltration accounted for only 31% of the inflow runoff in the 0.6-m media cells. With the increase in exfiltration, the deeper media depth met a previously defined low-impact development (LID) hydrology goal of volume reduction more frequently than the shallower media system (44% of events compared to 21%). Larger outflow reduction consequently increased the reduction in pollutant loads. Estimated annual pollutant load reduction for total nitrogen, total phosphorus, and total suspended solids were 21, 10, and 71% for the 0.6-m media cells and 19, 44, and 82% for the 0.9-m media cells, respectively. Overall, nitrogen reduction was poor owing to suspected export of nitrate from the fertilizer use, and phosphorus removal was hampered because of irreducible concentrations in the inflow. Pollutant reduction was limited because the cells were undersized as a result of construction and design errors.     

Use of a Sequencing Batch Reactor for Nitrogen and Phosphorus Removal from Municipal Wastewater

In this study, a suspended growth sequencing batch reactor (SBR) and an attached cum suspended growth SBR were used to investigate the performance characteristics of nitrogen and phosphorus (NP) removal from municipal sewage. The effects of three controlling factors, namely batch loading rate, feed pattern (initial feed or step feed), and mixing/aeration ratio, on NP removal were investigated under nine different experimental conditions. Owing to a large number of possible combinations among the controlling factors and different experimental conditions, it is very difficult to enumerate all the available combinations experimentally. In view of this, the Taguchi method, a cost-effective technique for design of experiments, was exploited for estimating the optimal operating condition. This study also evaluated the difference between the suspended growth SBR and the attached cum suspended growth SBR. The total nitrogen (TN), total phosphorus (TP), total biochemical oxygen demand (TBOD)5, and suspended solids (SS) removal efficiencies were 90.2, 83.9, 98.6, and 93.0%, respectively, for the suspended growth SBR. The corresponding values for the attached cum suspended growth SBR were 92.6, 82.1, 98.3, and 93.1%, respectively. It was observed that the batch loading rate influenced the efficiencies in terms of TN removal. It was also noted that step feed and mixing/aeration ratio had significant impact on TP removal performance. The optimal operating condition for the suspended growth SBR system in terms of batch loading rate, feed pattern, and mixing/aeration ratio were 0.170?mgBOD5/mgMLVSS?d, initial feed, and 1-to-1, respectively. The associated TN, TP, TBOD5, and SS removal efficiencies for the suspended growth SBR were 93.8, 98.2, 99.6, and 98.5%, respectively. The corresponding results for the attached cum suspended growth SBR system were 0.170?mgBOD5/mgMLVSS?d, initial feed, and 3-to-1, respectively. Similarly, the corresponding removal efficiencies for the attached cum suspended growth SBR were 94.7, 97.8, 99.3, and 98.8%, respectively.     

Performance of Wet Weather Treatment Facility for Control of Combined Sewer Overflows: Case Study in Cincinnati, Ohio

Efforts aimed at reducing pollutant loads from combined sewer overflows (CSOs) on the Muddy Creek receiving waters in Cincinnati, Ohio have been underway in recent years. This includes an investigation of the treatment performance of a flow-through wet weather treatment facility (WWTF) using off-line sedimentation tanks, fine screening and chemical disinfection (disinfection was inactive during this study). Calculations using hydrographs and water quality samples collected at the WWTF during rain events established the mass of biochemical oxygen demand (BOD)5, chemical oxygen demand, and total suspended solids (TSS) removed. Ten storm events sampled from January to September 2002 helped characterize pollutant removal efficiencies for flow-through treatment. Pollutant removal was classified into four components: flow to the wastewater treatment plant (WWTP), sedimentation, storage, and screening. Most pollutant removal was achieved through settling and storage in the treatment tanks, with removal efficiencies of 20–50% for BOD5 and 25–70% for TSS commonly observed. Owing to the high pollutant load in the early portion of the CSO hydrograph, first-flush containment, or capturing and conveying the early portion of the runoff event to the WWTP, was the most efficient treatment method for every storm investigated.     

Bioretention Technology: Overview of Current Practice and Future Needs

Bioretention, or variations such as bioinfiltration and rain gardens, has become one of the most frequently used storm-water management tools in urbanized watersheds. Incorporating both filtration and infiltration, initial research into bioretention has shown that these facilities substantially reduce runoff volumes and peak flows. Low impact development, which has a goal of modifying postdevelopment hydrology to more closely mimic that of predevelopment, is a driver for the use of bioretention in many parts of the country. Research over the past decade has shown that bioretention effluent loads are low for suspended solids, nutrients, hydrocarbons, and heavy metals. Pollutant removal mechanisms include filtration, adsorption, and possibly biological treatment. Limited research suggests that bioretention can effectively manage other pollutants, such as pathogenic bacteria and thermal pollution, as well. Reductions in pollutant load result from the combination of concentration reduction and runoff volume attenuation, linking water quality and hydrologic performance. Nonetheless, many design questions persist for this practice, such as maximum pooling bowl depth, minimum fill media depth, fill media composition and configuration, underdrain configuration, pretreatment options, and vegetation selection. Moreover, the exact nature and impact of bioretention maintenance is still evolving, which will dictate long-term performance and life-cycle costs. Bioretention usage will grow as design guidance matures as a result of continued research and application.     

好氧颗粒污泥的培养及处理低碳氮比废水效果

采用"搅拌-曝气-搅拌"间歇曝气运行模式,探索好氧颗粒污泥(AGS)在低碳氮比(1～6)废水中的形成规律及其对污染物的降解效果,旨在为低碳氮比污水的高效处理提供技术支持.当进水碳氮比为1～2.25时,接种污泥表现出明显的不适应,污泥量及颗粒化率增长缓慢,化学需氧量(COD)、总无机氮(TIN)及总磷(TP)的去除率较低...     

Swine Wastewater Treatment Using Submerged Biofilm SBR Process: Enhancement of Performance by Internal Circulation through Sand Filter

Pollutants removal from swine wastewater by a submerged biofilm sequencing batch reactor (BSBR) with internal circulation of liquor through a sand filter was studied. The variation of nutrient removal efficiencies with changes in volumetric circulation ratios and rates were determined. The reactor was operated under the following conditions: One cycle per day, hydraulic retention time of 15 days, average NH4–N loading rate of 55?g?m?3?d?1, and without supplemental external carbon source. System performance was enhanced by conducting internal circulation of liquor through the sand filter. When compared with the performance of a single BSBR without sand filter, nitrogen and phosphorus removal efficiencies were found to increase by 18% and over 33%, respectively. With a circulation rate of 170?L?h?1?m?3, and duration of 22 h (circulation ratio of 0.9), TOC, NH4–N, and total soluble inorganic nitrogen (as NH4–N plus NOx–N) removal efficiencies of 73, 97.8, and 85.6%, respectively, were achieved. The enhancement of nitrogen removal was attributed to the occurrence of denitrification in the sand filter during circulation of liquor. The denitrification rate was proportional to the volumetric circulation ratio per day, resulting in an average 15% NOx–N removal in the sand filter. Also, it was found that continuous circulation during the entire reaction phases could be one way to achieve better performance.     

Evaluating Bioretention Hydrology and Nutrient Removal at Three Field Sites in North Carolina

Three bioretention field sites in North Carolina were examined for pollutant removal abilities and hydrologic performance. The cells varied by fill media type or drainage configuration. The field studies confirmed high annual total nitrogen mass removal rates at two conventionally drained bioretention cells (40% reduction each). Nitrate-nitrogen mass removal rates varied between 75 and 13%, and calculated annual mass removal of zinc, copper, and lead from one Greensboro cell were 98, 99, and 81%, respectively. All high mass removal rates were due to a substantial decrease in outflow volume. The ratio of volume of water leaving the bioretention cell versus that which entered the cell varied from 0.07 (summer) to 0.54 (winter). There was a significant (p<0.05) change in the ratio of outflow volume to inflow volume when comparing warm seasons to winter. Cells using a fill soil media with a lower phosphorus index (P-index), Chapel Hill cell C1 and Greensboro cell G1, had much higher phosphorus removal than Greensboro cell G2, which used a high P-index fill media. Fill media selection is critical for total phosphorus removal, as fill media with a low P-index and relatively high CEC appear to remove phosphorus much more readily.     

Quality of Runoff Leachate Collected from Biosolids and Dairy-Manure Compost-Amended Topsoils

Compost amendment of pavement shoulder subgrades was attempted to mitigate shrinkage cracking, which otherwise would result in severe distress to adjacent pavement infrastructure systems. Two types of composts, biosolids and dairy-manure composts, were evaluated. As a part of this application, the runoff leachate emanating from the compost soils needs to be environmentally assessed as this leachate potentially ends up in storm sewer collection systems. As a part of the research, runoff collection systems were placed in both dairy-manure and biosolids compost-amended soil sections and a control untreated soil section. The collected water samples at various time intervals were then subjected to various chemical and environmental tests, including total suspended and dissolved solids, biochemical and chemical oxygen demand, total Kjeldahl nitrogen (TKN), and phosphorous measurements. This paper presents a summary of these test results from both sections and their comparisons with similar results from another leachate collected from a control or untreated section. These test results are also compared with a few local studies conducted on highway runoff samples and EPA benchmark values. Possible causes for chemical contaminant concentration differences in the leachate samples from both composts are also explained.     

Biological Kinetic Data Evaluation of an Activated Sludge System Coupled with an Ultrafiltration Membrane

A membrane bioreactor (MBR) system treating wastewater containing high molecular weight compounds was operated at solids retention times (SRTs) ranging from 30 to 2 days. Chemical oxygen demand removal efficiencies exceeded 99% and effective nitrification was obtained at SRTs between 30 and 5 days. A significant shift in the biological population structure was observed at the 2 days SRT as the content of gram-negative microorganisms increased and nitrifying bacteria were washed out. At this low SRT, limitations in the biological reaction kinetics resulted in incomplete degradation of the feed protein increasing the presence of soluble organic matter in the effluent. Furthermore, the diluted mixed liquor prevented the formation of a filtration cake on the membrane surface, further deteriorating effluent quality. Biological kinetic data parameters were analyzed using three different representations for biomass: volatile suspended solids, lipid phosphates, and total enzymatic activity. All three indicators exhibited similar trends resulting in very comparable estimates for endogenous decay coefficients, thus demonstrating the reliability of volatile suspended solids as a measure for biological activity in activated sludge. Lower than typical endogenous decay rates in the MBR suggested favorable environmental conditions for respiration and a lower potential for self oxidation and predation. The true yield coefficient was in the range of conventional activated sludge systems, refuting previous suggestions of lower yields in MBRs.     

Enhancement of Denitrification in Upflow Sludge Bed Reactors with Sludge Wasting

From the performance data of the upflow sludge bed (USB) reactors (with sufficient carbon), the rate-limiting step in denitrification is nitrate reduction. Biological denitrification in the USB reactors (superficial velocity=0.5, 1.0, 2.0, and 4.0 m/h) can be greatly enhanced with sludge wasting from the bioreactor [i.e., maintain granular sludge retention time (GSRT) at 20 days], including high volumetric loading rates of up to 6.61 g NO3?–N/L day, high specific denitrification rates [arithmetic mean=0.31–0.42 g NO3?–N/g volatile suspended solids (VSS) day], high denitrification efficiencies (97.6–97.8%), and relatively low washout rates of biomass granules (arithmetic mean ω?=0.13–0.31 g VSS/L day). The biomass concentration, average granule size (dp), and microbial density of the USB reactors with sludge wasting were greater than those of the USB reactors without sludge wasting (i.e., the former grew more compact granules than the latter). From the granulation experiment, the granule size distribution and dp of the broken-up granules in the sludge-bed zone can restore to those of the original granules in one GSRT, implying that spontaneous flocculation of extra-cellular polymer of denitrifying-bacteria cells occurred in the USB reactor, which may also be accelerated by a rigorous backing-mixing effect of continuous production of biogas. Accordingly, the USB reactor with sludge wasting can be regarded as a promising alternative to treat high-strength nitrate wastewater.     

Simultaneous Nitrogen and Phosphorus Removal in a Continuously Fed and Aerated Membrane Bioreactor

This research demonstrated the feasibility of simultaneous biological nitrogen and phosphorous removal in a single tank membrane bioreactor without cycling of air and/or feed through operation at a low dissolved oxygen (DO) and a high biomass concentration. Chemical oxygen demand removal efficiency was more than 98% and total nitrogen removal efficiency was 55%. Seventy-five percent of the total nitrogen removal was through simultaneous nitrification–denitrification (SND) and 25% through assimilation into the biomass. Interestingly, more than 98% phosphorous was removed and microbiological analysis showed the presence of polyphosphate-accumulating organisms in the activated sludge. The operating mixed-liquor suspended solids was between 16 and 23?g/L. The optimum DO was found to be 0.7–0.8?mg/L.     

New Approach to Evaluate Pollutant Removal by Storm-Water Treatment Devices

A methodology was developed to monitor and evaluate the removal of solids and associated constituents by a nutrient separating baffle box (NSBB) storm-water treatment device treating runoff from a 4.3 ha (10.6 acre) residential watershed discharging into the Indian River Lagoon, Florida. The NSBB was monitored over a 359-day time period using autosamplers to quantify water column removal during runoff events, and by quantifying and analyzing solids that accumulated within the NSBB. Flow composited influent and effluent samples were collected to represent water column performance. Event mean concentration (EMC) reduction was moderate (mean: 17%) and variable (range: ?39 to 68%) for suspended solids, and negative for nitrogen, phosphorus, fecal coliforms chromium, and copper. The mass of solids that accumulated in bottom chambers and in a strainer screen was quantified and analyzed for nitrogen, phosphorus, heavy metals, and polycyclic aromatic hydrocarbons. A quantitative evaluative framework was devised to estimate the total pollutant mass removal by NSBB, which consisted of the summation of the separately calculated mass removals for water column, bottom chamber material, and strainer screen material. The water column accounted for only 4% of total solids that accumulated in the NSBB, which was equally divided between bottom chamber and strainer screen. Removal of nitrogen, phosphorus, and metals could be accounted for only by considering mass accumulations. Results suggest that overall assessment of pollutant removal by NSBB must be cognizant of the materials not captured by typical autosamplers: larger size sediment particles, large floating and suspended matter, and the pollutants associated with these materials. Using water column EMCs as the sole measure of performance significantly underestimated loading reduction of storm-water constituents by the NSBB. The monitoring and evaluative methodology applied to the NSBB may be applicable to load reduction evaluations for other storm-water treatment devices with a similar function.     

Pollutant Mass Flushing Characterization of Highway Stormwater Runoff from an Ultra-Urban Area

Water quality of highway stormwater runoff from an ultra-urban area was characterized by determining the event mean concentration (EMC) for several pollutants and by evaluating pollutant flushing. Thirty-two storm events were monitored between June 2002 and October 2003. Mean EMCs in mg/L were 0.035, 0.11, 0.22, 1.18, 420, 3.4, 0.14, 1.0, and 0.56 for Cd, Cu, Pb, Zn, total suspended solids (TSS), total Kjeldahl nitrogen (TKN), NO2–N, NO3–N, and TP. First flush as defined by flushing of 50% of the total pollutant mass load in the first 25% of the event runoff volume occurred in 33% of the storm events for NO2?, 27% for TP, 22% for NO3? and TKN, 21% for Cu, 17% for TSS, 14% for Zn, and 13% for Pb. Median values for the mass flushed in the first 25% of runoff volume were greater than the mass flushed in any 25% portion beyond the first for all pollutants. The mass in later 25% volume portions were greater than in the first 25% volume in at least 17% of the events for all pollutants, indicating that a significant amount of the pollutant load can be contained in later portions of the runoff volume. Nonetheless, management of the first 1.3?mm (1/2?in.) of runoff was able to capture 81–86% of the total pollutant mass.