Salt recovery from agricultural drainage water using a liquid film solar-assisted concentrator – Simulation and model validation

Salt management in irrigated agriculture is critical to the economies of the San Joaquin Valley of California and many other areas around the world. Purified salts can be recovered as marketable products through fractional crystallization following concentration of final stage drainage water from integrated on-farm drainage management systems. To obtain recovered salt and use as a commercial product, new systems which can perform with higher efficiency and lower environmental impact than solar evaporation basins or solar ponds that have previously been used for the final stage are in need of development. For this purpose, a number of solar-assisted brine concentration concepts have been explored, including an open liquid film-type using a tilted evaporation surface described here. Model performance was conceptually evaluated and then experimentally verified.A transient model was developed from energy and component mass balances and employed constitutive heat and mass transfer relationships from various other sources for simulating concentration of agricultural drainage water using a liquid film solar-assisted concentrator.Measured maximum evaporation rate and productivity were between 1.3 and 1.5 kg m⁻² h⁻¹, and 80 kg m⁻² over a 7 day experimental period respectively which was about a third better performance compared with a shallow basin horizontal concentrator. Measurements were in good agreement with model predictions: within 2 °C at the peak and 4 °C at the lowest evaporation, and 0.2 kg m⁻² h⁻¹ for evaporation rates during the peak evaporation periods of the day when compared with independent data sets. Cumulative evaporation rates were from 75 to 85 kg m⁻² for the tilted concentrator model and 60 to 65 kg m⁻² for the horizontal concentrator model after 7 days. The tilted concentrator yielded productivity and efficiency that were 33% higher than the horizontal concentrator according to the experimental result for the same period and location.     

High-temperature optical properties and stability of AlxOy–AlNx–Al solar selective absorbing surface prepared by DC magnetron reactive sputtering

Al_xO_y–AlN_x–Al selective absorbing surface was prepared by DC magnetron reactive sputtering with aluminum alloy (LY13)¹ in air and argon. The studies were carried out to access the high-temperature (400°C–600°C) optical properties and stability of the coatings. The coatings were found to withstand heating at 600°C for 30 min in 4.5×10⁻³ Pa vacuum with absorptance 0.94 and emittance 0.07 after annealing. After heating at 450°C for 10 h, the specimen still had good performance whose absorptance and emittance was 0.93 and 0.07, respectively. Auger electron spectroscopy was used to analyse the structure of the solar selective surface before and after annealing.     

Experimental study of a solar desalination pond as second stage in proposed zero discharge desalination process

This work represents the efficiency of a solar desalination pond as a second stage of proposed zero discharge desalination processes to reach fresh water and also concentrated brine from the effluent wastewater of the desalination unit of Mobin petrochemical complex. So a solar desalination pond is constructed after a pretreatment unit to concentrate the softened wastewater to about 20 wt%. The concentrated wastewater is as a suited feed for a forced circulation crystallizer. During one year, the effects of major parameters such as ambient temperature and solar insolation rate are investigated, experimentally. specific gravity in each layer of concentrated brine wastewater is evaluated. Also, evaporation rates are calculated theoretically and are verified by experimental data. Theoretical values predict evaporation rate accurately. Results show good agreement with experimental data. According to results, maximum evaporation rate is 5 l/m² day when the insolation rate is about 24,602 kJ/m² day Solar energy absorption factor on June is max. Also, experimental results show the best proposed time to gain highest thermal energy is on spring therefore performance efficiency of solar desalination pond promote on spring comparing with the other months. Extracted data for specific gravity prove the bottom of solar desalination pond, layer 1, is best zone for energy saving and energy utilization.Also, theoretical values of evaporation rate are calculated according to measured temperatures and related mass conservation equation. Comparison between theoretical and experimental values shows dusty weather, humidity and wind velocity affects on heat transfer coefficients approximately. So, deviations between theoretical data and measured values can be explained. Results show good agreements with experimental data.     

Blue sensitizers for solar cells: Natural dyes from Calafate and Jaboticaba

Blue-violet anthocyanins from Jaboticaba (Myrtus cauliflora Mart) and Calafate (Berberies buxifolia Lam) were employed as TiO₂ dye-sensitizers. Solar cells sensitized by Jaboticaba extracts achieved up to J_sc=9.0 mA cm⁻², V_oc=0.59 V, P_max=1.9 mW cm⁻² and ff=0.54, while for Calafate sensitized cells the values determined were up to J_sc=6.2 mA cm⁻², V_oc=0.47 V, P_max=1.1 mW cm⁻² and ff=0.36. Other natural dyes were evaluated without significant photocurrent, demonstrating that only selected extracts are capable of converting sunlight in electricity. The results obtained with extracts of Jaboticaba and Calafate show a successful conversion of visible light into electricity by using natural dyes as wide band-gap semiconductor sensitizers in dye-sensitized solar cells. It also represents an environmentally friendly alternative for dye-sensitized solar cells with low cost production and an excellent system for educational purposes.     

Maintenance strategy for a salt gradient solar pond coupled with an evaporation pond

In a previous study, the authors presented a simple mathematical model for predicting the ratio of the evaporation pond area to that of a salt gradient solar pond area. The evaporation pond idea provides a very attractive method of salt recycling by evaporation, especially in areas of high evaporation and low rates of rain as it is the case for North Africa.In this paper, the model was elaborated upon and applied to two types of surface water flushing (fresh water and seawater) under the prevailing conditions of Tripoli, Libya (latitude=32.86°N). All the results presented were predicted for the first three years of operation. The daily variations of brine concentration in the of Tajoura's Experimental Solar pond and those based on different designs were predicted and discussed under different scenarios. The quantities of brine provided by the evaporation pond and that required by were predicted for both cases of surface water flushing (fresh water and seawater) under the different design conditions. It was predicted that the can provide 20–40% during the first year and 45–95% during the third year depending on the design selected.     

Investigation of solar radiation in Botswana and some anomalous phenomena observed

Daily global insolation on a horizontal surface in Botswana is recorded continuously at several synoptic stations and at the University of Botswana's Physics Department. Over a number of years, daily total insolation on a tilted surface (β = −30°) was recorded at the Botswana Technology Centre. Hourly, and instantaneous direct normal, global, diffuse and UV-components are continuously recorded at the University of Botswana. All these measurements are done with standard EPLAB equipment.It is found out that the instantaneous direct normal radiation at Solar noon can be as high as 1150 W·m⁻²; and that at 30 min before sunset it can be above 600 W·m⁻²; and it can also be as high as 100 W·m⁻² at sunset or sunrise moments (i.e. with half of the solar disk under the horizon).Daily direct normal solar radiation can exceed 45 MJ·m⁻². Mean daily global radiation varies from 31 MJ·m⁻² in December to 16 MJ·m⁻² in June. Such big values of daily direct normal and global radiation are explained by low humidity and low turbidity.Cases of an anomalous phenomenon which lead to an abnormally big phase shift when direct normal radiation is increasing greatly after Solar noon are observed, and discussed. It is also found that when humidity is low and visibility is high, hourly I_g values recorded with a pyranometer can be less than I_bn (cosθ_z) + I_d-values. This discrepancy could be quite common for regions where humidity and turbidity are low. The trend in the behaviour of the UV-component during the last five years is also analyzed and discussed. The conclusion is made that the ozone layer over Botswana is continuously being depleted.     

Drying of hot chilli using solar tunnel drier

A mixed mode type forced convection solar tunnel drier was used to dry hot red and green chillies under the tropical weather conditions of Bangladesh. The drier consisted of transparent plastic covered flat-plate collector and a drying tunnel connected in series to supply hot air directly into the drying tunnel using two fans operated by a photovoltaic module. The drier had a loading capacity of 80 kg of fresh chillies. Moisture content of red chilli was reduced from 2.85 to 0.05 kg kg⁻¹ (db) in 20 h in solar tunnel drier and it took 32 h to reduce the moisture content to 0.09 and 0.40 kg kg⁻¹ (db) in improved and conventional sun drying methods, respectively. In case of green chilli, about 0.06 kg kg⁻¹ (db) moisture content was obtained from an initial moisture content of 7.6 kg kg⁻¹ (db) in 22 h in solar tunnel drier and 35 h to reach the moisture content to 0.10 and 0.70 kg kg⁻¹ (db) in improved and conventional sun drying methods, respectively. The use of a solar tunnel drier and blanching of sample led to a considerable reduction in drying time and dried products of better quality in terms of colour and pungency in comparison to products dried under the sun. The solar tunnel drier and blanching of chilli are recommended for drying of both red and green chillies.     

CONSTRUCTION AND OPERATIONAL EXPERIENCE OF A 6000 m SOLAR POND AT KUTCH, INDIA

A 6000 m² solar pond was constructed at Bhuj in India in the premises of a milk processing dairy plant to supply process heat and demonstrate the technical and economic viability of solar pond technology in the Indian context. An inexpensive lining scheme, consisting of alternating layers of clay and LDPE (low density polyethylene) combination was used for lining the pond. The pond attained a maximum temperature of 99.8°C under stagnation in May 1991 but developed leakage soon after. A failure analysis that was carried out subsequently indicated that the leakage was caused by the combination of high stagnation temperature and large air pockets below the liner. The lining scheme was re-designed and the pond re-established in June 1993. Hot water supply to the dairy started in September 1993 and continued until April 1995. After an interruption of nearly one year, hot water was resumed in August 1996. The total cost of construction of the Bhuj Solar Pond was US$90 000 (1997 prices), including heat exchanger and piping etc., corresponding to a unit cost of US$15 m⁻².     

Contact resistivities of sputtered TiN and Ti---TiN metallizations on solar-cell-type-silicon

Contact resistivities of TiN and Ti---TiN contacts on a shallow junction solar-cell-type silicon substrate have been investigated. The contact materials were sputter-deposited. The method of the transmission line model was applied for contact resistivity measurements. The contact resistivity of the n⁺Si---TiN contact system was 2 × 10⁻³ Ωcm² ± 50 per cent and remained constant after annealing up to 700°C for 30 min. For the n⁺Si---Ti---TiN system, the contact resistivity of 9 × 10⁻⁴ Ωcm² ± 50 per cent was measured. A heat treatment of 700°C. 30 min decreases this value by one order of magnitude and the interposed Ti fully reacts with Si and forms a TiSi₂ layer. The voltage drop caused by the n⁺Si---TiN contact system in a standard non-concentrator solar cell is negligible. The n⁺Si---TiSi₂---TiN contact system should be acceptable for Si solar cells used at up to 100 times solar concentration.     

Proof-of-concept study of an integrated solar desalination system

This paper describes the performance of a directly heated solar desalination system. The design concept is based on using a direct solar energy collection unit, integrated with flash evaporation and low temperature multi-effect distillation (LT-MED) equipment. Key parameters affecting desalination rate include flashing evaporation pressure, first effect distillation pressure and seawater temperature. The experimental results indicate that at flash evaporation pressure of 0.01 MPa, first effect distillation pressure of 0.004 MPa, and the temperature of solar-heated seawater of 78 °C, the system can reach steady state operation in 17 min. At steady state, desalination rate of 0.204 × 10⁻³ m³/min is obtained. On raising temperature from 70 to 78 °C, net increase in desalination rate of 0.165 × 10⁻³ m³/min is achieved. In contrast, the change of first effect distillation pressure only had minimum effect on desalination rate. Experimental results are in agreement with the theoretical analysis. If temperature continues to increase beyond 78 °C, scaling due to precipitation of CaSO₄ takes place. In this study, the techniques that prevent the system from scaling deposits are discussed.     

Electrosynthesis and characterization of GaAs in acid solutions by potentiostatic method

Gallium arsenide (GaAs) is one of the important materials used for the fabrication of light emitting diodes, solar cells, microwave devices, etc. In the present work, electrodeposition of GaAs was successfully carried out potentiostatically from an aqueous solution mixture of gallium chloride (GaCl₃) and arsenic oxide (As₂O₃). The optimum deposition potential, pH and bath temperature to synthesize GaAs thin films are found to be −0.8 V versus SCE, 2.0±0.1 and 60 ^°C, respectively. The effects of solution pH, bath temperature and deposition potential on the gallium content of GaAs films are studied. Photoelectrochemical (PEC) solar cells using n-GaAs photo-anode in a polysulphide electrolyte is constructed and I–V, C–V studies are carried out. Various semiconductor parameters such as, flat-band potential, band bending, donor density, depletion layer width are evaluated and the results are discussed.     

The study on high efficient AlxGa1−xAs/GaAs solar cells

The investigation of Al_xGa_1−xAs/GaAs solar cells is carried out by means of both metalorganic chemical vapor deposition (MOCVD) and liquid-phase epitaxial (LPE) technique. The measurements of illuminated I–V characteristics, dark I–V characteristics and quantum efficiencies were performed for the GaAs solar cells made in author's laboratory. The measuring results revealed that the quality of materials in GaAs solar cell's structures is the key factor for getting high-efficient GaAs solar cells, but the effect of post-growth technology on the performances of GaAs solar cells is also very strong. The 21.95% (AM0, 2×27 cm², 25°C) high conversion efficiency in a typical GaAs solar cell has been achieved owing to improving the quality of materials as well as optimizing the post-growth technology of devices.     

Preliminary results of a V-groove back-pass solar collector

The study conducted by the Solar Energy Research Group, Universiti Kebangsaan Malaysia shows that solar energy has a great potential to be used in drying processes. A prototype solar drying system was designed and tested in the campus (Othman et. al, 1994). The study shows that the system can be upgraded by improving the solar collector. This paper presents the preliminary result on the performance of the V-groove back-pass solar collector modified from V-groove double flow solar collector designed earlier (Othman et. al, 1992). The results shows that the collector maintained the output temperature eventhough there are changes of solar radiation intensity. At 0.65 ms⁻¹ air flow rate, the output temperature of the collector can manage to maintain 40°C in the range of solar intensity of 800 Wm⁻² to 300 Wm⁻² within 15 minutes time interval, and at 0.45 ms⁻¹, the output temperature is 43°C in the range of solar intensity of 800 Wm⁻² to 600 Wm⁻². The min daily efficiency of 20% is recorded at 450 Wm⁻² of min daily solar radiation at 0.65 ms⁻¹ flow rate. At 0.45 ms⁻¹ flow rate with the equal amount of daily min solar radiation the min daily efficiency is 13%. The result is expected to be better if the study is conducted in May - June when the weather is better.     

Optimization and microbial community analysis for production of biohydrogen from palm oil mill effluent by thermophilic fermentative process

The optimum values of hydraulic retention time (HRT) and organic loading rate (OLR) of an anaerobic sequencing batch reactor (ASBR) for biohydrogen production from palm oil mill effluent (POME) under thermophilic conditions (60 °C) were investigated in order to achieve the maximum process stability. Microbial community structure dynamics in the ASBR was studied by denaturing gradient gel electrophoresis (DGGE) aiming at improved insight into the hydrogen fermentation microorganisms. The optimum values of 2-d HRT with an OLR of 60 gCOD l⁻¹ d⁻¹ gave a maximum hydrogen yield of 0.27 l H₂ g COD⁻¹ with a volumetric hydrogen production rate of 9.1 l H₂ l⁻¹ d⁻¹ (16.9 mmol l⁻¹ h⁻¹). The hydrogen content, total carbohydrate consumption, COD (chemical oxygen demand) removal and suspended solids removal were 55 ± 3.5%, 92 ± 3%, 57 ± 2.5% and 78 ± 2%, respectively. Acetic acid and butyric acid were the major soluble end-products. The microbial community structure was strongly dependent on the HRT and OLR. DGGE profiling illustrated that Thermoanaerobacterium spp., such as Thermoanaerobacterium thermosaccharolyticum and Thermoanaerobacterium bryantii, were dominant and probably played an important role in hydrogen production under the optimum conditions. The shift in the microbial community from a dominance of T. thermosaccharolyticum to a community where also Caloramator proteoclasticus constituted a major component occurred at suboptimal HRT (1 d) and OLR (80 gCOD l⁻¹ d⁻¹) conditions. The results showed that the hydrogen production performance was closely correlated with the bacterial community structure. This is the first report of a successful ASBR operation achieving a high hydrogen production rate from real wastewater (POME).     

Bulk p-CuInSe2 photo-electrochemical solar cells

Dense CuInSe₂ of high quality, prepared by the fusion technique in evacuated quartz ampoule from stoichiometric melt, crystallizes in the chalcopyrite structure. Compositional analysis carried out by secondary ion mass spectrometry (SIMS) and energy dispersive spectroscopy (EDS) indicates a uniform distribution of elements through the depth and a composition close to the stoichiometry. The diffuse reflectance spectrum gives a band gap at 0.94 eV. The electrical conductivity follows an Arrhenius-type law with activation energy of 23 meV in conformity with polarons hopping. Above 320 °C, CuInSe₂ undergoes an irreversible oxidation. The thermal variation of the thermopower indicates p-type behavior attributed to copper deficiency and a hole mobility μ_300 K of 0.133 cm² V⁻¹ s⁻¹, thermally activated. In KCl media, the compound exhibits an excellent chemical stability with a corrosion rate of 8 μmol cm⁻² month⁻¹. The photo-electrochemical properties, investigated for the first time on the ingots, confirm the p-type conductivity. From the capacitance measurements, the flat band potential (V_fb=−0.62V_SCE) and the holes density (N_A=4×10¹⁷ cm⁻³) were determined. The valence band, located at 4.43 eV below vacuum, is made up of mainly Se orbital with little admixture of Cu character. The change of the electrolyte causes a variation in the potential V_fb (dV_fb/dpH=−0.058 V pH⁻¹) indicating strong OH⁻ adsorption. The fill factor in S²⁻ media was found to be 0.54; such result was corroborated by semi-logarithmic plots.     

Angular distribution of clear sky short wavelength radiance

Over 3000 scans of the clear sky short wavelength (0.3–3.0 μm) radiance were used to produce sky radiance contour maps for solar zenith angles 32° to 80°. The radiance contours are symmetrical about the solar meridian with minimum radiance in the solar meridian at approximately 90° to 110° from the sun. There is no significant change in contour for a change in aerosol optical depth from 0.1 to 0.5. The clear sky radiance is given analytically by N(ψ) = (1.63 + 53.7e−5.49ψ + 2.04 cos² ψ cos θ^*) (1 − e^{−1.90 sec θ}) (1 − e^{−0.53 sec θ}*) where θ^* is the solar zenith angle, θ the zenith angle of the sky radiance direction, and Ψ is the scattering angle between sky and sun directions.     

Preparation of selective absorbers based on CuMn spinels by dip-coating method

CuMn-spinel thin films were prepared on aluminum substrates by the so-called dip-coating method. The layers were deposited from alcoholic solutions based on nitrate precursors and subsequently sintered in air at 500 °C. Reflectance spectra in the NIR–vis–UV interval were measured for samples with different composition and thickness. The absorber quality of the films was checked by calculating the solar absorptance. The films displaying the best reflectance spectra and the highest solar absorptances (α_s>0.87) were deposited from solutions containing molar ratio Cu/Mn=1. The analysis of composition showed that Cu/Mn ratio in the film was very close to the ratio in the dip-in solution and supported the formation of a spinel-like material of stoichiometry Cu_1.5Mn_1.5O₄. Solar absorptance was dramatically improved when a SiO₂ antireflective layer was deposited onto the spinel. By optimizing film thickness of both CuMn-spinel and SiO₂ layers optical parameter values as good as α_s=0.94 and ε_T(1 0 0)=0.06 were achieved.     

CIS thin film solar cells with evaporated InSe buffer layers

This paper describes the investigations of CIS-based solar cells with a new In_xSe_y (IS) buffer layer. Studies were concentrated on determining the deposition conditions to get In_xSe_y thin films with adequate properties to be used in substitution of the CdS buffer layer, usually employed in the fabrication of this type of devices. Before the solar cell fabrication, the buffer layers grown by evaporation of the In₂Se₃ compound were characterized through transmittance and X-ray diffraction measurements. It was found that good results can be obtained using indium selenide film as the buffer layer, grown in the In₂Se₃ phase.Solar cells with structure Mo/CIS/In₂Se₃/ZnO were fabricated. The ZnO layer was deposited by reactive evaporation and the absorber CIS layer was grown on Mo by a two-stage process. The preliminary results obtained with this type of solar cells are J_sc=30.8 mA/cm², V_oc=0.445 V, FF≈0.6 and η=8.3% with an irradiance of 100 mW/cm². Solar cells fabricated using a CdS buffer layer deposited by CBD on CIS substrate, prepared under the same conditions used in the fabrication of Mo/CIS/In₂Se₃/ZnO cells, gave the following results: V_oc=0.43 V, J_sc=34 mA/cm², FF≈0.63 and η=9.2%.     

Estimation of monthly Angström–Prescott equation coefficients from measured daily data in Toledo, Spain

In this study, daily global radiation for Toledo (39°53′05″N, 4°02′58″W, Spain) were utilized to determine monthly-specific equations for estimating global solar radiation from sunshine hours and to obtain improved fits to monthly Angström–Prescott's coefficients.Models were compared using the root mean square error (RMSE), the mean bias error (MBE) and the t-statistic. According to our results, all the models fitted the data adequately and can be used to estimate the specific monthly global solar radiation.Average RMSE and MBE for comparison between observed and estimated global radiation were 1.260 and −0.002 MJ m⁻² day⁻¹, respectively. The t-statistic was used as the best indicator, this indicator depends on both, and is more effective for determining the model performance. The agreement between the estimated and the measured data were remarkable and the method was recommended for use in Toledo (Spain).