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1.
《Displays》2005,26(3):129-132
A white-light-emitting device has been fabricated with a structure of ITO/NPB/BCP/Alq3/LiF/Al. The hole blocking layer(BCP) result in a mixture of lights from NPB molecules (blue-light) and Alq3 molecules (olivine-light), thereby producing white-light emission. The chromaticity can be readily adjusted by only varying the thickness of the BCP layer. The CIE coordinates of the device are largely insensitive to the driving voltages. The maximum brightness is 5740 cd/m2, the EL efficiency is 2.12 cd/A at the applied voltage of 18 V.  相似文献   

2.
Two phenylanthracene-substituted fluorene derivatives, 10-(9,9′-dimethyl-2-(10-phenylanthracen-9-yl)-9H-fluoren-7-yl)-phenylanthracene (1) and 2′,7′-di-(10-phenylanthracen-9-yl)-9,9′-spirobi[9H-fluorene] (2) have been designed, synthesized, and characterized. A device using compound 1 as an emitting material exhibited luminous efficiency, power efficiency, external quantum efficiency and CIE coordinates of 3.37 cd/A, 1.50 lm/W, 1.87% at 20 mA/cm2 and (0.18, 0.25) at 7 V, respectively. Furthermore, by exploiting this efficient blue fluorescent material as a blue emitting material with the combination of red phosphorescent bis(2-phenylquinoline)acetylacetonate [(pq)2Ir(acac)], an efficient white OLED (WOLED) with a external quantum efficiency of 1.70%, luminous efficiency of 1.38 cd/A, power efficiency of 0.94 lm/W at 20 mA/cm2 and the color coordinates of (0.33, 0.36) at 14 V is demonstrated.  相似文献   

3.
《Displays》2007,28(1):26-30
White organic light emitting devices (WOLEDs) with an RBG stacked multilayer structure were demonstrated. In RGB stacked OLEDs, blue emitting, 2-t-butyl-9,10-di-(2-naphthyl)anthracene (TBADN) doped with p-bis(p-N,N-diphenyl-amono-styryl)benzene (DSA-Ph), green emitting, tris-(8-hydroxyquinoline)aluminum (Alq) doped with C545, and red emitting, tris-[8-hydroxyquinoline]aluminum (Alq) doped with 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)- 4H-pyran (DCJTB), were used. By adjusting the order and thickness of emitting layer in RBG structure, we got a white OLED with current efficiency of 5.60 cd/A and Commission Internationale De L’Eclairage (CIE) coordinates of (0.34, 0.34) at 200 mA/cm2. Its maximum luminance was 20,700 cd/m2 at current density of 400 mA/cm2. The results have been explained on the basis of the theory of excitons generation and diffusion. According to the theory of excitons generation and diffusion, an equation has been set up which relates EL spectra to the thickness of every layer and to the exciton diffusion length.  相似文献   

4.
Organic light-emitting diodes (OLEDs) with C60 buffer layer were fabricated. The effect of C60 buffer layer on the performance of the devices was investigated by inserting C60 buffer layer at the interface between the electrode and organic layers. The device structures were (1) ITO/C60 (0.0, 0.4, 0.7 and 1.0 nm)/NPB/Alq3/LiF/Al and (2) ITO/NPB/Alq3/C60 (0.0, 0.4, 0.7 and 1.0 nm)/LiF/Al. The highest brightness and efficiency of the device (1) with 0.7 nm-thick C60 layer reached 6439 cd/m2 at 16 V and 1.80 cd/A at 6.4 V, respectively. The enhancements in brightness and efficiency are attributed to an improved balance of hole and electron injections due to C60 layer blocking parts of the injected holes. On the contrary, the brightness and efficiency of the devices with the structure (2) had been hardly enhanced.  相似文献   

5.
《Displays》2007,28(2):81-84
Organic light-emitting diodes (OLEDs) with multilayer quantum well (MQW) structure were fabricated, which consisted of alternate organic materials 2-(4-biphenylyl)-5(4-tert-butyl-phenyl)-1,3,4-oxadiazole (PBD) and tris(8-hydroxyquinoline) aluminum (Alq3). PBD is used as potential barrier layer, Alq3 used as potential well layer and emitting layer. Compared with double-layer structure, the luminescent characteristics of the devices with MQW structure were investigated. MQW structures conduce to energy transfer between wells and barriers, which is attributed to good overlap and the decrease of the distance between layers. The MQW structures make electrons and holes distribute in different wells and then increase the number of the formation of excitons to further enhance their recombination efficiency. Hence, such device achieves the maximum brightness and efficiency of 3630 cd/m2 and 3.28 cd/A, respectively.  相似文献   

6.
Thin films of polymethylmethacrylate (PMMA) doped with perylene provide selective, robust and easily prepared optical sensor films for NO2 gas with suitable response times for materials aging applications. The materials are readily formed as 200 nm thin spin cast films on glass from chlorobenzene solution. The fluorescence emission of the films (λmax=442 nm) is quenched upon exposure to NO2 gas through an irreversible reaction forming non-fluorescent nitroperylene. Infrared, UV–VIS and fluorescence spectroscopies confirmed the presence of the nitro adduct in the films. In other atmospheres examined, such as air and 1000 ppm concentrations of SO2, CO, Cl2 and NH3, the films exhibited no loss of fluorescence intensity over a period of days to weeks. Response curves were obtained for 1000, 100 and 10 ppm NO2 at room temperature with equilibration times varying from hours to weeks. The response curves were fit using a numerical solution to the coupled diffusion and a nonlinear chemical reaction problem assuming that the situation is reaction limiting. The forward reaction constant fitted to experimental data was kf∼0.06 (ppm min)−1.  相似文献   

7.
Blue organic light-emitting devices (OLEDs) combing a composite hole transporting layer (c-HTL) and novel homogeneous double emitting layers (DELs) have been fabricated. The c-HTL plays a significant role of rectification in balancing the carriers’ injection concentration which matches well with the DELs structure. The DELs is consisted of two homogeneous hosts, such as 2-methyl-9,10-di(2-naphthyl) anthracene (MADN) and 9,10-di(2-naphthyl) anthracene (ADN). The optimal device presents the maximal current efficiency of 15.9 cd/A at 4.9 mA/cm2 and the minor efficiency roll-off of 13.4% under the driving voltage varying from 5 V to 10 V, respectively. Meanwhile, the device’s maximal current efficiency and the corresponding efficiency roll-off have been obviously improved by 55.9% and 63.9% compared with those of the conventional device. These results indicate that the homogeneous DELs not only greatly facilitate carriers’ injection into the emitting layer (EML), but also evenly modulate carriers’ distribution due to natural energy barrier of the interface. The transient photoluminescence decay of double hosts further illustrates that the DELs structure can increase the recombination ratio of electron–hole pairs and improve the exciton’s utilization. Additionally, the optimal device’ current density is reduced by 44.1% under the same luminance of 25,780 cd/m2 compared with that of the conventional device.  相似文献   

8.
Ce3+–Mn2+–Tb3+ cooperative barium–yttrium-orthosilicate phosphors composed of Ba9-3m/2-n-3p/2CemMnnTbpY2Si6O24 (m = 0.005–0.4, n = 0–0.5, p = 0–0.5) were prepared using a solid-state reaction. The X-ray diffraction patterns of the resultant phosphors were examined to index the peak positions. The photoluminescence (PL) excitation and emission spectra of the Ce3+–Mn2+–Tb3+ activated phosphors were clearly monitored. The dependence of the luminescent intensity of the Mn2+–Tb3+ co-doped Ba9-3m/2CemY2Si6O24 host lattices on Ce3+ content (m = 0.025, 0.1) was also investigated. Co-doping Mn2+ into the Ce3+–Tb3+ co-doped host structure enabled energy transfer from Ce3+ to Mn2+; this energy transfer mechanism is discussed. The phosphors of Ce3+–Mn2+–Tb3+ doped Ba9Y2Si6O24 host lattice were prepared for efficient white-light emission under NUV excitation. With these phosphors, the desired CIE values including white region of the emission spectra were achieved.  相似文献   

9.
Accurate assessment of phytoplankton chlorophyll-a (chla) concentrations in turbid waters by means of remote sensing is challenging due to the optical complexity of case 2 waters. We have applied a recently developed model of the form [Rrs? 1(λ1) ? Rrs? 1(λ2)] × Rrs(λ3) where Rrs(λi) is the remote-sensing reflectance at the wavelength λi, for the estimation of chla concentrations in turbid waters. The objectives of this paper are (a) to validate the three-band model as well as its special case, the two-band model Rrs? 1(λ1) × Rrs(λ3), using datasets collected over a considerable range of optical properties, trophic status, and geographical locations in turbid lakes, reservoirs, estuaries, and coastal waters, and (b) to evaluate the extent to which the three-band model could be applied to the Medium Resolution Imaging Spectrometer (MERIS) and two-band model could be applied to the Moderate Resolution Imaging Spectroradiometer (MODIS) to estimate chla in turbid waters.The three-band model was calibrated and validated using three MERIS spectral bands (660–670 nm, 703.75–713.75 nm, and 750?757.5 nm), and the 2-band model was tested using two MODIS spectral bands (λ1 = 662–672, λ3 = 743–753 nm). We assessed the accuracy of chla prediction in four independent datasets without re-parameterization (adjustment of the coefficients) after initial calibration elsewhere. Although the validation data set contained widely variable chla (1.2 to 236 mg m? 3), Secchi disk depth (0.18 to 4.1 m), and turbidity (1.3 to 78 NTU), chla predicted by the three-band algorithm was strongly correlated with observed chla (r2 > 0.96), with a precision of 32% and average bias across data sets of ? 4.9% to 11%. Chla predicted by the two-band algorithm was also closely correlated with observed chla (r2 > 0.92); however, the precision declined to 57%, and average bias across the data sets was 18% to 50.3%. These findings imply that, provided that an atmospheric correction scheme for the red and NIR bands is available, the extensive database of MERIS and MODIS imagery could be used for quantitative monitoring of chla in turbid waters.  相似文献   

10.
A blue organic light-emitting device, based on an iridium phosphorescent dopant in a polyvinylcarbazole host, has been modified by the addition of an external CaS:Eu inorganic phosphor layer. By incorporating a surfactant in the phosphor mixture, a uniform coating could be achieved by drop-casting. The resulting hybrid device exhibited white light emission, with Commission Internationale de l’Eclairage, CIE (x, y) coordinates of x = 0.32, y = 0.35. No significant change in these coordinates was observed for current densities in the range 25–510 A m?2. The maximum power efficiencies of the white device was 2.3 lm W?1 at a brightness of 254 cd m?2.  相似文献   

11.
This article aims at finding efficient hyperspectral indices for the estimation of forest sun leaf chlorophyll content (CHL, µg cmleaf? 2), sun leaf mass per area (LMA, gdry matter mleaf? 2), canopy leaf area index (LAI, m2leaf msoil? 2) and leaf canopy biomass (Bleaf, gdry matter msoil? 2). These parameters are useful inputs for forest ecosystem simulations at landscape scale. The method is based on the determination of the best vegetation indices (index form and wavelengths) using the radiative transfer model PROSAIL (formed by the newly-calibrated leaf reflectance model PROSPECT coupled with the multi-layer version of the canopy radiative transfer model SAIL). The results are tested on experimental measurements at both leaf and canopy scales. At the leaf scale, it is possible to estimate CHL with high precision using a two wavelength vegetation index after a simulation based calibration. At the leaf scale, the LMA is more difficult to estimate with indices. At the canopy scale, efficient indices were determined on a generic simulated database to estimate CHL, LMA, LAI and Bleaf in a general way. These indices were then applied to two Hyperion images (50 plots) on the Fontainebleau and Fougères forests and portable spectroradiometer measurements. They showed good results with an RMSE of 8.2 µg cm? 2 for CHL, 9.1 g m? 2 for LMA, 1.7 m2 m? 2 for LAI and 50.6 g m? 2 for Bleaf. However, at the canopy scale, even if the wavelengths of the calibrated indices were accurately determined with the simulated database, the regressions between the indices and the biophysical characteristics still had to be calibrated on measurements. At the canopy scale, the best indices were: for leaf chlorophyll content: NDchl = (ρ925 ? ρ710)/(ρ925 + ρ710), for leaf mass per area: NDLMA = (ρ2260 ? ρ1490)/(ρ2260 + ρ1490), for leaf area index: DLAI = ρ1725 ? ρ970, and for canopy leaf biomass: NDBleaf = (ρ2160 ? ρ1540)/(ρ2160 + ρ1540).  相似文献   

12.
Let C be a curve of genus 2 and ψ1: C    E 1  a map of degree n, from C to an elliptic curveE1 , both curves defined over C. This map induces a degree n map φ1:P1    P 1  which we call a Frey–Kani covering. We determine all possible ramifications for φ1. If ψ1:C    E 1  is maximal then there exists a maximal map ψ2: C    E 2  , of degree n, to some elliptic curveE2 such that there is an isogeny of degree n2from the JacobianJC to E1 × E2. We say thatJC is (n, n)-decomposable. If the degree n is odd the pair (ψ2, E2) is canonically determined. For n =  3, 5, and 7, we give arithmetic examples of curves whose Jacobians are (n, n)-decomposable.  相似文献   

13.
In this paper, a series of Na3Ca6(1−x)(PO4)5:xEu2+ (NCP:xEu2+, 0  x  4%) phosphors were prepared by conventional solid-state reaction method, and their photoluminescence properties were studied. Upon 365 nm excitation, the typical NCP:2%Eu2+ phosphor shows an asymmetric bluish green emission band with the dominant peak at 498 nm which could be attributed to the 4f65d1-4f7 transition of Eu2+. By measuring the time-resolved photoluminescence spectra, it reveals more than one Eu2+ emission center in the Eu2+-activated NCP phosphors. By monitoring 498 nm, the excitation spectrum of NCP:2%Eu2+ demonstrates a broad excitation band ranging from 240 to 450 nm, which can match well with the emission wavelength of the NUV LED chip. The SEM image shows that the average particle size of NCP:2%Eu2+ is about 19.4 µm. The above results imply that the NCP:Eu2+ phosphor could have potential application in LEDs.  相似文献   

14.
Pb(Zr0.52Ti0.48)O3 (PZT) ferroelectric thin films with LaNiO3 (LNO) as bottom electrodes have been grown on amorphous TiN buffered Si(1 0 0) substrates by pulsed laser deposition. It was found that highly (0 0 1)-oriented LNO films could be obtained even if TiN underlayers were amorphous. XRD analyses showed that the subsequently deposited PZT films were also preferentially (0 0 1)-oriented due to the template effect of the perovskite structured LNO films. Dielectric constant of the PZT thin films remained almost constant with frequency in the range from 103 to 106 Hz, and tangent loss was as small as 0.02 at high frequencies. The remnant polarization and coercive field of an Au/PZT/LNO capacitor were typically 20 μC/cm2 and 30 kV/cm, respectively. CV and IV characteristics revealed the capacitance and leakage current variations with applied voltage were asymmetric when the bottom electrode was negatively as well as positively biased, indicating that ferroelectric/electrode interfaces and space charges play an important role in the electrical properties of ferroelectric capacitors.  相似文献   

15.
An interesting hydrogen sensor based on a high electron mobility transistor (HEMT) device with a Pd–oxide–In0.49Ga0.51P gate structure is fabricated and demonstrated. The hydrogen sensing characteristics including hydrogen detection sensitivity and transient responses of the studied device under different hydrogen concentrations and temperature are measured and studied. The hydrogen detection sensitivity is related to a change in the contact potential at the Pd/insulator interface. The kinetic and thermodynamic properties of hydrogen adsorption are also studied. Experimentally, good hydrogen detection sensitivities, large magnitude of current variations (3.96 mA in 9970 ppm H2/air gas at room temperature) and shorter absorption response time (22 s in 9970 ppm H2/air gas at room temperature) are obtained for a 1.4 μm × 100 μm gate dimension device. Therefore, the studied device provides a promise for high-performance solid-state hydrogen sensor, integrated circuit (IC) and micro electro-mechanical system (MEMS) applications.  相似文献   

16.
Light use efficiency (LUE) is an important variable characterizing plant eco-physiological functions and refers to the efficiency at which absorbed solar radiation is converted into photosynthates. The estimation of LUE at regional to global scales would be a significant advantage for global carbon cycle research. Traditional methods for canopy level LUE determination require meteorological inputs which cannot be easily obtained by remote sensing. Here we propose a new algorithm that incorporates the enhanced vegetation index (EVI) and a modified form of land surface temperature (Tm) for the estimation of monthly forest LUE based on Moderate Resolution Imaging Spectroradiometer (MODIS) imagery. Results demonstrate that a model based on EVI × Tm parameterized from ten forest sites can provide reasonable estimates of monthly LUE for temperate and boreal forest ecosystems in North America with an R2 of 0.51 (p < 0.001) for the overall dataset. The regression coefficients (a, b) of the LUE–EVI × Tm correlation for these ten sites have been found to be closely correlated with the average EVI (EVI_ave, R2 = 0.68, p = 0.003) and the minimum land surface temperature (LST_min, R2 = 0.81, p = 0.009), providing a possible approach for model calibration. The calibrated model shows comparably good estimates of LUE for another ten independent forest ecosystems with an overall root mean square error (RMSE) of 0.055 g C per mol photosynthetically active radiation. These results are especially important for the evergreen species due to their limited variability in canopy greenness. The usefulness of this new LUE algorithm is further validated for the estimation of gross primary production (GPP) at these sites with an RMSE of 37.6 g C m? 2 month? 1 for all observations, which reflects a 28% improvement over the standard MODIS GPP products. These analyses should be helpful in the further development of ecosystem remote sensing methods and improving our understanding of the responses of various ecosystems to climate change.  相似文献   

17.
Piezoelectric Pb(Zr,Ti)O3 (PZT) thin films with a composition near the morphotoropic phase boundary were deposited directly on cantilever-shaped stainless steel (SUS) substrates using RF-magnetron sputtering for application of micro-electromechanical systems (MEMS). X-ray diffraction measurements reveal that the PZT thin films have a polycrystalline perovskite structure with a preferential orientation of (1 0 1). Cross-section morphology – observed using a scanning electron microscope – indicates that the PZT films exhibit a dense columnar structure without pores or clacks. The films’ PE hysteresis loops indicate clear ferroelectricity. Based on the deflection characteristics of the cantilever, the effective piezoelectric coefficient e31 of the PZT films is measured to be −1.35 C/m2.  相似文献   

18.
Blue color organic/polymeric light emitting diodes are very important because they can be used for tri-color display applications, fluorescence imaging, and exciting yellow phosphor for generating white light for general illumination. But the efficiency of blue organic/polymeric light emitting diodes is considerably low due to their large band gap that requires higher energy for effective emission. In this paper we report the enhancement in polyfluorene blue organic light emitting diodes with a polymer nano-composite hole transport layer. Blue light emitting diode based on polyfluorene as an emissive layer and poly(3,4 ethylenedioxythiophene):poly(styrenesulfonate)–titanium dioxide nanocomposite as the hole transport layer were fabricated and studied. Different concentrations of titanium dioxide nanoparticles were doped in poly(3,4 ethylenedioxythiophene):poly(styrenesulfonate) in the hole transport layer and the performance of the devices were studied. Significant enhancement in the blue peak at 430 nm of polyfluorene has been observed with increase in concentration of TiO2 nanoparticles in the hole transport layer. The turn on voltage of the device has also been found to improve significantly with the incorporation of titanium dioxide nanoparticles in the hole transport layer. The optimized concentration of titanium dioxide in the hole transport layer for most efficient device has been found to 15 wt.%.  相似文献   

19.
《Displays》2014,35(5):279-286
Dysprosium doped di-strontium magnesium di-silicate namely Sr2MgSi2O7:Dy3+ phosphor was prepared by the solid state reaction method. The phase structure, surface morphology, particle size, elemental analysis was analyzed by using XRD, TEM, EDX and FTIR techniques. The EDX and FTIR spectra confirm the present elements in Sr2MgSi2O7:Dy3+ phosphor. The optical properties of Sr2MgSi2O7:Dy3+ phosphor was investigated utilizing thermoluminescence (TL), photoluminescence (PL), long lasting phosphorescence and mechanoluminescence (ML). Under the ultraviolet excitation, the emission spectra of Sr2MgSi2O7:Dy3+ phosphor are composed of a broad band and the characteristic emission of Dy3+ peaking at 470 nm (blue), 575 nm (yellow) and 678 nm (red), originating from the transitions of 4F9/2  6H15/2, 4F9/2  6H13/2 and 4F9/2  6H11/2. CIE color coordinates of Sr2MgSi2O7:Dy3+ are suitable as white light emitting phosphor. Decay graph indicate that this phosphor also contains fast decay and slow decay process. The peak of ML intensity increases linearly with increasing impact velocity of the moving piston. The possible mechanism of this white light emitting long lasting phosphor is also investigated.  相似文献   

20.
Ca (or Sr)TiO3:Eu3+, M (Li+ or Na+ or K+) and CaTiO3:Pr3+, M (Li+ or Na+ or Ag+ or K+ or Gd3+ or La3+) powders were prepared by combustion synthesis method and the samples were further heated to ~1000 °C to improve the crystallinity. The structure and morphology of materials were examined by X-ray diffraction (XRD) and a scanning electron microscopy (SEM). The morphologies of SrTiO3:Eu3+, CaTiO3:Eu3+ or CaTiO3:Pr3+ powders co-doped with other metal ions were very similar. Small and coagulated particles of nearly cubical shapes with small size distribution having smooth and regular surface were formed. Photo-luminescence spectra of CaTiO3:Pr3+ and co-doped either with Li+, Na+, K+, Ag+, La3+ or Gd3+ ions showed red emissions at 613 nm due to the 1D2  3H4 transition of Pr3+. The variation of intensity of emission peak with different co-doping follows the order: K+ > Ag+ > Na+ > Li+ > La3+ > Gd3+. The characteristic emissions of CaTiO3:Eu3+ lattices had strong emission at 614 and 620 nm for 5D0  7F2 with other weak transitions observed at 580, 592, 654, 705 nm for 5D0  7Fn transitions where n = 0, 1, 3, 4 respectively in all host lattices. Photoluminescence intensity in SrTiO3:Eu3+ is more than CaTiO3:Eu3+ lattices. A remarkable increase of photoluminescence intensity (in 5D0  7F2 transition) was observed if co-doped with Li+ ions in CaTiO3:Eu3+ and SrTiO3:Eu3+.  相似文献   

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