共查询到19条相似文献,搜索用时 125 毫秒
1.
微化工系统已经成为解决许多高新技术领域的化工过程问题的关键,而微反应器作为微化工系统的核心已经成为研究的热点之一。本文着重分析了微反应器的概念、分类及其性能优势,总结出近年来国内外微反应器的研究发展情况和存在的问题,并对发展前景进行了展望。 相似文献
2.
3.
4.
5.
6.
7.
8.
9.
《化工设计通讯》2017,(8)
当今的社会生产力水平高度发达,科学技术更是高度发展,延伸到社会的各个领域和人民群众的日常生活当中。二者相辅相成、相互促进,在作用与反作用过程当中使社会得到了高度的发展,达到了前所未有的程度。在二者相互促进发展的过程中催生了一种高新技术,即微化工技术,是一种将化学化工原理和微机电系统相结合的多学科交叉的科技前沿领域,所涉及的有物理、化学、化工、电子、控制学、材料等各种工程技术和学科等。并将几百毫秒和几百微米以内,并行分布系统和化工微设备设计、模拟、生产和应用过程中特征和规律这些作为微化学工程的主要研究内容。微化工技术能提高单位体积的生产能力,大大提高能量和资源的利用率,可见,发展微化工技术对促进经济的发展和社会的进步有着重大的意义。 相似文献
10.
11.
旋转填充床作为一种高效的传质、分离与反应设备,在化工、环境保护、纳米材料制备、能源、制药等工业过程得到广泛应用。本文对旋转填充床超重力环境下,流体力学特性、传质性能、微观混合、多尺度传递特性等方面的研究进行了总结归纳。近年来,随着计算机科学与多相流传递过程的研究进展,对传递过程的研究也由实验手段为主转变为实验与数值模拟相结合的手段,对有关的数值模拟研究以及相应的多相流模型也予以总结描述。在此基础上,对旋转填充床超重力环境下多相流研究的未来发展提出了有关设想。 相似文献
12.
13.
Multiphase catalytic reactor engineering and design for pharmaceuticals and fine chemicals 总被引:1,自引:0,他引:1
A review of recent developments in multiphase catalytic processes for the manufacture of pharmaceutical and fine chemicals, and an overview of reaction engineering principles needed for analysis of the local and overall reaction rate for reactor design and interpretation of performance is presented. The first section gives an overview of recent applications in pharmaceuticals and fine chemicals where heterogeneous and homogeneous catalyzed multiphase chemistries have been identified that are more efficient and represent safer operation with decreased environmental impact when compared to existing processes. The next three sections describe a scheme for classification of the various types of reactions that are typically encountered, along with distinguishing features of these reactions and commonly used multiphase reactor types. This is followed by a review of reaction engineering principles needed for describing the local overall rate of reaction, including a summary of typical models for evaluation of the intrinsic reaction kinetics, incorporation of transport-kinetic interactions, methods for identification of the controlling reaction regime and assessment of the relative contribution of transport effects. The next two sections set forth basic reactor models for commonly used reactor types, including mechanically agitated reactors and bubble column reactors. A brief summary of commonly used correlations for estimation of mass transfer coefficients in these reactors for gas-liquid and liquid-liquid systems is also given. The final section is devoted to a summary of key reaction engineering issues that occur in pharmaceutical and fine chemical multiphase catalytic processes, along with some thoughts on future needs and challenges. 相似文献
14.
Faïçal Larachi 《Topics in Catalysis》2005,33(1-4):109-134
Compared to alternative mature wet oxidation technologies that have tremendously proliferated in industry, heterogeneously mediated catalytic wet oxidation (CWO) has achieved, thus far, poor commercial penetration. The two factors that are likely responsible for this situation are (i) the lack of efficient and robust catalysts that pass with success the acid-test for commercial exploitation remote from the aseptic academic conditions, (ii) and the lack of a comprehensive reactor design framework and methodology for scale-up, reactor selection and operation inherent to the multiphase nature of the CWO reactors. This synthetic review summarizes the recent research and development work conducted at Laval University on the CWO from both the perspectives of catalyst development and testing, and multiphase reactor simulations and selection. Specific emphasis was put, on the one hand, on the development brought to some manganese oxide–ceria composites against deactivation, and on the other hand, on the formulation of multidimensional unsteady–steady non-isothermal mass-energy transport/reaction models, embedding catalyst deactivation or not, for trickle bed reactors, packed bubble column reactors, three-phase fluidized beds and slurry bubble columns. A micro–Meso–macro scale methodology was adopted from the materials synthesis up to reactor selection in which the catalyst performance (conversion, selectivity, and deactivation), the intrinsic chemical kinetics, the fluid phase thermodynamics, the pellet scale transport, and the reactor scale physical phenomena (heat, mass transport and hydrodynamics) were integrated. As a result, several aspects relevant to reactor behaviour such as solvent evaporation due to CWO reaction exothermic effects, catalyst partial wetting and catalyst deactivation, and back-mixing effects were covered, and recommendations were formulated. 相似文献
15.
多相微反应器等微通道设备具有高效、安全等优势与广阔的应用前景,其中气泡分散相的形变、聚并、破裂等诸多流体力学行为对反应体系具有非常重要的影响,然而由于微通道的尺度特征以及多相流动非均匀性、复杂性等特点,复杂限域结构内的气泡形变与破裂机理认识仍不够充分。本文针对近年来在微尺度限域结构中的气泡形变与破裂等研究进展进行综述,首先概述了微通道多相流主要研究对象及研究方法,探讨了含有颗粒等受限狭窄空间及复杂多相条件下的传递机理研究进展,总结了气泡界面演变及不稳定破裂过程的多相相间作用机制。最后,提出研究体系构建、研究方法改进、相间作用解析以及工程化需求匹配是微尺度复杂限域空间内的气泡行为研究关键,并对下一步研究方向进行了分析与展望。 相似文献
16.
The coupled CFD-E-model for multiphase micro-mixing was developed, and used to predict the micro-mixing effects on the parallel competing chemical reactions in semi-batch gas–liquid and solid–liquid stirred tanks. Based on the multiphase macro-flow field, the key parameters of the micro-mixing E-model were obtained with solving the Reynolds-averaged transport equations of mixture fraction and its variance at low computational costs. Compared with experimental data, the multiphase numerical method shows the satisfactory predicting ability. For the gas–liquid system, the segregated reaction zone is mainly near the feed point, and shrinks to the exit of feed-pipe when the feed position is closer to the impeller. Besides, surface feed requires more time to completely exhaust the added H+ solution than that of impeller region feed at the same operating condition. For the solid–liquid system, when the solid suspension cloud is formed at high solid holdups, the flow velocity in the clear liquid layer above the cloud is notably reduced and the reactions proceed slowly in this almost stagnant zone. Therefore, the segregation index in this case is larger than that in the dilute solid–liquid system. 相似文献
17.
The coupled CFD-E-model for multiphase micro-mixing was developed, and used to predict the micro-mixing effects on the parallel competing chemical reactions in semi-batch gas-liquid and solid-liquid stirred tanks. Based on the multiphase macro-flow field, the key parameters of the micro-mixing E-model were obtained with solving the Reynolds-averaged transport equations of mixture fraction and its variance at low computational costs. Compared with experimental data, the multiphase numerical method shows the satisfactory predicting ability. For the gas-liquid system, the segregated reaction zone is mainly near the feed point, and shrinks to the exit of feed-pipe when the feed position is closer to the impeller. Besides, surface feed requires more time to completely exhaust the added H+ solution than that of impeller region feed at the same operating condition. For the solid- liquid system, when the solid suspension cloud is formed at high solid holdups, the flow velocity in the clear liquid layer above the cloud is notably reduced and the reactions proceed slowly in this almost stagnant zone. Therefore, the segregation index in this case is larger than that in the dilute solid-liquid system. 相似文献
18.
19.
Bala Subramaniam Christopher J. Lyon Venu Arunajatesan 《Applied catalysis. B, Environmental》2002,37(4):190-292
Environmental concerns stemming from the use of conventional solvents and from hazardous waste generation have propelled research efforts aimed at developing benign chemical processing techniques that either eliminate or significantly mitigate pollution at the source. This paper provides an overview of heterogeneous and homogeneous catalysis in dense phase CO2, considered a green solvent. In addition to solvent replacement, the demonstrated advantages of using dense phase CO2 include the enhanced miscibility of reactants, such as O2 and H2 which eliminate interphase transport limitations, and the chemical inertness of CO2. Further, the physicochemical properties of CO2-based reaction media can be pressure-tuned to obtain unique fluid properties (e.g. gas-like transport properties, liquid-like solvent power and heat capacities). The advantages of CO2-based reaction media for optimizing catalyst activity and product selectivity are highlighted for a variety of reactions including alkylation on solid-acid catalysts, hydrogenation on supported noble metal catalysts and a broad range of homogeneous oxidations with transition metal catalysts and dioxygen as an oxidant. Through these examples, the need is emphasized for a systematic approach to research and development of supercritical carbon dioxide based processes, taking into account conventional multiphase reaction engineering principles, catalytic chemistry and phase behavior. 相似文献