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通过挤出、压延和拉伸等工序制备了聚四氟乙烯微孔膜,采用扫描电镜(SEM)分析了微孔膜的微观结构;采用差示扫描量热法(DSC)和广角X衍射(WXRD)表征了拉伸前后聚四氟乙烯结晶度的变化;研究了拉伸温度、拉伸倍率和拉伸速率对微孔膜力学性能的影响。结果表明:聚四氟乙烯微孔膜具有小岛状结点和与拉伸方向平行的微细纤维组成的微观结构;拉伸使PTFE的结晶度显著降低;拉伸工艺是制备微孔膜的关键因素,拉伸温度220~320℃,拉伸倍率为8倍时,微孔膜的最大拉伸强度可达8.5MPa;此外较大的拉伸速率可获得尺寸分布更均匀的微孔。 相似文献
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研究了疏水性聚四氟乙烯(PTFE)微孔膜的结构、润湿性、可重复使用性以及在不同温度、pH下对煤油、汽油和柴油的分离速率的影响。结果表明,在常温下,PTFE微孔薄膜对含油废水中油的去除率可达90%以上;PTFE微孔薄膜油水分离速率不受含油废水中pH的影响,但随着温度的升高而加快;对不同的含油废水有着不同的分离速率,其中对汽油的分离速率最高,稳定后可达800 L/(m2.h),煤油次之,对柴油的分离效率最低,低至稳定后为650L/(m2.h)。另外,由于PTFE微孔膜采用的是表面过滤的方式,所以膜具有非常好的可重复使用性,是一种非常理想的油水分离膜。 相似文献
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功能化聚四氟乙烯微孔膜的研究进展 总被引:3,自引:0,他引:3
罗衍慧;邓新华;孙元;王瑜;张玲 《中国塑料》2009,23(5):20-25
功能化PTFE微孔膜兼具PTFE微孔膜的优异特性及功能高分子的特殊性能,选择性透过、催化、传输药物、抗菌、质子交换等特殊功能的聚四氟乙烯(PTFE)微孔膜极具应用潜力。本文综述了PTFE微孔膜的特性,总结了近年来采用辐射接枝、表面沉积、涂覆或共混等方法功能化PTFE微孔膜的最新研究进展及其在化工、医学、服装、电子等领域功能化应用的最新成果,并指出目前存在的问题,对今后的研究提出了展望。 相似文献
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以聚四氟乙烯(PTFE)乳液为原料,选定化学稳定性、热稳定性优异的纳米二氧化锆(ZrO2)为增强剂,制备出PTFE/ZrO2复合微孔膜,并通过X射线衍射仪对PTFE/ZrO2复合微孔膜样品的结晶性能进行了表征,使用单因素法讨论了ZrO2的含量、拉伸倍数、热处理温度及热处理时间等因素对PTFE/ZrO2复合微孔膜结晶性能的影响。结果表明,复合微孔膜的结晶度与拉伸倍数、热处理温度和热处理时间成正比,与ZrO2含量成反比;ZrO2含量为7 %、拉伸倍数为1~2.5倍、热处理温度为310 ℃、热处理时间为10 min时,制成的复合微孔膜综合性能最佳。 相似文献
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聚四氟乙烯微孔膜具有化学性质稳定、透光率高、透水率高、耐高温、抗腐蚀等优点,应用非常广泛。本文综述了聚四氟乙烯微孔膜的制备方法及在电学、医学、化工、服装等多个领域的最新应用,并指出了其存在的问题及今后的发展方向。 相似文献
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We have systematically studied phase separation behavior in ultra-high molecular weight polyethylene/liquid paraffin/dibenzylidene sorbitol (UHMWPE/LP/DBS) ternary blends. The aim of this paper is to investigate the combined effect of DBS and flow field on the structure and water permeability of UHMWPE microporous membrane. The experimental results show that DBS molecules self-assemble into fibrils firstly during cooling and the blends exhibit a gel-like state before liquid–liquid phase transition. The relaxation time of DBS fibrils is quite long, which shows a great sensitivity to flow field as compared to UHMWPE chain. UHMWPE microporous membrane was prepared via thermally induced phase separation method. DBS fibrils, as in situ formed nucleating agent, decrease the pore size and water permeability and enhance mechanical properties of membrane remarkably. Shear flow can result in alignment of DBS fibrils, which facilitates the nucleation of UHMWPE and induces the lamellae aligned perpendicular to flow direction. This feature was used to design thermal and mechanical histories and obtained oriented UHMWPE microporous membrane. In comparison to the isotropic UHMWPE microporous membrane, the oriented UHMWPE microporous membrane provides low tortuous paths across the membrane and produces high water permeability. 相似文献
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用热致相分离法制备超高相对分子质R聚乙烯(UHMWPE)微孔膜,并通过调节成型条件(UHMWPE的含量及其相对分子质量、冷却速率)实现了UHMWPE微孔膜微观结构的可控化,研究了成型条件对微孔膜的结晶性能和力学性能的影响.结果表明,在UHMWPE含量和相对分子质量增大,冷却速率加快时,微孔膜的结晶度降低,平均孔径和孔隙... 相似文献
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Zee Ying Yeo Thiam Leng Chew Peng Wei Zhu Abdul Rahman Mohamed Siang-Piao Chai 《Journal of Porous Materials》2013,20(6):1457-1475
Removal of CO2 by membrane technologies is one promising approach as compared to other CO2 capture technologies due to advantages such as simpler operation, higher reliability, lower capital and operating cost, higher energy efficiency, and a cleaner process. In the field of CO2 gas separation, inorganic membranes have been attracting a lot of attention. Three classes of microporous membrane family, i.e. microporous silica membranes, microporous carbon membranes and zeolite membranes, have been widely studied due to their potential in separating CO2 gas molecules, contributed by their distribution of selective micropores which are almost identical to the required molecular sizes for diffusing CO2 gas. This paper review various methods to fabricate the above three types of microporous membranes, at the same time, looking at other researchers employing these methods to fabricate microporous membranes for CO2 separation. 相似文献
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Phase separation behaviors of the blends that consist of high-density polyethylene (HDPE) and LP was investigated by means of thermal analysis. The miscibility of the two components was evaluated in terms of the Flory–Huggins interaction parameter, determined from the Hoffman–Weeks plot, gave a value of 0.36. This leads us to a conclusion that this blend system is applicable to the preparation of microporous hollow fiber membrane by melt spinning of the blend. The homogeneous blends in the molten state become heterogeneous systems to yield microporous HDPE membranes in the course of cooling due to thermally induced phase separation. The influence of the phase separation on the membrane morphology was also discussed. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2135–2142, 1999 相似文献
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Control of transport properties with a microporous membrane reactor to enhance yields in dehydrogenation reactions 总被引:1,自引:0,他引:1
D. Casanave A. Giroir-Fendler J. Sanchez R. Loutaty J-A. Dalmon 《Catalysis Today》1995,25(3-4):309-314
The dehydrogenation of isobutane has been studied in a membrane reactor using either a mesoporous alumina membrane or a microporous zeolite membrane. It has been shown that for both membranes an increase in the isobutene yield is observed when compared to a conventional reactor. However, these increases are related to two different phenomena: a complete mixing of reactants, products and sweep gas in the case of the mesoporous membrane and a continuous separation of hydrogen when the microporous zeolite membrane was used. 相似文献
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聚丙烯微孔膜的研究进展 总被引:2,自引:0,他引:2
介绍了由熔融纺丝-冷却拉伸法和热致相分离法制备聚丙烯微孔膜的原理和过程。对当前膜研究领域的热点即膜的亲水化改性研究进行了重点评述,包括暂时性改性和永久性改性。阐述了各种改性方法的特点,着重讨论了亲水化改性对膜性能如膜的微孔孔径、孔隙率、透水量等的影响,强调膜表面亲水性的提高可改善膜的耐生物污染性。指出聚丙烯微孔膜的应用领域和发展前景。 相似文献